Search Documents

By Claude Deveau

"With ever decreasing feed grades, finer mineralogy and increased demand for product, it became obvious that a major step in equipment performance was required to reduce operating costs and increase production. Offsite testwork indicated that a Centrifugal separator was capable of recovering fine tantalum and that the newly developed C Series Falcon concentrator would be capable of replacing many pieces of aging equipment and provide improved performance. Further investigation led to the rental and the purchase of a Falcon C20 concentrator followed by a C10 to maximize circuit performance.Falcon Concentrators Inc’ s practice of working with the customer mirrors Tantalum Mining Corporation of Canada’s (Tanco) philosophy of continuous product development. This synergy honed valve design for continuous operation in a highly abrasive ore environment.Tanco has recently purchased two more Falcon concentrators for the recovery of additional tantalum from its spodumene circuit. These new units have additional user friendly operating features partially based on developments made at Tanco.The Falcon C Series units have enabled Tanco to maximize recovery of tantalum that was otherwise lost while using the original conventional gravity circuit."

Jan 1, 2000

By Peter Broad

"Extracting any metal, especially specialty metals and rare earth elements, requires an in-depth analysis of the costs and potential revenue as well as a due diligence study of other stakeholder interests. Rare earth projects are generally in the billion dollar US range or above, and thus failure to accurately predict any loss of revenue caused by impurities within the product or additional effluent treatment costs can destroy an otherwise viable study. Two prime sources of input impurity are considered: impurities in the material feed and from reagents. The effect of these impurities factor on both the product (in reduced revenue) and on residual “tailings” that may incur additional unforeseen costs.INTRODUCTION“Truth passes through three stages. First, it is ridiculed. Second, it is violently opposed. Third, it is accepted as being self-evident” – Arthur SchopenhauerThe era of unscoped, unbudgeted construction ended about 150 years ago. Today’s engineer must design with confidence; but do so amidst proprietary secrets and unfamiliar pollutants, which present a myriad of interesting challenges. Is it possible to build a viable rare earth plant to a realistic budget, without destroying that which we cherish? Some see this as contradictory but in reality it is the only viable option.WHEN GOOD PROJECTS FAILWithout rare earths the Copenhagen agreement might be null and void. Running a wind turbine with a 30 tonne conventional magnet requires some hefty engineering and prohibitive investment. Despite their ‘Green metal’ applications, production of rare earths have created environmental nightmares, as Folger stated in 2011 when visiting Baotou, or has Jaing Mainheng who has been quoted by Ambrose Evans-Pritchard 6 Jan 2013. This comment is not a criticism of China; the details are from a 2012 white paper published by the Chinese Government that initiated a $6 billion environmental clean-up. Nor is China unique; other plants have had problems as well. There were toxic leaks in the 1990s from Mountain Pass, and the Mitsubishi Bukit Merah Plant (built in Malaysia in 1958) required a $100 million clean-up."

Jan 1, 2016

By N. Kuyucak

"Acid mine drainage (AMD) is one of the most significant environmental challenges facing the mining industry worldwide. It occurs as a result of natural oxidation of sulphide minerals contained in mining wastes at operating and closed/decommissioned mine sites. AMD may adversely impact the surface water and groundwater quality and land use due to its typical low pH, high acidity and elevated concentrations of metals and sulphate content. Once it develops at a mine, its control can be difficult and expensive. If generation of AMD cannot be prevented, it must be collected and treated. Treatment of AMD usually costs more than control of AMD and may be required for many years after mining activities have ceased. Therefore, application of appropriate control methods to the site at the early stage of the mining would be beneficial.Although prevention of AMD is the most desirable option, a cost-effective prevention method is not yet available. The most effective method of control is to minimize penetration of air and water through the waste pile using a cover, either wet (water) or dry (soil), which is placed over the waste pile. Despite their high cost, these covers cannot always completely stop the oxidation process and generation of AMD. Application of more than one option might be required.Early diagnosis of the problem, identification of appropriate prevention/control measures and implementation of these methods to the site would reduce the potential risk of AMD generation. AMD prevention/control measures broadly include use of covers, control of the source, migration of AMD, and treatment. This paper provides an overview of AMD prevention and control options applicable for developing, operating and decommissioned mines."

Jan 1, 2002

By T. Y. Chong, J. A. Folinsbee, M. Fullam

PJV Dome Mine has used some form of gravity concentration since start of milling operation in 1909 to recover free milling gold. Amalgamation and conventional jigs were first used and were replaced with the Knelson Concentrators in 1993. The Knelson concentrates produced were upgraded on a conventional shaking table prior to smelting and refining into gold bullion. In May 2002, a comprehensive review of the latest gravity recovery technology led to a piloting campaign aimed at further improving gravity recovery. The Knelson concentrates, subjected to intensive cyanide leaching in an Acacia pilot plant, were found to be amenable to intensive cyanide leaching with over 98% of the gold being dissolved within 24 hours. An Acacia Intensive Leach Reactor was successfully installed and commissioned in December 2002, to replace the shaking table. his paper describes pilot scale testing, installation, commissioning and optimization of the Acacia Intensive Leach Reactor. Also, the economic impacts on down stream processes are highlighted.

Jan 1, 2005

By Zbigniew J. Hladysz

A Deep Underground Science and Engineering Laboratory (DUSEL) is being planned at the site of the former Homestake Gold Mine in Lead, South Dakota, under the sponsorship of the US National Science Foundation (NSF) in cooperation with the US Department of Energy (DOE). This national facility will host a variety of multidisciplinary science and engineering experiments including physics experiments that require shielding from cosmogenic radiation. Geotechnical mapping was performed in 2010 in large excavations of the Davis Campus at the 4850 Level of the former Homestake Mine. LIDAR mapping included laser scanning using a red light laser scanner and 288 Mpixels 360° still camera. The resulting vector map with the photographs digitally draped over the model, was used to create an accurate, virtual model of the excavations. For model verification, the laser scanning was accompanied by surveying and manual mapping of the geology and rock structure. The immediate use of the model was to perform structural analysis and interpretation of geology needed for the design of the DUSEL?s super large excavations. The second round of scanning, after the application of shotcrete to the excavations walls, will be used as a technical blueprint to assess the effectiveness of shotcrete application.

May 1, 2011

By Roy Lindsay, Paul O'Hara, Gary Halverson

"The New Britannia Minesite is located in Snow Lake, Manitoba, 420 miles north of Winnipeg (figure 1). The mine previously operated from 1949 to 1958 extracting some 5.39 million tons of ore at a 0.150 opt gold grade. From 1959 to 1986 the property was held by Nor-Acme and Hudson Bay Exploration and Development and in 1987 High River Resources Ltd. Optioned the property, dewatered the mine and conducted a diamond drill program between the 1 780 and 2400 levels. In 1988 two companies, Nor-Acme Mines Ltd. and High River Gold Mines Ltd., negotiated an option agreement with INCO Gold whereby !NCO assumed management control of all site exploration work. During this period, a bulk sample of 10,000 tons was extracted from the 1780 level with no further exploration recorded after its removal. Both Hudson Bay Exploration and Development and INCO Gold conducted feasibility studies on reactivating the property but at a calculated capital cost of Cdn $70 to $80 million found the rate of return on their investment unacceptable.In 1991 !NCO Gold merged its interest with the assets of TVX Gold Inc. and in February 1994 TVX Gold Inc. and High River Gold Mines Ltd. entered into a joint venture partnership to develop the Snow Lake property, naming TVX Gold Inc. the operator. Upon completion of a feasibility study in April 1994 by Bharti Engineering Associates Inc., a decision was made to reopen the Britannia Mine at an established project cost of US $33 million.Project construction commenced in July 1994 with the hoist house excavation. The first concrete for the hoist house level footings was poured on August 4, 1994 and the project was completed on October 1, 1995 at a cost of US $36 million. The first gold pour took place November 4, 1995.This paper not only presents the metallurgical aspects of the operation but also describes the novel approach used to complete the design and construction of the site facilities."

Jan 1, 1996

By Kosuke Hosoda, Shuji Owada, Hiroyuki Tokuichi, Hirobumi Ohta, Chiharu Tokoro, Moto-o Sato, Katsushi Okumura, Hiroto Ogawa, Hideaki Umezawa

The Japanese government enforced the "Small Domestic Appliances (SDAs) Recycling Law" in 2013. The law targets metals such as Ta, Nd, Dy, Co, and W to be recycled. Considerable amounts of these minor rare metals are mounted on printed circuit boards (PCBs) of the SDAs and/or e-scrap (electric and electronic scraps). Although precious metals and copper can be recovered from the e-scrap in non-ferrous metals smelters, most of the minor rare metals report to the slag in these smelters in non-recoverable forms. These metals are often used in particular types of devices, and therefore it is possible to concentrate them by separating such devices before feeding to the smelters. In previous work we developed technology for "Device Separation" to concentrate several minor rare metals, but some problems remained, such as how to remove the PCBs from e-scrap bodies, and how to detach devices from PCBs after their removal from escrap bodies. This paper proposes a two-stage crushing process in which, firstly, PCBs are removed from the e-scrap body with various crushers, and secondly, devices are detached from the PCBs involving the application of elevated temperatures. It was found that in the first stage, crushers with physically flexible rotating media such as chains, which provide high collision probability with the sample and consume relatively low energy, can quite effectively separate the PCBs from the e-scrap bodies non-destructively. In the second stage, heating was found to be remarkably effective in helping to detach mounted devices from PCBs, also non-destructively. This paper will also discuss the detailed mechanism of the heating effect on the detachment of devices from PCBs.

Jan 1, 2014

By Beaumier. M., J. -P. Lalonde

"Les réultats obtenus dans les sols sur quatorze aires d'essai et six cheminements régionaux dans I'A bitibi-Témiscamingue indiquent clairement qu'il existe des variations régionales importantes dans les teneurs en éléments traces de l'horizon A1 formé sur l’épais recouvrement glacio-lacustre de cette région. Les anomalies obtenues correspondent à celles qui ont été décelées lors de précédents levés des eaux souterraines et du till de base.Selon les critères d'évaluation utilisés, treize des quatorze aires d'essai ressortent comme anomales dans Ie contexte abitibien; dix de celles-ci sont tres anomales. Ceci suggère fortement qu'un levé régional de sols, fondé sur une approche multi-éléments, identifierait entre 70 et 90 % des cibles géochimiques reconnues par des échantillonnages en profondeur. Les résultats d'un échantillonnage systématique effectué sur une région de 1000km2 viennent aussi appuyer cette hypothèse. Conséquemment, les sols formes sur les sédiments glacio-lacustres sont un médium très utile pour inventorier de grandes regions recouvertes par ce typ e de sédiments.L 'horizon A1 est Ie plus utile pour ce type de levé parce qu'i1 est facil e d échantillonner, qu 'it assure une plus grande constance du typ e de matériel échantillonne et qu'il contient des teneurs accrues.De multiples mécanismes de dispersion géochimique ont joué des rôles d 'importance variable pendant et après la mise en place des sédiments glacio-Iacustres. Les plus importants sont la pression hydrostatique, la diffusion chimique et électrochimique ainsi que la bio-accumulation. Si on veut progresser dans la connaissance de ce milieu complexe, on devra adopter une approche plus systemique tenant compte de I'interaction des mécanismes agissant dans l'environnement global avant, durant et apres Ie depôt du mort-terrain."

Jan 1, 1984

By J. R. Emery, D. F. Coates

"FOUR PAPERS ON CEMENTED BACKFILL were given at the Annual General Meeting of The Canadian Institute of Mining and Metallurgy in 1970:Weaver, W. S., and Luka, R., ""Laboratory Studies of Cement-Stabilized Mine Tailings"".Pasieka, A. R., Beattie, H. F., and Espley, G. H., ""Cemented Hydraulic Backill within the Falconbridge Group of Companies"".McLeod, P. C., and Schwartz, A., ""Consolidated Fill at Noranda Mines Limited (Geco Division)"".Clement, W. P., and Sokoloski, R., ""Pumping Cemented Backfill"".These four papers give the impression of a development in mining technology that has been substantially completed. Somewhat over ten years ago, The Inter-national Nickel Company of Canada, Limited and Falconbridge Nickel Mines Limited started experimenting with the addition of Portland cement to mill tailings to produce improved backfill and cheaper floors for scraping. Shortly after, the Canada Cement Company Limited (now Canada Cement Lafarge Ltd.), with full support of the two mining companies, started an extensive research program to provide the technologic-al data necessary to exploit what was obviously going to be a significant development in mining technology."

Jan 1, 1970

By Arnaud Faucher, Claude Bazin, Marilène Renaud, Mohamed Mai Manga

"Grinding circuits are operated in the presence of disturbances due to ore changes and equipment malfunctions. One of the challenges faced by the operators is the detection of a disturbance, the identification of its origin and of the action needed to minimize its impact on the process. Hydrocyclones overloading, worn or partly plugged apexes of the units of a nest, surging and internal liner detachment may cause a loss of classification capacity and quality. Recovery losses in downstream leaching or flotation circuits justify the effort in developing techniques for the detection of hydrocyclone malfunction. Two approaches for the detection of hydrocyclone fault are presented in this paper. The first proposed method uses the conventional sensors available in a grinding circuit allowing real time detection of hydrocyclone abnormal operation. The second technique is based on the use of vibration sensors installed on the hydrocyclone of a nest. This last technique enables the classification of the hydrocyclone malfunction as surging, overloading and plugged apex. The two techniques can be combined to increase the robustness of the problem detection.INTRODUCTIONHydrocyclones are used for many purposes ranging from water separation, fines removal and obviously for the preparation of the feed for subsequent concentration circuits in a mineral processing plant. The strategic role of the hydrocyclones for the preparation of the feed to the concentration circuit is often underestimated because of their simplicity of operation and robustness (Napier-Munn et al., 1996; McIvor, 1988). It remains that despite their simplicity, hydrocyclones have been studied extensively from 1970 to 1990 with the objective of developing mathematical models of their operation to be incorporated into grinding circuit simulators (Napier-Munn et al., 1996; Lynch, 1977; Flintoff et al., 1987). Such a development effort is already an acknowledgement of the importance of these units in a mineral processing plant. Several authors (Del Villar et al., 1996; Plitt and Kawatra, 1979; Casali et al., 1998) proposed soft sensors to estimate the classification efficiency of hydrocyclones using sensor measurements. However, few of the proposed sensors are used in the industry. More recently several papers were published to discuss the application of 3-D modelling of the hydrocyclones (Narasimha et al., 2005; Cullivan et al., 2004) and sensors (Bond et al., 1999; Neesse et al., 2003; Hou et al., 1998; Olson and Waterman, 2004; Williams et al., 1995; Willams et al., 1997) to help in the detection of hydrocyclone malfunction."

Jan 1, 2010

By W. J. Pearson

"""POTASH"" is a term applied to the compounds of the element potassium (K) and when used in agriculture and industry is ex-pressed in terms of potassium oxide (K2O), regardless of the actual com-position of the compound. When a chemical analysis is made of a fertilizer, the amount of K is deter-mined and then calculated to the equivalent amount of K2O. However, the compound K2O does not exist in nature. Most of the world's potash supply is derived from mineral deposits similar to those in Saskatchewan and New Mexico. However, there is some production from concentrated surface brines such as occur in Searles Lake, California; Salduro Marsh, Utah; the Dead Sea; and from well brines in Micl1igan."

Jan 1, 1960

By Andrew Chapman

The scope of the SA (Situational Awareness) working group is to analyze the effectiveness of information delivery systems in mining equipment and develop a unified display design, to mitigate against the proliferation of screens within equipment cabs. This working group comprises a variety of stakeholders representing a cross-section of relevant mining and mining-related organizations. This stakeholder network will help guide the direction of the working group towards a common, mutually beneficial end. For now, the focus is on shovel displays; however it should be noted that this work is expected to form the foundation for similar work with other equipment in the future.

Aug 1, 2013

By Tapiwanashe Chenje, David Hewitt, Peter Radziszewski

"Steel media wear is a major cost component in mineral processing. In the case of existing operating mill, steel media wear prediction can be used to help compare the performance of steel media from different suppliers before completing marked ball tests. It can also be used to investigate how ores from different site of a given mine affect steel media wear. In the case of Greenfield cases, steel media wear prediction can be used to estimate the cost of steel media for a given feasibility study.This paper presents a wear testing and prediction methodology that ties together abrasion wear and corrosion wear testing results through the use of a simplified discrete element charge motion model. The experimentation dimension to this methodology takes samples for steel media, mine site ore and water to determine abrasive and corrosive wear parameters of a given media, ore, water set.The test methodology development is illustrated along with a comparison of wear predictions with observed wear rates in some operating mills. A case study is included that illustrates how this methodology was used to estimate steel media wear performance. The paper closes with a discussion on the use of parts of the experimental methodology to investigate other abrasive wear conditions such as liner wear, paste backfill piping and ore breakage as well as avenues for future test development.INTRODUCTIONThe cost of comminution processes represents a significant part of the overall costs of a mining operation. Grinding media/liner wear alone accounts for 15-25% of the total operating cost. The annual steel grinding media consumption is approximately 2.5 mtpa or 0.3% of total world steel production [Smorgon Steel Group, 2005]. Using an estimated grinding media cost of about US$0.75/kg [Halbe and Smolik, 2002], gives a media cost of over US$1.875 billion per annum. Mining continues to shift towards exploitation of lower grade ores as the higher grades get depleted. These low-grade ores require finer grinding for the liberation of the value minerals, and hence it can be assumed that grinding media consumption will also continue to rise.The Bond abrasion test, dating back to 1963, [Weiss, 1985] is still used to estimate the total mill media wear. This is a purely empirical test based on the ore. From Bond abrasion index tests, it is possible to determine a wear rate using the following function:"

Jan 1, 2009

By Dave Price

"Canada is scheduled to become the 4th highest diamond revenue producing country in the world by year 2004 with the already operating Ekati Mine and the anticipated operation of the Jericho Mine in 2002 and the Diavik Mine in 2003.This paper provides an overview of worldwide diamond production statistics and a brief introduction to a diamond processing plant. The dense medium separation (DMS) extraction process is presented and this process is discussed in more detail with respect to the extraction of diamonds in terms of feed preparation, dense medium, dense medium cyclones, ferrosilicon recovery and dense medium cyclone operating efficiencies.INTRODUCTIONThe Ekati Diamond Mine in the Northwest Territories started commercial production of diamonds in the 4* quarter of 1998. At full production, the mine is anticipated to produce annually some 3 million carats of diamonds. The Jericho Mine in Nunavut Territory and the Diavik Mine in the Northwest Territories are anticipated to come into production in the 1'' quarter of 2002 and 1st half of 2003 respectively. The combined annual diamond production of these three mines will total approximately 10.34 million carats by 2004, making Canada the 4~ highest diamond revenue producing country in the world.A diamond processing plant initially utilizes crushing, scrubbing and screening in the beneficiation process to liberate diamonds from kimberlite ore and size the product for further treatment through DMS. Alluvial diamond operations do not require initial crushing and scrubbing but incorporate a feed preparation and sometimes a recrush facility with the DMS plant. The heavy sink product from the DMS, which contains diamonds, is further upgraded through x-ray separation and high intensity magnetic separation prior to producing the final diamond product.DMS is a relatively simple separating principle. A mixture of particles of different density is immersed in a dense fluid, so that particles having a density lower than that of the fluid will float while those of heavier density will sink. The translation of the float-sink principle from a laboratory method to continuous industrial practice offers the prospect of very precise mineral separations based on density differences alone."

Jan 1, 2000

By W. D. Gould, A. Kapoor, K. Morin, P. Bédard

This paper presents the results of a research study that is being conducted by the Mine Effluents Program, Mining and Mineral Science Laboratory (MMSL), Natural Resources Canada aimed at evaluating biotechnology processes for the treatment of nitrogen compounds such as thiocyanide (CNS) and ammonia (NH4-N) which are present in gold mill effluents. A sequencing batch reactor (SBR) technology, commonly used for the biological treatment of municipal and industrial effluents, was used in this study. In the SBR process, the micro-organisms were able to degrade CNS to NH4-N and NH4-N to nitrate (NO3-N) at operating conditions of two 12 h treatment cycles per day, with pH maintained in the 7.4 to 7.6 range, and at room temperature (approximately 21°C) and also at 12 °C. The end products of CNS and NH4-N biological oxidation were NO3-N and sulphate (SO4) that are relatively non-toxic. Partial removal of NO3-N was achieved by biological denitrification reactions in the SBR process. The SBR process effluent was measured to be non-toxic to rainbow trout based on the 96 h acute toxicity test. The microbial consortium isolated from the SBR treating a simulated effluent was able to effectively oxidize CNS and NH4-N to NO3-N in water samples (under batch conditions) collected at three mine sites located in Quebec, the Northwest Territories, and Yukon.

Jan 1, 2004

By Brad Hewitt, Jeff Belke

"Murrin Murrin Operations has not had a successful beginning. Numerous reliability and operability issues many of which are the result of design decisions have been addressed through mechanical and operational changes and the CCD circuit is no exception. Four design aspects of the CCD circuit that have caused and continue to cause operational problems are:1. the inclusion of solution neutralisation gypsum in the CCD circuit feed which was designed solely for HPAL residue without proper investigation of its impact on the achievable underflow density and resulting wash efficiency;2. the decision to construct the thickener base from thickened solids;3. the lack of redundancy in the overflow, underflow and tailings pipe work; and4. the lack of thickener operational flexibility in the central rake-lift and feedwell dilution system.In November 2002, the lack of operational flexibility in the rake-lift and the feedwell dilution system through mechanical modification as follows:•, CCD1 has a modified rake mechanism that now allows central vertical lift of 600 mm;•, CCD1 has forced dilution using the Outokumpu Turbodil® technology and replacing the E-Duc® technology of Eimco;The decision to install, the installation and the results of the CCD1 rake-lift mechanism and feedwell dilution system are discussed in this paper. The installation was justified on improved operational robustness and an increase in the in the underflow density of 1 per cent (per cent w/w). At approximately the same time process modifications in the solution neutralisation circuit were implemented and these changes altered the rheology of the slurry reporting to CCD1. Since the modifications to CCD1 and the solution neutralisation circuit, the CCD circuit has averaged a 2 per cent improvement in the circuit underflow density.The CCD1 modification was completed on time and mechanically has performed well. From a risk point of view, the central rake-lift and Turbodil®dilution system add a degree of freedom and robustness to CCD1 operation that has extended the range of operational confidence. In this respect, the modification has been a success and is complementary solution neutralisation improvements."

Jan 1, 2005

By S. H. Ash

Introduction Probably the newest thing in mining safety is the apparent dissatisfaction on the part of the mineral industry, as represented by both management and labour, and the general public of many nations in which mining is conducted, with the safety record of the mining industry. This is reflected by published comments in the technical press;' in labour periodicals, in popular Journals and periodicals, and in the daily press (5, 11). Despite what may be said to the contrary, mining in the United States is becoming safer, and this trend has been evident for several years (see Figures 1 to 4). Because the author's experience has been mostly in the United States this paper will discuss briefly some recent observations in the United States that have a bearing on mining safety. Because coal mining is of primary interest to the Mining Society of Nova Scotia, the paper treats mostly of coal-mining safety; however, many hazards in mining .are common to all mines, regardless of the minerals mined.

Jan 1, 1950

By K. Pirapakaran

The Geotechnical Engineering research group at James Cook University has been working closely with all the leading mines in Australia in the area of minefills. They have carried out substantial research and consulting work on the drainage and stress developments within hydraulic fills. The objective of this paper is to summarize their work during the past five years on hydraulic fills. The paper will serve as a one-stop reference, pointing to relevant literature including the authors? own publications, on various issues covering drainage and stress developments within hydraulic fills. More than 15 different hydraulic fills, representing five major mines in Australia, were studied. Their grain size distributions and placement characteristics including permeability, porosity and dry density were studied and comparisons were made with the limited in situ data available in the literature. Stress development within hydraulic fills has been studied to minimize the risk associated with barricades failure. FLAC and FLAC3D were used to model stress developments within the hydraulic fills and were compared against the approximate closed form solutions available in the literature. A laboratory model was developed to study arching effects within the hydraulic fills.

May 1, 2007

By K. Yamaguchi, Sekimoto. H.

"Platinum Group Metals (PGMs) used as catalyst which reduces toxic substances in emission gas exhausted from an automobile should extensively be recycled because they are rare metals produced only at the limited regions. The recycling process is to smelt an alumina honeycomb, in which PGM is built, in molten iron with flux such as lime and silica to separate them. PGMs are concentrated in molten iron while alumina in slag.The objective of this study is to understand the factor to concentrate PGMs in liquid iron as much as possible. Fundamental research of the distribution of the PGMs between the slag and liquid iron was carried out to recover the value metals of platinum, palladium and rhodium from the three-way auto catalyst. The distribution ratios of platinum, palladium and rhodium between the Al2O3-CaO-SiO2 slag and liquid iron are from 10-6 to 10-5, and these are concentrated in comparison with slag phase by about 1 million times to the liquid iron at 1873 K. The distribution ratios of platinum between the FexO-CaO-SiO2 slag and liquid iron decrease from 0.1 to 2?10-4 with increasing the CaO content in the slag. The CaO addition to the FexO unary slag is effective in concentrating platinum in molten iron.Based on the distribution ratios obtained in this work, recovery of PGMs was determined. The recovery of platinum, palladium and rhodium increase with increasing the mass ratio, Mmetal/Mslag. In the case of the conditions of Mmetal/Mslag = 0.04, the recoveries of PGMs showed more than 99.97%. The use of liquid iron and carbon saturated liquid iron as the collector metal is advantageous for the PGM recycling of the three-way auto catalyst. We found that PGMs are enriched to the molten iron or the carbon saturated iron and the slag loss of PGMs is negligible small."

Jan 1, 2014

By D. Imeson, T. Grammatikopoulos, G. Pearse, M. Aghamirian, C. Mohns

"Spodumene mineral is a source of lithium for lithium ion batteries. Thus, the production of a spodumene concentrate with an approximate grade of 6% Li2O is targeted. Traditionally, spodumene is concentrated by froth flotation using fatty acid as the collector. Amine collector can also be used to float mica ahead of spodumene as required or feldspar from the spodumene tailings. Slimes have a negative effect on spodumene flotation and they are commonly separated by scrubbing and de-sliming prior to spodumene flotation. The main losses in spodumene flotation typically occur in cyclone overflow, scrubbing slimes, spodumene flotation tailings and mica concentrate. In recent years, dense media separation (DMS) is the main concentrating process in Australian spodumene operations. In these operations, DMS is efficient at generating coarse grain concentrates and rejecting large portions of silicate gangue, thereby directly reducing the milling cost. The ore should be crushed to 3/8” or coarser while further crushing is possibly necessary on the middling particles to scalp further spodumene. The DMS feed should be classified to remove fines (typically -0.5 mm particles). The final middlings and undersize fractions could then be processed by flotation. The main requirement in DMS operations is to have good spodumene liberation at relatively large grain size. This paper reviews the most significant DMS and flotation parameters in spodumene beneficiation. The treatments of different minerals in the spodumene ore are also addressed.INTRODUCTION A number of laboratory/pilot plant programs have been recently conducted at the SGS Lakefield site, sponsored by different clients. The main objective has been to develop a process flowsheet to generate a spodumene concentrate containing 6.0% or higher Li2O (~75% spodumene) suitable for producing lithium carbonate by a hydrometallurgical process. Depending on spodumene liberation size, dense media separation (DMS) can be an attractive option to produce a final high grade concentrate and to reduce the mass to be treated in the flotation circuit. In such a case, crushing would typically be performed in stages, with DMS separation to recover a spodumene concentrate and reject gangue minerals following each stage. DMS middlings and -0.5 mm fines can be processed by flotation to further recover spodumene. In the flotation process, coarse stage grinding minimizes the grinding cost and formation of slimes. In the majority of cases, a grind size (K80) of approximately 200 microns is sufficient for flotation. After primary grinding, mica, if present in an appreciable amount, should be floated to minimize interference with spodumene flotation. Desliming after scrubbing and high density conditioning are the key process operations prior to spodumene flotation. Spodumene can then be floated from silicate gangue minerals with a fatty acid or a mixture of fatty acid and petroleum sulfonate at slightly alkaline pH. Subsequently, feldspars can then be floated from the spodumene tailings."

Jan 1, 2012