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By W. Guiye, L. Chongjun, L. Huinan, Z. Yangge, H. Long

The current application of copper-molybdenum (Cu-Mo) separation inhibitors is often associated with large dosage, high toxicity, environmental pollution problems. In order to solve these problems, a light sensitive Cu-Mo separation inhibitor LS（light sensitive inhibitor，abbreviated to LS） was developed. In this paper, inhibitory performance, photodegradation rule, and acting mechanism of LS were studied. The subsequent test results showed that, compared with traditional inhibitors, LS has shown comparative advantages, with lower dosage and good inhibiting effect. A series of flotation tests with LS as inhibitor were conducted on a Cu-Mo concentrate. A locked-cycle test showed that a molybdenum concentrate containing Mo 49.88% and Cu 0.6%, with 93.23% molybdenum recovery and a copper concentrate containing Cu 29.92%, with 99.99% copper recovery can be obtained. The photodegradation performance of the reagent was investigated under 365 nm, 254 nm and sunlight irradiation. The degradation of the reagents could be completely achieved by irradiation of three wavelengths of light. However, with the different wavelength of irradiation light, the degradation rate is different, the time required to reach 50% degradation rate being 3 h (254nm), 4 h (solar light) and 6 h (365nm) respectively. The inhibition mechanism on chalcopyrite was studied. FTIR study showed that LS could be adsorbed on the surface of chalcopyrite by chemical adsorption, which could enhance the hydrophilicity of chalcopyrite. Ultraviolet adsorption tests indicated that the adsorption capacity of LS on chalcopyrite surface was greatly affected by pulp pH value, and the proper pH value was 5-9. Keywords: Copper-molybdenum separation, Inhibitor, Light-sensitive, Photodegradation, Mechanism.

Jan 1, 2020

A mineralogical study was conducted on the feed (3.51 g/t Au and ~90 g/t Ag) and four leach residue samples (assaying 0.09 to 0.19 g/t Au and 30.0 to 61.5 g/t Ag) from the Pinos Altos silver-gold deposit in Mexico to determine the cause for gold and silver losses. A comprehensive mineralogical and analytical approach including fire assay, gravity pre-concentration, ore microscopy, mineral liberation analyser (MLA) and electron microprobe was used for the current study. Results showed that gold and silver lost in the leach residues occurred mainly as inclusions in quartz and silicates (accounting for over 80% for Au and 92% for Ag of the head assays, respectively), with a minor amount in iron oxide and other minerals. The amount of liberated gold and silver is negligible. Results also showed that gold and silver particles in leach residues are mainly ranged from 1 µm to 5 µm in size, which implies that ultrafine grinding is required to improve the recoveries of these two metals. Keywords: mineralogy, gold deportment, silver deportment, silver-gold ore, leach residue, recovery improvement.

Jan 1, 2009

By Tian Yingzhong, Guo XIN, Wei Peihe

The intention is to solve a series of problems in the flotation and desiliconisation of complex bauxite; aiming to achieve monomer dissociation of target minerals based on process mineralogy. According to the mineral surface, there are differences in physical and chemical properties and the molecular design theory of flotation agents. Designing the polar and non-polar groups of the bauxite flotation collector to make the reagent group easily combine with the mineral to form a cyclic chelate, will enhance the collection performance, and strengthen the drug selection performance. Developing a new type of positive flotation collector for bauxite with small dosage, strong selectivity and low foam volume. Keywords: Process mineralogy, monomer dissociation, molecular design, new positive flotation collector

Jan 1, 2020

By D. Saramak, T. Gawenda, A. Stempkowska, Z. Naziemiec

The aim of the paper is to discuss the possibility of producing aggregates with an increased content of regular particles, as well as to present a method of aggregate production which has not previously been used in the industry. Traditional aggregate production circuits require the application of three or four grinding stages (depending on the particle size of the feed), but for fine particle fractions of aggregates, irregular grains occur on average with a content of 10%. The innovative technological circuit can produce the aggregates with the content below 3%, even in a single- or two-stage crushing circuit. Downstream jig beneficiation of such prepared material results in higher separation sharpness, lower probable error index (Ep) and imperfection (I). Keywords: Aggregate production, jig beneficiation, mineral processing, raw materials

Jan 1, 2020

By D. Sethuram, P. G. Koppad, S. Iyengar, R. Shobha

TiB2 and CeO2 particle-reinforced Al6061 hybrid composites were manufactured using stir casting and hot rolling techniques. The base alloy and composites were hot-rolled at 500ºC and a 50% reduction was achieved through 12 passes. The effect of varying TiB2 and CeO2 particle additions on the microstructure and mechanical properties of the Al6061 matrix was studied. Scanning electron microscopy showed uniform dispersion of both the reinforcements, with good interfacial bonding. Microhardness and tensile properties like yield and tensile strength were found to be higher for hybrid composite with 2.5% TiB2 and 2.5% CeO2 compared to Al6061 alloy and other hybrid composites. The increased tensile strength is attributed to good dispersion and interfacial bonding between the particles and Al6061 matrix. Fracture analysis using a scanning electron microscope revealed ductile fracture for the Al6061 alloy and mixed characteristics of ductile-brittle fracture for hybrid composites

Oct 1, 2021

By Y. G. Zhu, G. B. Zheng, X. X. Hu

Reverse flotation by cationic collectors is the classical method to reduce the silicon content in magnesite. But because of the low selectivity, there is a large loss of magnesite in the reverse flotation froth. To improve the efficiency of the collector, a novel collector named BK433 was developed in this paper. In order to determine the performance of the BK433 collector, a systematic experimental study was carried out with a high silicon magnesite in China. The suitable pH environment of slurry was confirmed, the depression effect of different depressants was investigated, and the flotation effect was compared with commonly used traditional collectors. The results show that the BK433 shows remarkable good selectivity and collection ability. After the 4 stages reverse flotation, the SiO2 content decreased from 3.76% to 0.25%, SiO2 impurity removal rate reached 94.69%. Meanwhile, the MgO content increased from 45.06% to 46.73%，the recovery of obtained concentrate (calculated by MgO) was 82.79%. Keywords: Magnesite, Desilicication, Reverse flotation, Collector

Jan 1, 2020

By Nicolle Krusberski

Potential errors in XRF analysis are discussed and investigated with specific reference to the analysis of ilmenite samples. A selection of ilmenite samples was chosen and prepared using two XRF preparation techniques: pressed powder pellet and unroasted fusion bead. The merits of the two methods have been discussed in this paper for ilmenite analysis by XRF. Recommendations have been made regarding the use of pressed powder pellets especially with regard to the mineralogical effects that were evidenced during this investigation. The fusion bead technique was found to be far more accurate and able to meet short turnaround requirements provided the calibration methodology used is specific to the grade of samples analyzed.

Jan 1, 2014

By G. A. Bezuidenhout, J. P. T. Kapusta, D. K. Chibwe

"Peirce-Smith converters (PSCs) are extensively used in the copper, nickel, and platinum group metals industries to remove iron and sulphur from the molten matte phase. This technology has not changed significantly since its inception in the early 20th century. The typical converting operation involves lateral purging of air/oxygen-enriched air into molten matte through a bank of tuyeres. This blowing operation occurs at low air pressure from the blowers, and the induced bubbling regime is considered inefficient from both a process and an energy utilization perspective. Inherent drawbacks include recurrent tuyere blockage, inevitable tuyere punching operation to clear airways, and low oxygen efficiency as a result of substantial air losses due to leakages.Investigations in the 1980s demonstrated1 that jetting into Cu and Ni converters could reduce or eliminate some of the process difficulties. In spite of these findings, very little progress has been made in the application of these concepts for converting of non-ferrous melts on a commercial scale.As part of its operational improvement and energy reduction initiative, Western Platinum embarked on a full-scale industrial evaluation of generating a jetting regime by using sonic injection. Prior to full-scale industrial evaluation, a numerical assessment was conducted to ascertain the feasibility of implementing sonic injection on Lonmin converters. The work included flow characterization at high injection pressures achieving sonic velocity at the tuyere exit. The 2D and 3D simulations of the three-phase system were carried out using the volume of fluid (VOF) and realizable k- e turbulence models to account for the multiphase and turbulence nature of the flow, respectively. These models were applied using the commercial CFD numerical code FLUENT.This paper discusses the key findings regard ing understanding of gas plume extension, velocity distribution, shear wall stress analysis, and phase distribution characteristics in the system. Plant trials are also discussed with reference to the commercial aspects of a fullscale implementation of sonic injection in the smelter."

Jan 1, 2014

By V. W. Lumadi, S. Nyasha

The mining industry has yet to fully accept and embrace the strategic role of technology and innovation in successful business planning and execution. In this study, we empirically determine the factors that influence acceptance of technology solutions in the mining industry in South Africa, assess critical success factors influencing adoption of advanced technology in the South African mining industry, and explore challenges faced by the mining industry in South Africa in adopting advanced technology in its operations. Thematic content analysis is employed in the data analysis. Results show that critical success factors to the adoption of mining technology include learning culture, knowledge sharing, high labour costs, and behaviour of other firms in the industry; commonly identified challenges include inadequate engagement with external stakeholders, uncertainties, the cyclical nature of the sector, and high risk related to the adoption of unproven technology and performance systems focused on volumetric production. The study encourages mining companies to implement usage of technology. This can be properly done through regular engagement with the Minerals Council South Africa.

Apr 14, 2024

By G. B. Abaka-Wood, J. Addai-Mensah, W. Skinner

Recently, coal fly ash has become a potential candidate as a secondary resource of rare earth elements (REE). In this investigation, we studied the recovery of REE from fly ash from a commercial power plant. The specific aim was to assess the technical feasibility of recovering REE from the coal fly ash using conventional preconcentration methods, including gravity separation, magnetic separation, and froth flotation. The experimental results revealed that flotation achieved major gains in REE recovery and upgrading. However, during gravity and wet magnetic separation tests, the bulk of REE reported to the tailings. The results showed significant variations in the performance of the various beneficiation methods investigated. This study has confirmed that existing physical separation methods could be used to recover REE from coal fly ash prior to hydrometallurgical and pyrometallurgical processing, although some challenges persist.

Jan 2, 2022

By S. Kahraman

The prediction of rock properties from indirect testing methods is important, particularly for preliminary investigations since indirect tests are easier and cheaper than the direct tests. In this study, we investigate the predictability of the uniaxial compressive strength (UCS) and Brazilian tensile strength (BTS) of rocks from the indentation hardness index (IHI) obtained using point load apparatus. Forty-six different rock types, 14 of which were igneous, 15 were metamorphic, and 17 were sedimentary were tested in the laboratory. The UCS and BTS values were correlated with the corresponding IHI values and the results were statistically analysed. The influence of rock classes on the relationships was also investigated. A strong correlation between UCS and IHI was found for all data. The correlation between BTS and IHI is not as strong as the correlation between UCS and IHI. However, it is in the acceptable limits. When the regression analyses were repeated for igneous, metamorphic, and sedimentary rocks, the correlation coefficients were generally increased. The results show the UCS and BTS can be estimated from IHI. In addition, the effect of rock classes on the relationships between IHI and both UCS and BTS is important.

Jan 1, 2012

By C. A. Snyders

This paper investigates the recovery of platinum group metals (PGMs) from a dilute cyanide leach solution containing base metals, in a manner similar to that used for gold extraction in a typical CIP process, and focuses on both the adsorption and elution stages. The carrier-phase extraction of precious metals using activated carbon offers significant advantages over other processes in terms of simplicity, the high pre-concentration factor, rapid phase separation, and relatively low capital and operating costs. As a sorbent, activated carbon is still by far the most important material because of its large surface area, high adsorption capacity, porous structure, negligible environmental toxicity, low cost, and high purity standards. Adsorption tests were performed on a pregnant alkaline leach solution (0.15 ppm Pt, 0.38 ppm Pd, 0.1 ppm Au) resulting from cyanide extraction performed in column leach tests. The initial adsorption rates of platinum, palladium, and gold were very fast and recoveries of these three metals were approximately 90 per cent after 2 hours and 100 per cent, 97.4 per cent, and 99.9 per cent respectively after 72 hours. The parameters that influence the extraction of PGMs and Au were examined to assess their relative importance during the adsorption process in order to provide the basis for process optimization. The concentration of thiocyanate was not identified as significant factor for PGMs adsorption, while nickel concentration was the most significant extraction process parameter. Base metal cyanide complexes adsorb and compete with the PGM complexes for sites on activated carbon, and while copper adsorption can be minimized by adjusting the residence time, nickel adsorbs at approximately the same rate as that of the PGMs, influencing the loading capacity and adsorption kinetics of the PGMs. The feasibility of eluting platinum and palladium cyanide complexes from activated carbon using an analogue of the AARL process was investigated. Platinum and palladium elute from activated carbon almost to completion in 4 to 5 bed volumes at 80°C, while the elution of gold at this temperature is slow, with a significant amount of gold still to be eluted after 16 bed volumes. Cyanide pre-treatment was found to have a significant influence on PGM elution. Higher cyanide concentration in the pre-treatment step results in more efficient elution up to a point, and experiments suggest the possibility of an optimum cyanide concentration, beyond which elution efficiency starts decreasing.

Jan 1, 2012

By B. M. Munyungano

Rössing Uranium Mine operates a recovery circuit with continuous ion exchange followed by solvent extraction. Serious organic degradation problems were encountered during 1985/6, 2000 and 2005 in the solvent extraction plant. The preferential loss of the tertiary amine extractant was observed during the above-mentioned period. Previous investigations revealed that the tertiary amine was breaking down to nitrosamine, which cannot take part in the exchange reaction with U3O8. A reduction in the redox potential of the solvent extraction plant feed to below 500 mV halted this preferential loss. A lot of effort has been made to try and understand the actual mechanism for nitrosamine formation. Current understanding for the degradation is that formation is due to high nitrates on the strip side of the circuit emanating from nitrates from the precipitation process using ammonia. It is the current belief that pH lower than 3.7 on the strip side results in loading of nitrates onto the solvent. If oxidizing conditions prevail on the extraction side of the solvent extraction circuit, the tertiary alamine will then degrade into nitrosamine. This phenomenon is yet to be established and verified. It has, however, been established that the above process is brought about the following conditions ?High redox potential greater than 550 mV predominately caused by a high Fe3+/Fe2+ratio (4:1) ?Perception that if Fe2+<0.5 g/lit will contribute to high redox ?High concentrations of NO-3 in the conc eluate (feed to SX)/ammonium sulphate (NO-3> 4 g/l based on historic values) ?Presence of Mo as a catalyst ?Tests also have proved that the presence of nitrous acid in a concentration of 1 g/lat 550 mV leads to formation of nitrosamines from alamine.

Jan 1, 2007

By I. V. Filippova, Y. Foucaud, M. Badawi, L. O. Filippov, S. Lebègue

To optimize the flotation of Ca-minerals, their separation contrasts were investigated by coupling experimental and theoretical techniques. We showed that they mainly rely on structural properties such as the Ca-Ca distance on their exposed surfaces but also on the ability to control the intermolecular interactions. An optimized composition of the carboxylic collector by calculating the collector-mineral and the intermolecular interactions was developed. Blending the saturated acids and non-ionic molecules with a fatty acid collector significantly increases the flotation selectivity between scheelite (CaWO4) and fluorite (CaF2). The theoretical results were validated by experimentally improving the separation contrast between Ca-minerals. After the tests of several depressants and collectors, the best depression of gangue Ca-minerals (fluorite, apatite and vezuvianite) was found by combining sodium silicate and sodium carbonate. Keywords: Ca Minerals, Fluorite, Scheelite, Carboxylic acids, Unsaturated Acid, Fatty acids

Jan 1, 2020

By M. Z. Emad, S. Raza, K. Jalil, M. A. Raza, M. U. Khan, S. A. Saki

Dimension stone mining is Increasing because of growing demand from the building and construction industries. Diamond wire saw cutting is a popular dimension stone mining technique around the world. Estimation of the production cost for this method is critical for these operations. n this research a production cost model was developed for the mining of granite using a diamond wire saw. Cost and production data were collected from a granitic dolerite operation in Pakistan for a 4.5-year period, and analysed to identify the cost components. Fuel (34%), labour (15%), consumables (40%), and maintenance (5%) were found to be the four major cost components in this operation. A regression-based dimension stone production cost model incorporating statistically significant variables was developed. The data presented a strong correlation of production cost with fuel, labour, and consumables costs. Finally, a production cost model based on the consumption cost of diamond wire is presented. The model was verified using actual production cost data, which indicated 95% (R2 = 0.95) variance in the data between the predicted and actual production cost values. The model may help field engineers in computing their dimension stone operational cost during the cutting phase.

Nov 6, 2023

By S. Banisi, A. Ghasemi, A. Fazeli, M. Rezaei, M. Maleki-Moghaddam

The efficiency of high capacity SAG mills which consume large amounts of energy depends on the grinding and slurry discharge systems. A 9.7 m × 4.8 m SAG mill with radial pulp lifters is used at the Sarcheshmeh copper complex grinding circuit. The process audit indicated that the pulp discharge system was not efficient, judging by the amount of slurry flow back and carry over. These events limited the discharge rate and increased the wear rate of the lifters and grates. With the objective of finding a new design for pulp lifters, a 3D DEM software (KMPCDEM ©), along with the plant operational data and photographic evidence was used. The KMPCDEM © software was used to compare the efficiency of the radial and curved pulp lifter design based on the material flow. The slurry flow was analysed in terms of ease of discharge and lifter wear rate. It was found that changing the radial pulp lifters to curved pulp lifters could improve the discharge efficiency,and decrease wear rate of the pulp lifter in particular at the base of the pulp lifters. The simulation results showed that if curved lifters with a radius of 0.3×mill radius are used, the amount of slurry flow back and carry over will be negligible. It is predicted that by installing the curved pulp lifters, the capacity of the mill increases by 10% and the pulp lifter service life improves by at least 20%. Keywords: SAG mill, radial pulp lifter, DEM,curved pulp lifter, Sarcheshmeh

Jan 1, 2020

By E. Y. Baafi, H. Fan, W. Zeng

We present a discrete event simulator, TSJSim (Truck-Shovel JaamSim Simulator), for evaluating the stochastic and dynamic operational variables in a truck-shovel system. TSJSim offers four truck allocation strategies: Fixed truck assignment (FTA), Minimizing shovel production requirement (MSPR), Minimizing truck waiting time (MTWT), and Minimizing truck semi-cycle time (MTSCT) including the genetic algorithm (GA) optimization and the frozen dispatching algorithm (FDA) optimization rules. Multiple decision points along the haul routes for all the trucks close to the decision points were included in the model. The simulation results indicate that the trends associated with production tons and queuing time utilizing the four truck allocation strategies (MSPR, MTWT, FDA, and GA) all demonstrated similar patterns as the fleet size varied. As the system fleet size increased, the system production tons under these strategies at first increased significantly and then remained relatively constant; the queuing time relating to these strategies showed a positive relationship with the system fleet size. The bunching time decreased when the truck allocation strategies were applied in the model. In the simulated truck-shovel network system with multiple traffic intersections, by assigning the trucks at the intersections, both productivity and fleet utilization increased.

Dec 13, 2022

By K. Forsberg, Ş. Kaya, C. Dittrich, M. Svärd, E. M. Peters

Scandium can be recovered from waste streams of other metallurgical processes such as red mud from the Bayer process and titanium dioxide acid waste. This is accomplished by an integrated process comprising leaching using acidic media, solvent extraction using organic solvents and stripping of Sc from the organic phase using NH4F solutions. The precipitation of scandium as (NH4)3ScF6 from NH4F strip liquors has been demonstrated at lab-scale with recoveries and purities greater than 98% and 98.3%, respectively. It is desired to assess the possibility of recovering the solvents for re-use in the process to improve its economy and environmental friendliness. Investigations have been conducted to recover alcohol by simple distillation from strip liquor-alcohol mixtures containing about 50 v/v% alcohol. The mixtures were obtained after anti-solvent precipitation of (NH4)3ScF6 using an alcohol to strip liquor volumetric ratio of 1:1. The starting strip liquor contained about 2000 mg/L scandium in 3 mol/L NH4F solution. In the recovery of methanol, the first distillate product collected had a purity of about 87 v/v% and this decreased slightly with time over two hours. The methanol distillate collected in the first 30 minutes with a purity of ca. 85 v/v% was re-used in anti-solvent crystallisation of (NH4)3ScF6 from the initial strip liquor, and the scandium recovery attained was about 98.6 w/w%, almost similar to that of 99.2 w/w% obtained using 100 v/v% methanol. For ethanol recovery, the first distillate product collected was approx. 84 v/v% pure and the distillate collected in the first 30 minutes with a purity of about 75 v/v% achieved a scandium recovery of about 97.2 w/w% in comparison to 98.5 w/w% obtained using 100 v/v% ethanol during anti-solvent crystallisation. Keywords: Alcohol recovery, methanol, ethanol, anti-solvent crystallisation, (NH4)3ScF6

Jan 1, 2020

By D. Odendaal, S. Bharat, R. D. Cromarty

The aim of this investigation was to determine the effect of high-temperature heat treatment on the electrical resistivity of charcoal. Samples of two different wood types (eucalyptus and black wattle) were pyrolised in a retort at a temperature of 700°C and the resulting charcoals heat-treated in an induction furnace at temperatures from 800°C to 1800°C and residence times from 60 to 120 minutes. After cooling, the resistivities of the samples were measured at room temperature using the four-point probe technique. It was found that as the heat treatment temperature increased the electrical resistivity of the charcoal decreased, approaching an asymptotic value at higher temperatures. Longer residence times decreased the resistivity, but this effect was not pronounced.

Oct 3, 2023

By C. Snyman, M. Le Roux, Q. P. Campbell, S. Engelbrecht

Due to the ultrafine particle size required for effective processing of chromite ores, dewatering of the concentrates presents a challenge. It is not uncommon for the ore to have elevated moisture contents even after dewatering, which must be reduced to required levels of between 8% and 10% by mass for further processing. Contact sorption drying has shown promise in test work on fine coal. This method was used to study the dewatering of chromite on a laboratory scale using 3 mm spherical activated alumina ceramic beads as a sorbent. Three different sorbent-to-chromite mass ratios, namely 0.5:1, 1:1, and 2:1, were tested with different process conditions, including dewatering in a stationary and a rotatingl bed. The experimental work showed that it was possible to achieve the target moistures in less than 10 minutes, irrespective of the sorbent-to-chromite ratio used. Ratios of 1:1 or higher, however, proved to be the best. The sorbent reusability at mass ratios of 1:1 and 2:1 were therefore tested. With a 1:1 mass ratio, the sorbents could be reused for three cycles, while with 2:1 ratio, the number of cycles increased to six. The sorbent-to-chromite mass ratio used had a significant influence on the required contact time and the reusability of the sorbents.

Oct 3, 2023