Study on photodegradation performance and mechanism of novel light-sensitive copper-molybdenum separation, inhibitors W. Guiye, Z. Yangge, H. Long, L. Huinan, and L. Chongjun

The current application of copper-molybdenum (Cu-Mo) separation inhibitors is often associated with large dosage, high toxicity, environmental pollution problems. In order to solve these problems, a light sensitive Cu-Mo separation inhibitor LS（light sensitive inhibitor，abbreviated to LS） was developed. In this paper, inhibitory performance, photodegradation rule, and acting mechanism of LS were studied. The subsequent test results showed that, compared with traditional inhibitors, LS has shown comparative advantages, with lower dosage and good inhibiting effect. A series of flotation tests with LS as inhibitor were conducted on a Cu-Mo concentrate. A locked-cycle test showed that a molybdenum concentrate containing Mo 49.88% and Cu 0.6%, with 93.23% molybdenum recovery and a copper concentrate containing Cu 29.92%, with 99.99% copper recovery can be obtained. The photodegradation performance of the reagent was investigated under 365 nm, 254 nm and sunlight irradiation. The degradation of the reagents could be completely achieved by irradiation of three wavelengths of light. However, with the different wavelength of irradiation light, the degradation rate is different, the time required to reach 50% degradation rate being 3 h (254nm), 4 h (solar light) and 6 h (365nm) respectively. The inhibition mechanism on chalcopyrite was studied. FTIR study showed that LS could be adsorbed on the surface of chalcopyrite by chemical adsorption, which could enhance the hydrophilicity of chalcopyrite. Ultraviolet adsorption tests indicated that the adsorption capacity of LS on chalcopyrite surface was greatly affected by pulp pH value, and the proper pH value was 5-9. Keywords: Copper-molybdenum separation, Inhibitor, Light-sensitive, Photodegradation, Mechanism.