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By John M. Gomes

In the repetitive electrowinning of tungsten from scheelite, the calcium impurity buildup in the molten electrolyte results in decreased metal purity, metal recovery, and current efficiency. Periodic addition of B2O3, which reacts with the lime liberated from the scheelite, more than tripled the life of the electrolyte in winning 99.9-percent-pure tungsten and also reduced the number of units of electrolyte required per unit of tungsten recovered from six to four.

Jan 1, 1966

By A. E. Wells

"When the United States entered the World War, the heavy requirements for sulphuric acid in the manufacture of explosives made necessary a definite knowledge of the sulphuric acid capacity of the country. The Bureau of Mines, under the authority conferred by the explosives regulation act, made a thorough survey of the sulphuric acid situation. In this work, which was personally directed by the writer, comprehensive data were collected on the situation and capacities of the various acid plants, sources of supply of raw materials (brimstone, pyrite, pyrrohotite, zinc ores and concentrates, waste sulphur dioxide gases from copper smelting, and spent oxide from gas works), the principal points in regard to manufacturing processes (chamber and contact) and the uses of the acid. The results of this investigaion have recently been published by the Bureau of Mines, as Bulletin 184, entitled ""The Manufacture of Sulphuric Acid in the United States"" by A. E. Wells and D. E. Fogg. The following paragraphs on the uses of sulphuric acid are abstracted from this bulletin.Sulphuric acid is one of the most important of all chemicals, not only because of the large quantities manufactured but also because of the wide use of the acid in many different industrial works. Sulphuric acid is to the chemical industry what iron is to metallurgy. The general public, however, does not realize this fact, for sulphuric acid does not appear in the finished product as does iron and steel, but is only a means to an end. It is essential in many industries, such for example as in the manufacture of phosphate fertilizers, explosives, dyes and petroleum products. In recent years in the United States, especially in the East, the demand for sulphuric acid for chemical and metallurgical industries has been an accurate and sensitive barometer of the general business conditions. This demand for acid responds much more quickly to a general slump or boom in the industrial world than does the demand for iron and steel."

Oct 1, 1920

By M. Howard Berliner

"INTRODUCTION During the last 4 months of 1943, the Bureau of Mines engaged in an investigation and exploratory drilling program in the area between the Coughlin and Galena Level mines near the town of Shullsburg, in Lafayette County, Wisconsin. The work was undertaken as part of a general Bureau of Mines investigation of the zinc-producing area of southwestern Wiscon¬sin at a time when an effort was being made to increase the production of metals important to the Nation's war program.The portion of the southwest Wisconsin zinc district in the immediate vicinity of Shullsburg and the Coughlin and Galena Level mines is well mineralized. The principal ore horizon is at shallow depth, and there is evidence that relatively extensive surface mining for lead was done over a period of many years. Underground mining' for lead and zinc has continued to the present time.The Bureau undertook an exploratory drilling program in the area immediately west and southwest of the Coughlin mine workings after thorough preliminary investigations and geologic studies indicated that such work would serve to guide operators in the development of new ore reserves needed for continuance of mining operations in that area."

Apr 1, 1947

By C. W. JEFFERS

During the past few years the use of mechanical equipment for the loading and transportation of coal at the working face has rapidly increased . Many mining officials are of the opinion that mechanical methods have tended to reduce the hazards of mining, and a number of statements have been made to this effect . Little actual data upon which to base conclusions in regard to the relative safety of various methods of mining have been made available . While it may be possible that these systems of mechanical mining are inherently less hazardous , obvious dangers should not be disregarded in the belief that the mere act of installing mechanical loading equipment automatically brings about better accident records . The same rules and regulations , modified to meet the new regime must be applied with the same discipline as heretofore . By diligent study and application there is reason to believe that new methods of concentrated mining can be utilized with at least a possibility of increased accident performance . With the idea of preventing accidents by taking available precautions against their occurrence , attention should be directed to the dangers that exist where room and face conveyors are in operation . Due to the cost pressure prevalent in the mining industry at the present time mechanical means are often used in an attempt to decrease cost of production. The management , after having spent considerable sums of money for new equipment , is expected by stockholders and investors to show results by increasing tonnage and reducing operating costs . Consequently the operating officials apply the same pressure to local mine officials to obtain results . The natural reaction of the superintendent and mine foreman is to secure the maximum production from the new method , and unfortunately safety is frequently , if not generally , sacrificed to this end . In many instances , operators of new types of mechanical loaders are difficult to secure and after being obtained are difficult to hold , especially if the new equipment is more or less in the experimental stage . The tendency is to handle the machine operators with " gloved hands " and to permit many unsafe practices which ordinarily would not be allowed, in order to keep from antagonizing them and losing their services . Although these unsafe practices become habitual and even uneconomical , conditions thus established are difficult , sometimes impossible , to change .

Jul 1, 1930

By Doris M. Hyde

The petroleum sector continued to dominate Ecuador's economic activity in 1978, accounting for nearly 10% of the gross domestic product (GDP) and 42% of total export earnings. In 1978, a more flexible petroleum export price was adopted which permitted an expansion of foreign market opportunities. During 1979, Ecuador took advantage of disruptions in the world petroleum supply and renegotiated existing export contracts to accomodate the rapidly escalating world market price. Petroleum sales on the spot market were maximized, and prices reached unprecedented levels. By taking royalty payments in-kind, Ecuador increased its volume of petroleum available for term and spot sales. Although the volume remained about the same as in 1978, the total value of 1979 petroleum exports increased to about $920 million, reflecting a 76% increase over the $523 million received for 1978 crude oil exports. Concerned about its steadily decreasing petroleum reserves (recently estimated at about 1.1 billion barrels), rapidly increasing and heavily subsidized domestic consumption, and the prospect of having to import substantial amounts of petroleum by 1983, Ecuador announced plane which it anticipates will double reserves within the next 5 years. The Government plans to spend $1 billion over the 5-year period. Plans include drilling 325 exploration and development wells and establishment of a secondary recovery program for the Sachs and shushufindi fields. Some exploration wells are expected to reach a depth of 17,000 feet. It is thought that substantial reserves exist in the southeast Amazon region. Late in 1979, it was announced that some 10 million hectares will be available for exploration tenders-probably in blocks of about 200,000 hectares each-in the Amazon jungle of the Orients and in the coastal and offshore regions. The Government planned to commission a private, independent analysis of Ecuador's petroleum reserves that would also include recommendations on efficient production levels.

Jan 1, 1981

By L. B. Berger, W. P. Yant, George W. Jones

Improper combustion of natural gas is the cause of low efficiency in heating appliances , also the liberation of carbon monoxide , an insidious and deadly gas . Carbon monoxide is produced during the incomplete combustion of any carbonaceous material , and quantities as low as 0.2 per cent may product death in a very short time . For healthy atmospheric conditions in the home , in which the occupants are continuously exposed , carbon monoxide should not be present in amount greater than 0.01 per cent , which value is taken as the safety limit in this report . The tests herein reported give the conditions which produce carbon monoxide when radiant -fire heaters burning natural gas are used . The conclusions drawn are based on tests made on one type of radiant heater only , but the general conclusions should apply to other types of radiant heaters of similar construction . The gas consumption , gas pressure , orifice pressure , size of orifice , and heater adjustments were changed so as to obtain as many different operating conditions as possible . In a general way the tests were carried out under the same conditions that the heater might be operated in the home .

Feb 1, 1923

By L. D. Tracy

The first study of this subject hits been made in Illinois, but as opportunity affords, similar studies will be made in other States. It is hoped that the data obtained will assist the coal-mining industry to standardize the forms of leases, and so avoid some of the abstruse and ambiguous clauses which slay be found in many of them and the consequent liability of costly litigation. In some of the publications of the Illinois Mining; Investigations prepared under a cooperative agreement with the U. S. Bureau of Mines, the Illinois State Geological Survey and the Engineering Experiment Station of the University of Illinois, the coal areas of the 'State have been divided into eight geological districts, each district being treated separately. This report covers District No. VI of that classification, and it is hopped that studies of the other districts will be completed in the near future and similar results published.

Jan 1, 1926

By Árpád B. Palotás, Adel F. Sarofim, John B. Vander Sande, Paolo Ciambelli, Lenore Rainey

"The evolution during oxidation of the internal structure of soot and carbon black particles was studied using high-resolution transmission electron microscopy (HRTEM) and an image analysis system. Increasing ordering to the carbon structure with increasing oxidation is observed. Measures of the increased order are increases in the fractional coverage of a cross section of the particles with a layered structure, a decrease in the mean interlayer spacing, and a decrease in the spread of the interlayer spacing. The changing structure of the carbon black impacts its properties, such as the rate of oxidation.There is considerable interest in the study of the structural changes of carbonaceous materials as a function of oxidation. Davis et al.1 measured the variation of carbon dioxide surface area of various coals as a function of residence time in a flow reactor. HRTEM measurements revealed that crystallite dimensions and interlayer spacings are altered by combustion. Ishiguro et al.2 showed that oxidation alters the structure of diesel soot. The aim of our current research is to develop a better understanding of the microstructural reordering of carbon blacks with implications to their properties. The carbon blacks used in this research have already been studied and their reactivities as a function of oxidation measured.3The methodology used in this work has already been described in detail elsewhere.4 This paper presents an application to quantify the structural changes of carbon black particles as a function of oxidation and graphitization. The technique used is based on the use of HRTEM (high-resolution transmission electron microscopy) and computational image analysis.It is well-known that carbonaceous materials like graphite, soots, coals, chars, etc., possess characteristic structural appearances which can vary from mostly random or amorphous to a perfectly ordered graphitic crystalline structure. The carbon structure has been variously described as turbostratic5 or as crumpled sheets6 to indicate that parallel layering, reminiscent of graphite, is observed over dimensions of nanometers but that these planes or crystallites show disorder over larger scales. The degree of order of such structures is strongly dependent on the thermal treatment of the material as well as the composition of the source of the carbonaceous material. The value of electron micros¬copy in studying the morphology of such materials has been well established,2,7,8 although only a few attempts toward quantification have been made.The sample observed was carbon black CB330 from De¬gussa. One set of carbon black samples were oxidized in a thermo-gravimetric analyzer (TGA) in air at 575 0C, so that the conversion varied from 0 to 96%. Another set of carbon black samples were graphitized (Graphpac-GB by ALLTECH) and then oxidized in the TGA at 680 °C until 92% burnout was reached. The latter samples are called GB 0% and GB 92%, respectively.For the HRTEM observation a small portion of each sample was ultrasonically dispersed in ethanol. The suspension was deposited dropwise on a copper TEM grid coated with a lacey carbon film. The examination of the samples was carried out on areas that extend over the holes in the supporting film in order to avoid interference from the amorphous carbon background film An oriented gold crystal was used as a calibration standard and subjected to the same techniques as the carbon black samples."

Jan 1, 1998

By O. M. Bishop

The Douglas fluorite property is in the Empire district of eastern Pope County, Ill., which lies near the west boundary of the productive Southern Illinois fluorspar field in Hardin and Pope Countios. Production from mines on the Douglas property accounts for about one-half of the 72,000 tons of fluorspar with which the Empire district is credited. This output was from the Sycamore, Pierce, Slapout, and Empire veins, which are normal fissure veins of little displacement along which there has been local wall-rock replacement by fluorite.

Jan 1, 1949

By J. Roger Loebenstein

Small amounts of arsenic trioxide were shipped in 1988 from remaining stocks at ASARCO Incorporated's closed plant at Tacoma, WA. Imports of arsenic trioxide were at about the same level in 1988 as in the previous year. Legislation and Government Programs The Occupational Safety and Health Administration (OSHA) levied a $1.6 million fine against Asarco for exposing its workers at its East Helena lead smelter in Helena, MT, to unacceptably high levels of lead and arsenic. The bulk of the fine was for violations of a respiratory protection program. The same smelter and its environs has been listed as a Superfund toxic-waste site by the Environmental Protection Agency (EPA). Tests had shown high levels of lead, cadmium, and arsenic in the soil near the smelter. EPA planned to extend the cleanup to areas within the town of East Helena because high levels of arsenic had been found in shallow test wells outside the smelter site. Federal and State health officials have warned residents living in the vicinity of East Helena to avoid eating certain home-grown vegetables because of high concentrations of heavy metals.2

Jan 1, 1990

By R. V. Ramani, R. Stefanko, G. W. Luxbacher

CALCULATION OF MINE HEAD LOSSES FROM ALTIMETER SURVEY DATA USBM PENNSYLVANIA STATE UNIVERSITY - MINERAL ENGINEERING DEPARTMENT USBM USBM USBM THIS PROGRAM CALCULATES PRESSURE LOSSES USING THE USBM METHOD GIVEN USBM IN USBH IC 7809 BY MCELROY AND KINGERY.1957. THE MAJOR DIFFERENCE USBM BETWEEN THIS PROGRAM AND THE CITED REFERENCE IS THE TREATMENT OF AIR USBM

Jan 1, 1977

By Isaac A. Zlochower

This paper presents data on the limiting (minimum) oxygen concentration (LOC), in the presence of added N2, of methane (CH4), propane (C3H8), ethylene (C2H4), carbon monoxide (CO), and hydrogen (H2), and some of their binary mixtures. It also addresses the issue of the flammable concentration (flammability) limits of these pure gases in air. The study is based on spark ignited explosions in large, spherical laboratory vessels (120-L and 20-L) using a 7% pressure-rise criterion for explosion propagation. The results of the study are compared with the older values which used long flammability tubes with a diameter >5 cm together with visual evidence of substantial upward propagation. They are also compared to results reported recently using a 12-L spherical flask with a visual flame propagation criterion. Finally, they are compared to results reported in Europe using more modest flammability criteria and smaller chambers. The findings reported here show excellent agreement between the 120-L and 12-L results, good agreement with the 20-L results, and reasonable agreement with the earlier flammability tube values for the lower flammability limits. They disagree, however, with the more conservative European values. These results and those from the 12-L experiments also feature lower LOCs than are given by traditional flammability tubes. A model for the LOCs of such fuel mixtures based on the Le Chatelier mixture rule for lower flammable limits is seen to reasonably fit the observed results on binary mixtures and can accommodate more complex mixtures as well. One such set of ternary mixtures containing CH4 and 1:1 CO:H2 is well fitted by the model.

Jan 1, 2009

By M. Kanda, J. W. Adams

A system for measuring amplitude probability distributions (APD’s) of electromagnetic noise in coal mines is described and typical APD’s from an underground coal mine are presented. The APD is a basic statistic required for the design and analysis of communication systems, especially those intended for use in noisy environments, and where neither overdesign nor underdesign is acceptable. The rms and average field strengths are obtained by integration of the APD, and examples are shown at several frequencies. All field strength levels are given in absolute units. Selected frequencies cover the range from 10 kHz to 32 MHz.

Jan 1, 1973

By William J. Campbell

The purpose of this investigation by the Federal Bureau of Mines was to design and construct a fluorescent X-ray spectrograph for dynamic rate studies of selective oxidation in molten metals and to establish basic principles for interpretation of data obtained by this method. An X-ray spectrograph was constructed in which the sample holder is a resistance wound furnace; it was operated up to 800° C. in oxidizing atmospheres. No difficulties were experienced with the cooling or heating systems nor with the protective layer of mica around the X-ray tube window, even though the oxidizing surface of the metal is only 0.5 inch from the X-ray tube window, Means are provided for heating under controlled atmospheres for selected time? temperature cycles.

Jan 1, 1961

By M. J. Spendlove, P. P. Zapponi

"INTRODUCTION In carbothermic processes for the production of magnesium, magnesium oxide is reduced by carbon according to the following equation:(1) MgO + C = Mg(g) + CO.The reaction is virtually complete at temperatures above 2,000° C. but reverses rapidly at somewhat lower temperatures. To produce magnesium by this reaction, therefore, it is necessary to cool the gas very rapidly to a temperature at which the rate of the reverse reaction becomes negligible. Several media for quenching the gas have been proposed, among which are hydrogen, natural gas, liquid hydrocarbons, and molten metals of low melting point.The results of a preliminary investigation on the use of molten lead as the quenching medium are summarized in this report. The work was done in 1941, when the threat of war made it imperative to investigate every process that offered possibilities for rapid expansion of domestic production of magnesium. Although the results were encouraging, other processes appeared to offer better prospects for immediate wartime development, so the work was not continued. Shortly before the investigation was completed, several patents on the use of low-melting metals for absorption of magnesium vapors appeared, 4/"

Jun 1, 1947

By Phillip W. Holland

The U.S. Bureau of Mines has developed a mass spectrometer method for determining helium in the parts-per-million to 10% range to an accuracy of ± 1%. The method employs a mass spectrometer, an inlet system utilizing a chromatographic gas-sampling valve, and an activated coconut charcoal trap cooled with liquid nitrogen. Gravimetrically prepared standards of helium in nitrogen were used to demonstrate the linearity of the method over the concentration range of 10 ppm to 10.66% helium.

Jan 1, 2010

The Bureau of Mines evaluated short-delay coal mine detonators manu-factured by three domestic companies for electrostatic sensitivity, strength, and no-fire current level. Electrostatic sensitivity was studied in pin-to-pin and pin-to-case modes employing lO-kV potential. Strength of detonation was measured in the Bureau's underwater test fa-cility. No-fire current was measured using a constant-current power supply unit. Test procedures and experimental data are included.

Jan 1, 1985

By Alfred E. Schwaneke

A versatile torsion creep tester was instrumented with electromechanical and servomechanical components to operate automatically and unattended, producing digital printed outputs. The apparatus uses an electrical system for applying torsional stresses, and a unique angular transducer as a null detector operating a servocontrolled strain measuring system with the digital readout. The tester is designed to measure the creep in single-crystal or polycrystalline zinc, zinc alloys, magnesium, magnesium alloys, or other metals and alloys. Applied stresses may be varied from zero up to 2,000 psi in the outermost fibers of a 1/8-inch-diameter, 4-inch-long specimen. Strain readings to 0.001 degree, equivalent to a strain of 2.73 X 10-7, may be made automatically from one every 5 seconds to one per month. The apparatus has provisions for programed temperature control and special atmospheres or vacuum operation. A discussion of applications of the system to other mechanical testing apparatus is included.

Jan 1, 1970

By Paul T. Allsman

THE THREE words, research, mechanization, and automation are keynote words for mining technology during 1962. Basically interrelated, they not only express the major technologic developments in mining but are the signposts pointing out the road ahead. The process represented by each of these words is evolutionary rather than revolutionary, but developments during the past year indicate a climactical stage has been reached in the process of evolution. Mining research has progressed beyond the stage of academic discussion and is a programed activity within the Federal Government,3 the mining colleges,4 and many of the large mining companies.5 Research was a major agenda item at various national and international mining meetings in 1962. A list of these meetings would include such diverse locales as the Workshop and Symposium on Computers and Computer Applications in Mining and Exploration at the University of Arizona in March; and the 5th Rock Mechanics Symposium at the University of Minnesota, in May; the Rock Mechanics Symposium at McGill University, Montreal, Canada, in September; and the Colloquium XIII, International Society for Rock Mechanics, at Salzburg, Austria, in November.

Jan 1, 1963

By H. W. Wainwright

1. A schematic diagram and a description of the apparatus are presented. 2. Five runs were made using gas having a hydrogen-carbon monoxide ratio of about 2:1 and sulfur concentrations ranging from nil to 1.53 grains per 100 std. c.f. 3. At constant space velocity of synthesis gas the product of the sulfur concentration and days of operation, with conversion of H2 + CO above 97 percent, was constant. With a gas containing 0.04 grain of sulfur ac carbonyl sulfide per 100 std, cu. ft ,, the conversion of H2 + CO remained over 97 percent for 40 days. During that time the heating value of the product gas (on a C02-free basis) remained relatively constant at 940 B .t .u. per c.f., based on dry gas measured at 600 F. and 30 inches Hg.

Jan 1, 1954