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By J. Shibata, K. Manabe, A. Fuji, N. Matsunaga, D. Murakami, Yamaguchi University, T. Suzuki

"Spent hydrodesulphurization (HDS) catalyst contains rare metals such as cobalt, nickel (Ni), molybdenum (Mo), and vanadium (V). The overall objective of this project is to develop a hydrometallurgical process that provides a degree of high recovery and selectivity of these rare metals from spent HDS catalyst. As a part of this project, this study focused on (i) development of a solvent extraction-precipitation stripping process for separation of Mo and V from solutions and (ii) optimization of grinding conditions of alkaline leaching residue for selective Ni sulfuric acid leaching against aluminum (Al). Experimental results showed that effective separation between Mo and V can be achieved by the two-stage process; solvent extraction of Mo and V with TOA (tri-n-octylamine) and precipitation stripping of V with ammonium salt at pH above 8.0. Regarding grinding conditions of alkaline leaching residue for selective Ni leaching against Al, it was found that Ni leaching efficiencies increased by providing higher grinding intensity, while the Al leaching efficiency increased and then decreased with increasing grinding intensity.INTRODUCTIONHydrodesulphurisation (HDS) catalysts account for about one third of the total worldwide catalyst consumption and are extensively used for sulphur removal in petroleum refineries (Zeng & Cheng, 2009). Fresh HDS catalysts generally contain molybdenum (Mo) and nickel (Ni) on an alumina carrier, but various elements included in the crude oil such as sulphur, carbon, silica, arsenic, cobalt, and vanadium (V) deactivates HDS catalysts during HDS reactions. As a result, spent HDS catalysts contain high concentration of rare metals. For example, regarding to Mo and V, it has been reported in the literature that the concentrations of Mo and V in the general spend HDS catalysts are generally 10-30% and 1-12%, respectively (Zeng & Cheng, 2009), which makes it economically viable to recover these rare metals (Biswas et al., 1986).Among a number of processes proposed for the recycling of rare metals from spent HDS catalysts, alkaline leaching is often used for selective Mo and V leaching (Zeng & Cheng, 2009). However, the process which provides a high degree of separation between Mo and V from a leaching solution had not been developed. Therefore, the first objective of this study was set to develop a solvent extraction-precipitation stripping process for the separation of Mo and V from solutions. More specifically, using artificial aqueous solutions of Mo and V, a series of experiments was performed to optimize the extraction pH, stripping agent, and the stripping pH."

Jan 1, 2016

By Xuanxue Mo, Kaihui Yang, Steven D. Scott

Abstract -The Changning-Menglian metallogenic belt in western Yunnan, China, is characterized by the occurrences of both Pb-Zn-Cu and Cu massive sulfides in Permo-Carboniferous mafic volcanic sequences. These deposits were formed in a back-arc basin at a rifted continental margin in the Paleozoic Tethys Ocean. Pb-Zn-Cu deposits are associated with alkalic basalt, andesite, and lesser felsic volcanic rocks intercalated with limestone, which probably formed along an immature rifting segment on a continental basement. These volcanic rocks are enriched in K, Ti, LREE, and other incompatible elements, and have the attributes of alkalic within-plate basalt. An extensive unit of sulfide- carbonate-silica shale in proximity to massive sulfides contains high values of Mn, As, Mo, W, Sn, Sb, and Hg, and has REE patterns that are similar to the volcanic rocks. This, together with the graded bedding in the footwall volcanic rocks, suggests that the sulfides precipitated in a shallow, unstable, and carbonate-saturated volcanic basin. A stringer zone is traced downward for 500 m below the massive sulfide orebodies. It is characterized by an upper sericite-quartz zone and an extensive lower skarn alteration with enhanced W, Sn, and Bi. Lead isotope data show both continental basement and magmatic sources may have supplied the ore metals. Cu deposit and occurrences are hosted by tholeiitic units that represent the mature spreading segments in the back-arc basin. The tholeiitic lavas have LREE-depleted or flat REE patterns similar to MORB or back-arc mafic lavas. The cupriferous massive sulfides are overlain by an extensive unit of chlorite-magnetite or ochre, suggesting a relatively oxygenated oceanic basin. Ni and less Co mineralization is found in dolomite veins of the stringer zone. Enhanced concentrations of Ni, Co, Au, and As are found in the massive sulfides and in sulfide-rich tuffites. The geological setting and mineralization of the Changning-Menglian belt has similarities with modern back-arc basins such as the Manus Basin in the western Pacific.

Jan 1, 1999

By G. J. Arseneau

ABSTRACT Mineral resource statements are reported as tonnage (volume × density) and grades. Effort is expended to accurately estimate the volume and grade, but accurately determining bulk density is often overlooked. Oversimplification of density modelling can result in potentially serious errors in tonnage estimates and over- or underestimation of metal content. A reliable bulk density model requires an adequate database and a good understanding of density variability, along with grade and geology. In this paper, the author summarizes density measuring techniques, draws on examples of simple and complex grade-variable density domains, and discusses improved approaches for minimizing density estimation errors.

Jan 1, 2014

By LUKE O. LINDOE

A major clay products industry in the Medicine Hat area since before 1910 has maintained a continued interest in the clays of the Cypress Hills. For the first forty years the materials used were local red-burning Cretaceous and Pleistocene clays and sands and high-quality stoneware clays of the Whitemud Formation at Eastend, Saskatchewan. Recently a much broader spectrum of raw materials has been brought into use. Including the exposures of the Eagle Butte structure, the Cypress Hills present a 1200 m section of clay-like sediments. Of this 1200 m about 94 per cent, the high montmorillonite shales of the Upper Cretaceous, can be considered useless, or nearly so; the remaining six per cent, all fresh-water beds, presents a wide variety of potentially useful materials. The development of these clay resources is complicated by deep surface creep on the south flank of the Cypress Hills, by largescale slumping on the north flank and by a structural complex in the Eagle Butte area.

Jan 1, 1984

By Robert B. Parsons

"Effective January 1, 1990, mines in British Columbia are subject to a new provincial mining tax statute, the Mineral Tax Act. Under this Act, mines are subject to a two-tier tax system, with a minimum tax payable on ""net current proceeds"" and a higher tax paid on net income. For many mines, the present value of tax paid under the new rules should be comparable to the amount paid under the old rules. Earlier cash payments could pose difficulties, particularly for smaller mines, but existing producing mines could benefit in the short-term.IntroductionEffective January 1, 1990, British Columbia has replaced the provincial mining tax regime under the Mineral Resources Tax Act with a new system under the Mineral Tax Act. The new rules borrow some ideas from other provinces (New Brunswick's two-tier concept, and Saskatchewan's indexed costs) with a view to levying a tax that is fairer to both the producer and the province."

Jan 1, 1990

By Daniel J. Corkery

Mines in Canada and the United States are subject to regulations limiting ammonia, nitrate and nitrite levels in mine effluents released into the environment. The primary source of these nitrogen compounds is typically explosive used in blasting operations, as ammonium nitrate (AN) remains a significant component of most explosives used in the mining industry. The amount of AN entering a local water drainage system is related to site conditions, explosives used, explosive handling and blast efficiency. Mining operators acknowledge AN loss to mine water from blasting operations. However, the mechanisms by which ammonia, nitrite and nitrate are entering the water drainage system, or the relative contribution of specific mechanisms, may not necessarily be assessed or monitored adequately. Characterization of these mechanisms, through systematic investigations, allows a mining operation to focus its efforts on reducing AN loss. This paper outlines a strategy for investigating the mechanisms through which AN enters the mine water drainage system and methods to mitigate this loss. This strategy includes collection and analysis of data to identify and quantify the AN loss mechanisms, design and implementation of tests to mitigate this loss, and assessment of the results. Such investigations are not intended to be a separate one-time project, but part of a long-term process of continual feedback and optimization that is related to the collection and reporting of AN levels for regulatory purposes. The implementation of the strategy must be tailored to each mine?s requirements and existing conditions.

Oct 1, 2010

By G. Gagnon

"HistoryMining of the Schefferville iron deposits began in 1954 on completion of the 357 mile railway linking the mines and the St-Lawrence river port of Sept-Iles. Apart from crushing, no treatment of these ores was required before smelting. In the late 1950's, testwork began at schefferville to develop a process for upgrading the extensive lower grade deposits containing 51% iron with 15% silica (natural analysis). Engineering for a six million ton per year beneficiation plant using cationic silica flotation and the A-C grate kiln Began in 1970 and the first pellets were produced in mid-1973.Production requirements and operating difficulties have restricted capacity to approximately 85% of design but on going improvements are being made continuously to attain design capacity.GeologyThe sedimentary ore bodies of the labrador trough occur in a belt 5 to 10 miles wide and 60 miles long and contain 51 individual deposits varying in size from 1 and 60 million tons. The ores are classified into three main color groups."

Jan 1, 1981

By Margaret Armstrong, Chris Roth

Abstract -Estimating ore reserves for vein type deposits is a two-stage procedure: first, calculate the geometry of the vein system, and second, estimate the grades within this system. The grade estimation can only be consistently performed if the vein geometry - its size, shape and orientation - has been correctly characterized. Getting the size and shape of the different veins right means that the ore tonnages will not be artificially inflated, e.g., by falsely classifying host rock as veins. Similarly, correctly estimating their orientation and location helps mine management decide on the appropriate mining technique, selective or not. When applying geostatistics to estimate the vein geometry all available information needs to be used and not just the standard lithologic indicator of being or not being in a vein.

Jan 1, 1998

By R. E. Dye

IF gold mining is to assume, or it might be better said to resume, a place of ' importance in the national economy of this country following the present war, then one must accept the thesis that gold will maintain the place it has for many generations held in the minds of men as a substantial and lasting emblem of material wealth-a metal in exchange for which men have always been ready to give up the possession of their worldly goods. The thought bas been advanced by some that gold is not necessary as a basis for exchange, that it has no real value anyway and, therefore, the world would wake up some morning to find that no one wanted gold and that, over night, its possession bad in some way ceased to be desired. Holding an equally extreme view there are those who advance the idea that, following the war, gold will in some mysterious way enjoy a fantastic increase in value. Neither of these extreme views can be successfully supported. To presume that by legislation or by general agreement gold would be or could be, over night, dethroned to the position of common stone is wholly beyond the realm of any possibility. The thought that this could come to pass is advanced by, and is attractive to, only those peoples who do not have gold and do r:ot have the means of producing it. To believe that the fundamental value of gold will suddenly change is likewise fantastic. I refer to the fundamental value, not the dollar price, of gold, for it cannot be denied that, with the colossal war expenditures now being made and with the huge national debts which are being piled up, there is a possibility, indeed per-haps a likelihood, that the dollar price .of gold may be revised upward. For the purpose of this discussion, however, that possibility is irrelevant and need not be considered.

Jan 1, 1943

By Jochen Petersen

This paper gives an overview of the various strands of postgraduate and undergraduate training offered in the Department of Chemical Engineering at UCT. Since 2003 the Department is offering a formal postgraduate MSc programme in hydrometallurgical engineering aimed especially at graduate work-based engineers, with 5 weeks of intensive course work plus a research dissertation on a work-related project. This programme has now run 5 times over the years and produced some 20 degrees. The paper reflects on the experiences with running the course, especially the difficulties experienced with supervising industry-based external students. Furthermore, through the Department a graduate training program is offered for all junior metallurgists at a major South African minerals company. This 2-year program, which is currently on its 12th cohort, offers 1 or 2 week intensive blocks of course work alternating with longer stints where the candidates are based at various operations. Although primarily focussed on minerals processing, it has a significant element of hydrometallurgy in it and in recent years an advanced hydrometallurgy stream has been introduced. The paper reflects on the development of the program over the years, the benefits it has provided to the company as well as some of the challenges that remain. Finally the paper gives an overview of hydrometallurgy related undergraduate and research-only postgraduate MSc and PhD projects at the university. Some emphasis is placed on the recently launched South African Minerals and Metals Research Initiative (SAMMRI), a joint government-industry programme to support university-based research in the area of applied metallurgy.

Jan 1, 2014

By John W. Korczak

The use of geological and grade block models has been standard practice in mine design for many years now, with a wide range of software available for creation and analysis. Although geotechnical parameters are of vital importance to mine planning there is very little in the way of commercially available systems for integrating geotechnical data into the mine planning and design process. Sirovision is a new technology developed by the CSIRO (Commonwealth Scientific and Industrial Research Organization) in Australia for automated, safe and accurate 3D mapping of geological and geotechnical features. Datamine has integrated this capability into its product range so that Sirovision has become an integral part of the day-to-day mapping, mine geology and geological / geotechnical modeling in both open pit and underground mine environments. This is the first integrated underground application of Sirovision from Datamine collaboration with Xstrata Nickel at the Nickel Rim South Project. This paper discusses the role of Sirovision in collecting the raw data required for geological and geotechnical analysis and the interpretation in a quick, safe, auditable and reproducible manner.

May 1, 2009

By A. P. E. Dirige

The stability design of cemented backfills is normally conducted using conventional approaches. Analytical or numerical models, backed by trial-and-error methods, are the primary means used to describe or predict the support performance of backfills during mining. The stability of paste backfill free-standing faces is a major concern due to potential consequences to production, ore dilution and safety. Available analytical or mathematical models are developed based on assumptions of the failure modes that may occur when vertical fill faces are exposed during adjacent mining. Numerical modeling serves to provide an understanding of backfill strength and deformation behaviour. Such approaches offer inherent limitations and generally result in conservative designs. In this paper, centrifuge physical modeling was conducted not only for performance evaluation studies, including stability analysis, but to develop an understanding of the strength and deformation behaviour of paste backfill exposed faces when the adjacent ore zone is removed. The failure mode and mechanics of failure observed in the centrifuge model of a given prototype situation are discussed in detail. Centrifuge model results were compared to numerical modeling and it was concluded that a sliding block failure mechanism that resembles a circular slip appears to be the predominant failure mode.

Aug 1, 2013

By M. Piard

The scarcity of literature referring to mines in the Rockies has compelled the writer to co-ordinate information and advice taken at the very source. Help was gladly given by active inspectors and mine bosses. Although the field is unimportant at the present time, due to its distance from markets for raw coal, it is quite worthy of the attention it is receiving from two continents; for, with the commercial synthesis of liquid fuels, it would become the largest fuel laboratory in the world, provided, of course, that freight cost drops to a low comparative level. As explained below, there are no obstacles to economical and safe operation under anything like the typical outcrop shown in Figure 1. Although coal dust is probably more dangerous in the Rockies than anywhere else, the damp outcrops afford means of control. The abundant gas may be bled to the open air, and the rigid roof will settle gradually under a wide span of opened outcropping. The Panel Retreating Wall The Measures: Coal measures having an attitude similar to that shown in cross-section in Figure x are characteristic of the active coalfield on the Alberta side of the Rockies, and they are also found on large tracts of undeveloped land west of the divide. The small anticlines, not shown in the cross-section, do not affect the progress of a pillar line, provided their crests are connected to the atmosphere by drainage bore-holes.

Jan 1, 1928

By Guy Brouillard

A bow-tie analysis is a safety review methodology that uses a structured approach that can be qualitative or quantitative to document the potential risk of safety incidents. The bowtie diagram itself provides a powerful graphical representation of the threats barriers, events, and recovery measures which are readily understood by the "non-specialist". This presentation will discuss how mining operations can use this valuable tool within their operations to understand the risks and apply the appropriate safeguards toward reducing these risks to acceptable levels.

Jan 1, 2014

By W. Díaz, R. A. Parra, L. E. Arias, C. A. Toro, M. Marin, E. Balladares, V. Parra, G. Reyes, S. N. Torres, D. Sbarbaro

This work presents visible-near infrared (VIS-NIR) spectroscopy measurements, and signal analytical techniques to characterize minerals and relevant pyrometallurgical process variables for the copper extractive industry. Data signal processing techniques such as baseline correction and numerical analysis are used to estimate the continuous and discontinuous spectral components. Such spectral components are used to estimate the process temperature, and patterns such as the integrated radiation. Also, metal combustion emissivity calculation are depicted. Our findings suggest that VIS-NIR spectroscopy may be a suitable technique to assess the process condition state, appearing as an interesting sensing alternative. INTRODUCTION Although the flash smelting process is one key stage in the copper extractive industry, representing about 40% of copper matte production worldwide (Cantallopts, 2017), few attention is dedicated to develop sensing solutions to assess process variables, such as mineralogical composition and temperature, in the feeding and bleeding stages, compared to the steel industry (Strakowski, et al., 2014). In this process and other industries, e.g. the thermoelectric power generation one, combustion and particularly the generated flame are the production chain’s heart. Since the flame is a highly radiative emitting process where chemical and physical transformations take place, many works had been dedicated to characterize the combustion state by sensing its radiation using optical and photonic technologies (Ballester & García-Armingol, 2010). In this context, this work aims to contribute with visible-near infrared (VIS-NIR) spectroscopy and pyrometry techniques to retrieve relevant information from a laboratory scale flash smelting process. On the other hand, since photonic instrumentation allow us to perform contactless measurements of emitted, absorbed, transmitted or scattered radiation, it appears as a suitable technique for sensing process properties in harsh environments, e.g. high temperature processes. One of these techniques is the Visible- Near Infrared (VIS-NIR) spectroscopy, which provides information about the spectral radiation intensity distribution, in this work, the emitted flame’s radiation. It is well known in combustion research that the spectral emission from a flame is composed by a black body continuous radiation background, molecular emissions, elemental emissions and additive noise features (Arias et al., 2011). To make sense of such information signal processing techniques are needed, here we propose to analyse the continuous and discontinuous spectral components separately.

Jan 1, 2019

By Jodi Wilding, Barry Lurnsden

The implementation of new technology to mineral separation operations requires rigorous testing to confirm the technology&apos;s technical and economic benefit. The Jaguar Mine owned by Jabiru Metals is located in Western Australia and sequentially separates a copper concentrate and then a zinc concentrate. Fine grinding (80% of zinc in tail is <25µm) is required to achieve efficient mineral separation. All mineral losses are therefore fine mineral losses, and so improvements in metal recovery must focus on this fine mineral. Magnetic aggregation technology has been shown to increase the recovery of fine paramagnetic minerals so it was an appropriate technology to evaluate at Jaguar. Testwork commenced in the copper circuit and it was found that there was a substantial reduction in copper in copper tail and an increase in zinc recovery to the zinc concentrate. The increase in zinc recovery in the latter zinc circuit was an interesting result and initiated the second stage of testwork that was to install and test a second magnetic conditioning unit in the zinc círcuit. This showed a further increase in zinc recovery. Magnetic conditioning technology has now been fully evaluated in the plant and is now part of the Jaguar flowsheet.

Jan 1, 2011

By C. -M. Katsari, G. N. Anastassakis

"Copper is considered one of the most important industrial metals because of its properties (conductivity, malleability) and variety of uses. Approximately 70% of the global copper is used for various electrical applications, with a significant part of copper originating from recycling, since copper can be recycled and re-used countless times, without any loss of performance and difference in the quality of recycled copper in comparison to that from ore. Copper recycling significantly contributes to natural resources conservation, waste minimization, energy saving, and overall cost reduction. Approximately, 35% of the globally produced copper originates from recycled copper.The objective of the current work is to investigate the recovery of copper from electric wire scraps using wet shaking table as an alternative to air separation methods that prevail over the wet ones in recycling processes. The tests were carried out using feed of correspondingly high- and low-grade in copper. In the first case, the wire scraps had been subjected to shredding only, prior to tabling separation; in the later, the low-content tailing of prior air separation was used as feed ?n table separation.In regard to testing, the following factors were examined: table tilt, water flow-rate, and reciprocating speed. The results of the tests clearly denote that copper wire separation from plastic polymer is feasible, as in most cases, table separation resulted in heavy products of high purity in copper and high recovery, and tailings of very low copper grade. The results of the current work clearly denote that wet tabling can be applied efficiently for the separation of recycled copper wire from plastic, as an alternative to air separation methods, as well as for the recovery of copper from the low-grade tailings derived from air separation methods."

Jan 1, 2016

High Pressure Grinding Rolls (HPGR) are said to be a good option in new grinding circuits. Due to their low energy consumption compared to other grinding systems such as SAG milling, there is a strong incentive to check their behaviour for certain ore types. With rising energy prices the operation will become even more beneficial in future. As published in the past, the HPGR is claimed to increase the liberation of the valuable mineral component within an ore. An investigation at the research centre of Polysius was conducted to substantiate the liberation behaviour in finish grinding operations. A pilot scale HPGR test unit (POLYCOM MAGRO) with a roll diameter of 950 mm and processing capacity of 80 t/h was used. Grinding tests were completed with a screen and a two stage drying air separation process (SEPOL). Analysis included standard screen analysis, fractional XRF and modern MLA technology. A technique was developed to oppose the amount of produced slimes (resuming bad flotation) against the positive effect of producing high mass fraction at flotation-easy sizes. The paper shows how effective the use of a dry grinding separation could be in terms of production of mass of liberated metal.

Jan 1, 2012

By J. H. Reiss, D. F. Bruhn, Idaho National Laboratory, Y. Jiao, D. W. Reed, Y. Fujita, D. L. Daubaras

"Bioleaching offers a potential approach for recovery of rare earth elements (REE) from recyclable materials, such as fluorescent lamp phosphors or degraded industrial catalysts. Microorganisms were enriched from REE-containing ores and recyclable materials with the goal of identifying strains capable of extracting REE from solid materials. Over 100 heterotrophic microorganisms were isolated and screened for their ability to produce organic acids capable of leaching REE. The ten most promising isolates were most closely related to Pseudomonas, Acinetobacter and Talaromyces. Of the acids produced, gluconic acid appeared to be the most effective at leaching REE (yttrium, lanthanum, cerium, europium, and terbium) from retorted phosphor powders (RPP), fluidized cracking catalyst (FCC), and europium-doped yttrium oxide (YOEu). The Acinetobacter isolate, BH1, was the most capable strain and able to leach 33% of the total REE content from the FCC material. These results support the continuing evaluation of gluconic acid-producing microbes for large-scale REE recovery from recyclable materials.INTRODUCTIONAn enhanced recovery, substitute, reuse or recycle paradigm is important for balancing the supply and demand of critical materials (DOE, 2011). The recovery of rare earth elements (REE) from recyclable materials is an important component in this model. REE are used in a variety of modern products. For example, neodymium, europium, terbium, dysprosium, and yttrium are important for applications such as permanent magnets, lamp phosphors, rechargeable batteries, etc. (Binnemans, Jones, Blanpain, Van Gerven, Yang, Walton, & Buchert, 2013; DOE, 2011; Graedel, Harper, Nassar, & Reck, 2013). Cerium and lanthanum are used in glass polishers and additives in fluidized cracking catalysts (FCC)."

Jan 1, 2016

By R. L. Christie

"THE ISLANDS lying north of the Canadian mainland, and the large Boothia and Melville peninsulas, form one of the great archipelagos of the world; this sparsely vegetated and nearly unpeopled region extends about 1,500 miles east to west and 1,200 miles from the mainland to the northern tip of the northern-most island. Sea access to most of the islands is restricted by ice to the summer season, and the 'polar pack' ice of the Arctic Ocean presses the year round against the northwest margin of the archipelago. Although the region is remote, the accessibility has greatly increased through a network of weather stations, airfields and air routes connecting with southern centres.The area considered in this paper is that part of the island region underlain mainly by sedimentary rocks. In broad terms, this includes the land and sea areas of the archipelago and the adjacent continental shelf, but excludes the dominantly 'Shield' terrain of Baffin Island, and of Melville and Boothia peninsulas. An impression of the size and potential of this sedimentary region may be gained by comparing some areas: the land area of islands underlain mainly by sedimentary rocks is over 300,000 square miles or about 50,000 square miles greater than the area of Alberta. The total area of the region, including the continental shelf and the inter-island areas, may be double this figure, and may approximate one-seventh of the land area of Canada."

Jan 1, 1970