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By P. E. Damon

An arsenal of isotopic techniques is avail-able that can date the full range of hydrothermal ore deposits. The following are prerequisites for ideal results: (1) Careful collection of samples that are related to the event in a field and process context; (2) Optical examination of the component selected for dating to be sure that it has not been altered; (3) Careful preparation of a pure component of the sample selected for dating; (4) Precise and accurate measurement; (5) Knowledgeable interpretation of the data with reference to decay systematics, properties of the component analyzed as well as the field context and thermochemical environment of the ore process.

Jan 1, 1992

By A. Pratt, G. Deschênes

This paper quantifies the detrimental effects of pyrite and stibnite on gold leaching kinetics. Means to reduce the effect of these minerals by addition of lead nitrate and oxygen are presented. A significant retarding effect was observed when the pyrite concentration was 20%. A pretreatment with lead nitrate reduced the extent of gold surface coating by Ag, Fe and S. Stibnite, at a concentration as low as 20 ppm, significantly affected the gold leaching kinetics through forming a passivating film of Sb(V) oxide possibly Sb2O5. The most practical way to alleviate the effect of stibnite is to leach the materials at a moderate pH with addition of lead nitrate. A low temperature reduced the efficiency of lead nitrate to counteract the effect of stibnite. The increase of dissolved oxygen is not favourable to alleviate the coating of stibnite on gold.

Jan 1, 2004

By Hervé Le Bissonnais, Jean-Pierre Janin, Anne Bergère, Pierre Renier

"The most important impact on the environment of a tunnel excavation is the creation of surface settlements. Nowadays, the mechanized tunneling allows minimizing the settlements, applying a confinement pressure which counterbalances the ground de-confinement. It is thus essential to determine the correct amount of confinement pressure. In this paper, the authors present a 3D numerical study simulating the EPB-TBM excavation of a water tunnel, in the Flanders clays (north of France). Firstly, a simplified 3D simulation, based on the concept of instantaneous longitudinal settlement curve, was performed to predict the surface settlements for different values of heading confinement pressures. Secondly, the same pressures were tested by the EPB-TBM in a monitoring zone. The comparison between the prediction settlements and the measurements was very satisfactory and allowed validation of the numerical approach and the choice of the optimal confinement pressure value for a sensitive area of the project. INTRODUCTION The excavation of a tunnel can create displacements of the surrounding soil which may affect existing structures and generate unacceptable dysfunction. The development of the closed shield tunneling has permitted to reduce the volume loss generated around the excavation and consequently the surface settlements. In this case, as explained by different authors (Clough et al., 1985; Kastner et al., 1996; Mair and Taylor, 1997), the ground movements are influenced by the TBM works: the heading confinement pressure, the shield overcutting and conicity, the annular void grout injection parameters, the segment concrete lining rigidity, the consolidation of the grout. Hence, in the tunnel design, it is important to take into consideration these different processes of the excavation works to simulate correctly the tunneling process."

Jan 1, 2016

By G. F. Joklik

Although the mineral shortages of twelve to eighteen months ago have given way to oversupply, their memory lingers on. These problems were man-made: booming demand throughout the industrial world, political and industrial unrest and the oil embargo all contributed. But in the minds of many, the shortages conjured up visions of the depletion of the world's mineral resources, a disaster that could be staved off only by drastic curbs on consumption and therefore, curbs on economic growth. A little historical research shows that fears such as this are not inventions of the 1970's. A hundred years ago, for example, the imminent exhaustion of the world's coal supplies was being predicted in Great Britain. The English economist, John Stuart Mill, who was usually more perceptive, wrote a few years earlier that "it is only in the backward countries of the world that increased production is still an important object". And later there was Franklin Roosevelt who said in 1932, "Our industrial plant is built; the problem just now is whether under existing conditions, it is not overbuilt". His concern, in other words, was not with the discovery and exploitation of new natural resources, but with the administration of known resources and with seeking foreign markets for surplus production. In light of copper prices at the time -- just under 6¢ a pound -- that was understandable. These instances illustrate how, throughout the world's industrial history, concern about surpluses of raw materials has alternated with alarm about the adequacy of supplies and with calls for restricting growth.

Jan 1, 1975

By G. Henry, S. J. Domvile

Arsenic management practices at the Con Mine in Yellowknife, Northwest Territories have evolved over the last fifty years of operations under changing regulatory, economic and technological conditions and incentives. As a result of a processing upset in the mine' s arsenic trioxide reclamation plant circuit in August 1988, arsenic levels in the mine' s tailings pond rose from 30 to over 100 mg V. At these arsenic levels, water treatment operations were unable to meet water licence discharge criteria and the mine itself was under risk of closure due to limited water storage capacity. Under these internal pressures, the mine initiated its own research initiatives designed to restore water treatment operations. The new process developed from the mine's research, utilized the mine's existing water treatment plant hardware but introduced a pretreatment step involving a discrete sludge recycle and removal system. In February 1989, water treatment operations resumed under the new process.

Jan 1, 1992

By J. O. Leppinen

FTIR measurements using a special ATR cell were carried out to investigate the adsorption of two thiol collectors, potassium ethyl xanthate (KEX) and sodium diethyl dithlophoshate (NaDTP), on an unoxidized lead sulfide surface. Both qualitative and quantitative determinations of the collectors were made at the coverages from two monolayers down to 2% of the monolayer. The experiments revealed that the thiol collector species coordinate to the lead atoms at the surface of lead sulfide but the surface products distinctly differ from the precipitated bulk lead compounds. There exists a linear relationship between the coverage and the signal intensity of the IR spectra within the coverage range studied.

Jan 1, 1987

By D. J. Bryden, J. W. Oberholzer

In response to the need for enhanced precautionary measures to safeguard mine workers in collieries from the consequences of methane ignitions in a heading, the coal mining industry has ex- pressed the desire for the development and testing of active on board suppression systems. As overseas systems cannot be used directly in the bord and pillar geometry it is necessary to adapt overseas and local technology to suit local mining conditions, as well as to test such developed systems for their compliance with the expressed needs. As the systems have to be tested in a specific roadway configuration, a facility was developed to enable the testing in South Africa. A surface test facility has been established which can be used to develop and test suppression systems on continuous miners and roadheaders. This facility consists of a tunnel wherein compliance tests can be conducted in simulated underground conditions. A number of methane explosion tests have been conducted in the test facility. The explosions conducted varied in CH,/air concentration (7,5 to 9 percent) and volume (26 to 88 m3). At lower concentrations there was a marked reduction in explosion strength and flame speed. Tests carried out with the Explostop system successfully suppressed the propagation of methane ignitions in both scenarios tested.

Jan 1, 1997

By L. H. Michaud

A mining company plans to extend its surface coal-mining operations in central Pennsylvania. Although the proposed site contains pyritic material, the results of the acid-base accountings for the site shows an overall Neutralization Potential to Maximum Potential Acidity Ratio (NP:MPA) of 4.26:1 for the entire site. The pyritic material is, however, associated with the lower of the three seams to be mined. If traditional dragline-mining methods are used, this would result in the acidic material being placed at the top of the spoil piles, exposing it to air and water, and therefore to the formation of acid mine drainage (AMD). Further concerns are associated with the fact that the alkaline material is not distributed evenly over the mine site. To prevent the formation of AMD, the company has proposed to mine the area using truck-shovel mining methods. This technique offers a more flexible alternative for cut sequencing and for the selective placement of waste material. Working with the Department of Mineral Engineering at The Pennsylvania State University, amine plan was developed for this site. This plan results in the layering of the alkaline and acidic spoil to achieve an overall net alkalinity in all spoil areas. Therefore, mining this site should not result in the formation of AMD.

Jan 1, 1996

By G. L. Brooke

At present, there are two known cobalt deposits in the 48 contiguous states. This paper is a brief description of one of these deposits. It is a Mississippi Valley type deposit, but somewhat atypical in that the metal of greater interest is cobalt as opposed to lead, zinc, and copper. The history and present work are outlined along with a discussion of the geology and mineralogy.

Jan 1, 1981

By R. Mensah-Biney

The aqueous biphase separation process (ABS) has been used to separate ultrafine industrial minerals. The partition behavior of TiO2, Al2O3, Fe2O3 and kaolin was not pH dependent. The partition behavior of SiO2 was, however, pH dependent. The partition coefficient of kaolin in PEG 3400/ Na2CO3 biphase system was = 150 and that of the silica in the same system was = 0.02, resulting in a separation factor of = 8500 between kaolin and silica. The aqueous biphase separation system was used to separate free silica from kaolin in a raw clay sample from Mexico. The partition behavior of mica, feldspar and clay from North Carolina was also evaluated.

Jan 1, 1999

By T. G. Rozgonyi

The basic goal of this investigation was to determine the degree of drying of high moisture lignite through the use of high temperature and pressure steam autoclaves. Specific items studied were: a) the effect of lignite particle size, b) steam temperature and pressure required, and c) the time of ahydration. Although removal of sodium, ash, sulfur and other ash-forming minerals was not the goal of this study, basic analysis of effluent water showed organic material and alkalai metal content. Removal of inherent moisture from run-of-mine lignite was tested by lock-feeding the lignite, which was previously sized by screening into 25 kg autoclaves. High pressure, up to 4.053 MPa (588 psi), saturated steam was then introduced into the pressure reactor. Reaction time, pressure, temperature, and depressurization rates were strictly controlled for each reactor test run. Results indicate that about 80% of lignite total moisture was removed, including some of the inherent moisture, yielding a non-oxidized, and thus stable, lignite product. As stated, a side benefit occurred as some reduction of non-combustible portions of the lignite also took place. The conclusion reached as a result of the tests is that the steam-drying process can be successfully applied to reducing moisture in lignite, and may be considered for additional studies on acceleration of the coalification process. On the basis of the data presented, the author believes that lignite can be economically upgraded in steam autoclaves by simultaneously reducing the moisture content by 80 percent and the sulfur content by at least 50 percent. Upgrading the lignite by this method will result in large energy and financial savings.

Jan 1, 1984

By K. Lang

A test section of the upper most lift and underlying lifts of a large scale copper heap leach operation was instrumented and monitored with advanced wireline geophysics, fiber optics and resistivity electrode arrays. Elemental Capture Spectroscopy (ESC) copper measurements, resistivity measurements from an Array Induction Tool (AIT), electrical resistivity tomography (ERT) and distributed temperature sensing (DTS) with fiber optics provided integrated near real time data about the performance of the heap. During the leaching cycle, ECS provided continuous vertical measurements of copper in the upper most and underlying lifts in the test section of the heap and was used to generate a copper recovery curve. ERT inversion modeling provided high resolution 3D resistivity measurements, which were used to evaluate moisture distribution. DTS measurements of temperature were used to track the PLS front and calculate velocity. AIT induction provided highly precise bulk resistivity measurements. In-situ samplers provided PLS chemistry at multiple points. Properly integrated monitoring data can provide the heap leach operator with information that can be used to evaluate the hydrodynamics and metallurgy of the leaching process in near real time. Problems in the heap, such as pooling, channeling, longer lag and breakthrough times, excess acid consumption, increased solution in inventory, toe saturation and slope stability can be detected in near real time with the in-situ measurements evaluated.

Feb 23, 2014

By A. B. Cecala

The Bureau of Mines performed a study to determine optimal locations for longwall face methane monitoring equipment. Longwall face ignitions continue to be a concern to the U.S. coal mining industry. Gains in ignition control technology have been somewhat negated by advances in longwall productivity. More reliable, heavy-duty longwall face systems generate higher production rates and increase methane liberation rates. These rates will likely continue to rise in the future as further coal production increases occur. Efforts will continue in the areas of methane drainage, methane containment, and methane dilution. In addition, more effective face methane monitoring is needed. As technology continues toward automated longwall panels, the importance of monitoring for methane at the shearer becomes even more significant. Since the primary face ignition source is the shearer mining machine, the Bureau ran tests to determine the best location to take methane readings on the shearer. This information, in conjunction with data obtained from field studies, provides a knowledge base for selecting optimum face methane monitoring locations.

Jan 1, 1993

By C. Braux

The aim of this study was to develop an integrated approach to enable identification of areas favourable for the presence of massive sulphide deposits in a given region (Las Herrerias, Spain). It is based on geochemical soil exploration, geophysical surveying (ground gravimetry), detailed geological mapping and a knowledge of the deposits of the South Iberian Massive Sulphide Belt. The multi-dataset approach consists, in the first instance, in standardizing and combining all the geochemical data with reference to their geological setting. Next, the "heavy" anomalies are extracted from the gravimetric survey, regardless of the surrounding context (heavy or light). The results from these two stages are then crossed, so that areas where heavy anomalies are associated with geochemical anomalies can be identified and classified. Crossing the geochemical and geophysical data enables a much tighter selection of anomalies than does the manual superposition of data provided by each method (geology, geophysics, geochemistry).

Jan 1, 1994

By J. C. C. C. Menezes, R. A. S. Silva, A. V. Colling, I. A. H. Scheneider

"Coagulants rich in ferric sulfate can be obtained from pyrite-containing coal tailings using a biohydrometallurgical process. The aim of this study is to evaluate the relationship between quantity of pyrite and rate of oxidation, with regard to the consequent production of ferric sulfate for potential use as a coagulant for water and wastewater treatment. Leaching experiments were carried out on the laboratory scale on four coal tailings with different concentrations of pyrite. Characterization of the coal tailings was conducted for the following parameters: total sulfur, pyritic sulfur, sulfate sulfur, organic sulfur, and elemental analysis of CHN (carbon, hydrogen, nitrogen). The samples were also subjected to X-ray diffraction analysis to assess their mineral compositions. The leaching experiments were accomplished using a laboratory column constructed as a packed bed reactor with a sprinkling system in a closed circuit. After four weeks of leaching, the liquor was filtered and evaporated to an iron concentration of about 12 percent w/w, which is typical of the ferric sulfate coagulants commercialized in Brazil. IntroductionCoagulants used for the treatment of water and wastewater are predominantly inorganic salts of ferric iron and aluminum. Aluminum salts, including aluminum sulfate and aluminum chloride, and prehydrolyzed metal-ion reagents, such as polyaluminum sulfate (PAS) and polyaluminum chloride (PAC), are the coagulants most widely used for water treatment (Bratby, 1980; Tchobanoglous et al., 2003; Buzin et al., 2014).However, the presence of residual amounts of aluminum in drinking water has been controversially implicated in neurological diseases (Association of California Water Agencies, 2000; Becaria et al., 2006; Campbell, Hamai and Bondy, 2001; Rondeau et al., 2000; Walton, 2006). A possible alternative is to use iron-based coagulants, such as ferric chloride, ferric sulfate or polyferric sulfate, instead of the aluminum salts (Jiang, Graham and Harward, 1996; Jiang and Graham, 1998). Iron-based coagulants are commonly produced by the acid dissolution of iron scraps or iron ore (Tchobanoglous et al., 2003).Recent studies have shown that it is possible to produce ferric sulfate coagulants from the pyrite present in coal tailings through a biohydrometallurgical process (Colling et al., 2011). The main advantage of this process is that it does not require acid addition, which can be favorable in terms of production costs. Acidophilic bacteria, such as Acidithiobacillus ferrooxidans, can increase the rate of pyrite oxidation and dissolution by several times (Kontopoulos, 1998; Brett and Jillian, 2003; Johnson and Hallberg 2003). They can be highly significant in the bioprocessing of coal tailings for the production of ferric coagulants, as their action favors the acidification of the medium and iron leach (Colling et al., 2011)"

Jan 1, 2016

By Francesco Chiappalone, Marco Invernizzi, Franco Gasperin, Brad Yoder, Fabrizio Fara

The Ship Canal Water Quality Project includes a 2.7-mile, 18-ft and 10-in internal-diameter tunnel that extends from Ballard to Wallingford, two popular neighborhoods in the West of Seattle. During the TBM Main drive a 12' × 12' boulder with variable strength up to 47,000psi was encountered resulting on signicant damages to the Cutter ead. The rst part of this paper describes the design and construction of an underground recess in front of the TBM to create a safe working environment for the TBM repairs. The second part describes an injection campaign performed to seal an unforeseen water inow appeared during the excavation of the 11 Avenue Diversion Structure.

Jun 23, 2024

Automated drilling in surface mines is here, it?s successful, and it?s already at work in mines around the globe. Coal, copper, iron and gold mines in large mining countries such as Canada, Australia, South Africa, the United States and Chile are meeting mining objectives previously ruled out as unattainable. Pit Viper automation enables operators to accomplish more objectives safely. Operator assist functions like AutoLevel, AutoDrill, Auto Rod Changer and multi-rig teleremote control are a few of the features mines are using to gain consistent, sustainable productivity.

By ANA E. BOHE, MICCO GEORGINA DE, GASTON G. FOUGA, JUAN P. GAVIRIA, FEDERICO J. POMIRO

To the best of our knowledge, this paper comprehensively summarizes a thorough study to determine the thermodynamic viability of the reactions between light rare earth oxides and chlorine with and without carbon. The kinetics and mechanisms of light rare earth oxide chlorination and carbochlorination reactions are analyzed and discussed according to results in the literature. Lanthanides between lanthanum (La) and gadolinium (Gd) are considered as light rare earth elements (LREEs) in agreement with previous literature and the results detailed in this review. Both laboratory- and industrial-scale light rare earth chlorinations and carbochlorinations, starting from oxides and ores, are reviewed.

By Soner Top

In this study, a process to separate manganese and iron from manganiferous iron ores by reductive acid leaching followed by magnetic separation was conceived and experimentally tested. In the leaching process, sulfuric acid was used as lixiviant and oxalic acid was used as reductant. The experimental results showed that the manganese and iron separation was optimal when the concentrations of the sulfuric acid and oxalic acid were 0.75 M and 30 g/L, respectively, at a temperature of 80 °C, a solid/liquid ratio of 67 g/L, stirring speed of 400 rpm and leaching duration of 60 min. Under these conditions, 90.49 percent and 6.78 percent of Mn and Fe were dissolved, respectively, from the ore sample in a size fraction of smaller than 106 µm. It was determined that the leaching of manganese from the ores was a second-order reaction with activation energy, Ea, of 53.38 kJ/mol. The leaching residues obtained under the optimal conditions were subjected to wet high-intensity magnetic separation tests to recover the remaining iron content. This separation process produced a concentrate containing 56.20 percent Fe and 1.79 percent Mn with iron and manganese recoveries of 56.83 and 66.73 percent, respectively. To the best of our knowledge, this is the first time that a magnetic separation process was used on a residue obtained from the reductive acid leaching of manganiferous iron ores to recover iron.

By Pedro Marques Bernardo, Carlos Dinis da Gama

This paper presents a methodology for design and simulation of underground ventilation networks, based on the analysis of real situations, followed by the careful interpretation of the obtained results in order to implement their optimization. The method involves two basic steps: the construction of a complete ventilation data base for the mine, upon a series of care- fully previous surveying studies in order to determine the values of its ventilation parameters, and the simulation of relevant situations for the ventilation system optimisation. A simulation model, modified after the Hardy Cross method, allows the testing of various mechanical means located at different points of the network, aiming to determine the technical-economical feasibility of each solution. These simulations obey the directions of air flow in each point of the mine, as determined by the directions of the natural ventilation flow established in the data base that represents the network. The methodology was validated upon studies developed in ventilation network of the Panasqueira Mine (Portugal), in two situations: regular production (mechanical ventilation) and care- maintenance (natural ventilation).

Jan 1, 1997