A panoramic overview of chlorination and carbochlorination of light rare earth oxides including thermodynamic, reaction mechanism and kinetic aspects

To the best of our knowledge, this paper comprehensively summarizes a thorough study to determine the thermodynamic viability of the reactions between light rare earth oxides and chlorine with and without carbon. The kinetics and mechanisms of light rare earth oxide chlorination and carbochlorination reactions are analyzed and discussed according to results in the literature. Lanthanides between lanthanum (La) and gadolinium (Gd) are considered as light rare earth elements (LREEs) in agreement with previous literature and the results detailed in this review. Both laboratory- and industrial-scale light rare earth chlorinations and carbochlorinations, starting from oxides and ores, are reviewed.