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By M. J. Collins

"Autoclaves were first used in the metallurgical industry in 1893 to recover alumina from bauxite. In the 1940s and 1950s, several high temperature and pressure processes were invented in the laboratory of Professor Frank Forward at The University of British Columbia, in parallel with advances in equipment and processes by the Chemical Construction Corporation. Sherritt Gordon Mines Limited enlisted these groups to help develop the nickel sulfide ammonia leach process that was commercialized in 1954. Autoclave processes that have since been commercialized include high-pressure acid leaching of laterites, zinc pressure leaching, and pressure oxidation of refractory gold feedstocks. RÉSUMÉ En 1893, l’industrie métallurgique est la première à utiliser les autoclaves pour l’extraction de l’alumine dans la bauxite. Dans les années 1940 et 1950, plusieurs procédés à haute température et à haute pression sont inventés dans le laboratoire du Pr Frank Forward de l’université de la Colombie-Britannique (UBC) ; parallèlement, la Chemical Construction Corporation fait de grands progrès en matière d’équipement et de procédés. Sherritt Gordon Mines Limited fait appel à ces groupes pour qu’ils aident la société à développer le procédé de lixiviation du sulfure de nickel dans de l’ammoniaque, commercialisé en 1954. Les procédés de lixiviation en autoclave commercialisés depuis incluent notamment la lixiviation acide à haute pression de latérites, la lixiviation sous pression du zinc et l’oxydation sous pression des matières premières de l’or réfractaire.INTRODUCTION Autoclaves are chemical reactors that are built to contain processes taking place at elevated pressure. They are used in metallurgical refineries throughout the world to take advantage of the increased reaction kinetics and different reaction products that can be obtained in aqueous systems above the boiling temperature at atmospheric pressure. The word autoclave comes from the French “auto” and the Latin “clavis” and literally means self-locking—that is, the core distinguishing feature of an autoclave is that it includes a means for pressure regulation (e.g., a pressure relief valve). Denis Papin (Figure 1a), one of the inventors of the steam engine, was the first to make use of a safety valve to control steam pressure. He is credited with inventing the autoclave in 1679. Papin’s “digester” (Figure 1b) was a type of pressure cooker that was originally used to liquefy bones. Most commercial autoclaves are horizontal, multicompartment vessels with mechanical agitation, as shown in Figure 2a; however, the steam-agitated Pachuca vessels used to leach laterite ore in Moa, Cuba (Figure 2b), are also classified as autoclaves according to the self-locking definition provided above."

Jan 1, 2018

By Jean Rosaire

?GWIOP Location ?Climate and Physiography ?History ?Geology ?Deposit Types ?Mineralization ?Historical Mineral Resources ?Conclusions and Work Program

May 1, 2007

By Dr. G. R. Hoey

"Abrasive wear and corrosive wear of carbon-steel grinding balls occurred simultaneously during the wet-grinding of hematite iron ore, and Ni-Cu sulphide ore, in laboratory ball mills. Two corrosion control methods, the use of corrosion inhibitors and pH control, were investigated and found to be effective means of reducing or preventing corrosive wear. Up to 50 % reduction of total ball wear resulted from the use of these methods.Corrosive wear is caused principally by the reaction of oxygen in air with the carbon-steel grinding balls, probably by the following reaction: 2Fe + O2 + 2H20 - 2Fe2 + 40H-.IntroductionA survey of corrosion problems in Canadian sulphide ore mines was completed and the findings were published in 197l(l). The corrosion survey was used to develop the present research program with the objective to find more economical and effective ways and means to reduce the corrosion that occurs in the mining and metallurgical industry. The purpose of this presentation is to review the projects being done by staff members of the Corrosion Section, Extraction Metallurgy Division, on corrosive wear and its control in wet-grind ball mills.Both abrasion and corrosion contribute to metal consumption during wet grinding of ores. The total wear of grinding media in this study is assumed to be equal to the sum of corrosive wear and abrasive wear. A great deal of research and development has been reported in the literature on ways to improve the abrasion resistance of grinding media but only a small number of studies has been reported on the corrosion resistance of conventional grinding media."

Jan 1, 1974

By Hamid Mahmoudabadi

In the present paper, the performance of four approaches based on neural networks and geostatistical method for grade estimation are compared and analyzed their performance to find a proper method. Four methods, Multi Layer Perceptron neural network (MLP), Radial Basis Function (RBF), General Regression Neural Network (GRNN) and Ordinary Kriging (OK) are selected for ore grade estimation of variable Fe in an iron deposit located in Iran. For each method, two diagnostic statistics are calculated: Mean square error (MSE) and correlation coefficient. The results show the superiority of the General Regression Neural Network.

Oct 1, 2009

By Richard P. Reiff

"The Facility for Accelerated Service Testing (FAST) program has been involved in numerous rail wear tests since its inception in 1976. A number of specialized tools have been developed to aid in assessing specific performance parameters including gauge face wear, head height loss, metal flow, head area loss, hardness, and welded rail end batter. The layout of a test site, including position in curve, number of measurements per rail, and train operation must be properly controlled/monitored to provide valid wear comparisons.This paper will provide an overview of the above-mentioned tools and techniques. In addition, a summary of recent test results from FAST, including information on head hardened rail investigations, will be provided. A set of guidelines for establishing a revenue service field test site will also be provided to aid users in performing evaluations of their own.IntroductionBackground of Rail Wear Testing at FASTThe Facility for Accelerated Service Testing (FAST) located at the Transportation Test Center, (TIC), Pueblo, Colorado has been involved with testing of rail since program initiation in 1976. A huge data base of rail wear information has been gathered from FAST operations under a variety of rail metallurgies, lubrication conditions, and measurement techniques. Attempts at obtaining meaningful rail wear information from early (1976-1978) FAST rail wear data was hampered by two main factors: (I) measurement techniques were insufficiently accurate for the amounts of wear being experienced, and (2) the lubrication was not sufficiently controlled to obtain uniform conditions for a sufficient measurement time period.Subsequent test periods were operated with improved measurement techniques and controls that ensured statistically valid data. The policies and conditions that permit accurate rail wear assessment will be reviewed and outlined in this paper, along with some specific TIC and field examples that will allow the user to improve the accuracy of a field rail test on their own operating property."

Jan 1, 1988

By CIM Mineral Resource, Mineral Reserve Committee

The CIM Mineral Exploration Best Practice Guidelines (the Exploration Guidelines) have been prepared to assist professional geoscientists and engineers to conduct consistently high-quality work in order to maintain public confidence. The Exploration Guidelines are meant to assist professional geoscientists and exploration practitioners in planning, supervising, and executing exploration programs. In Canada, there are generally two types of public resource reporting: “Disclosure”, as defined by NI 43-101, is the reporting of technical information to the public and market participants for securities legislation purposes where a Qualified Person (QP) must be involved, and reporting of exploration information for governmental agencies to support obligations under laws including the Mining Acts of each of the Provinces and Territories. The Exploration Guidelines are also relevant where the results will not be publicly reported but are intended for internal company use. While this document is intended as guidance for work conducted or supervised by geoscientists in Canada, many of the practices described herein can be adapted to mineral exploration activities in other countries. The Exploration Guidelines are not intended to inhibit original thinking, or to prevent the application of new approaches that may develop into fundamental components of successful mineral exploration programs. Rather than provide prescriptive solutions to specific issues, they include general guidelines for current professional practice and to demonstrate and defend the merits of new methods. These guidelines do not preclude individuals and companies from developing more detailed guidelines specific to their own requirements. The initial version of the Exploration Guidelines was prepared by the Canadian Institute of Mining and Metallurgy and Petroleum (CIM) Exploration Best Practices Committee and adopted by CIM Council on August 20, 2000. On January 9, 2018, CIM Council formed a new committee, the Mineral Resources and Reserves Committee (CIM MRMR Committee) with a mandate to, among other things, update the Exploration Best Practice Guidelines. The mandate for the committee was accepted by CIM Council on March 2, 2018. The new document was adopted by the CIM Council on November 23, 2018.

Nov 23, 2018

By Primak. George J.

"In the development of a new product as well as during its introduction on the market, it is very important to give due consideration to problems involving patents, licenses and trade marks. At the very beginning of the research and development program, it is obviously essential to ascertain, through a suitable patent search, that the product in question will not infringe any patents which are still in force. Then, a possibility of achieving one's own patent or proprietary position on the product or the process of its manufacture should be carefully explored. Licensing arrangements that one may reach with respect to patents and know-how covering such new product may, in the final analysis, determine its over-all success or failure. If one can count on licensing revenues or some favourable cross-licensing arrangements with respect to a newly developed product, this may go a long way to achieving profitability and success. The selection of a good trade mark is probably one of the most important acts that one has to perform once the product is developed, as customers will identify the new product by such a trade mark. In many instances, successful marketing and widespread acceptance of a product are largely due to its appealing name or trade mark, accompanied by proper promotion and advertising. Once the trade mark has been adopted, it should be registered in the Trade Marks Office to provide the protection afforded by federal statute. If the product is to be manufactured, sold or licensed in some other countries, similar considerations should be made with regard to each such country."

Jan 1, 1973

By J. Chlopas, D. J. Barratt, M. V. Sharp

"This paper describes the modifications made to the Fox Mine copper concentrate bin in order to obtain a continuous flow condition. The design of these modifications is based on test results obtained on Fox Mine concentrate using the flow factor testing machine in the research facilities of Cominco at Trail, B.C.The original design consisted of a cylindrical steel bin on a concrete slab with two slot-discharge openings. Based on predictions of the maximum mass flow hopper angle for conical and wedge shaped hoppers for the concentrate on various potential bin lining materials, Ultra-High Molecular Weight (UHMW) Polymer was selected as a liner.Using the recommended angles for conical and wedge shaped hoppers, the profile of the bin base was changed to suit the existing slot openings.The initial method of fastening the liner resulted in failure of the connections. Subsequent modification to the zinc concentrate bin fastener system proved satisfactory and it has now been in operation for over one year without any separation of the lining material.Utilization of flow testing procedures on concentrate samples has demonstrated that proper design of storage bins or hoppers to achieve continuous flow can be incorporated into the design of new plants."

Jan 1, 1978

By Jack J. Ayotte, Michael R. Nadon

"Today's demand for better and more efficient methods inspires new approaches to construction and mine development.A project at Asarco's Aquarius Mine provided a challenge that resulted in the adaptation of a civil construction technique to a mining application.This paper describes the construction of an escapeway shaft to surface from the mine's 150m level. The prime consideration was to provide the most cost-effective method of establishing a shaft collar in the 145 ft (44 m) of water-bearing overburden. This problem was resolved with the employment of the drilled in-caisson method.The remainder of the 500ft (152m) deep shaft was raise bored and portable hoisting equipment was used to install a permanentmanway and shaft liner.IntroductionHaving completed the first phase of exploration development in 1982, J.S. Redpath Limited was engaged to carry out an engineering and cost study to investigate the feasibility of re-opening Asarco's Aquarius Mine near Timmins, Ontario. The scheme was to develop the proven ore reserves and proceed with shrinkage stoping while carrying out further exploration development and diamond drilling.One significant and costly component of the project was the provision of an escapeway shaft to supply additional ventilation as well as a second means of egress from the mine. The major complication to this task was the presence of 145 ft (44 m) of water-bearing overburden at the site. The first and obvious approach was to use conventional ground-freezing methods as had been employed previously on .this property for the initial development shaft. This being the only ""sure"" method available at the time of the budget estimate, it was used as a basis for the study but its considerable projected cost and time demand inspired further investigation into other possible solutions.After considerable research and several brainstorming sessions, a Redpath team came up with an approach whose basic procedures had been used extensively in the civil construction field, although they were novel to the mining industry."

Jan 1, 1987

By Guy Chevalier, Jean-Guy Chartrand, Louis Barrette, Daniel Michaud, Michel Fortin

"COREM has developed, specifically for the mineral industry, a mobile laboratory using the Laser-Induced Breakdown Spectroscopy (LIBS) technique. It has been used to perform onstream analysis (OSA) of the chemical composition of slurries in both gold-ore and iron-ore processing plants. Industrial tests have been carried out respectively at La Mine Doyon (Cambior), a gold-ore processing plant near Rouyn-Noranda, Quebec, and at QCM's iron-ore pelletizing plant in Port-Cartier, Quebec. The aim was to demonstrate that the LIBS technique is capable of providing information that meets the needs for process control. C, Si, Ca, Mg, Mn and Al were the elements targeted on iron ore while Cu, Fe, Ag and Au were targeted for gold ore. The results obtained meet or exceed the requirements for process control and consequently clearly show that the LIBS technique is suitable for industrial applications.The feasibility of OSA, through in-plant validations using COREM’s LIBS mobile laboratory, has been demonstrated in four essential aspects: slurry sampling, LIBS chemical measurement, robustness for continuous operation, and functionality for industrial operators.INTRODUCTIONThere is a general need for optimization in the mineral industry. Process control is a favoured means to achieve this goal (McKee 1991). Real-time knowledge of process status is the key to effective control (Da Silva 1994). Only a few techniques, such as XRF, NMR and digital imaging, are currently amenable to chemically monitor industrial processes (Braden 2002). LIBS is an emerging technique with appealing characteristics for on-line and real-time measurement of bulk material (Lorenzen 1992, Palanco 2000). While our ultimate goal is to provide our industrial partners with performing monitoring tools, a shorter-viewed objective is to demonstrate the feasibility of developing a LIBS system for OSA. The LIBS technique has shown interesting capabilities for measuring solids, liquids, dusts and gases. Our work has focused on mineral slurries (Barrette 1999 and 2001, Turmel 1999). Special equipment is needed to perform in-plant validations. A mobile laboratory based on the LIBS technology has been assembled for this task."

Jan 1, 2004

By F. W. Gray

A GEOLOGICAL study seeking to determine, for economic purposes, the value of the Sydney coalfield as a source of coal supply. Limitations of the coalfield come under two main heads: (a) Areal extent of the undersea coalfield. (b) The distance from shore at which coal can be mined at a cost of production permitting its profitable sale. Conclusions reached are that the areal extent of seams below the Phalen seam is of. small economic importance, and that non-persistence of these seams in full thickness and quality in the undersea extension of the coalfield will put an end to profitable mining before any limitations connected with distance from the shore-line become operative. With respect to the Phalen seam, non-persistence or deterioration of the seam will become effective in the western part of the coalfield, and less certainly in the eastern part of the coalfield, before operation of limitations by distance from shore. In the central portion of the coalfield, the seam probably persists in commercially workable thickness and quality to beyond the limit of mining set by distance from the shore-line. With respect to the seams above the Phalen seam between the Mountain fault on the extreme western boundary of the coalfield and the assumed termination of the deposition area on the eastern extremity of the field near South Head of Morien, there appear to be only such limitations as arise from engineering approach, distance from shore, sufficiency of strata cover between the sea-floor and the upper coal seams, and quality of the coal (with certain reservations as to the continuity of the upper seams under Sydney harbour and in the Sydney Mines-Little Bras d'Or district). Some of these seams have fragmentary land outcroppings from which their persistence seaward is assumed, and there may be other and still higher seams in the strata column which are entirely submarine.

Jan 1, 1941

By Marc Ruest

A new instrumented cable bolt has been developed by the National Institute for Occupational Safety and Health at the Spokane Research Laboratory in Spokane, WA. Although various instruments are available to measure load distribution and magnitude along a grouted cable, this instrument is innovative in that it uses strain gauges internal to the cable as load-measuring sensors. The instrument has been successfully tested in the field at FMC?s Granger Mine, Meikle Mine, and Getchell Mine. A ?split-pipe? laboratory pull test was performed on each of three cable bolts instrumented with the new device. Each test consisted of grouting a 1.83-m-long cable in two 0.91-m-long sections of schedule 80 pipe. A numerical analysis was then performed in which laboratory boundary conditions were simulated and model properties derived from textbook guidelines. The loads calculated by the model were then compared to the measured loads.

May 1, 2002

By R. Tomás, J. B. Serón, M. Romana

The Slope Mass Rating (SMR; Romana, 1985) geomechanics classification was developed as a sequel of Bieniawski’s Rock Mass Rating (RMR) system, which was almost impossible to use in slopes due to the extreme range of the correction factors (up to 60 points of a maximum of 100) and to the lack of definition of them. A detailed quantitative definition of the correction factors is one of the advantages of SMR classification. During the last thirty years the use of SMR system has been extended to many countries from the five continents and, thus, it is time to review the most interesting developments. Both RMR and SMR are discrete classifications, depending on the values adopted by the variables that control the parameters. This can cause major changes in the parameters value due to small differences in the variables value, with changes in the final rock mass assigned quality. On the other hand, geomechanics quality indexes are extremely biased. To avoid this problem, some authors have proposed continuous functions for SMR. This classification has been also adapted for its application in heterogeneous and anisotropic rock masses, for high slopes, for is application trough stereographic projection and Geographical Information Systems, has been used as susceptibility rockfall parameters and has been included in the technical regulations of several countries. Additionally, some open access computer tools have been developed for the computation of SMR. Consequently, this paper reviews: 1) the most important modifications and adaptations of slope classifications which derive directly from SMR; 2) the use of SMR throughout the world; 3) many significant papers on slopes analysed with SMR all over the world; and 4) future trends in the use of SMR.

Jan 1, 2015

By Scott Martin

This paper will discuss the challenges currently facing the mining industry. By sharing experiences gained in the CIM Leading in Mining Course, I will highlight what’s working, what’s not, what are the challenges, what are the concerns, what are the opportunities, what needs to happen. Specifically, I will discuss what is currently happening with leadership and leadership development in members’ own organizations, what skill sets are important to develop in different hierarchical groups and how comprehensive leadership courses like the leading in Mining course can help improve leadership within individuals and the industry. Leadership development is a process not an event.

Jan 1, 2014

By Ting Lu, Gerard Laman

"This document compares the systems of coal classification described under ASTM standards used in Canada to GB standards used in China. A preliminary connection of metallurgical coal classes was set up between the two classifications. In GB classification system, there are nine metallurgical coal groups, namely PS, SM, JM, FM, ½ ZN, RN, 1/3 JM, and QM used in coal blending for coke production. PS coal is almost equivalent to the Low Volatile Bituminous coal; SM, JM, and FM coal groups fall into Low to Medium Volatile Bituminous range; ½ ZN, RN, 1/3 JM, and QM are equivalent to bituminous coal with medium to high volatile matters; QF contains higher volatile bituminous coal compared with High Volatile Bituminous coal. The caking properties commonly used in respective country are also compared in this document. These properties include free swelling index (FSI) and maximum fluidity used in Canada, as well as caking index (GR.I.), and the maximum plastic layer thickness (Y) mainly employed in China. It has been observed that the log of the maximum fluidity has a stronger correlation with the caking index than the Y values. Metallurgical coal processing strategy and typical coking coal product qualities are briefly discussed in the last section of this paper. Currently there is a trend to use heavy medium cyclone in both countries. In Canada the conventional two-product cyclone technology is the preferred practice; whereas in China the three-product heavy medium cyclone arrangement is widely used.INTRODUCTION Coal can be simply classified by applications into two categories: i) thermal coal used to provide heat energy in combustion, and ii) metallurgical coal which is converted to coke, in a carbonization process, and used mainly in the iron and steel industry. Metallurgical coal contains even higher heating values than thermal coal. In addition, it presents unique plastic properties during carbonization which in turn produces a porous solid, high in carbon referred to as coke. Coke is one of the most important raw materials in the iron and steel industry."

Jan 1, 2012

By P. Kolodziejczyk

Mining seismicity can be harmful both under and on the surface. ? Tremors are not totally damaging, but destructive to buildings and infrastructure, especially in highly urbanized regions, such as Upper Silesia in Poland ? Destroy the social appreciation, trust and support for mining industry ? To prevent or reduce these effects, engineers and scientists develop methods allowing prediction of ground shaking intensity near buildings and various losses that can result from it Evaluation and prediction of mining tremor?s damaging influence on buildings is usually solved with two steps: ? Estimation of local ground shaking intensity (based on known attenuation relation) and classification into one of several predefined intensity intervals ? Apply supposed relation between the shaking intensity interval and qualitatively defined damaging effects to express predicted effects This makes a mixed quantitative/qualitative procedure, difficult to analyze or optimize

Aug 1, 2013

By The Staff

THE gold mining industry in Canada is today the most important stabilizing influence in the country. This factor was brought out particularly during the 'depression' years, when steady employment was given to men in that industry and the monies spent in supplies and power in turn benefited the country to a great extent. At the same time, a commodity was produced which was saleable in any market of the world, thus maintaining Canada's credit in foreign markets and keeping her trade balances equalized. We have a vast area known as the Precambrian Shield. The agricultural possibilities of this area are practically negligible and it will depend entirely upon the mineral and forest resources to make this district an economic factor in the life of Canada. To date, from the mineral point of view, we have been highly successful. There are, however, still vast areas to be explored. It is tedious and laborious work, entailing great individual hard-ships and the expenditure of much energy and money. During my thirty years' experience in the search for, and operating of, gold mines, I have come to the conclusion that although individuals may give all their time, energy, and money, Governmental assistance is absolutely necessary in the development of hydro-electric power sites and roads. The Governments, to date, have given splendid co-operation along these lines, but in order that this great industry may go ahead they should continue their good work and, if possible, give greater relief from taxation to mines situated at a considerable distance from the railway.

Jan 1, 1938

By J. Patterson

"Acid Mine Drainage (A.M.D.) formed from oxidation of disposed pyritic wastes presents a potential pollution hazard for Equity Silver Mines Limited and the mining industry in general. Failure to collect and treat these acidic effluents can eventually affect the quality of receiving streams and endanger aquatic life forms. Treatment and discharge of A.M.D. to the receiving environment must comply with stringent anti-pollution laws.Wastes mined at Equity Silver Mines Ltd. are predominantly acid generating and must be handled according to a materials management plan to minimize impact on the environment. Effluent collection and treatment facilities have been constructed to address the short term environmental concerns with reclamation and research programs being developed to address and monitor abatement measures for control over the long term.The purpose of this paper will be to offer a brief overview of these measures. Key topics for discussion will be: kinetics of Acid Mine Drainage, acid generating potential, water treatment and sludge handling, special wastes, waste dump construction, waste rock amendments, bacteriocide research, simulations, and reclamation measures. Programs designed to evaluate impact on the receiving environment, although they form an extensive part of the program, will not be discussed in this paper.INTRODUCTIONEquity Silver Mines Limited is located in the Central Interior of British Columbia, within the Omineca Division, 35 kilometers southeast of Houston Mining and approximately 575 kilometers by air north-northeast ofVancouver (Figure 1).The deposit consists of three economic mineralized zones: The Southern Tail, Main and Waterline Zones. Mining of the Southern Tail commenced in April, 1980 and was completed in the first quarter of 1984. Main Zone production was initiated during the last quarter of 1983 and the Waterline Zone remains undeveloped to-date. Remaining reserves are in the order of four years contingent on favourable metal prices. The three deposits (Figure 2) occur within a window of interbedded volcanic and minor sedimentary rocks. The older volcanic sequence is bounded on the west by a small granite-like stock and on the east by a gabbro-monzonite complex. All are overlain by a series of younger lava flows."

Jan 1, 1988

By Laurence McGonagle

"The Highland Uranium Project (HUP) is located approximately sixty miles northeast of Casper, Wyoming and is owned and operated by Power Resources, Inc. (PRI). With an annual production of680 tonnes (1.5 million lbs) U308, HUP is one of the largest uranium producers by in-situ leach (ISL) in the western world. Uranium is currently produced from four wellfields with a total flow rate of approximately 1,135 m3/hr (5,000 gpm). The carbonate leach solutions are processed by anion ion exchange at two satellite facilities located in close proximity to the wellfields. The loaded resin is transported by truck to a central processing facility for elution of the uranium. Uranium in the pregnant eluant is precipitated and washed prior to calcining.Wastewater from the satellite facilities is treated and used for irrigation at a Land Application Facility. The wastewater generated at the central processing facility is injected into a 2,750 m (9,000 ft) deep waste disposal well.When economical mining of the orebodies is complete, restoration of the groundwater is initiated. There are currently two wellfields at HUP undergoing ground water restoration. Phase I restoration consists of removal of the carbonate leach solution from the ore body. Phase II includes treating the withdrawn fluid with reverse osmosis and reinjection of the permeate into perimeter wells.Future plans include construction of additional satellite facilities at the Gas Hills Project and other economical deposits located within 240 km (150 mi) of HUP. The capacity of the central processing facility will be increased to 1,815 tonnes (4 million lbs) U308 per year by late 1999."

Jan 1, 1998

By R. Webber, D. Averill, L. Whittle, D. Moffeti, G. Kassakhian

"This paper describes the recent pilot-plant work carried out on two alternative processes capable of producing an effluent containing less than 10 pCi/L total radium-226 activity and very close to 3 pCi/L dissolved radium-226. The processes incorporate coprecipitation of radium with barium sulphate by the addition of barium chloride in continuously stirred tank reactors followed by either chemical coagulation with ferric chloride, flocculation and clarification, or polymer-aided dual-media filtration. IntroductionUranium mines in Canada have practiced radium removal from tailings basin effluents since 1965. Treatment consists of addition of barium chloride to precipitate radium as barium- radium sulphate and provision of natural or constructed settling ponds for sedimentation. This process, however, has been identified as being deficient in that it allows particulate or suspended radium-226 releases which are higher than the regulated dissolved values». Also, the large size of some of the settling ponds is believed to represent a real limitation of the present technology because of inferred difficulty in recovery of barium-radium sulphate precipitates.The Federal Government Mining Task Force established a Radioactivity Sub-Group in 1974 to assist in the development of effluent regulations and guidelines for the uranium mining industry. Among the recommendations of the Sub-Group was the need to seek more effective methods of radium removal, including development of physical/chemical treatment systems as an alternative to settling ponds. In response to the SubGroup recommendations, a bench-scale study began in March 1976at the Wastewater Technology Centre (WTC) of Environment Canada . The results of this study indicated that coagulation and flocculation of the precipitate from barium chloride addition is a viable alternative to sedimentation in settling ponds(3). The bench work was expanded and accelerated in 1977, with financial assistance provided by the Atomic Energy Control Board. Subsequently, a research program with a larger scope was developed; this program is jointly managed and funded by government and industry, as shown in Table I.One of the goals of the joint program is to develop, at pilot scale, a physicalI chemical process to reduce the radium-226 content of uranium mining and milling effluents. Target radium-226 activities for treated tailings basin effluents were set: namely, 10 pCil L total and 3 pCil L dissolved radium 226. Extensive bench-scale and pilot-scale work was conducted through 1978 and 1979 and has culminated in the development of two physical/chemical processes. This paper describes work carried out at a pilot plant which led to the selection of the two physical I chemical processes for demonstration. In short-term tests, the processes produced effluents meeting the radium-226 target activities."

Jan 1, 1980