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By Gaballah I.

Elimination of arsenic, mercury and zinc from synthetic solutions containing H;\A.sD4. HgCI2 and ZnCI2 using modified barks was investigated. The pH range was varied from ?1 to 10. The initial concentrations of individual element were 10,100 and 1000 ppm. More than 99 % of mercury and 65 % of zinc cations were removed by the modified bark .. In this case, the modified bark reacts as a cation exchanger leading to the release of ' two protons for every HgII or ZnII fixed by this material. About 30 % of arsenic was eliminated from the solution. This 'low efficiency could be attributed to? the presence of arsenic ,as. anion. Decontamination of a treated industrial effluent containing 4 ppm of ion? metals was performed on a pilot plant scale by the modified bll(k. More than 70'% of these ion metals were eliminated.

Jan 1, 1995

By I. Gaballah

Decontamination of synthetic solutions of copper acetate, chloride, nitrate and sulfate containing 10, 100 and 1000 ppm of copper, using chemically treated barks has been studied. Metal percent removal from solutions depends on the pH and the initial concentration and to some extent on the salt used. It varies from 40 to 99 % of the solution initial metallic ion's content. The maximum retention capacity of the treated bark varies from 31 to 43 mg of Cu per gram of dry modified bark. Bark loaded with copper had been analysed by Scanning Electron Microscopy and lnfra Red spectroscopy. Cu is uniformally distributed in the bulk of the bark. No copper segregation is observed. It seems that copper is bound to the acidic sites of the bark. Anions are not detected on the copper loaded bark neither with the SEM or with the IR spectroscopy.

Jan 1, 1993

By Jeffrey W. Fergus, Shiqiang Hui

"Aluminum is an important alloying addition to the zinc used in the hot-dip galvanization of sheet steel to control the properties and appearance of the resulting coating. Optimization of the galvanization process requires control of the alloy concentration which can be improved through the use of chemical sensors. Aluminum sensors based on molten electrolytes are commercially available but are not widely used because of their high cost. One approach to reducing the cost is to use a solid electrolyte which can simplify the sensor design and thus reduce the cost of fabrication. In this paper, the development of an aluminum sensor based on a solid fluoride electrolyte, specifically magnesium fluoride, will be described.IntroductionThe concentration of the zinc bath used in hot-dip galvanization affects the galvanization process as well as the properties of the resulting coating. Thus, accurate in situ measurement of the alloy composition can be used to improve process control. This paper describes a solid-electrolyte-based aluminum sensor for monitoring the bath composition during hot-dip galvanization."

Jan 1, 1997

By W. K. Choi

Stainless steel exposed to wet environments at ambient temperature is subject to the formation of a surface biofilm. Depending upon the prevailing environmental conditions (dissolved oxygen, pH, Eh, concentration of cationic/anionic species), the biofilm may stimulate corrosion through formation of differential aeration zones and concentration cells. Corrosion significantly impacts the United States economy, since on a yearly basis, corrosion induced losses are estimated to be over $200 billion. A large portion of this corrosion is imputable to bacterial activity, and basic information is needed for a better understanding and control of the biocorrosion phenomenon. The present study has investigated the influence of Thiobacillus ferrooxidans in the corrosion of American Iron and Steel Institute (AISI) 304, 316 and 416 stainless steel samples. The formation of biofilm and microstructural changes on the surface of stainless steel samples and their weldments were assessed by microscopic examination, and the changes in the mechanical properties by stress-strain measurements. The significance of the results will be discussed.

Jan 1, 1993

By Tetsuya Uda, Sakae Shirayama

"With the aim of producing nickel (Ni) metal directly from acidic aqueous solution containing cobalt (Co) and other impurities, selective reduction of Ni was examined. As a preliminary experiment, sodium hypophosphite monohydrate (NaH2PO2·H2O) was selected as a reductant, and reacted with aqueous solution containing 0.1 mol L-1 nickel sulfate (NiSO4·6H2O) and 0 ~ 0.05 mol L-1 cobalt sulfate (CoSO4·7H2O) for 3 hours at 90 °C. As a result, it was revealed that Ni was selectively reduced and separated from Co in the acidic region (pH= 4.8). In this study, differences of reduction behavior between Ni and Co were investigated, and the feasibility of Ni I Co separation by the selective reduction of Ni was discussed.IntroductionEfficient Ni condensation and separation from Co are essential in nickel hydrometallurgical processes. Currently, the hydrometallurgical production of Ni from oxide ore is mainly carried out by acid leaching at elevated temperature, followed by the removal of impurities using neutralization, and condensation of Ni and Co into intermediate products such as hydroxides and sulfides. Then, the intermediate product is dissolved in acid aqueous solutions, and Ni I Co separation is conducted by solvent extraction. Finally, Ni and Co are recovered by electro-winning. This complicated process consumes large amounts of alkali, hydrogen sulfide (H2S), and organic solution in a multiple-staged process'. To reduce the consumption of these chemicals, it is important to recover Ni more efficiently from acidic aqueous solution containing impurities."

Jan 1, 2014

By Zhang Jianliang, Xu, Zuo, Runsheng, Haibin, Kexin, Jiao

Full oxygen blast furnace iron-making is one of the new technologies, which is most likely to realize large-scale application. In this paper, based on the technology of full oxygen blast furnace, the reduction behavior of pellets is studied systematically by using the analytic method of non-isothermal dynamics on the different atmosphere(CO,H2) and the dynamics model of gas-solid reduction reaction is constructed, which lay the foundation of reduction model establishment of full oxygen blast furnace burden. The result shows that the time of pellets which began to react is delayed with the increase of the content of H2. When the temperature is between 650 'C and 1050 'C, the content of H2 in the reduction atmosphere is larger, and the rate of the reduction pellets is larger. The reduction rate changes at 780 'C, and a certain amount of H2 in the reducing atmosphere will significantly improve the reduction reaction when the temperature is above 780 'C. Non-isothermal reduction behavior is controlled by interfacial chemical reaction and internal diffusion under high reduction potential. H2 ratio in reducing atmosphere increased from 0% to 100%. The reduction reaction of the apparent activation energy decreased from 49.03kJ-mor1 to 33.74kJ·mor1.

Jan 1, 2013

By R. G. Reddy

The Margules .equation is used for interpreting excess Gibbs energy of several ternary systems. In the present study activity coefficient of 'a dilute solute, 2, in a binary solvent 1-3 was derived. The derived expression is used to interpret logarithmic activity coefficient of oxygen and sulfur in several metallic systems. Self interaction parameter of the solute is derived from the partial function of solute using constant compositional path. An expression for logarithmic activity coefficient and self - interaction parameter of solute is also derived using Maclaurin infinite series. The derived equation is based on Maclaurin infinite series used successfully to deduce thermodynamics of self interaction of oxygen as a interstitial atom in two metallic systems. The predicted thermodynamic parameters values using Maclaurin infinite series and Margules. equations, are in excellent agreement with the experimental data and also our predictions are far more accurate than the predictions made by other models.

Jan 1, 1996

By Cang Daqiang, Bai Hao, Li Ning, Liu Xueting, Lu Xin, Zhao Lihua, Li Hongxu, Wei Wei

"Based on the principle of carbon balance, a model was built to calculate C02 emissions of each process and correspondingly the total course of production in iron and steel making. The data from a typical integrated steelworks in China was applied in the model. The results show that the BF and coking process account for the most emissions. Generally, C02 emissions in integrated steelworks depend on three factors, resources utilization efficiency, energy utilization efficiency and energy consumption structure, which were considered in an equation in this paper. Especially, General Emission Factor (GEF) was proposed to assess the relationship between C02 emissions and energy consumption. The results show that, higher GEF will result in more C02 emissions with the same energy consumption and in iron and steel making, the optimization of energy structure and development of eco-industrial park both have significant benefit on the carbon reduction.IntroductionThe Global Warming resulting from the increase of Greenhouse Gases (GHGs), especially C02, in the atmosphere has become the main reason of global climate change, and the carbon reduction is one of the most important ways for the sustainable development [1]. The iron and steel making is a manufacturing industry based on iron-coal high temperature chemical process, in which plenty of C02 is emitted. According to the data from IPCC (Intergovernmental Panel on Climate Change) in 2001, iron and steel making emitted about 650 million tons ofC02 every year, which is the fourth largest industry of the fossil energy consumption [2]. According to the data from EEA (European Enviromnent Agency) in 2006, iron and steel making is the largest source ofC02 emissions, which accounted for about 18% of the total C02 emissions in European manufacturing industry [3].It is estimated that the application of various well developed energy-saving technology, such as Coke Dry Quenching (CDQ), Top Pressure Recovery Turbine (TRT) and Coal Moisture Control (CMC), can make the C02 emissions reduced by 0.5%-3% in iron and steel making, and the further C02 emissions reduction can be achieved if more new energy saving technology is applied, such as sintering plant heat recovery, electricity generation with steam generated from converter and the various by-products gas and the hydrogen making process from COG[4,5]. In addition, the application of membrane separation technology is well expected in iron and steel making [6]. For example, the application of C02 Capture and Storage (CCS) in blast furnace combined with the Pure Oxygen Top Gas Recycled BF (TGRBF) technology can reduce the C02 ennss10ns greatly by about 50%-60% [4].That is, as a kind of C02 end-treatment technology, CCS applied with other technology of C02 recovery would be more meaningful. Actually, reduction of the C02 emissions by changing the structure of energy consumption and raw materials with new process of iron and steel making, such as direct reduction process or smelting reduction process [4,7,8], is the trend of ferrous metallurgical engineering, which is regarded as a kind of source-treatment technology. In this sense, source-treatment technology is more pivotal for the solution of carbon reduction in the future than the current popular energy saving technology. Hence, it is necessary to build the C02 emissions model based on the iron and steel making process and evaluate the relationship between the energy saving and C02 emission reduction."

Jan 1, 2012

By S. Seetharaman

The present paper presents. the concept of micro-models and illustrates the application of the same in the simulations metallurgical processes. Development of micromodels requires access to accurate thermodynamic, thermophysicaland kinetic information for the relevant systems with suitable models to extrapolate the data as functions of temperature and composition. Experimental measurements and modelling of the thermodynamic properties, sulphide capacities and viscosities of oxide melts carried out in the department are presented. The incorporation of these models in process models, with special reference to ladle refining of steel is illustrated. Typical example of micro-modelling of solid-gas reactions is also presented.

Jan 1, 1999

By S. R. Reddy, R. G. Reddy

"The Margules equation is used for interpreting excess Gibbs energy of several ternary systems. In the present study activity coefficient of a dilute solute, 2, in a binary solvent 1-3 was derived. The derived expression is used to interpret logarithmic activity coefficient of oxygen and sulfur in several metallic systems. Self interaction parameter of the solute is derived from the partial function of solute using constant compositional path. An expression for logarithmic activity coefficient and self - interaction parameter of solute is also derived using Maclaurin infinite series. The derived equation is based on Maclaurin infinite series used successfully to deduce thermodynamics of self interaction of oxygen as a interstitial atom in two metallic systems. The predicted thermodynamic parameters values using Maclaurin infinite series and Margules equations, are in excellent agreement with the experimental data and also our predictions are far more accurate than the predictions made by other models.1 IntroductionIn most of the pyrometallurgical high temperatures processes, interactions of solutes such as oxygen, nitrogen and sulfur, with the solvent atoms are most important during refining processes. There are numerous theories are developed [1-25] to interpret the thermodynamics of solutes in multicomponent alloy systems. Which are mainly developed using statistical or Quasichemical equations.Wagner [4] developed one energy parameter ideal solvent model based on activity coefficient of solutes compositional dependency. He used one energy interaction term which is not able to account for interaction energy parameters for the same solute concentration at different solvent compositions and also it is ineffective model to predict for strong interacting systems."

Jan 1, 1996

By Charles A. Sorrell

Two red muds, two fly ashes, and several aluminosilicate minerals were subjected to direct treatment with concentrated H2SO4 at temperatures of 175°C and below. X-ray analysis showed that virtually all the sulfate reaction products remained in the solid residue because of their low solubilities in x SO Substantial portions of the Al2O3 Fe2O3TiO2, Na2O, and K2O components of the materials reacted to form water soluble sulfates, which were then removed by H2O leaching at 55°C. The solid residue after water leaching consisted largely of amorphous silica and, in lime bearing compounds, CaSO4, The reaction and leaching processes were effective in removing all or nearly all the Al2O3. Fe2O3, TiO2, Na2O, and in lime components in the fly ashes, red muds, china clay, bentonites, the nephelioe fraction of nepheline syenite, and a plaster insulating brick composed of anorthite and mullite. Reaction with potassium feldspar and petalite took place, with formation of alkali aluminum sulfates, but the reaction rates and yields were extremely low. Potassium feldspar can be heated with Na2O and x O in air at 700°C for 24 hours, or with CaO at 1000°C for 24 hours, after which the reaction product kaliophilite, nepheline, and leucite-like phases, prove to be very susceptible to H2SO4, reaction and H2O leaching, providing yields near 100% of the Al2O2 content. An alternative method of H SO treatment consists of heating the sample in a silica tube and passing H2SO4 vapor over it. Preliminary results indicate that this method can be effective in enhancing the kinetics of reaction with the Al O component of potassium feldspar and offer the possibility that formation of Al2 (SO ) Fe2(SO4)3 and TiOSO4 can be accomplished selectively by taking advantage of the fact that the upper stability limits of the respective sulfates in the presence of H2SO4 vapor will be different.

Jan 1, 1982

By P. N. Anyalebechi

"The as-cast microstructure of two commercial-size ingots of aluminum alloy 3004 produced by the electromagnetic casting process was quantitatively characterized. This involved the quantitative determination of through-thickness and across-width variations in dendrite cell size, grain size, macrosegregation of alloying elements, interparticle spacing, and the types, volume fractions, and sizes of the constituent or second phase particles. More than ninety-five percent of the constituent phases in the ingots consisted of the A16(Mn,Fe) phase; the desirable a-Al 12(Fe,Mn)3Si phase was not detected in any of the ingots by Guinier X-ray diffraction analyses or electron probe X-ray microanalyses. A significant microstructural heterogeneity through the thickness and across the width of both ingots was observed. For example, macrosegregation, and the sizes of the constituent phase particles, dendrite cells, and grains increased concomitantly from edge to mid-width and from surface to center of the ingots. There was a -20% depletion (negative macrosegregation) of Mg and a +54-87% enrichment (positive macrosegregation) of Ti in the center of the ingots. With the exception of grain size, there was no significant microstructural difference between the two ingots examined. The causes and practical implications of the observed microstructural heterogeneity in the ingots are discussed.IntroductionThe first step in the fabrication of majority of wrought products of aluminum and its alloys is the casting of large ingots or billets of simple shapes (round or rectangular). The sizes of the ingots vary from 10 mm to 450 mm diameter or 25 mm to 780 mm thick. The quality of the finished products is established at the ingot casting stage. This is because the microstructural characteristics, such as secondary dendrite cell size or arm spacing, amount of alloying elements retained in solid solution, macrosegregation, and the characteristics of second phases, produced during casting cannot be reversed by subsequent processing. Up until twenty-five years ago, the effect of as-cast microstructure of large ingots on the structure and behavior of thin sheets (0.34 mm thick) during drawing and ironing processes was incorrectly assumed to be minimal or nonexistent. This was based on the erroneous notion that the thermal treatments and large reduction (>99.94%) and strain that the ingot undergoes during production of the sheets completely destroys the original ingot structure and its inherent heterogeneity. However, the effects of ingot structure can, a priori, be deduced from the observed effects of constituent phase particle size, type and volume fraction on recrystallization, development of texture during annealing and deformation, and earing. In fact, careful examination of the behavior of products produced from different size ingots or castings have shown that the original microstructure of the ingot has a direct impact on the properties and performance of the end products."

Jan 1, 2011

By Pertti Koukkari, Nagendra Tripathi, Karri Penttilä, Justin Salmine

ChemSheet is a thermodynamic multi‐phase multi‐component simulation software, which is used as an Add‐in in Microsoft Excel. In ChemSheet, the unique Constrained Gibbs free energy method can be used to include dynamic constraints and reaction rates of kinetically slow reactions, yet retaining full consistency of the multiphase thermodynamic model. With appropriate data, ChemSheet models can be used to simulate reactors and processes in all fields of thermochemistry. The presentation will cover off‐line modeling of Cu‐flash smelters and advanced thermochemical simulation coupled with on‐line process control of Cu‐Ni smelting. The presentation will describe an off‐line model of Cu‐smelter based on critically assessed properties of the Al-Ca-Cu-Fe-O-S-Si –system (slag, matte and liquid metal) by using the quasichemical model. A four‐stage reactor model (shaft, settler, uptake and bath) is used for optimizing process parameters and feed particle distribution. As a second example, an advanced thermochemical model of a Ni-Cu sulphide smelting plant will be given. The on‐line model covers the operation of treating Ni-Cu-S concentrate via roasters, electric furnace and converters, producing a high grade Bessemer matte product for further refining. The model integrates the thermochemistry of the roasters and electric furnace, and predicts important process parameters such as degree of sulphur elimination in the fluid‐bed roasters, matte grade, iron metallization, slag losses and the iron to silica ratio in the electric furnace slag. Both models can be used to assist process engineers and operators in calculating the addition rates of coke, flux and air for different feed scenarios.

Jan 1, 2014

By Bingchen Chen, Zhitong Sui, Junwei Ma

"In the blast furnace slag, titanium disseminated in various mineral phases Titanium could be concentrated mainly in perovskite, which could be selectively precipitated and grown by optimizing the operation factors like the slag composition, temperature of heat treatment and additive agents. This study aims at establishing the titanium slag mineralogy and its distribution in the treated slag and the as-received slag, as well as the methods of perovskite separation. After heat treatment, the grain size was grown from 5 - 20µm to 80 - 200µm, the distribution of Ti02 in perovskite was increased from 48% to 81 %, the morphology was changed from snow-shaped grain to coarsening dendrites or equiaxed crystals. A concentrate were produced by gravity separation analyzing 35.25% Ti02 with a recovery of 68.28% and a tailing analyzing 9.53% Ti02 , and a possibility of flotation upgrading was discussed. I INTRODUCTION CHINA is rich in mineral resources of titanium, 92.4% of which is vanadium-titanium bearing magnetite. About 53% titanium were in iron concentrate after mineral processing, by which the blast furnace slag containing about 25% TiO2 were produced[11 • The content of TiO2 in such slag is too low to separate titanium dioxide, and it is also too high to produce slag cement[21. It has been accumulated to 50 million tons so far, which is still increasing at a rate of 3 million tons per year, and results in a waste of titanium resources and pollution of environment. Due to the dispersed distribution of titanium component in various mineral phases, very fine grain(<10µm) and complex interfacial combination, it is very difficult to recovery titanium component from the slag by traditional separating technique. In this paper, a novel technique to recovery titanium from the waste slags was proposed [3H4l, on which three continuous processes were involved: selective concentrating, selective growing and selective separating. Perovskite was designed as a titanium-rich phase, in which the most titanium was concentrated promptly, then perovskite could be selectively grown and coarsened by optimizing the heat treatment and the appropriate additives [ 5l[6l. The grain size of perovskite phase was larger than 80 µm, and the crystals appeared as coarsening dendrites or equiaxial grains like lump."

Jan 1, 2000

By W. K. Connor, O&apos

The Bureau of Mines has conducted beneficiation, carbothermic reduction, and leaching tests of Mn oxide ores as part of its evaluation of the Mn and Co resources of the West- Central Arkansas District. The major Mn oxides in the ore include cryptomelane, psilomelane, pyrolusite, and lithiophorite. Cobalt is contained within the Mn oxides. Nonbeneficiated ore was reduced at 800&apos; C with coal and leached in ammonium sulfate and ammonium carbonate leach liquors. Ore concentrates were calcined at 600" C prior to reduction under the same conditions as the raw ore. Head analyses reported up to 21 ptt Mn and 0.11 pct Co. Extractions of 70 to 90 pct Mn and 40 to 60 pct Co were achieved.

Jan 1, 1992

By E. Açma

Sivas-Divrigi flotation plant has a capacity of 90,000 tpy. Beneficiation of the tailings of iron ore magnetic separator seems to be attractive, because of its Cu, Co, and Ni contents. In the experimental work, sulfidic flotation concentrate is produced from these tailings. A roasting-leaching-H2S precipitation procedure is used to treat this concentrate, containing 0.55% Cu, 0.51% Co, 0.74% Ni, and 0.027% Zn. Sulfatizing roasting is carried out in a rotary furnace at 690°C. Roasted product is leached with 10 gpl HzSOl at 70°C and 30% pulp density. For the precipitation of desired metal, H2S is bubbled through the concentrated solution of repeated leaching, under controlled temperature and pH. Final metal recoveries of 91% Cu, 91% Co, and 50% Ni, and 92% Zn are attained. Roasting gases with their 13% SO2 content are suitable for H2SO4 production and the leach residues can be integrated with the iron ore processing plant as they contain 57.4% Fe and very low non-ferrous metals.

Jan 1, 1993

By M. L. Apel

A conceptual approach to the bioremediation of uranium mill tailings (UMT) is presented., This approach focuses on, biosorption to remediate the. effluent solution and bioleaching remediate the. solid fraction. Comparative biosorption studies were performed with synthetic single metal solutions using a commercially available biopolymer. The maximum rate of metal sorption by calcium alginate was found to be 5.43, 6,39, 6.48, and 9.74 mg dm-3 min-1 for U022*, Ba2+, Cd2+ and Zn2+, respectively. Activation energy (AEa) for barium uptake by calcium alginate beads was determined to be 11.5 kJ, indicating a diffusion controlled reaction mechanism. Thermodynamic values (AG+ AH+ and ASt) of the metal-alginate activated complex, as reported in the literature, were found to be in agreement with those calculated from this research. Results show that this biopolymer can be effectively applied in the removal of select metals prevalent in uranium mill tailing effluents and associated waste streams.

Jan 1, 1991

By Jun Li, Lin Chen, Tian-zu Yang, Wei-feng Liu, Wan-da Bin

"The Chinese bismuth production accounts for more than 80% all over the world in 2011. The main raw materials of bismuth smelting are bismuth concentrate and by-products of Cu or Pb smelting process. Many traditional methods of bismuth smelting in china was reviewed in this paper, such as reverberating furnace smelting, blast furnace smelting, fire-refining, ferric chloride leaching-hydrolysis, slurry electrolysis, and so on. But all the traditional pyrometallurgy or hydrometallurgy process have such shortages of low recovery, poor environment, and high cost. Therefore new technologies are introduced into the smelting process of bismuth concentrate, such as low-temperature alkaline smelting and side-blown bath smelting with oxygen-enrichment. These technologies have got great progress on energy saving, emission reduction, and friendly environment. Finally the development direction of new technology on bismuth smelting was prospected.IntroductionAs a green metal, bismuth has a wider applications, just extending from the traditional medicine, metallurgical-chemical engineering, low-melting alloys, solders, catalyst, and electronics to cosmetics, flame retardant, storage battery, semiconductor, supper conductor and nuclear energy etc[1,2,3,4,5,6,7]. This will increase the production of bismuth and promote the development and progress of bismuth smelting technology. At present, The major bismuth-product countries are China, Mexico, Peru, KZ, Bolivia and Canada etc, and China are dominating. A survey from the USGS[8] showed that Chinese bismuth production were 12,500 tonnes and got 80% of the world's in 2011. Thus the technology of Chinese bismuth smelting have a great representativeness."

Jan 1, 2013

By Mingchun Lu, Yunjin Yan

"This paper describes a new type of bell-less top installed on two relined blast furnaces at Tianjin Iron Works and another new-built at Echeng Steel Works in China. A compact installation was presented for existing furnace top innovation with the least reformation of existing top structure. A water cooling and sealing gearbox used for driving the chute discards completely the traditional idea about necessity of continuous supply of cooling gas for the gearbox. A multiring spreader and its dozens of selectable charging patterns enables an operator to achieve optimal burden distribution easily under the condition of a minimum investment of control equipment. Some useful conclusions have been made through a small-size model and a full-scale model tests. The excellent characteristics and the superiority of the new top have been fully proved at both works.IntroductionIt is known that there are some advantages with the bell-less top of a blast furnace: suitable for furnace to operate at high top pressure, capable of realizing optimal burden distribution, less investment and maintenance costs, etc. But why do most of blast furnaces in the world still remain using conventional bell top. One of the concerns is that current bell-less tops still have some shortcomings:1) The height of a current bell-less top might be lower than three or four-bell top or two-bell plus valve seal top, but still much higher than an ordinary two-bell top.2) The gearbox for driving the rotating chute is positioned onto the lip of the furnace. It is subject to attack by crude hot bf gas. Continuously pumping cooling gas (pressurized nitrogen or clean bf gas) into the gearbox is indispensable to withstand such a harsh working environment. Therefore, a plant furnished with blower8 and its ancillaries has to be built, It involves a large sum of investment and much expense in its annual running costs.3) Although the current bell-less charging device as a means of controlling burden distribution possesses a wide range of freedom, it is difficult to realize optimal burden distribution. There are some large blast furnaces realized better burden distribution, but sophisticated control means is indispensable so that the investment of control means is much higher."

Jan 1, 2000

By P. Lussiez

Precipitates consisting of amorphous ferrihydrite and crystalline goethite have been prepared by aging hydrolyzed Fe (III) solutions at room temperature. The precipitates have been characterized by x-ray diffraction and differential thermal analysis. The amorphous ferrihydrite transforms to goethite with time. The ferrihydrite to goethite transformation is affected by the presence of small amounts of copper or nickel coprecipitated with the iron. .The addition of copper decreases the amount of goethite at a given aging time and increases the amount of coprecipitate which is initially dissolved in sulfuric acid, but it does not seem to affect the dissolution of the crystalline part&apos;. It is proposed that adsorption of copper hydroxo species on goethite nuclei delays the ferrihydrite to goethite transformation. The effect of nickel is less dramatic than that of copper. Apparently a portion of the added nickel is adsorbed on the goethite crystallite surface rather than incorporated into the goethite lattice.

Jan 1, 1981