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By G. S. Scott, G. W. Jones, F. E. Scott

An important activity of the Bureau of Mines is the promotion of safety in mining and industry . In connection with these activities , the Bureau determines the explosion hazards of combustible gases , liquids , and solids , and investigates means by which explosions may be eliminated or reduced in violence . The limits of inflammability and ignition temperatures of combustible gases , vapors , and solids are of practical importance because such materials can be manufactured , transported , and used with greater safety , provided the range of concentrations and temperatures that cause explosions are known. Acetic anhydride , ( CH3CO) 20 , with which this report is concerned , is a liquid at ordinary temperatures . It is used in the preparation of a number of organic chemicals and in the manufacture of photographic film and of artificial silk . It is perhaps the most important acetylating agent for industrial uses - a property that is especially important at this time because of its direct application in the manufacture of munitions . The sample tested was supplied by the Carbide & Carbon Chemicals Corporation . Its specific gravity was given as 1.083 at 20/20 . The vapor pressures , supplied by the manufacturer , are plotted in figure 1 .

Dec 1, 1943

By Robert P. Vinson

The U.S. Bureau of Mines evaluated a light-scattering technique for discriminating between spherical and nonspherical particles. This evaluation was a three-step procedure. The first step required collecting light-scattering data for a variety of particles. This was accomplished with a particle analyzer called the DAWN-A. The DAWN-A measured the scattered light intensities of individual particles at a forward scattering angle of 40°. These DAWN-A measurements of individual particles are called scattering signatures by the Bureau researchers. The second step in this evaluation was to calculate a sphericity index number using the scattering signatures produced by the DAWN-A. The sphericity index number can range from 0 to 1. A calculated sphericity index of 1 would show that based on the intensity of scattered light, the particle was a perfect sphere. The third and final step of this evaluation was the comparison of the calculated sphericity indices of the various particles. Comparing these indices made it possible to discriminate between the nearly spherical waterdrops and the nonspherical coal and rock dust particles.

Jan 1, 1993

By M. P. Ristenbatt, E. K. Holland-Moritz, K. Metzger

A new post-disaster signalling system for the Bureau o Mines, using through-the-earth EM propagation, was successfully field-tested in the Lake Lynn test mine. Successful detection at an estimated input SNR of -30dB was accomplished using a coherent integration time of 4.46 minutes. The transmitted waveform consisted of a repeating pseudonoise maximal length sequence phase modulating a 1950Hz carrier. The receiver used a sliding-window matched filter, optimal for signal known exactly except for phase and starting time, implemented via a special purpose processor. Parallel processing permits adaptive signalling, where the detection (integration) time is determined by the actual input SNR encountered. This field test demonstrates a trapped miner detection system that is about 36dB more sensitive than a current pulsed system. This increased sensitivity permits some desired combination of increased range, shorter detection time, and reduced transmitter power or antenna-size. The combination of pulse-compression-type-signal, coherent integration, parallel-processing, and output peak-detection algorithms permit implemention of an ultra-reliable detection system. The same combination is compatible with digital Pulse Position Modulation and Emitter position location strategies.

Jan 12, 1983

By Kihong Park

A hygroscopicity tandem differential mobility analyzer (HTDMA) technique is used to determine size-effect of nanoparticles (NaCl, (NH4)2 SO4, KCl, NH4NO3, MgCl2,CaCl2) on their hygro­scopic properties (deliquescence relative humidity (DRH) and hygroscopic growth factor (GF)). The HTDMA system uses a combination of two nano DMAs and two regular DMAs to measure particle size change in a wide dynamic particle size range. Particles are subsequently analyzed with a transmission electron microscopy to investigate the potential effect of particle structure or morphology on the hygroscopic properties. We found that structural properties of NaCl and (NH4)2SO4 particles also play an important role in determination of the DRH and GF and are more pronounced at smaller diameters. Data show that the DRH of NaCl nanoparticles increased from *75% up to *83% RH at 8 nm and that their GF decreased with decreasing size. The extent to which the GF of NaCl nanoparticles decreased with decreasing size was greater than theoretically predicted with the Kelvin correction. The GF of furnace-generated NaCl nano­particles that have pores and aggregate shape was found to be smaller than that of atomizer-generated particles that are close to perfectly cubic. For the case of atomizer-generated (NH4)2SO4 nanoparticles, we observed no signi?cant size-effect on their DRH, and the measured GF agreed well with predicted values using the Kelvin correction. For furnace-generated (NH4)2SO4 nanoparticles, a gradual growth at moder­ate RH without noticeable deliquescence behavior occurred. Their TEM images showed that contrary to atomizer-generated (NH4)2SO4 nanoparticles the fur­nace-generated (NH4)2SO4 nanoparticles are not perfectly spherical and are often aggregates having pores and holes, which may favor holding residual water even in the dried condition. For atomizer-generated KCl, MgCl2, and CaCl2 nanoparticles, we observed no signi?cant size-effects on their DRH and GF for the mobility size as small as 20 nm.

Jan 1, 2008

By K. R. Farley

A simplified method for the atomic absorption determination of antimony is described. Samples are dissolved in hydrobromic acid and diluted to volume with water. Solutions can be ready for analysis in about 10 minutes and are stable for at least 24 hours. The spectral line at 231 nanometers is used, and there is no effect on absorption resulting .from the presence of any concentration of HBr. Absorbance is linear with antimony concentrations up to 120 micrograms per milliliter. Sensitivity is 1.48 micrograms per milliliter per 0.0044 absorbance. Relative errors on National Bureau of Standards Standard Reference Materials were 3 percent or less, and relative standard deviations on 12 determinations of each of three flue dust samples were 4 percent or less (95-percent confidence limit).

Jan 1, 1980

By Kenneth L. Rubow, Virgil A. Marple, Bruce K. Cantrell

"In a cooperative study by the University of Minnesota and the U.S. Bureau of Mines, diesel exhaust and mineral dust concentrations have been measured for aerosols generated in the laboratory and in five underground coal mines. Three mines utilized diesel-powered haulage equipment and two used all-electric equipment. Two source apportionment techniques have been applied to differentiate between the mineral dust and diesel exhaust aerosol concentrations measured. The first technique, using a micro-orifice, uniform deposit impactor (MOUDI) for size selective sampling, is based on modeling aerosol size and the premise that the diesel exhaust portion of the aerosol is predominantly submicron and the mineral dust portion is mostly greater that one micrometer in size. The second technique, Chemical Mass Balance (CMB) modeling, was used to referee the analysis of diesel exhaust and mineral dust aerosol concentrations from the size selective sampling results.The MOUDI size distribution data were modeled to obtain parameters describing the fine and course fractions of the sampled aerosol and to estimate the contributions to each mode from both mineral dust and diesel exhaust aerosol sources. The results showed the size distribution of the mixed aerosols exhibited two definite modes with the minimum between the modes occurring at 0.8 µm. Less than 5 pct of the coal mine diesel aerosol was found in the coarse size fraction. CMB analysis confirms the original premise for using aerosol size to separate diesel exhaust and mineral dust aerosol during sampling.Based on the results from the size selective sampling, a personal diesel aerosol sampler has been developed for measuring diesel aerosol mass concentrations. Th.is sampler uses an inertial impactor to size separate the respirable aerosol at 0.8 µm. All material less than 0.8 µm is collected on an after filter for subsequent gravimetric analysis."

Jan 1, 1990

It is suggested in chapter 1 that emergency activities (including escape) are not individualistic. They tend to be group responses. If escapes from mine fires are group activities, then preparation for such events must take group behavior into account. This chapter explores the hypothesis that the miners who escaped from the three mines under study did so as members of groups. For development of this chapter, the database was examined for evidence of the existence of escape groups and for instances when individualistic behavior was paramount. Illustrations of group and/or individualistic behavior were analyzed and representative examples are provided in the following discussion. The nature of groups was discussed in chapter 3 and the following working definition was offered: "We mean by a group a number of persons who communicate with one another often over a span of time, and who are few enough so that each person is able to communicate with all the others, not at second-hand, through other people, but face-to-face" [Homans 1950]. To determine whether or not groups existed during the fire evacuations, it is important that the concept of group be clearly defined. Therefore, the discussion started in chapter 3 will be elaborated here. The defining characteristics of group given in chapter 3 were taken from Homans [1950]. They include size, person-to-person com¬munication, feelings that members have for each other, explicit and implicit rules for behavior, and common activities. An additional characteristic that is sometimes used to define groups is cohesiveness. Kiesler and Kiesler [1970] state, "Cohesiveness would include not only the attraction that the group holds for its members but also any other force operating on the individual to stay in the group." Variables said to contribute to cohesiveness include "(1) the attractiveness of a group for its members," and "(2) the coordination of the efforts of the members" [Keisler 1970]. One source of the attraction to a group occurs when "the goals or exterior tasks confronting the group are consistent with those of the individual person, and can best be handled by group action" [Cartwright and Zander 1968, in Davis 1969]. In other words, a common goal and a coordinated effort mounted to achieve that goal contributes toward the creation of a cohesive group. As discussed in the earlier review of research (chapter 1), groups have frequently been studied in laboratory or simulation settings. These methods allowed control over variables of interest. Kiesler and Kiesler [1970] state, however, that they "find group variables conceptually imprecise and experimentally difficult to work with." Experimental control, in other words, is difficult to achieve in the study of groups. The richness of the naturalistic mine fire data may provide an opportunity for an examination of groups that cannot be found in laboratories or simulations because this environment was not

Jan 1, 2000

By P. A. Bloom

Arsenic-containing flue dusts are currently being stockpiled by several nonferrous smelters in the United States. These stockpiles are a source of environmental concern since the dusts can be transported by wind and contain water-soluble arsenic. The stockpiles also represent an alternate source of metals. To provide a quality environment, the Bureau of Mines investigated a process to make environmentally acceptable the discard of arsenic obtained from the treatment of arsenical flue dust. The process includes (1) leaching arsenic from a lead smelter copper dross flue dust, (2) fixing arsenic as an insoluble compound, and (3) recovering other metal values. Overall results of acid-leaching tests on lead-smelter flue dusts showed that H2S04 dissolved 80 to 90 percent of the As, Zn, and Cd, and up to 86 percent of the In. Pb, Ag, and Au remain in the residue, which can be recycled to the smelter. Indium was recovered from the strong acid leach solution by solvent extraction; arsenic was fixed in a stable form by precipitation with Fe2(S04)3 and CaO or CaC03.

Jan 1, 1982

By T. M. Ruff

A prototype mucking machine designed to operate in narrow-vein stopes was developed by Foster-Miller, Inc., Waltham, MA, under contract with the U.S. Bureau of Mines. The machine, called a compact loader-trammer, or minimucker, was designed to replace slusher muckers in narrow-vein underground mines. The minimucker is a six-wheel-drive, skid-steered, load-haul-dump (LHD) machine that loads muck at the front with a novel slide-bucket system and ejects it out the rear so that the machine does not have to be turned around. To correct deficiencies of the tether-remote-control system, a computer-based, radio-remote-control system was retrofitted to the minimucker. Initial tests indicated a need to assist the operator in guiding the machine in narrow stopes. An automatic guidance system that used ultrasonic ranging sensors and a wall-following algorithm was installed. Additional tests in a simulated test stope showed that these changes improved the operation of the minimucker. The design and functions of the minimucker and its computer-based, remote-control system are reviewed, and an ultrasonic-sensor-based guidance system is described.

Jan 1, 2010

By G. L. Oldright, John D. Sullivan

"The present article is the second of a series of papers dealing with the dissolution of copper minerals in various reagents. Work done on the problem has been carried out at the Southwest Experiment Station of the United States Bureau of Mines, in cooperation with the Department of Mining and Metallurgy, University of Arizona. The first paper4 dealt with the dissolution of azurite, malachite, chrysocolla, and tenorite. Preceding articles5 have also dealt with other factors involved in the leaching of copper ores.Cuprite (Cu20) is usually considered as a mineral which is not adaptable to sulphuric acid leaching. Hofman,6 in describing leaching by sulphuric acid, states: ""Cuprite is decomposed into CuO and Cu; and ore carrying cuprite has to be oxidized (weathering, roasting) before treatment."" Greenawalt7 says: ""When acted upon by dilute sulphuric acid, it is partly reduced to metallic copper and partly oxidized into copper sulphate. When heated with strong acid it is entirely oxidized to sulphate."" Work to be described in this article was undertaken to ascertain the conditions whereby all the copper in cuprite could be converted into the soluble sulphate."

Dec 1, 1929

By A. R. Taylor

Using solution calorimetry, the following heats of reaction were determined: (1) NaCN(c) + 1/Cu20(c) + 129H20(l) ? CuCN(c) + NaOH?128.5H2O ?H = -13.44±0.10 kcal/mole, (2) HCN(2) + NaOH?128.5H20 ? NaCN(c) + 129.5H20(l) ? = -2.52±0.02 kcal/mole. From these reactions, the heats of formation for CuCN(c) and HCN(2) were calculated to be 22.7±0.4 kcal/mole and 24.9±0.4 kcal/mole, respectively. Reaction 2 was made to check the consistency of literature values for heats of formation of HCN and NaCN. Adiabatic calorimetric measurements between 10° and 400° K showed the entropy and heat capacity of CuCN(c) to be 21.51±0.06 eu and 14.58±0.04 cal/mole deg, respectively, at 298° K. A broad anomaly in the heat capacity was found in the temperature range 285°-320° K. The heat of transition associated with this anomaly was less than 1 cal/mole, the sensitivity of the measurements.

Jan 1, 1971

Validate the premise that there is measurable seismic activity associated with abandoned mint lands and that this activity can be used to determine stability of the abandoned mine openings, failure cycle of these openings, and susceptibility of the area to surface subsidence. Approach The U.S. Bureau of Mines conducted field investigations at two geologically contrasting sites, Colorado Springs, CO, and the Allegheny Portage Railroad Historical Site near Cresson, PA, to demonstrate that developing monitoring technology can be applied to any site. An array of seven geophones (velocity-measuring sensors) were strategically located to encompass an area at each site where failure in the underground mine openings could be expected, based on historical, geological, and engineering information. How It Works Bureau research has effectively demonstrated that stress changes within a rock mass can stimulate the development of cracks and fractures, resulting in the release of strain energy that generates seismic waves. These seismic waves, traveling outward from their source, can be detected, and the point of origin can be located in three-dimensional space. Furthermore, these seismic signals contain information that defines the source mechanism and the conditions between the source and the receiving sensor.

Jan 1, 1992

Decrease dust concentra¬tions of longwall face workers by keeping them up¬wind of the headgate stage loader and crusher. Approach Direct the face airflow from tailgate-to-headgate, the direction of coal transport. How It Works Ventilation is the primary method of dust control on longwall faces, and the most effective ventilation control is to put workers upwind of dust sources. Recent ad¬vances in longwall dust sampling by the Bureau have shown that on some faces, the headgate crusher and transfer points are signifi¬cant sources of dust -some¬times making up more than half of the total dust to which the face workers are exposed. Also, when the air is coursed from head-to-tail, the relative velocity between the air and moving coal on the face conveyor can cause dust entrainment from the conveyor, particularly if the coal is dry. On the faces where these dust sources are a signifi¬cant problem, they may be eliminated by coursing the air from tailgate-to-headgate, provided that the mine roof is stable enough to permit the necessary intake of the tailgate along with an aux¬iliary intake at the headgate.

Jan 1, 1982

Determine what diameter piping is necessary to obtain sufficient water flow to spray nozzles used for dust suppression. Approach A simplified, diagrammatic method of calculating the flow of water through a proposed system consisting of a supply line and two banks of spray nuzzles is outlined. How It Works The pressure versus flowrate of the supply at the tapping point must be known or measured. The supply curve of typical city water at a 1 ¼ -inch pipe outlet is shown by the lowest curve in Figure 1. A supply curve for a typical pump fed from an open sump is shown by the middle curve. The combination of these, the supply curve of a pump fed by the city water supply is shown by adding the lower two curves to get the upper curve. A pump supply curve showing flowrate versus pressure is usually supplied by the manufacturer. The water supply line flow curve can be determined by measuring the time required to fill a 55 gallon barrel at various valve settings to determine flow, and by measuring corresponding pressures at the valve with a gauge.

Jan 1, 1979

By Paul T. Allsman

THE THREE words, research, mechanization, and automation are keynote words for mining technology during 1962. Basically interrelated, they not only express the major technologic developments in mining but are the signposts pointing out the road ahead. The process represented by each of these words is evolutionary rather than revolutionary, but developments during the past year indicate a climactical stage has been reached in the process of evolution. Mining research has progressed beyond the stage of academic discussion and is a programed activity within the Federal Government,3 the mining colleges,4 and many of the large mining companies.5 Research was a major agenda item at various national and international mining meetings in 1962. A list of these meetings would include such diverse locales as the Workshop and Symposium on Computers and Computer Applications in Mining and Exploration at the University of Arizona in March; and the 5th Rock Mechanics Symposium at the University of Minnesota, in May; the Rock Mechanics Symposium at McGill University, Montreal, Canada, in September; and the Colloquium XIII, International Society for Rock Mechanics, at Salzburg, Austria, in November.

Jan 1, 1963

Predict the spontaneous combustion potential of a coal, using an expert system computer program. Background Approximately 15% of underground coal mint fires in the United States are attributed to spontaneous combustion. These spontaneous combustion fires frequently occur in worked-out or abandoned areas of a coal mine, This makes the control and extinguishment of the fire difficult and often requires large sections of the mine or even the entire mine to be scaled for long periods of time. A prior knowledge of the self-heating potential of the coal can be useful in preventing spontaneous combustion fires through the use of aggressive monitoring and control measures at existing coal mining operations, and in the planning oh new mines. Many factors can affect the spontaneous combustion process in a mine, including the self-heating potential of the coal, ventilation, geologic factors, and mining conditions and practices. Various test methods have been used to evaluate the relative self-healing potential of coals, including crossing point temperature and adiabatic heating methods, and oxygen adsorption techniques. However, these tests arc usually time-consuming and difficult to conduct, limiting their use to laboratories.

Jan 1, 1992

By F. Cherpereel, R. Gabillard, J. P. Dubus

We present an electromagnetic method taken from the well known radiogoniometer that allows us to locate at the surface of the ground the vertical axis of a magnetic antenna transmitter buried at a depth h in the earth. The method and the equipment achieved are called R. E. P. E. (Relevé Electromagnétique de Points Enterrés). They are daily used to accurately survey old quarries by using triangulation instruments at the surface of the earth rather than in galeries where the setting difficulties considerably reduce their accuracy and increase the work length. The results of several surveys allow us to give the optimum working conditions of the instruments and show that, when the transmitter is at a 20 meters depth, its position is known at the surface with an error lower than 1 centimeter. The power transmitter is of about 8 watts and we can find its location with an error smaller than 1 meter when buried at a depth of about 100 meters. This equipment may be successfully used for location of subsurface miners. The space surrounding the transmitter must then be free from ferromagnetic bodies.

Jan 1, 1973

Develop a simple and practical technique to measure in situ rock mass properties for realistic design and stability evaluation of underground structures. Background The Bureau of Mines has developed basic principles and techniques to determine in situ rock mass properties including Poisson's ratio, deformation modulus, and yield and failure strengths. An instrumentation package consisting of three pressure cells is installed in a single drill hole. Cell pressure response data are acquired and used to calculate and determine the rock mass properties. How It Works A test hole of BX size (approximately 5.7 cm) or larger is drilled to the approximate depth of the measuring point. The last portion of the test hole is drilled with precision bits to EX size (approximately 3.8 cm). The instrumentation package, which consists of one 3.8-cm-diameter cylindrical pressure cell (CPC) and two 5.7-cm-diameter cement-capsulated, flat borehole pressure cells (BPC's), is then installed. A complete history of cell response to changing strata loads is acquired on a continuous basis with a chart-type hydraulic pressure recorder. From these cell pressure data, Poisson's ratios, deformation moduli, and yield and failure strengths are calculated and determined.

Jan 1, 1990

By W. C. Phalen

"The term ""manjak"" is applied to a variety of bitumen or solid hydrocarbon occuring on the Island of Barbados, West Indies, and in Utah, Cuba, and Trinidad. The deposits on the latter island are found within a distance of three miles of San Fernando, the second largest town on the Island, and within three miles of the famous asphalt lake.In chemical composition, manjak is like asphalt. It is almost pure bitumen. Its melting point is, however, more than 4000F. whereas asphalt melts at 1000F. In composition, it consists of 80 to 90 per cent carbon, the balance being chief¬ly hydrogen, with a small quantity of sulfur. It resembles coal in appearance, is odorless, hard, and brittle. It is found in thin beds between layers of clay.The island of Trinidad is rich in this mineral resource. Its development has as yet hardly begun, and the exportations already made have been with the view of testing out the ma-terial. During 1918, exports to the United States were valued at about $3100, and in 1919, up to October 1, they totaled 41 tons, valued at $1900. Prior to 1900, manjak was mined on a small scale in Trinidad, but for various reasons, very little was done between 1900 and 1913. In the latter year, mining operations were resumed by the Trinidad-Tarouba Oil Development Company, of San Fernando. At the present time, there are five shafts, one of which has reached a 37 foot bed of manjak at a depth of 400 feet. Operations could be greatly extended if there were a greater demand for the material.It has not been found profitable to export manjak from Trinidad in the crude state as the price received, namely $35 per ton, hardly covers mining expenses. These are increased by the necessity for careful and thoro timbering on account of the clay formation.Compounds, made by combining manjak with mineral oil command fair local prices which have enabled mine operations to proceed at a profit. Experimentation is still in progress with different mixtures of manjak and oil for various purposes. The manjak, recently sent to the United States was for the purpose of ascertaining whether American oils would be more economical and useful for mixing with the manjak than the Trini¬dad oils. It is the plan to erect a plant very soon for the manufacture of a variety of manjak paints and compounds.Manjak is rapidly increasing in use, particularly in connection with the oil industry. It is produced in close proximity to the oil wells in Trinidad. It is boiled with oils at high temperatures and converted into compounds and paints for nearly every purpose where a preservative is needed, for example, on pipe lines, boilers, chimneys, and miscellaneous iron ware, machinery, etc. It is usually applied in the liquid state, hardening into a tough, rubberlike coating. It has low viscosity, and is not affected by ordinary heat. It makes an excellent insulating material and is impervious to both air and water. In hot and damp climates, like that of Trinidad where pipe lines quickly deteriorate, their life has been pro-longed for extended periods when painted with this material."

Nov 1, 1919

By Thomas M. Barczak

Purchasing a new set of longwall shields requires a substantial investment. A poor shield design can lead to economic hardships, safety concerns for the mine workers, and closure of the mine. This paper addresses several key points that should be considered in the procurement process: (1) understanding your goals and the logic in selecting a higher capacity shield, (2) the importance of completing performance testing before production shield fabrication begins, (3) making sure performance testing is properly done, (4) measuring load(stress) development during performance testing, (5) testing a shield to failure, and (6) the value of buying extra shields. In addition, several challenges are proposed for consideration in future shield designs. These include (1) 100,000 life-cycle expectancy, (2) improved hydraulic diagnostic capability, (3) smart load control by optimizing setting pressures, (4) lubricated link joint design concepts, (5) composite material applications to reduce shield weight, (6) incorporating periodic weighting predictive algorithms into the data-processing software, (7) advanced component load measurement on two to three specially instrumented shields to detect loading in the structural components, and (8) constant set leg cylinder design.

Jan 10, 2000