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By B. E. Burakov, S. D. Lupal, O. A. R. Thalhammer, B. Saini-Eidukat

Electric-pulse disintegration is a mineral separation technique that liberates all mineral grains from any igneous or metamorphic rock irrespective of its lithology or grain-size distribution. The normal mechanical crushing of whole-rock samples is replaced by the rending effect of an explosion, produced by applying an electric current from a high-voltage power source. A voltage greater than the 100 kV necessary for the electrical breakdown of rock samples is achieved by using capacitors charged in parallel, but discharged in series. The sample sits in a water bath and the rapid distribution of electric pulses leads to an explosion which occurs preferentially along grain boundaries of the sample. Individual, undamaged mineral grains can be recovered in their original shape and form regardless of grain size. Examples are given of the liberation and concentration of important accessory minerals from different rock types. The examples show the recovery of diamond from two types of non-kimberlitic host rock in Popigai and Kumdykol in Kazakhstan and platinum group minerals associated with chromitites from the Konjdor intrusion and sulphides from intrusions in the Kola Peninsula in Russia

Apr 1, 1995

By L. J. Barnes, R. O. Koch, J. H. Versteegh, C. J. N. Buisman, P. J. H. Scheeren

Several water treatment options have been studied and piloted. A process based on activity of sulphate reducing bacteria combines sulphate removal and heavy metal removal in one process step. The anaerobic bacteria reduce the sulphate to sulphide and consequently metal sulphides will precipitate. The final design for the commercial scale plant is described.

Jan 12, 1992

By M. K. G. Whateley, W. Hatton

Paper presented at the conference: Risk assessment in the extractive industries, held in Exeter, UK, 23-24 March 1994, and first published London: IMM, 1994, preprint volume, 20pp., 31 refs. Estimates of coal tonnage on UK open cast mining sites often vary from the recoverable tonnage. This is because the estimates depend on the geological variability of the coal measures. Geological parameters, such as thickness, quality and disturbance of the seam, have a direct control upon this variance. Risk analysis techniques have been applied using commercially available software to combine each parameter's variability into a cumulative variance, resulting in a tonnage distribution. Sensitivity modelling has also been used to identify the geological parameters which have the largest influence on the variance of the simulated tonnage distribution. An understanding of the relationship between the tonnage and geological variability has helped to focus exploration more efficiently. A cost to risk relationship can now be monitored, helping management to avoid negative consequences on site

Aug 1, 1995

By B. B. Dhar

Slope stability at the proposed mine in Rajasthan was analysed in two dimensions using a finite difference code. The properties of the rock material were determined in the laboratory and subsequently modified to approximate those of the in situ rock mass. Geotechnical mapping was undertaken to determine the critical orientation of structural discontinuities. The results of the work indicated that an open pit 148 m in depth would be stable with overall slope angles of 60 degrees

Aug 1, 1994

By Xiao Min You, D. R. Swonbourne

Smelting of Cu anode slimes involves the use of a slag to hold the oxidised Cu, but some Ag is also inevitably oxidised to the slag. The solubility of Ag in sodium silicate slags at 1 100 and 1 150 degrees C has now been determined over a very wide range of oxygen partial pressures. Silver was found to be present in the slags both as neutral atoms and as AgO(0.5). The activity coefficient for atomic Ag was a very strong function of slag composition and temperature, whereas that for AgO(0.5) was much less affected by slag composition and was almost independent of temperature over the limited range examined. The results reveal that the dissolved Ag cannot be fully recovered by reduction of the slag with very reducing gases

Jun 21, 1905

By Xuejing Xie, Tianxiang Ren

Paper presented at the 28th International Geological Congress held in Washington DC, July 1989 (International geochemical mapping sessions). Standardised stream-sediment sampling procedures have been used in mountainous and hilly terrains. Special sampling procedures were developed for application in remote environments, such as high mountains, desert, semi-desert, karst and loess-covered regions. The diversified analytical methods used in more than 20 analytical laboratories participating in the project have been unified into two multi-element, multi-method analytical systems. A unified data monitoring procedure was developed based on primary and secondary standard samples. To date the project has covered about 4 000 000 km2 and the aim is to complete the coverage within the present decade

May 1, 1991

By S. P. Godby, S. P. Sharples

Wind-tunnel tests were carried out of the conditions under which nuisance dust particles (100-1 000 micrometres) become entrained by wind. A laser entrainment monitoring system (LEMS) was used, and was found to provide an accurate means of assessing nuisance dust emissions from a surface. Accurate determination of the threshold entrainment velocity of dusts using the LEMS gives a baseline against which the performance of dust control techniques can be evaluated. Minerals tested included coal, petroleum coke, limestone, sand and pulverised fuel ash. Pilot field trials of a portable wind tunnel equipped with the LEMS have been successfully completed, providing a means of validating laboratory results in the field

Jun 19, 1905

By N. Krauland, A. Nystrom, M. Board, S. Sandstrom

Several deep Swedish cut-and-fill mines experience severe ground control problems, including roof collapse and wall sloughing, as a result of variable rock quality and high in situ stresses. A project to examine the problem included two main areas. The first was prediction of mining conditions at depth and the adaptation of cut-and-fill mining to such conditions; the second was the assessment and improvement of support methods at present and future depths. Simple, elastic, mine-scale numerical models were used to optimise stope sequencing and more detailed, stope-scale models to simulate the failure processes around a stope and the interaction of rock mass and support. Kristineberg was chosen for testing and calibration of the predictive methods because of its long history of severe ground conditions and the large base of observational and monitoring data available for comparison. Horizontal cut and fill was found technically suitable to depths beyond 1 000 m and economically viable if ore value covers support costs. Stability can be achieved with the present support technology down to 1 000 m but the 7-strand 15.2 mm cables have poor deformation properties (5% failure strain) compared with rebar rock bolts (17%). Reducing the intervals between levels from 100 m to 50 m will cut support costs and improve production reliability and capacity. Simulation of sill-pillar mining indicated that conditions would be most severe when pillar height was reduced to 15-20 m; mining of a sill pillar has been carried out successfully to the last 3 m, whose extraction is planned for the near future

Dec 1, 1995

By G. G. Roy, R Shekhar

Pachuca tanks are extensively used for the cyanide leaching of gold and the carbonate leaching of uranium, processes in which oxygen mass transfer plays a very important role. Experiments were carried out to clarify the effect of design and operating parameters on oxygen mass transfer. Parameters such as the ratio of tank height to tank diameter, the ratio of draught-tube diameter to tank diameter and the tank design were found not to influence oxygen mass transfer. Results also showed that equal superficial gas velocities may be used as a criterion for scaling up oxygen mass transfer in both full-centre-column and free-air-lift Pachuca tanks with clear water. A volume-averaged, volumetric gas-liquid mass-transfer coefficient (k'av) was used to characterise oxygen mass transfer in full-centre-column tanks. The axial dispersion model was used to determine k'av. The resulting model used only tank geometry and air flow rate as inputs for the prediction of k'av in industrial-scale tanks. Predictions from the model show clearly that "local" mass-transfer coefficients, measured at one or two locations, may not adequately represent gas-liquid mass transfer in industrial tanks. It is therefore necessary to obtain an estimate of k'av

Jun 18, 1905

By Jinsheng Chen, S. S. Peng

The relationship between support performance parameters and parameters representative of mining and roof conditions is characterised by uncertainty, non-linearity and dependence, so the theory of artificial neural networks was selected as a basis for shield design. A computer program based on a back-propagation training algorithm was written to derive the weighting factors between inputs and outputs from field data; once these had been established two mathematical models were developed to describe the relationship. Back-calculation of field data indicates that the results generated from the neural network models are much more accurate than those derived by traditional methods and can be used with a higher level of confidence. The support density, possible yield frequency of face supports and interval of periodic roof weighting under specific mining and roof conditions can be determined by application of the models

Jun 21, 1905

By G. G. Barbante

The oxidation behaviour of selenide matte with a substantial Cu content and low Ag differs significantly from that of high-Ag matte. Low-Ag selenide mattes display a large oxygen solubility and the upper boundary of the miscibility gap in the Ag-Cu-Se-O system is depressed to quite low Se contents. As a result, the formation of Ag metal is considerably delayed. The oxidised selenide matte, low in Se and with a relatively high oxygen content, has previously been termed oxymelt. With further oxidation, its composition enters the misciblity gap and crude Ag is formed. The sodium silicate slag captures very little of the SeO2 and the dissolved Ag2O(s) content of the slag is relatively small, with a Raoultian activity coefficient of 0.57. This value was found to be independent of the slag's Cu2O content

Jun 19, 1905

By S. Kelebek, J. A. Finch, Zhenghe Xu, S. R. (Ram) Rao

To improve SO2 emission compliance, pyrrhotite from Sudbury copper-nickel ores is being depressed with DETA. To understand the mechanism of depression, the role of complexing in controlling metal-ion activation of pyrrhotite was investigated. DETA was found to remove Cu and Ni ions but leave hydrophilic ferric species on the pyrrhotite surface. The metal:DETA ratio appeared to be 1:2. Cu was more readily removed than Ni, but the combination of DETA with sulphur dioxide was equally effective for both metal ions. Certain combinations of DETA, Ni ions, xanthate and dithionite (S2O4) or dithionate (S2O6), as representative derivatives of SO2 in water, produced hydrophilic precipitates. These may enhance pyrrhotite depression

Jun 19, 1905

By W. P. C. Duyvesteyn, B. J. Sabacky

Reprinted with revisions from Extractive metallurgy of copper, nickel and cobalt, volume I: Fundamental aspects. ed. Reddy R.G., Weizenbach R.N. Warrendale, Pennsylvania: The Minerals, Metals and Materials Society, 1993. Development work on the Escondida process, concluding with the successful operation of an integrated leach-SX-EW pilot plant and a pilot flotation plant for the upgrading of leach residues, demonstrated that all major process objectives could be achieved. Extraction of 40% of copper in concentrates containing monovalent copper was achieved with essentially no oxidation of sulphide sulphur. The Cu contents of leach residues from four different types of concentrate were successfully upgraded to the original feed grades, giving a product that has potential as a high-quality concentrate for the smelter market. A compact solvent extraction section effectively recovered the ammonia lixiviant for recycling to leaching and selectively transferred Cu into a conventional acid sulphate electrowinning system. High-quality "six-nines" copper cathode was produced on commercial-scale stainless steel blanks, demonstrating that the process will be able to compete effectively in the premium cathode market

Dec 1, 1995

By K. Nielsen, J. Kristiansen

A series of laboratory blasting and grinding tests on three types of hard and competent rock (coarse-grained monzonite, fine-grained granite and very fine-grained gabbro) showed that a higher level of applied explosive energy enhanced grindability and produced a larger amount of fine (-0.106 mm) material. This confirmed reported industrial experience and the results of previous investigations. However, the results did not provide any information on the quantitative relationship between the energy applied in primary blasting and that required in subsequent comminution. Only about 1% of energy consumed in conventional grinding is used to create new surfaces, while power efficencies in cone crushers have been estimated at 70-80%. In blasting, up to 20% of explosive energy may be transmitted to the surrounding rock as elastic strain energy, leading to both primary rock breakage and the generation of microcracks

Dec 1, 1995

By O. R. Eckstrand, M. Asif, P. L. Schwann, A. J. Naldrett, R. J. F. Scoates

Paper presented at the IAGOD international symposium on mineralisation related to mafic and ultramafic rocks, held in Orleans, France, 1-3 September 1993. PGE-bearing sulphide mineralisation is contained in the lower 600 m of the Upper Central Layered Zone of the intrusion. There are four regimes with distinctive crystallisation characteristics. PGE content is low, both in bulk rock and in terms of metal in 100% sulphides, in the sulphide-rich cumulates but increases sharply in the sulphide-poor cumulates at the base of regime 1. Increases in regime 2 have no such clear relationship with incoming cumulus sulphides. PGE contents are low throughout regime 3, but regime 4 has sulphides with high PGE content, decreasing rapidly upwards, at the base of many of its cyclic units. The observations are interpreted as indicating that sulphide saturation occurred in the middle of a cyclic unit in regime 1, after which fractional segregation of sulphide caused a systematic decrease in PGE content. The resulting contrast between 40 000 ppb PGE in sulphides below the mineralised zone and less than 1 000 ppb above is of practical importance in exploration for such zones. In regime 2 the magma chamber was open to fresh influxes and PGE content was not so sensitive to sulphide saturation. In many regime 4 units influxes of new magma caused immediate sulphide saturation and PGE depletion, so that PGE-rich cumulates do not underlie PGE-bearing sulphide zones. Theoretical analysis indicates that regime 1-type behaviour is likely to characterise intrusions below the level at which plagioclase has entered as a cumulus phase and regime 4-type behaviour above

Apr 1, 1994

By M. Foguenne, A. van Lierde, P. Henry

Leaching experiments were carried out on a spent catalyst sample with a honeycomb structure, containing 47.5% Ti, 5.8% Mo, 2.7% Si, 2 035 ppm As, 52 ppm Pb and 8.8 ppm Hg. More than 93% of the Mo and As was removed by direct alkaline leaching after grinding to 80% -36 micrometres. The residue contained 0.3% Mo and 60 ppm As. To obtain a TiO2 matrix with 30 ppm As, acid leaching at controlled pH with 90 kg/t Al scrap was followed by oxidising alkaline leaching. Treatment of the direct alkaline leach solution or of the mixed solutions from the two-stage process involved two successive operations: purification by neutralisation with Al(OH)3 addition to raise the Al concentration to 4 g/l, and ion exchange on Amberlite IRA 94 S resin. Whatever the type of solution treated, elution with 200 g/l NH4OH solution gave an eluate of very high purity containing 164 g/l Mo, less than 70 mg/l V and less than 2 mg/l As

Jun 19, 1905

By P. J. Rowsell, M. D. Waller

Paper presented at a meeting on: Artificial intelligence in the minerals sector, held in Nottingham, UK, 20 April 1993. The applications of artificial intelligence systems in the upstream petroleum industry are reviewed. Particular emphasis is placed on current and potential applications in drilling engineering. Several recent advances in drilling technology have led to a large increase in the quality and volume of data available. This combined with the escalating cost, particularly of off-shore operations, is testing the traditional reliance on the skill and judgement of rig operators. AI systems offer enormous scope in enhancing and aiding the performance of these operations

Apr 1, 1994

By R. D. Stewart

Paper presented at the conference: Risk assessment in the extractive industries, held in Exeter, UK, 23-24 March 1994, and first published London: IMM, 1994, preprint volume, 18pp., 5 refs. A seismic risk assessment method has been developed for application to rockburst prone deep-level mining sites which have sufficient seismic coverage. The technique utilises several seismic hazard parameters simultaneously and assesses the seismic risk on a daily basis according to the individual levels of these parameters. Critical levels are determined from investigation of the long-term behaviour of the parameters in relation to recorded potentially damaging seismic events. The method has been applied to a data set comprising 15 months' worth of seismic data, with encouraging results

Aug 1, 1995

By B. S. Terry, C. L. Harris

Reduction kinetics from slags containing CuO(0.5), ZnO, PbO, NiO and SnO into a Cu-based metal phase were subjected to computer simulation using a previously developed model for the kinetics of metal-slag-gas reactions that assumes mass-transfer control in all phases. The effects were examined of changing bulk Fe oxide activity, gas reducing potential, temperature, Fe content of the Cu phase and metal/slag ratio. The results permit practical conclusions to be drawn about industrial slag-cleaning practice, but the model is still limited in terms of thermodynamic inputs and the idealisation of reaction conditions

Aug 1, 1995

By T Grenne, R. B. Larsen

Paper presented at the conference on Economic geology in Europe and beyond II, models for mineral deposits in sedimentary basins, held in Keyworth, UK, 13-14 April 1994. Paper originally entitled: Processes in a newly discovered sulphide-PGE mineralisation in Norway. The Stormyrplutten mineralisation is hosted by a minor tholeiitic metagabbro of low-Ti composition intruded at a high level in the volcanic lithology. It is thought to be the subvolcanic counterpart of submarine basalts generated during an extensional episode of ensimatic arc evolution. The sulphide-PGE mineralisation occurs as stratabound pyrite, pyrrhotite and chalcopyrite disseminations with average grades of 376 ppb Pd, 313 ppb Pt, 40 ppb Au, 0.5% Cu and 0.08% Ni in a deposit 15-25 m thick. Locally the PGE content peaks at 2 ppm over 1 m. Microprobe analysis isolated 14 different platinum-group minerals, dominated by sperrylite, temagamite and borovskite and occurring as 1-20 micron compounds embedded in the main sulphide minerals or along the sulphide/silicate grain boundaries. Mantle-normalised plots reveal strong depletion in Os, Ir and Ru and enrichment in Pt, Pd, Cu and Au. The general decrease in Pd and Pt and increase in S up through the stratigraphy is similar to PGE distribution in the Darwendale subchamber of the Great Dyke in Zimbabwe, and may reflect strong fractionation of Pd and Pt in favour of the first droplets of sulphide melt; two reversals of the trend at the 4 and 12 metre levels represent replenishment with fresh magma and repetition of the cycle. In contrast to the Darwendale system, Cu and Ni also show peak concentrations in the first-formed liquids and Pt appears to have fractionated more strongly into the sulphide melt than Pd

Aug 1, 1995