Search Documents

By Irven A. Jacobson

The thermal reactions of l-methylindole were studied in the temperature range of 525° to 627° C in a flow reactor. The major products consisted of 2-methylindole, 3-methylindole, indole, quinoline, hydrogen, and methane. 2-Methylindole is formed from 1-methylindole by an irreversible isomerization reaction. The 2-methylindole isomerizes in a reversible manner to 3-methyl-indole, the equilibrium favoring the 3-methyl isomer. Indole is formed directly from 1-methylindole. Quinoline is formed from l-methylindole, 2-methylindole, and 3-methylindole.

Jan 1, 1971

Coal-bearing beds underlie 23,000 square miles, about one third of Missouri's total area. Twelve out of more than twenty named coal seams have been or are being commercially mined. The remainder are too thin for commercial production. The coal is high volatile bituminous, with reserves estimated to be six billion tons, 1.24percent of U.S. coal reserves. Coal-bearing strata are generally thin seams which can be up to five feet thick. Typically, mined seams are about 28 inches thick. Coal deposits were first mined in Missouri in the 1840s, with the coal used primarily for domestic heating and blacksmithing. Production increased with the introduction of steamboats on the Mississippi. Coal production in 19 17 was six million tons. Production has steadily declined from a high of nearly seven million tons in 1984 to 2.3 million tons in 1991. Declining production is the result of several factors, including competition from other energy sources and the high sulfur content of Missouri coal. Today, coal-fired electric generating plants are the biggest consumers of Missouri coal. The Missouri regulatory program was conditionally approved November 21,1980, and fully approved January 17,1983. Its Abandoned Mine Land program was approved January 29, 1982.

Jan 1, 1992

By Rudolf E. Greuer, Linneas W. Laage, Xinton Chang

The usual run time errors occur when illegal mathematical operations are attempted by MFIRE For exam¬ple, if the user enters a negative value for the input variable HEAT to model a heat sink or cooling station, a run tame error will occur because an exponential function is employed to better model the changing temperature dis¬tribution in the airways. DATA FILE ERRORS Two types of data file errors can occur. 1 An error may occur because the input data file itself is invalid This may be caused by: The data file cannot be found due to incorrect spelling, drive, or path specification Check the spelling and path at the prompt for location of the data file. The data file contains non-ASCII symbols Check op¬eration of the text processor to insure that only ASCII characters are produced Delete all non-ASCII and/or all out of place characters. 2 Data are accepted by the program, but are incorrect for the data types or ranges or the combination causes a data inconsistency This may be due to. An invalid character is located where a numerical value is required The input data value is outside the reasonable range The input data is insufficient to build the model for simulation. The input data exceeds the capacity of the program. PROGRAM ERROR DETECTION When the program is running, tracing messages are given on the screen indicating the group and lines of data that have been read and the section of the program that is executing Program termination indicates that problems are caused by the subsequent (not read) data file section. For each detected error, descriptive message starting with * ERROR * is issued and the program terminates. When a possibly wrong value and/or its calculated intermediate result is detected, a descriptive message starting with * WARNING * is issued and the program continues. If a modification of input value or calculated intermediate result is automatically made by the program, descrip¬tive message starting with * ATTENTION * is issued and the program continues. LOCATING ERRORS If a message indicates that the error condition occurred due to the data input file, locate and correct the data item. If no error message is issued, but the simulation results are not as expected, carefully check the list of input data shown in the output file WARNING messages and ATTENTION messages may reveal an error in the input data even though the program continues to operate Insure that the default values or modifications adopted by the program run are acceptable. Anomalistic data, though not incorrect or impossible, may lead to an unusual simulation For example, making a fan unusually powerful may prevent a normal strength fire from affecting the airflow distribution in the system Much care must be employed before considering an ex¬treme case. If a message indicates that the accuracy criterion in the temperature section of the program was not satisfied, a table detailing the current parameters of airways which have large fluctuation in the average air temperature from iteration to iteration is produced If the pattern of the parameters is clearly cyclical, while the variation of natural ventilation pressure is stable or cyclical from iteration to iteration, then, most likely there is no single equilibrium stage for the event If the variation of natural ventilation pressure decreases steadily though slowly, increasing the value of data item variables MADJ or ITN (on control line number 1) may allow convergence.

Jan 1, 1990

By Robert F. Chaiken, Thomas H. Dubaniewicz, Gregory M. Green, Kenneth L. Cashdollar

Optical technologies have progressed rapidly in the past 15 years. One application of laser technology in underground coal mines currently under evaluation is the remote measurement of explosive methane gas. Federal regulations require that atmospheric monitoring systems used in gassy underground mines where permissible equipment is required shall be intrinsically safe. Mine Safety and Health Administration criteria for the evaluation and testing of intrinsically safe apparatus and associated apparatus contain no specific guidance for optoelectronic components such as diode lasers. The National Institute for Occupational Safety and Health is conducting a study to help provide a scientific basis for developing appropriate safety guidelines for optical equipment in under- ground coal mines. Results of experiments involving ignition of methane-air mixtures by collections of small heated particles of Pittsburgh seam coal and black iron oxide are reported. The inert but more strongly absorbing iron oxide targets consistently ignited methane-air mixtures at lower powers than the coal targets. Minimum observed igniting powers for laser energy delivered by 200, 400 and 800 pm core fiber optic cables and directed onto iron oxide targets in methane-air atmospheres were 0.6, 1.1, and 2.2 W, respectively. Comparisons with the results of other researchers are made. A thermal layer theoretical approach to describing the process is included as an appendix.

By Howard E. Parkinson

Since 1969, the Department of Interior, Bureau of Mines, has carried out communications research. Research has been directed toward developing emergency and nonemergency mine communications. This paper gives an overview of the progress made in the last two years. Particular emphasis is given to the overall program, noise and signal measurements, systems studies, guidelines, products, and demonstrations now being carried on in operating mines.

By Oleg Terichow

Electrophoretic mobility measurements were made on samples of Florida phosphate slimes to determine the optimum conditions of coagulation and precipitation in aluminum sulfate solutions. The addition of silica sand and other selected materials as mutual coagulants has demonstrated the practicability of coagulating two dissimilar particle systems by elimination of the repulsive double layers. By proper selection of the solution and its concentration, the reduction of the double layer to a zero point of charge causes coagulation and rapid precipitation of both particle systems. Confirmation was found in filtration tests and sedimentation tests.

Jan 1, 1973

By J. Litsenberger, T. E. Marshall, P. R. Coyle, L. J. Prosser, A. T. Iannacchione

For the first time in an underground stone mine, the relationship between roof movement and microseismic emissions was examined in conjunction with two distinct roof fall areas. As roof monitoring increases in acceptance and monitoring technology advances, the goal of providing reliable roof fall detection systems to enhance the safety of underground mine workers moves closer to reality. Instrumental to reaching that goal is the ability to interpret accurately and completely roof movement and microseismic emissions, which can serve as precursors to roof falls. This paper examines the capabilities of convergence and microseismic monitoring systems to better understand roof rock failure mechanics and to anticipate roof falls. An understanding of how these techniques are used and how they interact with each other is critical in developing the most effective ground control strategy for our nation’s mines.

By George J. Conroy, Angel G. Jordan, Eugene W. Bartel

Time-domain reflectometry has long been an accepted and used method for locating electrical faults in electrical cables. The process has, however, required the use of equipment that is somewhat complex and difficult to use. The skill level needed to operate such equipment is high. Therefore, the use of the time-domain reflectometry process has been limited to selected locations and controlled environments. The process, however, has great potential for mine system applications. The ability to locate and repair trailing power cable without removing it from the mine would result in great savings in cost and employee-hours. Therefore, an automatic microprocessor-controlled time- domain reflectometry system was developed to reduce process complexity and skill level needed to operate the unit. The theory of operations is discussed along with the computer analogies used in the unit. The present unit capabilities are presented and future areas of application and research are discussed.

Jan 1, 1979

By H. R. Shell

Variations between laboratories on the silica and alumina content of calcined kyanite led to this Bureau of Mines study of the extent and nature of the differences. In particular, Bureau scientists hoped the study would lead to correction of the causes of the dissimilarities. A sample of calcined Kenya kyanite was analyzed by seven different laboratories familiar with silicate analysis. The compiled data indicated differences originating from lack of recovery of silica after two acidic dehydrations, from high alumina caused by several factors, from loss or gain of iron during sample fusion, and from indifference regarding the accurate determination of minor constituents.

Jan 1, 1959

By Julie Mitchell, Robert King, Len Eros

The Bureau of Mines has studied the Deserado Mine computerized monitoring and control system, located in Rangely, Colorado, to acquire knowledge about the overall costs and benefits of mine monitoring systems. The Deserado system is a complex system monitoring environmental parameters, electrical power, and operation of all mine equipment, and controlling the entire conveyor haul age system. This paper discusses the evaluation of the Deserado monitoring system from initial design through system installation and operation. It also examines the costs, benefits, and performance of the monitoring system.

By Andrew B. Cecala, Robert J. Timko, Alexander D. Prokop

Bag loading and stacking processes are the highest dust-exposure job categories in the metal/nonmetal mining industry.1 To cost-effectively decrease respirable dust levels, the Pittsburgh Research Center of the National Institute of Occupational Safety and Health (NIOSH), formerly of the U. S. Bureau of Mines, designed and tested a system called the Bag and Belt Cleaner Device (B&BCD). [ ]

By Arthur E. Goddard

Radio propagation measurements were conducted in a coal mine at UHF (200 to 1000 MHz) and VLF (1 to 50 kHz) to characterize the transmission loss of intra-mine paths. The basic experimental parameters included frequency, polarization, path orientation and distance. Further tests evaluated the performance of roof-bolt vs. loop antennas at VLF and parasitic reflectors at UHF. Measurement results are summarized in a series of transmission loss curves. Examples are presented to show the use of these curves in predicting the performance of radio communication systems in mines.

Jan 1, 1973

By W. Blake, J. Whyatt

Sixty years of rockbursting in the Coeur d’Alene district has taught painful lessons and led to a number of practical advances in controlling rockburst hazards. This paper summarizes those lessons, concentrating on practical measures that have been successfully adopted to reduce hazards. These lessons are explained in the context of district mining history and current understanding of rockburst phenomena. Overall, the paper provides the practicing mine engineer with an appreciation of rockburst hazards and an overview of practical measures that can be used to control these hazards in the context of Coeur d’Alene district experience.

By Staff

This Bureau of Mines publication contains five papers pertaining to the effective grounding of mine power systems, as follows: Ground-check monitor types and safety characteristics; ground wire monitors for surface coal mines; ground bed design and measurement; electrical ground rod corrosion; and a continuous ground 'bed resistance monitor.

Jan 1, 1979

By Sean Gallagher, William S. Marras, Alan S. Litsky, Deborah Burr

Background. There is currently little information regarding factors associated with specific modes of motion segment failure using a fatigue failure model. Methods. Thirty-six human lumbar motion segments were fatigue tested using spinal compressive and shear loads that simulated lifting a 9 kg weight in three torso flexion angles (0, 22.5, and 45). Twenty-five segments failed via fatigue prior to the 10,000 cycle maximum. These specimens were visually inspected and dissected so that the mode(s) of failure could be determined.Failure modes included endplate fractures (classified into nine varieties), vertebral body fractures, and/or zygapophysial joint disruption. Logistic regression analyses were performed to determine whether certain morphometric variables, amount of motion segment flexion, disk degeneration scores, and/or loading characteristics were associated with the occurrence of specific failure modes. Findings. Results indicated that stellate endplate fractures were associated with increased posterior shear forces (P < 0.05) and less degenerated discs (P < 0.01). Fractures running laterally across the endplate were associated with motion segments having larger volumes (P < 0.01). Endplate depression was more common in smaller specimens (P < 0.01), as well as those experiencing increased posterior shear force (P < 0.05). Zygapophysial joint damage was more likely to occur in a neutral posture (P < 0.01).Interpretation. These results suggest that prediction of failure modes (e.g., specific endplate fracture patterns) may be possible (atleast for older specimens)

By R. V. Ramani, R. Stefanko, G. W. Luxbacher

Table

Jan 1, 1977

By D. O. Kennedy

THIS CHAPTER on minor nonmetals covers greensand, meerschaum, mineral wool, and wollastonite. Mineral wool was by far the most valuable material among these minor nonmetals reported in the United States in 1956. GREENSAND Output of greensand (glauconite) declined in 1956. The Kaylorite Corp., Dunkirk, Md., and the Inversand Co., Sewell, N. J., were the only firms that reported production of this commodity. Output came from open pits in Calvert County, Md., and Gloucester County, N.J.

Jan 1, 1958

By George T. Faust

The Southern Experiment Station of the Bureau of Mines, United States Department of the Interior, in cooperation with the University of Alabama, is investigating the various types of clays to be found in the Southern States. In connection ,with this work, the petrographic laboratory is called

Jan 1, 1940

By Robert F. Chaiken

A quasi-steady-burning channel model is used in this Bureau of Mines study to describe the conductive heat loss from an in situ coal combustor to the surrounding rock strata. The calculated heat losses are significantly greater than those previously estimated, but are still very acceptable from the viewpoint of energy recovery. Approximately 80% to 90% of the heat of combustion of the coal should appear as sensible heat of the gaseous exhaust, with exhaust temperatures in the range of 1,000° to 1,200° C. The effects of burning stoichiometry and channel size on the heat loss are also discussed in terms of the model. Such effects are shown to be compatible with an in situ combustion process even in thin seams. However, these results depend on gas leakage and adverse roof falls not being important factors in deter-mining the heat loss mechanism.

Jan 1, 1977

By R. V. Ramani, A. S. C. Owili-eger

The origin of gaseous hydrocarbons in coal, predominantly methane, can be traced to the natural processes of coalification. The higher rank coals or the more deeply buried seams retain more gas than low rank coals or shallow seams. It is estimated that up to 460,000 cubic feet of all types of gases are produced during the formation of one ton of coal (Cervik, 1969). The chief components of these gaseous products are methane, carbon dioxide, nitrogen and water vapor. Most of these gases escape during the various stages of decomposition but with eventual presence of overlying impermeable beds, there may be as much as 2,000 cubic feet of gas retained per ton of coal. Over geologic time, diffusion and other processes such as geologic disturbances in the earth&apos;s crust remove all but 500 to 2000 cubic feet of gas per ton of coal (Cervik, 1969). It is this residual methane which is of primary concern when mine openings are made in coal measures. Extensive data compiled by the United States Bureau of Mines reveal that some coal mines in this country emit up to 20 million cubic feet of methane per day (Spencer, 1970; Irani et al, 1972). Toxic, poisonous and respirable gaseous pollutants and explosive gases, predominantly methane, are injected into the ventilation stream from active sections and gobs. The liberation of methane in gob areas may, under certain circumstances, become extremely large. In some instances it may constitute up to 70 percent of the total yield of gas in a mine. The basic physical factor which determines the yield of gas into the mine environment is the gas content of the seam. The influence of the gas content of a seam on the overall yield of gas

Jan 1, 1974