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By D. C. Fraser

Copper occurs invisibly in a geo-logical environment characterized by swampy conditions and an accumulation of forest peat. This swamp, located in southeastern New Brunswick, contains up to ten per cent cop-per (dry weight), in the organic sediments. This occurrence appears unique in that the metal is apparently organically combined in a chelate compound. Unlike the acidic nature of most peat bogs, the pH of the cup-riferous peat is nearly neutral. Analyses of the peat and associated soils have indicated that the bulk of the copper is contained in the organic sediments. It appears that the cop-per distribution is affected by capillarity, evaporation and the growth of frost crystals, and that the copper fixation is effected by organic sequestration resulting in the metal being bound to the nitrogen or oxygen components of the forest peat. While such a fixation mechanism is not definitely established as responsible for the immobilization of the metal, the facts at hand are compatible with

Jan 1, 1961

By Jr. Fackler

The ionization potentials of gaseous Group 11elements are similar, with Au(0) being 1.5 eV greater than the next highest member of the group, Cu(0). The ionization potentials are all very much greater than the alkali metals, making these ?coinage? elements rather unreactive to chemical oxidation. Ionization from the first oxidation state shows a different pattern, with Ag(I) being the most difficult of the Group 11 ions to lose an electron. Gold(I) is noble and only normally oxidized in the presence of strongly coordinating ligands such as thiols or cyanide. Gold(I) compounds are 2-, 3- and 4- coordinate, with 3-coordinate species generally showing visible photoluminescence under UV excitation. Dinuclear Au(I) compounds with strongly coordinating S or C ligands can be oxidized to form isolable metal-metal bonded Au(II) compounds which are often readily isolable. Many have been structurally characterized. T he ease with which electrons are lost from closed shell dinuclear sp ecies (with anti-bonding M-M interactions) increases when metalmetal bonded compounds are formed. T his observation was made by our group with oxidative-addition studies of dinuclear gold(I) ylide complexes. It was superbly demonstrated recently by Cotton?s group who reported the isolation and characterization of a dinuclear closed shell transition metal species which is more readily oxidized than cesium. Trinuclear Au(I) pyrazolates, TR(pz), carb eniates, TR(carb), and benzylimidazolates, TR(bz), are well known and undergo electron loss through oxidative addition forming Au(I,III) mixed valence species and ultimately trinuclear Au(III) species. Au(II) species are absent from isolation in these oxidations. These carbeniates and benzylimidazolates also are excellent bases for metals ions such as Tl(I) and Ag(I). The acidic, neutral trinuclear compound [Hg(C6F4)3]3 also interacts with these bases. We have also shown that the neutral organic pi acids C6F6 and TCNQ form stacked pi-acid pi-base products with the trinuclear Au(I) compounds. In this paper, the structure of the octafluoronaphthalene acid-base product will be described. It displays a feature not observed previously in that the product is photoluminescent with a bright yellow emission. The 3.5 ms lifetime is very long and reminiscent of the long lifetimes observed by Balch for the stacked methyl,methoxy Au(carb). The electrochemical oxidation of tetragold(I) clusters, [Au4(form)4] have been studied in 0.1 M Bu4NPF6/CH2Cl2 at Pt working electrode at different scan rates. Three waves are obtained at 0.75, 0.95, and 1.09 V vs Ag/AgCl at scan rate 500 mV/s. The potential of the three reversible waves is independent of the scan rate in the range 50 mV/s to 3 V/s. The current at the third wave is larger than those at the first two waves. These tetranuclear species app ear to be effec tive catalyst precursors for the oxidation in air of CO. Introduction. The electronic structural relationships of the coinage elements and the alkali metals are similar in the sense that each have a [closed shell]ns1 configuration, yet their ionization energies (Table) and chemistries are clearly vastly different. The Group 11coinage elements have an underlying nd10 level immediately below the ns1 level. Unlike the alkali elements, ionization leaves the filled d electron shell the next accessible for further ionization. The coinage elements are all relatively ?noble?, much less reactive to environm ental conditions than the alkali metals. With the coinage elements, oxidation becomes very much dependent upon the types of ligand s availab le to bo nd to the ionized state.

Oct 1, 2003

"The asbestos mining industry in the Eastern Townships of Quebec has early recognized the undesirable side-effects associated with mineral production, such as air pollution, noise and unsightly waste dumps. In order to efficiently achieve the industry's aim of eliminating or minimizing these objectionable features of mining, all of the asbestos producers in Quebec interchange information, knowledge and design dealing with the environmental control measures through the Environmental Committee of the Quebec Asbestos Mining Association.The paper describes what has been done and what is planned for the future in the various problem areas, such as control of dust emitted during the open-pit drilling operation, control of dryer stack emissions, control of the environment in ore, fibre and tailings handling operations, rehabilitation of the countryside covered by waste dumps, and many others."

Jan 1, 1971

By George W. Bain

The area in Quebec immediately north of the Ottawa river is underlain by a large area of granite gneiss intruded in lit-par-lit fashion into Grenville sediments and low silica intrusives of the Buckingham Series. This complex of metamorphic rocks is intruded by a much later magma found, chiefly, as a very large stock about 20 miles in diameter and extending from Brownsburg to Grenville, and as dykes and small outliers at various places adjacent to its outer margin. 1A similar stock at Rigaud, Quebec, is situated south of the Ottawa river and has been described by O. E. Le Roy. The earliest representatives of the later magma are a series of granodiorite dykes characterized by abundant hornblende, along with primary magnetite and subordinate sulphides scattered as roundish grains through anorthoclase and aligoclase feldspars and subordinate quartz. The rock is found as narrow dykes and shows no prominent secondary structures, either in the field or in thin sections under the microscope.

Jan 1, 1926

By G. S. Ospanova

The results of complex processing sulphide copper ore and advantages of recovery of copper by vat and heap leaching, sorption, cementation and electrolytic solutions processing and utilization of waste material after heap leaching of copper for production of building materials were investigated. The combined chemical solvents with the additives of oxidizing agents are developed at the KazNTU. The solvents are inorganic or organic chemical reagents, which form complexes of Cu, Au, Ag, Pt, Ni, Sr, Co etc. Recovery of non-ferrous metals from solutions and purification of industrial waste waters is carried out on the base of using new synthetic and natural sorbents (from local raw materials) which are able to bind ions in both cationic and anionic forms depending on type of ligands and external conditions. Optimum parameters of copper sorption were determined. The developed wasteless technologies of copper extraction from sulphide ores with usage of new non-toxic solvents and accessible sorbents with full recycling of water are tested in pilot scale heap leaching, and are recommended as the ecological, economical and practical alternative to traditional methods.

Jan 1, 2007

By S M. Roscoe

Relationships of Noranda sulphide deposits to volcanic rocks are reviewed and chemical variations within the volcanic sequence are described. The assemblages of minor elements in the pyrites and pyrrhotites of the Noranda and l\llatagami deposits are similar and are characterized by a high content of cobalt, tin and other elements. Isotopic compositions of lead, other geochronological data and stratigraphically disposed zonal distributions of sulphides and minor elements indicate that the deposits were formed prior to folding and metamorphism. Lead isotope data indicate that the Matagami deposits, and several others, were probably formed about 2.95 x 109 years ago and that the Noranda deposits may be about 50 million years younger. The volcanic sequence at Noranda is younger than the thick sequences bordering it on the east and on the west. The relationships are consistent with the hypothesis that these strata-bound sul1>hide de-posits are coeval with their associated volcanic rocks. T HE writer has been engaged in a metallogenic study of the region between Sault Ste. Marie and Chibougamau. An essential objective of this study is the classification of mineral deposits with regard to their composition, form, geological

Jan 1, 1965

By C. Campero, C. Nicolau, L. Pagliero

The Chilean Congress has recently promoted desalination as a solution to meet the mining industry’s growing water demand. However, this rapid expansion of desalination infrastructure comes with trade-offs. This includes a significant energy cost for treatment, as well as socio-environmental impacts on indigenous communities, tourism, fisheries, and the marine ecosystem. This paper advances a regional-scale model for analyzing competing trade-offs through a case study in the Antofagasta mining region of Chile. Through geospatial data analysis in ArcGIS, new desalination infrastructure investments supplying water to mines are overlain with features of concern raised by communities during the environmental impact assessment (EIA) process, such as national parks, fisheries and exploitation areas for benthonic resources. The resultant model provides a test-bed for analyzing the cumulative effects associated with desalination expansion and for investigating scenarios to mitigate negative social-environmental impacts. The model simulates alternative scenarios for desalination locations and pipeline routes according to competing constraints (i.e. to minimize cost and energy constraints while also avoiding ecological and social hotspots). The ultimate contribution of the work is a demonstration of how the proactive adoption of a regional-scale infrastructure planning might have led to different desalination investment decisions. INTRODUCTION Chile represents the largest producer of copper globally, and holds approximately a third of the world’s estimated copper reserves. However, access to water represents a major constraint to industry expansion and creates conflicts with competing water users (Aitken et al., 2016; Côte et al., 2010). Recently, the Chilean Congress has promoted desalination as a solution to meeting the industry’s growing water demand, which is likely to lead to significant growth in desalination infrastructure to support large-scale mining projects that extract freshwater over a rate of 150 l/s1. By most recent projections, the Chilean copper mining sector is set to increase seawater use by 230% by 2029 (Faversham House Group Ltd, 2019). By the year 2015, Chile had 11 projects serving the mining industry and there are at least other 12 planned plants (Cochilco, 2015). While the use of seawater allows continued expansion of the sector without depletion of scarce underground aquifers, it is nonetheless accompanied with important socio-environmental drawbacks. One such challenge with desalination is the associated energy costs, expressed, both economic and environmental (e.g., CO2 emissions). This includes the energy required for reverse osmosis treatment facilities, as well as to pump water to inland regions at high elevations around 3.100 m.a.s.l in Chile. (Dixon, 2013; Knops et al., 2013). Additionally, the impacts of desalinated water use on flotation chemistry are generally poorly understood, necessitating the need for further research into the impacts, both positive and negative (Cisternas and Gálvez, 2018; Liu et al., 2011).

Jan 1, 2019

By J. F. Davis

Pegmatite dykes containing lithium minerals and beryl occur dose to the borders of intrusive masses of granitic rock in the Winnipeg River area of Manitoba. Both vertical and flat-lying dykes are present. Most of the pegmatites consist of zones, containing characteristic mineral assemblages, arranged more or Jess parallel to the borders of the dykes. Five important lithium minerals are present; each occurs in a separate zone, but all the lithium-bearing zones are situated toward the centres of the pegmatites. Spodumene is the most abundant and widespread of the lithium minerals and occurs as small crystals intimately intergrown with quartz. Beryl is not an important constituent of the lithium pegmatites, but when .present, occurs outside the lithium zones, toward the margins of the -dykes. Beryl is most common in dykes containing few or no lithium minerals. The mineral assemblage in the beryl zone of the lithium dykes is the same as that of the beryl dykes. The attitude and internal structure, particularly zoning, of the pegmatite dykes, and the texture and assemblages of the constituent minerals, have an important bearing on exploration, development, and mining of these pegmatites, and on the extraction of various mineral products from them.

Jan 1, 1958

By M. Huang

Electrodeless conductivity was employed to investigate the feasibility of continuous on-line monitoring of the free acidity of sulphate and/or chloride solutions of Cu and other base metals from various hydrometallurgical processes. These solutions were measured with both commercial and experimental electrodeless conductivity sensors from 15 to 250°C. It was confirmed that hydrogen ion has the greatest impact on conductivity by carrying the bulk of the current because it is the most mobile ion. In combination with a solution speciation analysis the conductivity sensor can be calibrated to account for the contribution of Cu electrolytes as well other dissolved salts allowing fast and accurate on-line measurement of free acid. The sensor was tested at both lab and pilot scale with very good performance. The average difference between the measured and the titrated acid concentration was less than 5%, which is excellent for industrial applications.

Jan 1, 2007

By Ivan Malinsky, Gérard Castonguay

"On a développé un procédé qui donne une fonte (2,3% C, 0,07% V) du V2O5 (99%) et un rutile synthétique (94% TiO2) à partir d'un minerai, dont les réserves au Québec sont importantes. Le procédé comprend les opérations suivantes: 1) la concentration magnétique du minerai (30% Fe, 9% TiO2 et 0,65% V2O5) pour produire un concentré (65% Fe, 7% TiO2 et 1,6% V2O5); 2) le smeltage du concentré aggloméré dans un four à arc, sans fondant, pour produire une fonte et une scorie (30% FeO, 40% TiO2 et 8,0% V2O5) qui contient plus de 95% du vanadium et du titane présents dans le concentré; 3) le grillage alcalin (37% Na2CO3) de la scorie suivi d'une lixiviation à l'eau et de la précipitation de l'hexavanadate d'ammonium à partir du filtrat; 4) la lixiviation du résidu par l'acide sulfurique pur ou usagé pour produire un rutile synthétique. Un estimé préliminaire de la valeur économique du projet laisse croire à sa rentabilité à la condition que l'investissement pour le smeltage soit inférieur à environ 400$/tonne de fer.IntroductionLes gisements de magnétites titanifères sont nombreux dans le monde. Ils consistent en une magnétite étroitement liée a l'ilménite, La teneur trop élevée en TiO2 empêche l'exploitation de ces gisements pour la production de fer. Cependant, dans certains cas, la magnétite a une teneur intéressante en vanadium qui peut rendre l'exploitation de ces gisements rentable. Aujourd'hui, les magnétites titanifères constituent la plus importante source de production de vanadium. On estime qu'environ 70% du vanadium produit provient de ces sources."

Jan 1, 1983

By Xiaowen (Wendy) Ma, Hans Liang, Xiaoying Chen, David Way

"The mineralogical characteristics of the process streams provide key indicators to the potential improvement in the metallurgical performance. Therefore, the process mineralogy and diagnostic metallurgy have been widely used as a tool to assist the metallurgists at the operating plants. The challenge of this study was then how to characterize the diagnostic flowsheet of the minerals of interest in the process streams across the flotation circuit. The investigation from this study indicates that the minerals chematic flowsheet can visibly demonstrate the sources that caused the gold losses during the mineral processing.In this paper, we present studies of the flotation process stream samples, representing the feeds, intermediate products, final concentrate and final tails, which were produced from the flotation concentrators of Mt Carlton mine in Queensland, Australia. This study was focused on characterizing the process streams and learns how the gold in the process streams was associated with other sulphide minerals and host minerals on a size by size basis. The automatic QEMSCAN/MLA Particle Mineral Analysis (PMA) and Trace Mineral Search (TMS) were applied to identify the minerals and to detect the gold in the sized fractions of process streams. The Laser Ablation ICP-MS (LA) spot analysis, QEMSCAN EDS spot analysis and electron microprobe spot analysis were employed to identify and quantify there fractory gold concentrations in the sulphide minerals, like pyrite, and the elemental concentrations of visible gold grains. The diagnostic flowsheet of gold recoveries by the process streams, by mineral association classes and by the particle sizes were generated and discussed."

Jan 1, 2017

By M. B. Mansur, A. S. Guimarães, A. J. M. Santanilla, D. C. R. Espinosa, J. A. S. Tenório, R. A. Pini

The separation of Ni and Co from sulphate medium containing Mn, Mg, Cu and Ca was carried out by solvent extraction. The object of this study was to investigate the synergistic effect using phosphinic acid (Cyanex 272) and carboxylic acid (Versatic 10) and their mixtures in kerosene. The extraction percent of each metal ion was found to increase with increasing pH and extractant concentration. Co was preferentially extracted over Ni under the same extraction conditions. The separation factors of Ni/Co increased with the use of the synergistic systems investigated.

Jan 1, 2014

By Frédéric Flament

The aim of this paper is to present the development of a data validation software as component of a commercial mass balance package. Data reconciliation through mass balance is basically an optimization problem constrained by the law of mass conservation. As any optimization problem solved with a modern and robust software application, erroneous information or starting point will always lead to a solution, whether it is realistic or not. Moreover, good information wrongly weighted by an incorrect error model will lead to the same bad ending. In an industrial context where competition requires accurate information, data reconciliation without validation can be disastrous and calls for data validation before and after reconciliation. The challenge in automated data validation resides in the development of general theoretical solutions. Until now, none has been presented and only partial solutions are available. The development presented in this paper incorporates some of these partial solutions. The integration of human knowledge into the application paved the way to a more general solution. The combination ?theoretical validation ? human expertise? proved to be flexible and reliable enough to be integrated in a commercial data validation package. Numerous examples though industrial applications are presented. These applications demonstrate the validation of raw measurements, user support in the development of error models and validation of reconciled measurements.

May 1, 2001

By L. T. Pasiechnyk

After a brief review of the various hydrocarbon storage methods currently being utilized and statistics on underground hydrocarbon storage, this paper will briefly describe the technology involved in solution mining salt to create caverns of engineered shape and size and briefly discuss the economical and environmental advantages of hydrocarbon storage in solution-mined salt caverns. Other possible uses of salt caverns will be mentioned.

Jan 1, 1978

By Fred V. Seibert

The Functions and the Responsibilities of the Institute The Canadian Institute of Mining and Metallurgy is unique. ln addition to the welfare of its members, it has a real interest in the welfare and promotion of one of Canada's largest and most important basic industries. It is because of this that the membership is composed of both individual and corporate members. The individual members are both technical and non-technical (Members and Associates). Both Members and Associates have the same status in the Institute and all are interested in the welfare of the mineral industry. The aims and objects of the Institute 11re twofold. The education and welfare of its individual members and the sound promotion and welfare of the mineral industry. Perhaps it might be well if we reviewed these aims and objects as stated in our Constitution: "First - To promote the arts and sciences connected with the economical production of valuable minerals and metals, by means of meetings for the reading and discu11ion of technical papers, and the subsequent distribution of such information as may be gained throo.gh the medium of publications". It cannot be denied that we have do ne a good job in this particular phase of our work. Nevertheless, there is still room for improvement. It has been suggested that we might have more discussion and, on occasions, more criticism of our papers and programmes. This can best be done if the authors will have their papers prepared in sufficient time to permit of preprints being made availa1ble before the meeting at which they are to be presented.

Jan 1, 1950

By T. Alan O'Hara

"Annual mining revenue can be computed by formulae relating metal prices, smelting schedules, concentrate grade and recovery to known ore grade and an assessment of core samples. Operating costs at different daily tonnages are related to orebody shape, mining method, milling process and general plant services. Capital costs are related to sizing of mining equipment, mine development, plant-site topography, climate and accessibility, plant services and personnel housing. IntroductionA crude guide to the average 1978 cost of mine projects is shown in Figure 1, but the costs of many mine projects have differed widely from the graphed average costs of $800,000 T0.6 for underground mine/mill projects and $400,000 T 0.6 for low-grade open-pit mine/mill projects.High mine project costs and high operating costs are characteristic of open-pit mines with high stripping ratios, underground mines with thin orebodies, mills with complex metallurgy, and projects located in isolated regions with severe climate, mountainous topography, and lacking access to existing roads, towns and electric power. When none of these adverse conditions prevailed, the mine project cost was typically much less than the graphed average cost. Virtually all the conditions likely to cause high capital and operating costs are known from knowledge of the local topography, climate or accessibility, or can be assessed by tests on core samples, as soon as the orebody has been outlined by drilling .A more accurate estimate of over-all project capital cost and operating cost can be made from a summation of items of cost after judging the effect of specific local conditions on each item of capital and operating cost. This paper offers guides in judging the effect of local conditions on the sizing and 1978 cost of specific items of capital cost and operating cost and operating cost of mine projects. When the specific items of capital cost and operating cost are totaled and measured against expected net revenue and taxes over the life of the mine using the net-present-value or discount-cash-flow methods, the result should show whether the mine project development is clearly feasible, doubtfully feasible or clearly uneconomic. If the development of the mine project is clearly feasible, or probably feasible, a detailed feasibility study by experienced consulting engineers should be commissioned before any financial commitments are made; but if project development appears to be uneconomic, the time and cost of a detailed feasibility study is not warranted."

Jan 1, 1980

By R. S. Bigelow

Part 1.- Metal Mines Early experiments with mechanical loaders in metal mines were confined largely to machines of the shovelling type and generally air-operated. Although the first application of the scraper to metal mines dates back to 1910, it was not until about twelve years ago that it came to be used extensively. Generally, the scraper gives better results in metal mines than in coal mines, as degradation due to soft bottom and breakage are not factors, but it has a wide range of application and is successfully used in the mining of salt, potash, gypsum, zinc, copper, and a variety of ores, from soft material to hard chunky ore which settles compactly. Today, the scraper has replaced to a large extent the shovelling type of machine in metal mines. Scrapers have offered an inexpensive solution for the mucking problem and are now employed in most mining districts throughout the world. They are operated by labourers of all colours and degrees of skill. Each installation, however, requires individual study on the part of the mine mechanical department to determine the type of scraper, horsepower of hoist, and most economical speed of rope, as well as method of rope rigging. Unfortunately, the scraper has no power to select pay ore from waste and its suitability for use under circumstances which might require sorting of the ore can only be decided by a weighing of the economic factors involved

Jan 1, 1931

By P. A. Crane, N. Shirley, Aung Moe, H. M. Nicholson, D. Kan

Kazakhstan’s first commercial copper-leach solvent extraction-electrowinning plant, Central Asia Metals’ Kounrad project, was commissioned in April 2012. Exploiting low grade waste stockpiles produced during Soviet era open pit mining, a 10,000 tpa copper cathode plant was designed, constructed and commissioned within 18 months. Overcoming initial challenges with a workforce unfamiliar with the technology and with extensive periods of sub-zero conditions during winter the project has consistently met targets and produced high quality copper cathodes at cash costs of less than US$1/lb. Challenges encountered during the first two years of operation are described and future plans briefly discussed.

Jan 1, 2014

By Mark W. Bartlett

Program Objectives ??Identify and implement a tool for haul truck drivers that: -Reduces or eliminates fatigue-related injuries and fatalities -Reduces accidents and equipment damage ??Following evaluation period, apply tool where most effective Why do We Need a Fatigue Monitoring Tool? ??Everyone has probably fallen asleep while driving ??Driver fatigue is a major source of property damage and serious haul truck serious incidents ??To protect ourselves from the other ?tired?driver ??To know when to ask for relief ??To know when we are seriously distracted from driving ??To measure improvements in sleep incidents based on shift changes and intervention ??To help prevent incidents like the following:

May 1, 2011

By S. Broda

Waste rock piles (WRP) are made of heterogeneous, coarse grained waste rock, with inclined layers due to segregation along the slopes and haul traffic compacted layers, creating highly contrasted hydrogeological conditions. The internal structure of the pile has a major impact on water and oxygen movement and pore water pressure distribution. In the presence of reactive minerals, this influences the production of acid mine drainage (AMD) or contaminated neutral drainage (CND) with metal leaching from the WRP. Water flow and distribution may also affect slope stability, particularly following major infiltration events (rain/snow melts).The prediction and interpretation of water distribution in WRP is a challenging problem. Numerous numerical investigations of short and long term forecasts have been conducted, and many of these were found of limited reliability. The shortcomings of existing approaches are typically due to difficulties in representing preferential flow processes in macropores. Such phenomena are in fact often neglected in the assessment of water flow in WRP because these are unattainable with the classical porous media approach typically used in this field. This paper focuses on the use of modeling techniques originally designed for massive fractured rock media to simulate flow in WRP. Waste rock properties used in this study are retrieved from large scale laboratory permeability and water retention tests and from in situ infiltration tests. The effect of WRP configurations on water flow into potentially reactive zones is examined with the numerical 3D fully-integrated surface/subsurface, variably saturated flow model HydroGeoSphere. Material properties retrieved from the laboratory tests are represented by means of stochastic facies distribution generated within a probability framework. Modelled soil water contents and hydraulic head distributions, as well as fluxes within a simple waste rock pile, with compacted layers, are compared with results retrieved from simulations based on the classical equivalent porous medium approach. Results indicate significantly increased flow towards the looser waste rock zone by considering heterogeneous material distribution, causing weak or absent capillary barriers and preferential flow paths. Practical implications for the design of waste rock piles are also discussed.

Aug 1, 2013