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By K. D. McBean, W. H. Hannay, B. A. Stimmel

The electrolytic plant at Trail, B. C., was erected by the Consolidated Mining and Smelting Company of Canada, Ltd., for the treatment of zinc ores and concentrates, particularly those of the Sullivan mine at Kimberley, B. C. It began operations in 1916 at a rated capacity of 60 tons of cathodes per day, which has been steadily increased to the present production of 400 tons per day. The Sullivan has furnished the greater part of the zinc so far produced, although notable tonnages of customs zinc concentrates have been treated. The maximum yearly tonnage of customs concentrates, 25,000 tons, was treated in 1926. Practically no customs concentrates hale been treated since 1929. The total bar zinc production to the close of 1935 was 1,092,782 tons. The zinc mineral in the Sullivan ore is marmatite of somewhat variable composition, ranging between 6ZnS.FeS and 8 ZnS.FeS. Practically all the zinc ores tributary to this plant are marmatites; and the iron content of the zinc mineral varies considerably. The formation of zinc ferrite during roasting is now a matter of common knowledge, so the possible extraction from any zinc concentrate is largely a function of the iron content; the progress made in concentration is reflected directly in zinc-plant recovery. The Trail plant operafes on the low-acid system, as do all the other major plants on this continent at present operating, except the electrolytic plant of the Sullivan Mining Co. at Kellogg, Idaho. The new Magdeburg plant, in Germany, occupies an intermediate position between high and low acid. Plant operation at Trail will be treated in this paper under five main sections: roasting, leaching and purification, electrolysis, cadmium recovery and melting. The oxide section of the plant, treating zinc fume from re-treatment of lead blast-furnace slag, is practically a separate zinc plant; this is necessary because of the presence of fluorine in the smelter zinc fume. Cadmium is recovered electrolytically from the purification residues of both the sulphide and oxide leaching plants.

Jan 1, 1937

By ERNEST W. ELLIS

MORE or less contradictory findings as to the most satisfactory feed for concentration tables of the Wilfley type is shown by the diversity of opinion among experimenters. Prof. R. H. Richards,l as a result of his work, favors classification. On the other hand the work of Messrs. Cox, Gibbins, and Porter,' of McGill University, points in general to the desirability of screen-sized feed The ore used was obtained from the West mill of the Bunker Hill and Sullivan Mining and Concentrating Co., Kellogg, Idaho, and consisted of argentiferous galena in a gangue of quartzite and siderite. The natural feed was taken from the launder supplying the Fahrenwald classifier. Classified feed was collected from each of the ten spigots of this same classifier. From the natural feed the screen-sized feed was pre- pared in the laboratory. All three types of table feed were therefore derived from the actual mill circuit of a large plant.

Jan 1, 1926

By Charles H. Fettke

The Bradford field of northwestern Pennsylvania and adjacent portions of New York state has attracted world-wide attention in recent years on account of the remarkable success that has been attained in the application of water-flooding as a means of increasing the extraction of oil from a pool that had almost reached the economic limit by ordinary production methods. It is one of the few large oil fields in which artificially conducted water drives have thus far proved successful, although many attempts have been made to apply them elsewhere. As detailed a knowledge as possible of the character of the producing sand in this field is therefore of considerable interest, not only from a scientific but also from a practical standpoint. Outside the Bradford field, such knowledge should aid operators in determining whether or not their sands are amenable to flooding. In the Bradford field itself flooding operations are not uniformly successful over the approximately 85,000 acres of productive area, due in many instances primarily to variations in sand conditions. A knowledge of just what these variations are would often be a great aid in overcoming the difficulties, or else would save considerable sums of money which might otherwise be wasted in experimenting in areas where the chances of success are very small. Realizing that more precise information in regard to the nature of the reservoir rock was essential to improvements in the methods of oil recovery, the Northwestern Pennsylvania Oil Producers Assn., by private subscription of its members, took a core of the Bradford sand from a well 1/2 mile west of Custer City, Pa., during the spring of 1925. The Forest Oil Co. also took a core of the same sand from a well about 8 miles east of Bradford at that time. The cores were submitted to the United States Geological Survey for study and A. F. Melcherl has published the results of porosity determinations on the Custer City core.

Jan 1, 1929

By Morgan Walker, C. D. Watson, Reid W. Bond, D. L. Trax

Common practice in the Mid-Continent until recently was to prolong the natural flow of oil wells as long as possible by agitation, and then swab for a short period until the well was put on the pump. Comparatively recently the gas-lift has superseded the swabbing and agitating period and in some cases encroached on the natural flowing life, particularly where it was evident that the potential oil capacity of the well was greater than the gas supply, or lifting medium. The majority of wells are finished with either 6¼, 65/8 or 8¼-in. casing and connected to a separator through a flow line which is usually 65/8 in. The flow line is generally designed to eliminate sharp turns and has reduced the gas-oil ratio and therefore increased the efficiency in a good many instances. Until recently all wells were allowed to flow without restriction against the possible trap pressure until it was deemed advisable to put them on gas-lift. This resulted in a fairly efficient flow during the early life of the well if the well was rather large but was usually inefficient in small wells and in the later flowing life of large wells, on account of the large area in the casing and therefore excessive slippage. Recently, considerable effort has been made to increase the efficiency of small flowing wells by running tubing to eliminate as much slippage as possible. With large wells there is a considerable trend toward back-pressuring, or beaning to find out whether it is possible to reduce the gas-oil ratios and increase the flowing life. The greater number of fields that have been back-pressured have been produced in that manner through necessity, either to restrict production for proration purposes or, in fields producing by hydraulic pressure, to reduce water encroaching. The recent Cromwell sand development in Little River is an example where both back-pressuring by means of high-pressure traps and beans and flowing through tubing were used to conserve gas, reduce the high gas-oil ratio and prolong the flowing life. It

Jan 1, 1930

By Robert L. Haffner

When mining operations of The Eagle-Picher Co. began in the Illinois-Wisconsin zinc mining field in 1949, all underground loading of broken ore and waste was by caterpillar-tracked machines. Beginning in 1956 rubber-tired end-loaders were brought in; ultimately they completely supplanted the tracked units. End-loaders proved to have the mobility needed for the mining conditions and additional merit in auxiliary capacities. Eagle-Picher operates five mines in this area; two are entered by shafts and three by inclined adits. Several ore zones, some of which are attenuated over a considerable distance, are worked from the same entry. Consequently underground haulage roads connecting or following these orebodies have attained great length. In addition, working places are often widely separated because of the character of the mining operations which include pillar recovery and extending haulage connections into old workings. At one mine, the haulage distance is 5000 ft on either side of the shaft, at another the maximum one-way distance is 8400 ft, and at another the present road system of 6800 ft is expected to reach 10,000 to 12,000 ft.

Jan 6, 1962

By N. A. Ziegler

A CERTAIN amount of interest has been indicated recently in the resistance to oxidation at high temperatures of iron-aluminum alloys (rich in iron). Hautman1 published a paper in which some interesting results are given. According to his paper, only alloys containing at least 8 per cent aluminum indicate a marked improvement in their resistance to oxidation. At about this aluminum content, however, alloys become brittle, which considerably reduces their commercial value. About two years ago the author performed a series of experiments, the results of which are presented here. A series of iron-aluminum-carbon alloys was prepared by melting electrolytic iron, aluminum and high-carbon iron alloy in an induction vacuum furnace.2 The list of these alloys is given in Table 1. Each alloy was forged in the ordinary way to

Jan 1, 1932

On. Tuesday, Apr. 8, the Rocky Mountain Club held its 12th annual dinner at the Waldorf-Astoria, New York. In reporting the dinner the Evening Telegram says: "General Coleman du Pont was sort of master of ceremonies, and he conducted the affair at the end of a Colt .45. It was the General's `forty-five' which filled the banquet hall of the Waldorf-Astoria with the brand of smoke which Uncle Sam showered so generously upon Germany's hordes. It was General du Pont's `forty-five' which bellowed and thundered and echoed through Fifth avenue, scaring horses and shell shocking pedestrians: But no one was hurt or badly shocked except those who could not discern the artistry of Miss Doraldino's dance. "There were Western men around the table who have just come hack from over there. For instance, there were Brigadier General G. H. McManus, General Shanks and a score of others. And there were Thomas H. Watkins, who is said to own half the State of Pennsylvania and is known as the `Coal Baron'-of Pennsylvania,, and Alba B. Johnson, president of the Baldwin Locomotive Works, each one a Westerner, with personality and type suggestive of some of the wonderful men Bret Harte wrote so much about. "It seemed as though General du Pont, who was chairman of the Reception Committee, tried to eclipse all former meetings, and he succeeded if congratulations are a criterion. " General du Pont startled the management of the Waldorf and surprised the diners by staging a three-round bout between Frankie Fay and Phil Wagner. The clash between these two featherweights made Waldorf history, because it was the first boxing contest ever held in the hotel. Tex Rickard, who is going to chaperone Jess Willard and Jack Dempsey in a fight in the near future,-was scheduled to referee the contest, but at the last moment, for some obvious reason, M. E. Schermerhorn was sent in as third man. The bout was a slashing one. Miss Amparito Farrar, lately returned from France, where-she sang for the 'dough-boys;' Eleanore Wetmore, the Rath Brothers and Phil Baker were among the others who entertained.

Jan 5, 1919

Jan 1, 1928

By David J. Mack, T. V. Philip

The effects on the Cu-A1 eutectoid transformation of the addition of a third element from the second long period and from Group IIB of the periodic table, were studied by isothermal transfomation techniques. The valency of the third element shows the most pronounced effect on the eutectoid decomposition. With some exceptions, the atomic size factor of the third element shows some consistent effects on pearlite nucleation and growth. The atomic concentration or the electronegative valency of the third element shows wo consistent effect on the eutectoid decomposition. Addition of the third element helps spheroidization of pearlite. SINCE the pioneering work of Davenport and Bainl on the eutectoid decomposition in steel by the isothermal transformation technique, an enormous amount of data has been accumulated on the eutectoid transformation characteristics of commercial steels. While the eutectoid reaction in steel is of tremendous industrial importance, it appears to be quite unique among the eutectoid reactions. Though the metal-lographic structures developed in the Fe-C and Cu-A1 eutectoids are similar, it is now evident that the two eutectoid reactions are quite dissimilar. The eutectoid decomposition in the Cu-A1 system is more complicated partly due to the appearance of transitional phases in addition to the equilibrium phases. * The first isothermal studies of aluminum bronzes were made by Smith and Lindlief2 and later by Mack,3 Klier, and Grymko,4 and recently Hayne 5,6 A few other systems, structurally analogous to the above, have been studied by the same technique.7-10 Kasberg and Mack1' studied the effects of iron on the transformation of commercial aluminum bronze. The effects of manganese and nickel on this aluminum bronze and those of iron, manganese, and nickel on the binary Cu-A1 eutectoid have been recently studied.12 The object of the present investigation was to study, by isothermal transformation techniques, the effects (with respect to the fundamental factors of alloy formation) of the addition of a third element on the transformation of a Cu-Al eutectoid alloy, 11.8 pct Al. The third elements chosen for the purpose were silver, cadmium, indium, tin, and antimony from the second long period, and beryllium, zinc, and cadmium from group 11B of the periodic table. They were added in nominal amounts of 0.5, 1.0, and 2.5 pct by weight to a eutectoid Cu-A1 alloy. These third elements were expected to show the effects of electron valency, atomic size factor, and electronegative valency effects on the binary eutectoid transformation. PFLEPARATION OF ALLOYS AND PROCEDURE All alloys were made as 400-g heats by induction melting in a graphite crucible with a graphite lid. The molten alloy with a layer of graphite powder on top was stirred at regular intervals by a graphite rod. When the melt was judged to have acquired sufficient superheat, a pinch of common salt was sprinkled on top and any crust scraped off to one side. It was then chill cast into a 5/8 in. rod. The alloys with silver were prepared by remelt-ing the high-purity Cu-A1 eutectoid alloy used by Mack3 with high-purity silver (99.99 pct pure from Hardy and Harmon, Inc.). In the preparation of all the other alloys, polished electrolytic copper shot (from Belmont Smelting and Refining Co.) and high-purity aluminum (99.99 pct pure from Aluminum Co. of America) were used.

Jan 1, 1962

By Tong Guangxu

INTRODUCTION Throughout the world, the caving mining methods of ore-draw under the overlying waste rock are sublevel caving in Sweden, block caving in U.S.A. and forced block caving and sublevel caving with sill-pillar in U.S.S.R. These caving methods are of high efficiency, low cost and large production (especially the block caving method) when compared to opencast mining. From the ore production of all under- ground mines, the largest annual production of underground metalliferous mines in the world is caving methods. The sublevel caving in Kiruna Iron Mine of Sweden has reached annual ore production over 20 million tons in 1974. The block caving in Climax Molybdenum Mine and San Manuel Copper Mine of U.S.A. both have produced about 40 thou- sand tons of ore per day in 1971. At the same time, the productivity of Kiruna was 12 thousand tons of ore per man-year, Climax 42.8 tons (48.3 short tons) per man-shift and San Manuel 29.01 tons (32.1 short tons) per man-shift. The main feature of this group of mining methods is the underground extraction of ore from beneath overlying caveable waste rock. Since the loss and dilution of ore are inherent (sometimes to a great extent), the control of ore-draw in these methods as com- pared with other methods is very important. Consequently, concerned Universities and Research Institutes have devoted great amounts of research on ore-draw theory and control management which has provided positive results to mine production, and has apparently promoted the development of the caving methods. During 1979 in China, metalliferous underground mines accounted for 15.22% of the total iron ore produced, while also accounting for 56% of total non-ferrous production. According to the mining methods, sub level caving in the principal underground iron mines counted for about 56.74% of total principal underground iron mine production, but only about 1% of total non-ferrous underground mine production. Relative to forced block caving and sublevel caving with sill pillar, the Chinese non-ferrous under- ground mines estimated about 35% of total non-ferrous underground mine production from these two methods, mainly from the latter. From the trend of development of underground metalliferous mines in China, the percentage of production in caving will be increased in the future, especially in block caving and forced block caving which have already been given great attention in the mining circle. In these types of mining methods the ore is drawn from the stope under a large area of overlying waste rock, which complicates the basic regulation and control of ore-draw, but provides lower loss and dilution than sublevel caving. Because of these reasons, the Kiruna Iron Mine in Sweden is intending to change its sublevel caving by testing a sublevel shrinkage caving method and considering a large area of ore-draw beneath the stope as an advantage. Therefore, the basic regulation and control management of ore-draw under a large area, as practiced in China, will be discussed in this paper. BASIC REGULATION OF ORE- DRAW FROM CAVING STOPE The aim of studying ore-draw under a large area of overlying waste rock is to se- cure a planned draw schedule that guarantees a certain plane of interface between ore and waste rock, and controls the change of its shape in spatial position for reducing ore loss and dilution during the draw process. Presently, the ellipsoid theory is comparatively near the actual attitude of ore-draw from the cave. 1. Ore Drawn Out from Single Drawpoint Laboratory testing and practical experience all show that after a certain amount of ore has been drawn out from a drawpoint, its original shape in the stope before drawing is more or less similar to an ellipsoid, hence the name "draw ellipsoid." This draw ellipsoid is cut at the bottom by a horizontal plane corresponding to the raise of the drawpoint, and its volume can be calculated by the following formula:

Jan 1, 1981

By Takahide Wakamatsu, Shigeru Mukai

Fundamental investigations were made on the treatment of slime and the chrysocolla flotation, both of which are urgent problems to be solved in copper oxide mineral flotation. Unfavourable effects of slime on flotation are caused by the slime adsorption at the air/liquid Interface as well as the slime coating on the mineral surface. The adsorption of slime at the air/liquid interface was measured by using various kinds of slime particles. As a consequence, goethite, bentonite and talc tended to adsorb markedly at the interface. As a desliming method, slime flotation with a polymer flocculant such as polyethylene-oxide prior to the ordinary copper oxide flotation was found to be effective. The use of both a copper-avid organic reagent and an alkyl xanthate was examined for a selective collection of chrysocolla through xanthate adsorption tests, chrysocolla float- abllity tests and flotation tests for synthetic and natural ore. The copper-avid reagents used were salicylaldoxime, 8- hydroxyquinollne and benzoin-a-oxime. As a result, the ad- sorption of higher xanthate such as amyl xanthate on chrysocolla as well as the chrysocolla-to-air bubble attachment was increased by the presence of a copper-avid reagent under suitable reagent addition and pH of pulp. Flotation tests for synthetic and natural ores confirmed that chrysocolla could be floated sufficiently and selectively with a copper- avid reagent like 8-hydroxyquinoline or salicylaldoxime with its subsequent collection by amyl xanthate.

Jan 1, 1976

By L. W. McKeehan

IT is no longer necessary, if it ever was, for your annual lecturer to apologize for including in his remarks frequent references to the arrange-ment of metal atoms in crystals and for basing his arguments that metals behave as they do upon their crystal structure. Neither will any objec-tion be raised because the large metallic crystals of which we will speak are hard to prepare and of negligible commercial interest. The particular set of physical properties we propose to discuss-ferromagnetic proper-ties-may require more justification. Very few in this audience are primarily, or even remotely, interested in the ferromagnetic behavior of the metals they handle. By no means all of you ever deal, by choice or by necessity, with metals which display any ferromagnetism at all, and even those who study or control ferrous metallurgy must usually depend upon electrical engineers for assistance in ferromagnetic applications. My excuse for talking about such an obvious specialty is, like all Gaul, divided into three parts. In the first place, the members of the com-mittee who select the annual lecturer must wish the speaker to confine himself to matters he has at least thought about before he prepares his speech. In the second place, the study of ferromagnetism in crystals has, as you will soon realize, suffered in the not-too-distant past from inade-quate metallurgy. Further progress probably depends upon proper use being made of the skill and knowledge of some members of the Institute of Metals Division who have not, before today, been asked to think about the problems presented here. Finally, there is at least a sporting chance that the ferromagnetic properties of a few metal crystals will give some insight into the more generally interesting properties which they share with nonferromagnetic metal crystals.

Jan 1, 1934

By L. L. Wyman

THE resultant embrittlement caused by the exposure of oxygen-bearing copper when hot and exposed to reducing gases has been the subject of many studies.1 Little attention, however, has been given to the possible embrittling effects due to atmospheres or conditions that under some circumstances might be the source of a reducing gas. At rather infrequent intervals there occur reports of copper becoming embrittled during normal annealing cycles in commercial steam-atmos-hered furnaces such as customarily are used for this operation. As might be expected, several other factors exist-such as oil, dirt on the wire, or in the furnace, or metallic surface contacts that might produce reducing gases and be the source of the trouble. However, in consider-ation of the statement made by Ruder,2 it would seem that under some conditions steam itself might prove to be the source of trouble. A consideration of the amount of the dissociation of water vapor up to temperatures of the melting point of copper shows that' the amount of hydrogen that could come from this source is far too minute to account for any embrittlement. What such information does not tell is what will happen at the surface of copper when subjected to steam at elevated temperatures, for entirely different conditions may persist, which would account for Ruder's observation. Furthermore, there are no data as to what might happen at the surfaces of other materials present, the result-ant of which might affect the condition of the copper present. For this reason, it was decided to make a series of experiments com-parable to those previously conducted by the writer,1 which would clarify the effect of the steam on copper, and in copper in the presence of steel.

Jan 1, 1940

By J. E. Ostberg, G. Phragmen, A. Hultgren, S. Wohlfahrt

Detailed study was made of a number of rimming ingots, both low and high carbon, and especially upon effects of superimposed air pressure. Requirement to suppress core bubbles is between 10 and 15 atm; at 6.5 atm freezing was in semikilled manner and at 3 atm, steel was of rising type. Probable mechanism of freezing under various conditions is discussed. AN earlier paper' reported an investigation made by a committee for studying rimming steel ingots appointed by Jernkontorets in Stockholm. The present paper is the outcome of some further work done by the same committee. Since the characteristics of ordinary rimming steel are connected closely .with the amount of gas liberated during freezing and since this amount of gas is governed by the pressure, it was considered of interest to ascertain in what manner and to what extent definite pressures applied to the top of the liquid steel in the mold would affect the solidification process and the consequent structure of a rimming steel of ordinary composition. The experiments were made at the Domnarfvets Steel Works. The steel was made according to normal practice in a 4-ton Rennerfelt electric furnace. Ferromanganese was added in the furnace; no aluminum was added, with one exception. Analyses of the four heats are given in Table I. The top-poured ingots measured about 12 in. sq x 48 in. and weighed about 1300 lb. One or two ingots of each heat were allowed to solidify under pressure, using a special device for admitting compressed air to the upper closed part of the mold, as shown in Fig. 1. A heavy plate sealed with asbestos was bolted to the top of the mold. The plate had a tapered aperture for pouring. Immediately after pouring the hole was closed by a wedged plug, and compressed air was admitted through a hole in the plug. Because of some delay in applying the plug, full pressure was not reached immediately. The pressure was adjusted to the desired value as indicated by a manometer. In order that the interior of the ingot might have the benefit of the pressure, the freezing of the top crust was delayed by a refractory lining applied to the top part of the mold, Fig. 1. Ingots were also cast from each heat without applied pressure, and with and without refractory lining at the top. Axial sections of ingots were cut either of the whole ingot or of some part of it of special interest; sections were polished and usually etched.' To facilitate description of structures the following terms may be used for different types of ingots solidified under gas evolution: 1. Box-hat or boot-leg ingot: Abundant gas evolution during casting and during rimming; no rim holes. 2. Normal rimming ingot: Lively gas evolution during rimming; usually rim holes in lowest part of

Jan 1, 1952

By Morris Cohen

This paper deals with the calculation of the composition of the infinitesimal trace of alloy that transfers from the liquid to the solid state at each temperature during the equilibrium solidification of a binary solid solution, and which thereby enables the compositions of the coexisting liquid and solid phases to follow along the liquidus and solidus lines respectively during the cooling. A general expression for the composition (S) of the liquid-to-solid transfer at each temperature has been derived S - ZLXL(XL - P) + Zsxs(P - XS) ZL(xL - P) + Zs(P - XS) where ZL and Zs are the slopes of the liquidus and solidus lines at the given temperature, XL and xs are the composi-tions of the stable liquid and solid phases at the same temperature, and P is the composition of the alloy under considera-tion. The S equation is valid for the process of equilibrium heating as well as cooling, and may be applied to vapor-to-liquid, vapor-to-solid, liquid-to-liquid, and solid-to-solid transfers if the corresponding equilibrium diagrams are known.

Jan 1, 1940

By T. F. McCormick

THIS year, 1950, is the golden anniversary of the construction and operation in this country of a tube mill for the sole purpose of fabricating aluminum alloy tubing. For a short period prior to the beginning of this mill, aluminum alloy tubing was obtained from foreign sources or produced in mills fabricating other metals. Indeed, it was a very short period because aluminum itself was a newcomer in the field of metals. The first sheet rolling mill had been in operation just eight years and a rod rolling mill for the production of wire and cable had been functioning one year. The first tube mill for aluminum was built by the Aluminum Co. of America in May 1900 and started production with four draw benches and five men, including the mill superintendent. The building itself was a lean-to attached to a sheet-rolling mill at New Kensington, Pa. The cost of equipment, including the draw benches, dies, mandrels, and other tools, was about $5000. This figure seems absurd in the present day but nevertheless it was questioned at that time whether or not such a large sum should be spent to embark on a new and uncertain venture. The initial production system for the new mill consisted of casting round hollow ingots in a tilting-type iron mold, reducing the ingots to bloom size outside the plant, and finally drawing to size on the draw benches. This method of producing aluminum alloy tubing survived just two years, as blooms of satisfactory quality were not obtained consistently. It was superseded by the cupping method in which a 24-in. diam circle cut from a rolled plate was formed into a tube bloom using first a small cupping press and then a push bench. It was stated that tubing so produced was limited to a maximum diameter of 2 3/4 in. and to wall thicknesses varying from 12 to 24 gage. However, for the first time all the operations were performed at one plant and the result was a quality product. Later larger cupping presses and push benches were obtained and the method continued to be the principal one for aluminum alloy tubing for almost a quarter of a century. During the interim the use of a Alan Mannesmann -type billet piercer was explored and it was used to some extent, but failed to produce consistently a smooth inside surface suitable for drawing with aluminum alloys. Experiments started during the latter stages of World War I in the production of tube blooms with a hydraulic extrusion press, led to the use of this type of equipment to make tube blooms for further drawing during a change-over period extending from 1925 until 1930. At this time the cupping method was discarded completely. From these humble beginnings, the aluminum alloy tubing business expanded until well over six million pounds were produced in a single month in the United States during World War II. The major portion of this production was in strong alloys which did not appear in the tubing picture until 1022, when 17S alloy tubing was introduced for aircraft construction.

Jan 1, 1951

By Francis B. Foley

Fundamentally, slag control in acid open-hearth steelmaking cannot be considered from any different viewpoint than can that in basic open-hearth melting. The same laws of mass action and distribution apply in both cases, so that while most, if not all, of the recent intensive study of slag-metal reactions have been carried on in basic furnaces the principles evolved are nevertheless applicable to acid open-hearth steelmaking and it is therefore not our intention to discuss the various possible chemical reactions in the slag and between slag and metal. The points we have to carry in mind, in considering acid melting practice, are the differences in the type of steels produced and the difference in the chemistry of both the steel and the slag. The acid furnace is used to produce, let us not say "quality" steel, for, after all, a "quality" steel for one purpose is not a "quality" steel for another, but steels that require acid melting practice to be of proper "quality." Steels that are required to have high physical properties in tests taken transversely from forgings are peculiarly the product of acid furnaces. In this class may be placed various ordnance materials, notably gun forgings and projectiles and large commercial forgings requiring high transverse ductility. Forgings requiring an extremely hard surface, polished and free from imperfections, are also typical acid-steel products. Of course, such forgings can be made of basic open-hearth steel, but not with the same assurance of success. At the start, the preparation of the slag in the acid and basic furnaces differs. Lime is charged in the beginning of a basic heat to form a slag, but in the acid furnace nothing is added for the special purpose of producing a slag when the heat is melted down. The result is that the acid furnace has much less volume of slag than the basic. The slag formed upon melting down is made up almost entirely of the oxides of elements contained in the metallic charge, notably oxides of iron, manganese and silicon, the amount of silica being augmented somewhat by erosion of the furnace lining. A typical acid open-hearth slag, when the bath is completely melted, will have an analysis about as follows: CaO, 3.40 per cent; SiO2, 51.9; Fe2O3, 1.25 ; FeO, 28.86; Al2o3, 1.82; MnO, 12.22. The high iron oxide content of the slag gives it a black appearance. The metal is high in carbon and some manganese and silicon will be present, depending on the amount in the original charge, the amount of

Jan 1, 1935

By Francis B. Foley

Fundamentally, slag control in acid open-hearth steelmaking cannot be considered from any different viewpoint than can that in basic open-hearth melting. The same laws of mass action and distribution apply in both cases, so that while most, if not all, of the recent intensive study of slag-metal reactions have been carried on in basic furnaces the principles evolved are nevertheless applicable to acid open-hearth steelmaking and it is therefore not our intention to discuss the various possible chemical reactions in the slag and between slag and metal. The points we have to carry in mind, in considering acid melting practice, are the differences in the type of steels produced and the difference in the chemistry of both the steel and the slag. The acid furnace is used to produce, let us not say "quality" steel, for, after all, a "quality" steel for one purpose is not a "quality" steel for another, but steels that require acid melting practice to be of proper "quality." Steels that are required to have high physical properties in tests taken transversely from forgings are peculiarly the product of acid furnaces. In this class may be placed various ordnance materials, notably gun forgings and projectiles and large commercial forgings requiring high transverse ductility. Forgings requiring an extremely hard surface, polished and free from imperfections, are also typical acid-steel products. Of course, such forgings can be made of basic open-hearth steel, but not with the same assurance of success. At the start, the preparation of the slag in the acid and basic furnaces differs. Lime is charged in the beginning of a basic heat to form a slag, but in the acid furnace nothing is added for the special purpose of producing a slag when the heat is melted down. The result is that the acid furnace has much less volume of slag than the basic. The slag formed upon melting down is made up almost entirely of the oxides of elements contained in the metallic charge, notably oxides of iron, manganese and silicon, the amount of silica being augmented somewhat by erosion of the furnace lining. A typical acid open-hearth slag, when the bath is completely melted, will have an analysis about as follows: CaO, 3.40 per cent; SiO2, 51.9; Fe2O3, 1.25 ; FeO, 28.86; Al2o3, 1.82; MnO, 12.22. The high iron oxide content of the slag gives it a black appearance. The metal is high in carbon and some manganese and silicon will be present, depending on the amount in the original charge, the amount of

Jan 1, 1935

By Arthur G. Metcalfe

Arthur G. Metcalfe (SOLAR)—Three explanations to account for mechanical nucleation effects are considered in the paper, viz., theories based on fragmentation, agglomeration, and pressure-wave mechanisms. The authors show that none of these mechanisms will explain the results observed with tin and Sn-Pb alloys. A fourth mechanism of nucleation enhancement was developed during work at Armour Research Foundation on casting of beryllium and, although presented briefly on various occasions, the theory has never been discussed adequately. It is believed that this theory will explain many of the observations. Classical homogeneous nucleation theories assume that embryo nuclei are formed in the melt as a result of compositional and/or thermal fluctuations. Stable nuclei are formed when a critical size is reached such that the decrease in free energy for conversion of this volume of melt to solid offsets the increase of surface, energy. The assumption is made that the average properties of liquid and solid metal can be used. In practice this assumption is invalid and indeed is contrary to the postulation of thermal and compositional fluctuations in the melt. Actually the conditions favoring embryo formation bring the seeds of its own destruction—the thermal and compositional fluctuations leave the embryo surrounded by atoms of higher thermal energies and/or by solute atoms that depress the melting point. Any mechanical method of dispersing this destructive

Jan 1, 1964

Oil-well driller with extensive experience in this line of work. Location, Bolivia, South America. Salary depends on experience. R.-789. Mining Engineer, with geological knowledge, who can locate suitable spots for drilling oil wells. Location, Bolivia, South America. Salary depends on man. R-788. Construction Engineer, mechanical or civil engineer with experience in installing oil plants for foreign field. Must be able to install entire equipment including tanks, piping, buildings, etc. Salary depends on experience. R-782. Geologist, competent petrographer for micropetrographic work and training of two assistant students under the direction of the Director of a Geological Institute. Engagement is for six months with option on the part of the Director for an equal period: Location, Mexico. Salary, 450 pesos Mexican gold ($225 per month). R-765. Operating Mechanical Electrical Engineer, with extensive experience in charge of the maintenance, repair, and betterment of all mechanical and electrical equipment on mining operations. Desirable that the man have had this experience in connection with phosphate mining. Applicant must be competent to direct shop repairs on motors and generators, including rewinding, the building and maintenance of transmission lines, etc. Must also have ample machine-shop experience to enable him to direct repairs of light locomotives, steam shovels, brown hoists, caterpillar tractors, and auto trucks. Duties will include the betterment and maintenance of phosphate-rock washers and rotary-work dryers. The applicant must also be competent to conduct efficiency tests on all such equipment and be enabled to interpret data collected. Splendid opportunity for the right type of man. Climate and living conditions excellent. The company will furnish house rent free, including light .and water. Location, Florida. Salary depends on experience. R-854.

Jan 7, 1919