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The Effect of Mineral Liberation on the Floatabilities of Pyrite, Arsenopyrite and Arsenian Pyrite for Carlin Trend Ores

Sep 13, 2010

By K. Peake, A. Dalvi, V. Hernandez, S. Chang, M. Oliazadeh

"Ironstone Resources Ltd. is developing the Clear Hills oolitic iron ore deposit in northwest Alberta, Canada. Sources of oolitic iron ore worldwide are abundant and ubiquitous, but there is currently no commercial technology to extract iron from oolitic iron ores. Mineral processing of the ore to generate a commercial iron ore concentrate is very challenging due to the nature of these ores. Accordingly, Hatch and Ironstone are developing a new pyrometallurgical process (Hatch Ironstone Chloride Segregation) to produce metallic iron from high silica and high phosphorus oolitic iron ores. Following the chloride segregation process, the treated ore is subjected to fine grinding. The iron is then separated by magnetic separation. The iron grade and phosphorus content of the final product shows a strong dependence on the separation methodology and the grind size. The pyrometallurgical process has been developed and tested at a lab-scale pilot plant. The commercialization of this technology could provide an opportunity for the development of a new alternate iron making technology. This paper presents the results of test work done on the raw iron ore to create a concentrate and also on the products of the pyrometallurgical process for the production of a high grade 90% metallic iron product.INTRODUCTION Oolite is a sedimentary rock formed from ooids – spherical particles with concentric layers. There are a number of large oolitic iron deposits where the mineralogical form features a low iron content and high concentration of impurities making them presently impossible to exploit on either a technical or economic basis. The fifteen largest oolitic iron ore deposits in the world are estimated to contain approximately 337 billion tonnes of iron ore, which would be a significant source of supply for worldwide steel production. A viable process that can economically recover iron from these oolitic iron ore deposits could become an important new technology to meet future demand in the steel industry. Hatch and Ironstone have demonstrated that oolitic iron ores can be exploited to produce direct reduced iron (DRI). Direct reduction ironmaking is a method for producing solid metallic iron using different techniques compared to the blast furnace process, which is the more conventional ironmaking route. The demand for the construction of direct reduction ironmaking plants has increased in response to the increasing demand for crude steel. It is viewed as a method of providing low-residual iron sources to scrap-based steelmaking in electric arc furnaces."

Jan 1, 2014

By E. T. Boshoff

Paper written on project work carried out in partial fulfilment of B. Eng. (Metallurgical Engineering) The weathering of kimberlite can be accelerated with cations in solution if swelling of the kimberlite occurs in contact with the weathering medium. The type and amount of swelling clays present, along with the surface charge and cation valence, determine the degree of swelling that can occur. Crystalline swelling occurs by the incorporation of cations in the interlayer spacing of the silica sheets. Kimberlite exposed to cupric cations showed very strong weathering, indicating that this type of weathering may be considered a viable process option. Kimberlite fines generated after weathering with monovalent cations showed poor settling behaviour compared to kimberlite weathered with di-, and trivalent cations.

Jan 1, 2005

By Joe Maher

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Jan 1, 1976

By N E. Whitehead

An application to mine an ilmenite-rich sand deposit in Westland led to public concern about potential radioactive hazards should the ore be further processed to recover zircon or monazite. A review recommended that any material involved in the heavy mineral sand industry containing more than 0.05% thorium, uranium or their mixture should be considered a radioactive substance and, for mining purposes, a notifiable product. Safeguards for those occupationally exposed would operate via the Radiation Protection Regulations. The major safety requirement would be the minimisation of dust in certain operations.

Jan 1, 1993

By Luis E. Vallejo

The strength measured by the uniaxial compression test is a parameter that is widely used for the engineering classification of rocks. Sedimentary rocks such as shales, however, are difficult to evaluate by uniaxial compression tatting because the rocks slake during the preparation of the standard samples required for the tests. Indirect methods such as the point load test have been proposed to determine the unconfined compressive strength of shales and other soft rocks. It is current practice to use 24 as the conversion factor between the point load strength, Is, and the unconfined compressive strength, sf (sf = 24 Is). The present study investigated index-to-strength conversion factors for shales and sandstones obtained from surface coal mining sites in the Appalachian region. Regression analyses indicate that a conversion factor of 12.5 best correlated the strengths obtained from the point load and unconfined compression tarts in the case of shales. For the sandstones, a value of 17.4 best correlated the strengths.

Jan 1, 1989

By Laurance L. Oden, Jack C. White, Alan D. Hartman

The U.S. Bureau of Mines, under a Memorandum of Agreement with the American Society of Mechanical Engineers (ASME), established design criteria for a facility to field residues from municipal waste combustion. This facility, which is available to potential users on a cost-sharing basis, is also applicable to a variety of inorganic waste materials from smelting or melting operations. The design consists of a mechanical feed handling system, electric arc melting furnace, fume-off gas handling system, and thermal oxidizer for final off gas treatment. Screw conveyors and a bucket elevator deliver up to 2,000 Ib/h of minus I-in material to a three-phase electric arc melting furnace. This unique 800-kVe A furnace has a water-cooled shell and roof to minimize interaction of the melt with the refractory lining. The volume of the hearth below the slag taphole is approximately 1.2 st of steel. The furnace is sealed, allowing atmosphere control within the furnace and fume duct by nitrogen or inert gas injection. A jet-pulsed baghouse removes particulate from the off gas and serves as an acid gas scrubber. The clean off gas is heated to 1,800' F for 1 s in a propane-fired thermal oxidizer before being vented to the atmosphere.

Jan 1, 1993

By M. E. Hawkins

This Bureau of Mines report provides information on all of the 329 proved salt domes in the Gulf Coastal States and offshore area of the United States. It includes specific data related to location, depth to the cap rock and to the salt, storage facilities for LPG, and production of salt, sulfur, petroleum, and rock related to or associated with the dome structure in the subject area. Also included is a brief history of the salt, sulfur, and petroleum industries as related to the salt domes. Gulf Coast salt domes were the scene of the first discovery of a large deposit of rock salt in North America, the birthplace of the Frasch sulfur industry, and the location of the first large oil gushers that ushered in the modern liquid fuel age.

Jan 1, 1966

By Yoginder P. Chugh

This study has appraised available deeper soil loosening equipment in the 1-4 ft. depth range, in the U.S. and abroad which has potential for Illinois prime farm-land reclamation. The appraisal was based on written and/or oral contacts with equipment manufacturers, reclamation experts, and visiting with selected equipment manufacturers. The results indicate that several manufacturers in the U.S., West Germany, and England market static and vibratory deeper soil loosening equipment which may have potential for application in Illinois. The pertinent information concerning each equipment with potential is presented in this report.

Jan 1, 1983

Improved Process & Practices Result In: ? Reduction of undesirable downtime, & expensive secondary damage ? Improved equipment performance & health ? Extension of equipment life, & reduction of operating costs ? Safety and environmental performance improvement Equipment knowledge capture and consistently applied

May 1, 2010

By Bryan A. Bartley

"Jim Macdonald was promoted from Waterworks Engineer to Streetworks Engineer for the Wellington City Council. He thus took over the City quarry and responsibility for its performance. The crushing plant needed upgrading and he thought it would not be difficult to make a crusher to overcome a problem. If he had a longer association with the quarry industry he would have used conventional methods and equipment, so his invention arose from a fresh view of crushing.He invented the Barmac Rotopactor after observing a wear resistant chute with a lining of dead stone trapped above a piece of angle. This idea led to a rotor lined with trapped stone, rotating on a vertical spindle. In trying - a model rotor he observed the impact against a circular rill of stone in half an oil drum and thus was started a very fertile new area of developement in comminution. The writer helped in the developement and shares in the patents. Jim died in January 1982, just as the machine was becoming known and some 200 were in use in various countries. Most were working in hard rock quarries et that time but recent uses have carried the machine into the mining and mineral processing field. This paper is directed at that industry."

Jan 1, 1985

By Dina M. Aloi

In today?s evolving and globalized world, mining companies are being pressured to move beyond compliance towards long-term sustainability and sustainable development. Companies are expected to ?engage? communities without a clear understanding of ?how? to do this or to what end. This move, away from compliance, develops more of a focus on ?Community? Social Responsibility and sustainability. This shift leads to the development of world-class projects that provide sustainable development for people, reduce the incidence of costly delays, and promote good global citizenship for companies. The process of ?engaging? communities in mining project design and development leads to a stronger license to operate, and a reduction in social and political risk. To create this mutually beneficial relationship between communities and companies, communities must be ?engaged? in the project development and risk assessment processes as early as possible, preferably during the exploration or the concept phases. How to create this ?engagement? and manage this risk will be discussed.

May 1, 2007

By J. W. Thompson

RAILROAD GRANT-MDIERALS. Diatomaceous or infusorial earth when found in such quantity and quality as to render lands containing deposits valuable therefor are mineral lands within the meaning of the mining laws and must be excepted from grants to the Central Pacific Railway Company. Central Pacific Ry. Co., In re, 45 Land Decisions, 223, p. 226. RAILROAD GRANT-CLASSIFICATION, If any evidence of minerals is found upon lands within a railroad grant and the showing is sufficient in the opinion of prudent and qualified persons to warrant further exploration and expenditure, with reasonable prospects of success, then the land can not be classified as nonmineral and is not subject to the grant to a railroad company. But where there is no present indication of minerals nor any geological evidence upon which to base a mineral finding, land should not be classified as mineral, or held for further classification and reserved from the railroad's grant, upon the surmise that future prospects might disclose evidences of minerals. Southern PacUl.c Ry. Co., In re, 45 Land Decisions, 326, p. 329. INDEMNITY SELECTION BY RAILWAY COMPANY, Under section 3 of the act of July 2, 1864 (13 Stat., 365), and the joint resolution of May 31, 1870 (16 Stat., 378), the Northern Pacific Railway Company could take coal and iron land within its primary or grant limits. It could not base an indemnity selection upon the claim that certain land was coal or iron in ;;haracter, as such land was not lost to it as part of the grant. But the company was authorized to select other lands in lieu of those lost because of their mineral character, but the word "mineral" did not include iron or coal, and, accordingly, the railroad company was entitled to take coal lands under its indemnity selection.

Jan 1, 1917

By Charles Barnhart

This paper is a discussion of the causes of deflagration in cast blasting and a description of a project intended to demonstrate how changes in six critical parameters contribute to the deflagration chemical reaction. Control of these parameters is key to solving the nitrogen dioxide “orange smoke” problem. Preliminary results of an investigation into the development of a technology addressing the problem of atmospheric releases of nitrogen dioxide during cast blasting in surface mine operations are described. The project is funded by a $600,000 Small Business Innovative Research grant from the National Science Foundation and an $80,000 Abandoned Coal Mine Land Reclamation Program grant from the state of Wyoming. The presentation will address the measures required to control the blast chemical reaction so that it does not produce nitrogen dioxide through deflagration. Experimental blast data will be focused on a new shaped charge detonation system designed to instantaneously bring the powder column to maximum velocity of detonation (VOD), thus insuring efficient detonation of the entire colulnn.

Jan 1, 2003

By S. McAlister

"Falcon Concentrators Inc. has developed a high capacity centrifuge for the recovery of fine, free gold as well as other metals and minerals which were previously thought to be unrecoverable by gravity means. Development started in the early 1980's and the first commercial operation was commissioned in 1986. Gold applications include scavenging conventional gravity and cyanidation circuit tailings, cleaning gravity concentrates, cleaning flotation concentrates to melting grade, scavenging flotation tailings, and placer mining. Recent development work by Falcon has expanded the applications scope of the centrifugal concentrator to include many minerals amenable to gravity concentration including iron, tin, industrial minerals, and hazardous wastes. This paper discusses this technology including its history, present applications, and future potential. OVERVIEW OF CENTRIFIJGAL CONCENTRATIONUsing centrifugal force to enhance the separation of materials by differential specific gravity has been researched for over a century. Many attempts have been made to concentrate minerals in high gravity fields. Patents were granted on this subject as early as 1891 (see Figure 1). Patenting activity continued into the 1920's and has been relatively quiet since. It is significant that no centrifugal system of gravity concentration has been broadly accepted by the mineral processing community until recently. Much of the world's reserve of mineral deposits which are amenable to conventional gravity concentration technology (coarse-grained) have been mined and therefore there is an increasing demand for technology which can economically recover the fine-grained gravity recoverable minerals in the remaining deposits. In addition, centrifugal concentration can play an increasing role in solving environmental problems by offering an inexpensive method of concentrating hazardous materials such as uranium, plutonium, mercury, lead, and other heavy metals. The overall cost of disposing of these substances safely can be drastically reduced if they are recovered into a concentrated form prior to disposal."

Jan 1, 1992

Application of Gy?s formula is appropriate for calculation of the Fundamental Error (FE) prior to samples being collected at any stage of the minerals process, provided that sampling parameters K and a (alpha) have been determined by calibration of the ores. Two types of calibration procedure are well established in the industry, the Hetrogeneity test and the 32-piece sampling tree experiment. The sampling tree experiment uses the variance and average grade of metal analyses from four series of samples at different nominal fragment size, as the basic input data. Pierre Gy suggested the cube as an appropriate exponent of the nominal fragment size for use in his equation. More recent work suggests that this exponent is variable and characteristic of specific ores and therefore requires calibration. The method described here explains the experimental procedure of the calibration. It is then possible to calculate a sampling nomogram using the sampling parameters K and a. This allows the sampler to determine a suitable protocol for the sampling event that will ensure that the FE does not exceed a predetermined precision at any point in the sampling procedure.

Jan 1, 2007

By H. W. Earnest

This report covers the results of a two-phase study to determine the feasibility of underground disposal of retorted oil shale. Two mining methods, chamber and pillar mining and sublevel stoping, were specified for backfilling. Phase I of the study covered the evaluation of hydraulic, mechanical, and pneumatic transport and stowing systems, individually and in various combinations, and the selection of the most feasible methods. Conveyor transport and stowing and a combination conveyor transport and stowing with pneumatic topfilling were selected for detailed study of phase II. Phase II activities included detailed engineering analysis and design of the selected systems, an engineering economic analysis, and a cost comparison with total surface disposal of retorted oil shale. An extensive literature search was conducted and the bibliography is included in the report. Research done under Contract No. J0265052 by the Cleveland-Cliffs Iron Co. Available for reference at Bureau of Mines facilities in Denver, Colo., Twin Cities, Minn., Bruceton and Pittsburgh, Pa., and Spokane, Wash.; U.S. Department of Energy facilities in Carbondale, Ill., and Morgantown, W. Va.; National Mine Health and Safety Academy, Beckley, W. Va.; and National Library of Natural Resources, U.S. Department of the Interior, Washington, D.C. Order ONLY from NTIS:

Jan 1, 1978

By W. E. Schroeder

Two underground installations of the sprayfan system are described and evaluated. The spray fan proves capable of reducing by 1300 percent downtime due to high methane. Spray fan face ventilation at 20 ft brattice setback is shown to give improved methane control over conventional sprays at 10 ft setback. In addition, this report describes: ? A simple method for determining the most economical application of ventilation for face methane control ? The effect of place variables (primary ventilation, auxiliary ventilation, seam height, etc.) on methane concentrations ? The correlation of methane concentrations with brattice setback. These results are utilized to suggest a safer and more economical approach to face methane control.

Jan 1, 1981

By Robert B. McElwaine

"The demand for barite has increased greatly in the last 10 years, especially during World War II. Depletion of oil reserves and subsequent increase in deep drilling created a heavy demand by the oil industry for barite to be used as drilling mud. The great increase in demand for barite gave impetus to the development of a, deposit of impure barite near, Magnet Cove in Hot Spring County, Ark.The critical condition of the national barite supply early in 1944 led the War Production Board to recommend that the Bureau of Mines attempt to prove the existence of a large reserve tonnage of barite in the Magnet Cove area and arch for new deposits. To carry out this program, the Bureau explored on newly reported. Barite deposits in southern Montgomery County, Ark. The Gap Mountain, Fancy Hill, and Sulphur Mountain barite deposits were investigated. Eight diamond core-drill holes and 1,336 linear feet of surface trenching were completed, and barite samples obtained were analyzed, A study of the Montgomery County barnse district indicates that the lenticular bodies of barite replace a favorable host rock near the base of the Stanley shale formation. Barite is exposed along the side of anticlinal mountains where erosion has truncated the beds on the limbs of the associated synclines. An appreciable amount of barite suitable for commercial use has been indicated by trenching and core drilling. The Gap Mountain and Fancy Hill deposits are controlled by the Magnet Cove Barium Corp. and Baroid Sales Division of National Load Co., respectively. The ore is similar to that of the Magnet Cove area and is amenable to concentration by a flotation process. Mining of these deposits had not been begun by the time the Bureau completed its exploration project."

Nov 1, 1946

By R. Jackman, D. Koningen, G. Wilcox

"Gowest Gold Ltd. is in the process of developing the Frankfield East gold deposit located along the largely undeveloped Pipestone fault northeast of Timmins, Ontario. In addition to resource development and environmental permitting work the company has had an ongoing program of metallurgical and engineering studies aimed at evaluating options for processing the Frankfield East ore. Mineralization at the Frankfield project contains arsenopyrite and pyrite as the major sulphide minerals. Bulk flotation of all sulphides results in extremely high gold recovery. However, the gold is almost entirely associated with the arsenopyrite fraction of the ore and is refractory in nature requiring preoxidation treatment. Selective flotation was investigated to recover a gold-arsenopyrite concentrate thereby reducing the mass which would be subjected to further gold processing. As part of this work, a pyrite concentrate low in arsenic content was also recovered that would be suitable as a source of sulphur for a smelter (or other pyrometallurgical facility). Production of separate arsenopyrite and pyrite concentrates is frequently examined but rarely adopted due to the distribution of gold between the two products or the inability to achieve adequate separation. Several flowsheet options were investigated in the study. The best results were achieved following a sequential flotation flowsheet. The flowsheet configuration was key to meeting the targets for the two products. In this paper, the various options investigated are reviewed and the results of the final flowsheet are presented. The overall plan by Gowest was to evaluate all process options to bring the Frankfield East deposit into production. The ability to effectively separate the arsenopyrite and pyrite components in the ore provides Gowest with added opportunities to pursue both short and long term production scenarios."

Jan 1, 2012