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By J. M. Toguri, K. Grjotheim

It is known 1,2 that the equilibrium between titanium metal, TiCl2 , and TiCl3, in a solvent of molten metal chlorides, is influenced both by the total amount of dissolved titanium and by the type of solvent. Assuming that the trivalent titanium forms the complex ion Ti111 Cl4, the equilibrium reaction may be expressed by the following equation, (Me) TiIII cl4+ 1/2 Ti = 3/2 TiII cl2+ (Me) Cl The ideal ionic equilibrium constant for this reaction is, Where the N's are the molar ionic fractions in the equilibrium melt, and (Me) the different types of cations present in the equilibrium mixture. The following thermodynamic relation is derived between Kand the concentration of cations in the equilibrium melt, mix The N"S are the equivalent ionic fractions, and so forth are constants corresponding to the standard changes in free energy for reactions in melts where only the cation indicated is present, and f (y1) is a function of the activity coefficients in the equilibrium mixture. When this term vanishes, a simplified linear relationship between In Kideal and the concentration is obtained. The simplified relationship has been applied with satisfactory results to the experimental data of Mellgren and pie,' and Kreye and Kellogg.2 MANY existing methods for the production of light metals involve the reduction of their respective metal halides in the presence of salt melts composed of alkali or alkaline earth chlorides. In such a solution phase, the light-metal halide may undergo stepwise reduction from a higher, to a lower valence, and finally to a zero valent state. In this connection, the disproportionation equilibrium is of great interest. In the case where the higher valence is three and the lower valence is two, the disproportionation equilibrium may be written as follows, 3 Me11 = 2 Me111 + Me [I] If this equilibrium occurs in a salt melt containing a large excess of alkali chlorides, a typical ionic melt is obtained. It is then possible to formulate the cation equilibrium: 2 Me+h' + Me = 3 Me++ [II] Reaction [11] is analogous to a cation exchange reaction. It has been shown thermodynamically that the equilibrium constant for such a reaction in 2

Jan 1, 1960

By J Wei, A Yo, R Levy

Waste water reuse from municipal and industrial effluents is becoming increasingly important in many areas around the world. Water scarcity, local regulation and environmental impact are driving many industries like coal and copper mines to reuse the large volume of waste water they produce. For example, the Chinese coal industry generated about 4.2 billion tons of mine waste water in 2005 of which only approximately 30 per cent was reused. Coal energy represents 76.6 per cent of the total energy generated in China in 2007 and most of the coal-fired power plants are located in north-west of China, which is a water stressed area.The selection of mine waste water treatment process is challenging as the effluents typically contains high levels of organic compounds and salinity and their composition can vary significantly. In recent years there has been a growing interest in the integration of ultrafiltration (UF) and reverse osmosis (RO) membrane technologies for mine waste water treatment and reuse.In this paper, an overview of the design and performance of ultrafiltration and RO membranes applied for reuse of mine waste water are discussed. A study was carried out in two effluents treatment plants treating copper and coal mine waste water, which are located in Chile and China respectively. The following topics will be discussed to demonstrate the performance of an integrated membrane system in mine waste water reuse: The main challenges from copper mine waste water treatment: high level of chemical oxygen demand (COD); high level of total suspended solids (TSS); high salinity; high concentration of silica, sulfate, iron and other contaminants; and fluctuation of raw water quality. The main challenges from coal mine waste water treatment: high level of total dissolved solids, and waste water quality fluctuation. Design parameters for waste water treatment systems: Selection of pretreatment for dual-membrane system in the copper mine: Clarifier with coagulation and flocculation to remove high TSS; Dissolved Air Flotation (DAF) to remove non-settling solids; Media filtration to handle fine solids and particulate organics; Activated Carbon filters (ACF) to remove dissolved organics, colour and odours. Selection of UF and RO membranes and specific design of their recovery, flux, chemical dosage and cleaning regimes. Finally, the performance of UF and RO, including the main fouling factors and efficient cleaning procedures, will be presented and compared to the design parameters to demonstrate the efficiency and performance of the selected integrated membrane systems in each case.

Jan 1, 2009

By Liang Shen

The Cooper River Bridge, the longest cable-stayed bridge in North America, replaces two existing bridges along U.S. Highway 17 and connects the City of Charleston and the town of Mount Pleasant, South Carolina. Two diamond shaped towers support the 1,546 ft long main span over Cooper River and allows for a 1000 ft wide navigation channel. The Charleston high-level approach is 4351 ft long and provides a 250 ft wide navigation channel for Town Creek, while the Mount Pleasant high-level approach is 2,090 ft long. Due to the high seismicity in the region, potential vessel impact, and hurricanes, large lateral loads are expected. From various types of foundations, 10-foot diameter drilled shafts were selected for their high capacity against vertical and lateral loadings. The shafts are founded on a stiff to very stiff lightly cemented calcareous sandy clay or sandy silt layer, called Cooper Marl, which underlies the coastal sediments of the interbedded clays and sands. A group of 11 shafts supports each main tower, while a rock island protects it from vessel collision. A group of 4 to 8 shafts foundations support the other piers of the main span unit. A pair of shafts supports the High Level Approach piers. The shaft tip elevations vary from 120 ft to 230 ft below water line. An elaborate geotechnical investigation was conducted on the site, including a load test program on full-scale shafts under axial and lateral loads. The results of the tests were used to calibrate the lateral and axial soil resistance. The objective of this paper is to present the different aspects of the bridge foundation design.

Jan 1, 2013

By H. Dong

This paper presents a heat conduction model to determine the erosion profile of freeze linings in a ferronickel submerged arc furnace. Kirchhoff transformation was adopted to simplify the nonlinear equation governing heat conduction. The boundary element method (BEM) and Nelder-Mead simplex optimization method were employed to solve an inverse heat conduction problem. Erosion profiles could be obtained when calculated temperatures at sensor locations agreed well with measured temperatures. The model was validated by comparing the heat loss through the linings, which was calculated by BEM and integral operation after erosion profiles were obtained, with the value calculated from industrial data such as actual power consumption, tap-to-tap time, and ferronickel output. The optimal solution for the erosion profile could be acquired when the difference in heat losses calculated by these two methods is at a minimum.

Jan 1, 2014

For the purposes of this discussion it is assumed that contributors should express the thoughts that arise from their personal experience. So wide is the range of mineral deposits, and so varied the methods employed in their discovery and development, that no two geologists are likely to have been impressed with the same applications of their science. The author's own personal experience has been, during recent years at least, very largely concerned with the broader aspects of the employment of scientific method and geological knowledge to the problems of exploration and exploitation, for the guidance of the general public and governmental authority rather than of mine executives and directors. The view-point thus reached is likely to differ in many respects from that of men who are much more intimately concerned with the mining problems of a single metal or a single mining field, and for this reason a statement may perhaps supplement those from others whose experience has been markedly different.It may well happen that, at some not distant date in the future, when systematic and comprehensive instruction in economic geology is embodied in the courses- prescribed for mining engineers during their years of training, the author's comments will be quitesuperfluous; but at the present time they appear to him to call for expression.The Need for Training of Mining Men in Economic Geology.Contact over a period of many years with mining men who have had different kinds of training and experience has been convincing that there is a general reluctance to acquire a full rational understanding of the geological factors involved in exploratory and developmental problems. The correction of this attitude is regarded as vital to the industry and it is necessary to insist that the outstanding requirement of the present day is the utilization of all branches of geological, investigation in the field and the laboratoryby men who have had systematic and specialized training in these matters. The science of geology is many-sided, but is, nevertheless, whole and essentially indivisible. No one can afford to disregard any fraction of its content 'or any of its methods of investigation.The greatest advances have been made in the understarnding of the occurrence of mineral deposits by those whose knowledge Qfbasal principles, has been soundest, whose endeavour has been to ascertain all their relationships in space and time, whose attention to detail of all kinds has been keenest, and at the same time, whose capability to distinguish between major and minor features has been most marked.With the passage of the years and the accumulation of data from many lands, it has been possible to build up a great body of information regarding the primary deposition and secondary alteration of mineral occurrences, which is of the utmost value in guiding thesearch for new deposits to take the place of those that become exhausted. This heritage is due not only to the efforts of gifted in...

Jan 1, 1950

By D. Grobbelaar, A. Cichowicz, D. J. Birch

The Q-coda method for estimating the quality factor Q(f)= Qo(f)n was used to characterize seismic wave attenuation in a region of the Kaapvaal Craton that includes the mining areas of the Bushveld Complex and Witwatersrand Basin. Seismic waveform data, collected by locally distant stations of the South African National Seismograph Network (SANSN), consisted of mining-related events with magnitudes ranging from ML 1.8 to ML 4. Q was calculated for nine different source-receiver pairs spanning the study region. A weighted average Q based on the number of available data gave an estimated attenuation relation for the study region of Q(f) = 327 f 0.81.

Jan 1, 2015

By G. J. Hasenfus

This paper presents the results of an extensive hydrological and geomechanical monitoring program which Gas conducted at a longwall coal mine in W. Va. The field program included monitoring of groundwater levels. overburden hydraulic conductivity, overburden movement, and surface subsidence relative to the passage of the longwall. Overburden geology and rock strength characteristics were evaluated prior to mining. A postmining corehole was drilled to evaluate main roof fracturing. An overburden response model is proposed based on the correlations between hydrological and geomechanical data.

Jan 1, 1988

By Dunkin H. H

Flotation tests in a laboratory flotation cell at pH 8-8.5 and other sui}plementary tests were carried out on sphalerite-quartz and sphalerite-pyrite-'quartz mixtures. Depression of sphalerite resulted vvhen the addition of copper sulphate exceeded an optimum value. Evidence that this depression was due to collector deficiency because of reaction between copper sulphate and collector is presented. It was not found possible to devise a direct analytical method suitable for .plant control of reagent addition. A possible means of control using potassium cyanide and a higher pH is discussed.INTRODUCTIONAt the Rosebery mill of Electrolytic Zinc Co. of Australasia Ltd., recovery 'of sphalerite in the zinc concentrate occasionally drops unexpectedly. Experiment in the mill and mill laboratory has suggested that one of the factors causing this may be the addition of more than an optimum amount of copper sulphate. On such occasions, an increase in the collector addition improves zinc recovery in the zinc concentrate, but only at the expense of sphalerite-pyrite selectivity.To examine the phenomenon more thoroughly, and if possible to find some means of determining the optimum addition of cepper sulphate and controlling the actual addition at this optimum, one of the authors (W. J. T.) was employed by the Electrolytic Zinc Co. of Australasia' to carry out investigations in the Mining Department, University of Melbourne, under the joint direction of R. B...

Jan 1, 1954

By Jan E. Nesset, Antonio DiFeo, James A. Finch, Jose Hernandez-Aguilar, Cesar O. Gomez

"The gas dispersion measurement sensors and methodology developed by the mineral processing group at McGill University have to-date been employed at a number of plants in Canada, Australia, the U.S., South Africa and South America. In some cases the measurements have been directly linked with metallurgical performance while in others the gas dispersion surveys on their own have proved very useful in understanding the behaviour of the flotation cells. In addition to reviewing the current state of the gas dispersion measurement technology, the paper will present a series of case studies from the various plants and will show how this technology brings a remarkable new level of understanding to flotation behaviour. The influence of the bubble size distribution on recovery and grade are emphasized in the paper.INTRODUCTIONBackgroundThe advent of new sensors to characterize gas dispersion parameters in flotation cells is a development that is long overdue. While the chemistry of flotation has been studied since the early 1900’s, it is only now that the significance of bubble size distribution, gas rate and gas holdup can be meaningfully measured in-plant with robust and precise sensors. Early researchers, like T.A. Rickard (1916) recognized the importance of understanding the role of air and bubbles in flotation when he wrote in 1916 “we know that the key to the flotation process is to be found not in the oil, the acid, or the apparatus, but in the bubbles. The man who understands the mystery of a soap bubble has mastered the chief mystery of flotation”. In his 1999 review paper on The Froth Flotation Century D.W. Fuerstenau laments the fact that due to their “inert nature”, bubbles have never received their due attention from researchers who tended to focus on the chemical, physical, surface and colloidal aspects, rather than the physics of the process. It is perhaps fitting that now, 100 years after the inception of industrial flotation practice at Broken Hill, Australia, researchers and industry have turned their attention toward the importance of truly understanding the role of bubbles in flotation."

Jan 1, 2005

By Luis Martín Tejeda

El presente texto señala cómo los parámetros geotécnicos de resistencia y deformabilidad pueden generar mayor confiabilidad en un estudio técnico. En este sentido, la literatura geotécnica indica que los resultados obtenidos a través de métodos numéricos son sensibles a la variación de estos parámetros y que algunas propuestas de cálculo son más satisfactorias. Para ello, se utilizó el criterio de falla de Hoek & Brown en términos de Mohr–Coulomb, donde se presenta un ejemplo aplicativo para mineria superficial, en el cual el factor de seguridad y la probabilidad de ruptura del macizo rocoso son calculados mediante métodos geoestadísticos aplicados a la ingeniería de rocas (FOSM - First Order Second Method y puntos de estimación de Rosenblueth).

Sep 19, 2006

The Porgera Joint Venture commenced production during September 1990. A small tonnage underground mine extracts high grade gold ore using small scale stopes. Conventional drill and blast methods are used for development and production mining. Ground support is effected with Splitset anchors, grouted rebar bolts and grouted cable bolts. Splitsets and grouted rebar can be installed by mechanised means. Vertical crater retreat, slot and massfire, and modified VCR stoping tech- niques are used at Porgera. Stopes are backfilled with a relatively strong cemented rockf ill. Future stope sequences require recovery of pillars beside and under filled stopes.

Jan 1, 1991

High-sulphidation (HS) gold, silver and/or copper deposits are generated in both the epithermal and the upper parts of the underlying porphyry environments over vertical intervals of up to 2 km. The HS deposits are generated in advanced argillic lithocaps, which are products of the absorption of acidic magmatic volatiles by voluminous groundwater systems. Mineralisation styles in HS systems reflect depth of formation as well as the interplay between structural, lithological and hydrothermal parameters. The deep parts of HS systems, at depths of >1000 m, are typified by disseminated copper¦gold mineralisation comprising digenite, chalcocite and covellite in pervasive advanced argillic as well as underlying sericitic alteration. In highly telescoped systems, such mineralisation may overprint porphyry stocks and associated quartz-veinlet stockworks. Intermediate levels of HS systems commonly contain fault-controlled copper-gold mineralisation, typically as enargite in bodies of vuggy residual quartz, silicification and/or massive pyritic sulphide. The shallow parts of HS systems, at depths of The exploration focus is on four principal HS mineralisation styles:copper (eg Chuquicamata, Monywa) or copper-gold (Wafi) in the deep porphyry-hosted parts of systems preferably, in the case of the latter, where supergene oxidation is limited and, hence, flotation may be used for metal recovery; copper¦gold-bearing replacement mantos and pipes hosted by carbonate wallrocks in the deep parts of systems (eg Bisbee); high-grade gold in late-stage veins or hydrothermal breccias that overprint the intermediate to shallow levels of systems (eg El Indio, Goldfield); and large, bulk-mineable gold deposits in the shallow parts of systems that were subjected to supergene oxidation, thereby permitting heap-leach treatment (eg Yanacocha, Pierina). To these preferred HS styles may be added the low-sulphidation vein or disseminated gold¦silver mineralisation that is commonplace alongside many HS systems (eg Victoria at Lepanto).

Jan 1, 1999

By Mark McComb, Geoffrey R. Lane

"Over the years many differing approaches have been developed to clearly understand the nature, mode of occurrence, associations and deportment of both free-milling and refractory gold in a wide variety of differing geologic environments and plant products. Many approaches can be taken to characterize the ore which may occur as complex fine grained gold, ultra-fine grained gold, coarse nuggetty gold, complex Asrich refractory gold and double-refractory gold. The approach taken in assessing small drill core composites from Novo Resources Beaton Creek Paleoplacer gold project located in the Pilbara region of Australia was complicated by the nature of the ore, the small amount of sample available from current exploration work, and the gold grade and the grain size distribution. In this case the scope of the study was limited by sample availability although significant amounts of valuable information was also gained. This gold characterization study included the following elements:??Size fraction assays??Ore microscopy??Preparation of heavy mineral concentrates from sized fractions (screening) of crushed or milled head using heavy liquids and Superpan table.??Systematic scans of the heavy mineral concentrate, middling, and tailing fractions using TIMA Automated Scanning Electron Microscopy integrated with an Energy Dispersive Spectrometry to provide semi-quantitative elemental analysis of the individual grains found in the sample.The unique methodology employed to detail the gold deportment was the combination of the Tescan Integrated Mineral Analyser (TIMA) and the Oxford INCA GSR software. This technique not only allowed us to document the deportment of gold but recognize other associated minerals, which included gersdorffite, chalcopyrite, uraninite, coffinite, brannerite and several Rare Earth-bearing minerals.INTRODUCTIONGold deportment studies are commonly carried out on preliminary gold exploration projects in order to determine the various limitations, which may effect processing of the potential ore. This is often because it may be expected that there may be a refractory component to the gold, which may limit physical separation techniques and suggest more costly hydrometallurgical techniques. Often when carrying out gold deportment studies the mineralogical methods may be limited to assuming that the gold will be fine and easily found using standard techniques of optical microscopy or Scanning Electron Microscopy. This may not always be the case as various geological environments may pose their own individual problems to determining the deportment of the gold grains."

Jan 1, 2015

By John Ellenberger

The National Institute for Occupational Safety and Health (NIOSH) has collected pillar and span data at 34 stone mines in 10 states to develop pillar and roof span design guidelines for underground stone mines. Pillar, floor and roof conditions each contribute significantly to the overall mine stability. The roof may be stable for a century, or it may appear to be stable but fail with little warning. Clearly, an assessment of the mine roof is critical to the safety of these operations. However, up until now, the assessment of the mine roof came primarily from exposures in roof falls or portal areas. This provides only limited information, and a more proactive approach is needed to assess changing mine conditions. A separate effort was undertaken to examine the roof structure with the use of a borescope. Numerous physical and geologic roof structures were observed with a stratascope/borehole video camera. The objective of this work was to develop a technique of assigning numerical values to features seen within the mine roof and apply those values to formulate a roof stability evaluation. Such features as changes in color, grain size, and general lithologies are readily observed. Minor structures in the rock, fossils and fractures are also readily identified. Each feature may have a variable and site-specific impact on roof quality. A number of mines were visited and a series of holes were borescoped in each mine. The features identified in the roof were classified and potential for roof damage related to each feature was assessed. A process is presented that relates the structures and their locations to provide a numerical value, or roof quality index that can be used to assess roof stability.

Jan 1, 2009

By G. K. Rogers

The portal, which is the near-horizontal, surface point of entry to an underground excavation, can often be an exceedingly difficult area in terms of ground control. Surface and subsurface failures at portals, as discerned during a study involving over 300 case histories, are unfortunately, common. To aid in the engineering evaluation of portals, the Geomechanics Classification System was appended with discontinuity orientation assessment values and support/excavation guidelines. Also, a design model utilizing RMR predicted rock loads in conjunction with half-dome theory is proposed for the most common type of portal failure. Other pertinent comments and recommendations relating to portal stability are included.

Jan 1, 1989

By Tom Olsen, Tom Ohrling, Peter Taggart, Chris Martin

"North American Palladium commissioned the new concentrator at the Lac des Iles mine in the summer of 2001. The 15,000 tonnes per day mill replaced the existing 2,400 tonnes per day facility, as part of a major mine expansion.At Lac des Iles, the grain size distribution of the platinum group minerals (PGM) is bi-modal. Roughly two-thirds of the PGM are relatively coarse-grained, and often associated with fast floating copper and nickel sulphides. The remainder is ultra-fine, and locked in silicates, which poses a special challenge to the metallurgist. The previous mill typically recovered just the fast-floating mineralisation, but to achieve target recoveries, the new mill has to recover a substantial amount of the ultra-fine PGM. The metallurgical challenges associated with the recovery of fine-grained PGM in the talcous Lac des Iles ores, are described.The paper describes the approach used in circuit optimisation, and how metallurgical and operational optimisation raised palladium recoveries by more than 6% in six months, by tuning the circuit to recover some of the ultra-fine PGM mineralisation.BACKGROUNDThe Lac des Iles mine, owned and operated by North American Palladium Limited, is located about 115 kilometres north of Thunder Bay, Ontario. The mine originally opened in December 1993, and prior to 2001 included a mill capable of handling 2,400 tonnes per day of ore delivered from the nearby Roby pit.Following an intensive exploration programme conducted in 1999, and a detailed feasibility study, conducted in 2000, North American Palladium initiated a mine expansion project, the objective being to expand milling throughput from 2,400 tonnes per day to 15,000 tonnes per day. This required construction of an entirely new mill, which was commissioned in May 2001."

Jan 1, 2003

By Roger A. Dworak

This report describes in detail the work done on the development of the Time Domain Reflectometry Microcomputer (TDRM). Modifications to the FMC-Model 302A Cable Fault Locator is described in Appendix D. The TDRM unit uses an 8080 microcomputer to accurately locate major faults in low capacitance cables to within ± 1 foot when properly calibrated. Major faults in high capacitance cables are usually located within ± 5 feet. The upper limits of fault detection are <1 kilohm shunt fault and >7 ohm series fault. In practice fault detection limits are reduced to <300 ohms shunt fault and >30 ohms series fault because of discontinuities caused by cable repair.

Jan 1, 1977

Resonance re-emission from nickel vapour affords a convenient method for isolating the resonance lines at 3415A, 3515A, and 3524A. The vapour is generated by cathodic sputtering and is illuminated by light from a nickel atomic spectral lamp. The resonance lines thus isolated can be usefully employed for absorption measurements on mineral samples where the nickel concentration is too high for measurements with the more sensitive line at 2320A. A spectrophotometer employing a resonance lamp as monochromator possesses several advantages where a great number of determinations are made under routine conditions. The wavelength setting is stable under even the most rigorous conditions and with the provision for automatic setting of full scale deflection the instrument requires virtually no adjustment. The instrument has been used under routine conditions for the determination of nickel (in the range O&#183; 05-2 per cent) in mineral samples.

Jan 1, 1968

By A Prinsloo, R Tewu

Automatic control of semi-autogenous grinding (SAG) mills has often been considered complex. Recent experiences at Century Zinc (worldÆs second largest open pit zinc mine) refute this. Together with operating knowledge and appropriate control techniques high quality control is achievable. In this application model-based, constraint, and multiple output control were employed. The control was implemented using standard blocks in the plant DCS. The resulting overall control strategy fulfils the operating objectives and controls the mill with minimal operator involvement over 95 per cent of the time. Previous campaigns using expert systems and complex DCS based control have lacked durability. Their fall into disuse is briefly discussed.

Jan 1, 2009

By Eric Low

Raising capital by issuing debt or equity is necessary in almost every corporation. In the field of corporate finance, the raising of capital is a heavily-studied topic. However, some of what is studied on this topic in corporate finance is not applicable in the mining industry. There are also many financing options that were created for the mining industry such as flow-through shares, prepaid forwards, and royalty sales. The cyclical nature of the industry makes the risk-return profile of financings more difficult to estimate than in other industries. Additionally, the methods used to assess firm value are different than other industries, as the values of orebodies are not included on balance sheets. For precious metals companies, which are a hedge against most other securities, there are additional complications with determining investor expectations and cost of equity. This thesis puts forth a decision-making framework to explain mine financing choices from the perspective of mining companies. The approach is threefold. First, all of the major equity and debt financing instruments available to mining companies are presented and analyzed. Each financing method is assessed on a wide range of criteria. Next, these concepts are applied in case studies of four companies: BHP Billiton, Barrick Gold, Teck Resources, and Noront Resources. For each company, the overall choice of financing methods is shown and analyzed. The effect of financing choices on the weighted average cost of capital (WACC) is calculated. The final section deals with case studies of individual mine finance decisions during the past two years.

May 1, 2011