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By F. L. Pirkle

The mineral zircon is mined for use as specialty foundry sands, abrasives, ores of ZrO2 and zirconium metal, refractories, and zirconium chemicals. It is produced as one of several products from heavy-mineral sand deposits associated with fossil shorelines. Because of its low coefficient of thermal expansion, its high melting point, its high refractive index, and its chemical inertness, it is an attractive refractory material. Zircon varies from deposit to deposit in terms of grain size, grain shape, and chemical impurity. Thus, there is a wide range of commercial products differing in impurity levels, particle shapes, and grain sizes.

Jan 1, 1992

By R. Brantley Sudderth

There are three broad categories in which most solvent extraction technology can be distributed?: 1) reagents, 2) equipment, and 3) systems. Reagents which are now used in commercial solvent extraction plants are of many chemical types, and each possesses certain properties which make it more economically desirable than another alternative. The equipment which is' used in solvent extraction plants for contacting the organic and aqueous phases and separating the same is varied. Most common to the industry is the mixer-settler unit which in itself, can be of varied design; but many new innovations in contacting and separating equipment have been recently introduced or are :now being studied. Each specific solvent extraction application will often dictate the type of contacting and separating equipment used. Obviously, the trend is toward smaller less expensive equipment which reduces the often expensive organic inventories necessary for most solvent extraction plants. The current thrust of .investigations in ancillary equipment is usually aimed at recovering organic from solvent extraction sludges or from aqueous streams exiting the process.6 This type of equipment helps to reduce the total organic losses from solvent extraction plants and thus reduce the operating costs. The term "systems" in solvent extraction applies to the manner in which a solvent extraction process is carried out. This manner is usually dictated by the properties of the reagent which is used, and it involves a tailoring of the equipment or the process flowsheet. Some of the things which can be tailored are: 1) The aqueous media -whether acidic or basic and what type of acid or base 2) Counter-current or single stage (co-current) contacting 3) EMF or pH control 4) Organic "crowding" alternative 5) Heating or cooling process streams Regardless of the type or extent of tailoring, efforts to do this are usually a result of the low cost of solvent extraction as a unit process.

Jan 1, 1977

By William G. Pariseau

The flexure of geologic strata, a phenomenon of inter- est to geologists and mining engineers alike, is examined as a sheet bending problem' in Coulomb plasticity. Formulae for the distribution of stress, strain and displacement increments, volume change, change in the length of the central surface and power of dissipation, as well as for the neutral surface shift are given. Strains of any magnitude are considered. The analysis shows that deeply buried strata may bend and develop "tensile" cracks under generally compressive states of stress. It is also shown that bed separation and high capacity props are desirable in mechanized longwall mining, a result in keeping with operating experience. Although speculative at this time, the analysis provides a rational working hypothesis as regards the problem of strata flexure and control.

Jan 1, 1968

By G. J. J. Aleva, A. H. Hilversum

The northern spur of the Bakhuis Mountains contains bauxite deposits on a dissected planation level, a region formerly indicated as the Adampada-Kabalebo area. Iron-rich laterites are ubiquitous on all more or less flat and horizontal to moderately sloping interfluves and planation levels. The known aluminous laterites and bauxites are restricted to those laterites that have relatively leucocratic and silica-poor parent rocks. The whole area is underlain by high-metamorphic Precambrian. In the northern half of the Guiana Shield at least four Cainozoic planation levels can be distinguished. The bauxite and aluminous laterite deposits are related to the oldest, Early Tertiary level. These deposits, occupying the highest positions in the present day landscape, show the destructive influence of post-laterite weathering, erosion and denud- ation; they are erosion remnants and as such are of irregular thickness, grade and shape. Consequently, exact mineable tonnages can only be determined after intensive and detailed sampling and evaluation, taking into account the latest technical and economic parameters. The bauxite potential of the region is negatively influ- enced by the complicated uplift history of the Bakhuis horst, and positively by the presence of suitable parent rock and possibly more than one phase of bauxitization.

Jan 1, 1984

By L. Donovan Clark

The term "powder factor" is almost universally accepted as the measure of the efficiency of a blasting program. It represents the economics of blasting since it designates quantity of explosive (thereby providing quality control in rock fragmentation) in terms of the associated volume broken. It is the wide use of this concept that explains the interest shown in an approach to rock blasting preferred by A. W. and Z. W. Daw* in a treatise on 3 blasting (1) substantiating its use in the form, Q = CVW3 for single shot hole, where Q = quantity of explosive lb Cv = blasting coefficient W3 = unit volume of rock It is obvious that the term Cv could also be called the apparent powder factor should the equation be written in the form, Cv = Q/W3 (lb per cubic unit). However, while the approach was ingenious** and the practical applications straightforward, their original, rather limited experimental work, along with certain assumptions, was questioned.

Jan 1, 1970

By J. A. Finch

A closed grinding circuit, typified by a ball mill-cyclone combination, is often required to treat a feed comprised of a variety of minerals of differing properties. Usually, the individual behaviour of the minerals is not assessed, a procedure which requires sizing and metal or mineralogical assaying of each size fraction. Further, sizing is frequently by screening to perhaps 325 mesh meaning that detail on the important -44 um fraction is unavailable. It is well appreciated that minerals can exhibit both individual classifying and grinding behaviour. Recognizing that cyclone classification results from differential centrifugal settling and acceleration rates, then minerals of differing specific gravity will exhibit individual mineral cyclone performance curves. If the minerals have differing grindabilities, then individual mineral rates of breakage may be expected. When treating an ore containing minerals of a range in specific gravity and/or grindability, individual mineral behaviour in the closed-circuit grind could be notable and perhaps important to the overall concentrator performance. An example is a lead-zinc ore, as shown by Kelsall et al.(1,2) This paper describes the individual mineral cyclone performance curves at sizes down to ti 10 um for the four major minerals at two lead-zinc concentrators; the Sullivan concentrator at Kimberley, British Columbia, and the Pine Point Mines concentrator at Pine Point, North West Territories, both operated by Cominco Ltd. In addition, individual mineral grinding behaviour for the four major minerals at the Sullivan concentrator is presented.

Jan 1, 1977

By W. C. Meyer

Surface tension and its control are important in the concentration of ores by froth flotation, both in terms of producing the proper bubble size distribution and to render the ore surface of interest hydrophobic such that adhesion to a bubble will take place. The influence a substance has on surface tension has traditionally been measured using static, equilibrium techniques. Yet many applications such as flotation involve rate-related effects of surface tension where equilibrium values are not reached. In the time frame of 1 - 300 seconds, aging effects have been noted for bubbles formed in dodecylamine acetate solutions; a slow decrease in surface tension occurs until an equilibrium value is reached, as studied by Finch and Smith (1972). Since stationary bubbles do not exist in flotation cells because of the turbulence generated by agitation and aeration, it is more likely that the chemical composition of the bubble is determined during its formation, under dynamic conditions. The chemical composition is extremely important because the induction time required for a particle-bubble entity to collide and adhere to each other is augmented by favorable surface tension (wetting) proper- ties between the surface of the particle and the bubble air-water interface or envelope, as considered by Mackenzie and Matheson (1963). Finch and Lyman (1976) have established that the probability of a "permanent" attachment taking place during this contact time is aided by the ability of an oil droplet (viz. bubble) to relieve non- equilibrium surface tension effects which are involved in the water-thinning process. This Maragoni effect, or surface elasticity, can be considered in the context of particle agglomeration addressed by Kao and coworkers (1975). Water drainage leads to the formation of a collector-frother meniscus appearing between the colliding entities, arising from their combined partial immiscibility in the water phase and promoted by hydrophobic bonding within the interface. Together they constitute a liquid bridge whose force of attraction drawing the particles together is proportional to the interfacial tension existing between the water phase and liquid bridge. This adhesive force shows an approximate linear decrease with separation distance until rupture occurs, that is, FX = Fmax (1 ? X/Xr) (1) for a distance of separation X and rupture distance G. The greater the surface elasticity of the bubble, the greater will be the rupture distance and the better will be the force of adhesion. Since van den Tempel (1965) has related surface dilational properties of bubbles to the elasticity, E, of the film as

Jan 1, 1983

By Sidney M. Cohen

[Portland cement is a product made from a combination of limestone and argillaceous material which would supply the necessary amounts f calcium, silica, alumina and iron to form cementious compounds when fired at high temperatures. The resulting mixture, usually around 80% limestone and 20% argillaceous, is ground nine (80% -200 mesh), blended and then fired1 (2600-2700°F) to produce a cement clinker from which the final cement product is produced by grinding. The argillaceous component can be shale, clay, slate or other sources of the individual components of silica, alumina and iron. This paper deals with a case where a clay component was under consideration. The planned Plant site was to be located at a well defined limestone deposit. When it came to the argillaceous component, the nearest uniform deposit of clay was over 50 miles away and would require purchase of land or clay from the owner plus the daily delivery costs to the plant site. This situation made the plant site economically questionable. It was decided that a local clay deposit, which was available at the plant site but was orginally not considered due to lack of chemical uniformity and its high free silica content, would be reconsidered.]

Jan 1, 1983

By Felicia F. Peng

The plant data were collected from three streams around a dense medium drum for coarse coal cleaning operated at various volumetric ratio of medium-to-feed. The effect of the volumetric ratio of medium-to-feed (MF) and particle sizes on the performance criteria, g50 and Ep, of the dense medium drum. These measured data were adjusted and calculated for the yields and balanced relative density distributions by mass balanced method based on the statistic principle. These balanced data were then used to formulate the mathematical models of the separation distribution curves for the various feed size intervals. The correlation equations for the g50 and Ep as the function of inverse of the feed size, and MF and total throughput were established. A numerical algorithm utilizing the Secant method, based on the root searching principle, was developed for yield optimization and simulation of dense medium drum separation to improve the separation efficiency and hence the product yield. The relationships between the direct ash content and relative density of the particles in feed and the products were established and incorporated into the numerical algorithm for predicting the product quality.

Jan 1, 1996

By H. X. Li, A. Correa, M. M. Zhang, W. Xuan, M. Andrade

"With increasing demand for steel and depletion of high-grade iron ore deposits, more research efforts are being directed toward extending the life of existing ore reserves and developing technology to treat low-grade iron ore resources. Among all the reported technologies, biotechnologies in mineral processing – specifically bioleaching and microbially induced flotation – have emerged to be considered as low-cost, environmentally friendly potential alternatives to many of the current mineral processing techniques. This paper provides a comprehensive review of current research on the use of microorganisms for iron ore beneficiation and, further, discusses the applicability of bioleaching, bioflotation and bioflocculation for the beneficiation of low-grade iron ores.IntroductionIncreasing global demand for raw materials has led to diminishing resources of high-grade iron ore. As a result, the mining and utilization of low-grade hematite, limonite, specularite, siderite and goethite ores have attracted more and more attention. However, these types of iron ores are of complex paragenesis and fine disseminated grain size, and often contaminated by phosphorus in the form of solid solution. The distribution of phosphorus throughout the iron mineral crystals prevents the effective use of physical separation techniques, and these complex ores are at present largely untapped due to a lack of cost-effective and efficient processing methods. Chemical leaching and roasting-magnetic separation approaches have been mainly tested only on the laboratory scale and are all either cost prohibitive or ineffective when used on low-grade complex iron ores."

Jan 1, 2015

By Yongsik Jeong, Kwangmin Kim

Conventional tailings slurry contains a significant amount of water, and water management is key to ensuring the stability of a tailings storage facility (TSF). Simply reducing the water content in the slurry before discharging it from the mill could be an effective way to improve TSF water management. This study investigated the potential for using an environmentally friendly polymer as a new drag reduction agent (DRA) to reduce frictional pressure loss and also conserve water. It entailed conducting pipe loop tests to assess the polymer’s effect on pressure loss in tailings flow and then applying the test results to validate a numerical model using computational fluid dynamics (CFD). The model was also used to determine the polymer’s optimal concentrations at given solid concentrations and flow rates, its effect on energy efficiency for tailings transportation, and its potential for saving water. A case study for a mid-sized, hard-rock mine with a throughput of 50,000 t/day found that the solid concentration could be increased from 30 to 45% with no pressure loss by applying 1996 m3 of the polymer per day. Adding the polymer also resulted in water savings of 57,552 m3/day. The results of this study demonstrated the potential for using the new DRA not only to improve TSF stability but also to save water.

Jun 29, 2020

By Paul Grisley

Air-supported belt conveyors-conveying systems that replace troughing idlers with a film of air-were a revolutionary concept when introduced in the 1970s. But high installation and operating costs limited their application. Now, system refinements have led to successful applications, even under the challenging conditions of mines and process plants. In this presentation the author will discuss the latest developments in the engineering of these systems, including the ability to retrofit existing transfer points with modular air conveyor components. Air conveyor applications and limitations in mineral-handling operations will also be examined.

Jan 1, 2002

By Firat Atalay

Estimating the spatial distribution of ore grade is one of the most critical steps to proceed with an investment decision on a deposit. Kriging is the most widely used method to estimate the ore grade, but alternative techniques are being developed. Machine learning algorithms can be used as alternative methods to classical kriging. In this paper, the iron (Fe) grade of a deposit is estimated with the XGBoost algorithm, and the results are compared with kriging estimation results. For the estimations, samples collected from drillholes were used. Due to the different natures of the estimation methods, different steps were taken to perform the estimations. The results show that XGBoost produced higher-range estimates, which is a desired result in ore grade estimation, and the minimum and maximum of the estimates were lower and higher than the kriging estimates, respectively. However, like kriging, the estimation results were smoother than composites, and the variance of the XGBoost estimates was lower than the variance of composites. This means that even though estimation with XGBoost mitigates the smoothing effect, the estimation results suffer from smoothing like kriging.

Dec 1, 2024

By K. Osseo-Asare

LIX63 in combination with DNNS selectively extracts nickel and/or cobalt from acidic leach liquors with pH values as low as 1.0. Nickel/cobalt and cobalt/nickel selectivities are achieved by varying the relative concentrations of LIX63 and DNNS. Increasing LIX63 concentration retards both extraction and strip-ping rates while DNNS has the opposite effect. Slope analyses of equilibrium data indicate that both LIX63 and DNNS are present in the extracted complexes. Examples of possible flowsheets are presented.

Jan 1, 1978

During a period of six months in FY2018, a series of trials were conducted to compare drilling accuracy using two different methodologies and the subsequent impact this had on ore dilution. Testing was conducted at Cracow underground gold mine in Queensland, Australia. The drill rig’s existing alignment process was compared to a new technology system with the following observations: - Using the existing alignment process only 20% of holes surveyed recorded toe points within the +/-300mm (11.8in) tolerance blast-hole deviation. - The new technology was proven to limit rig alignment error, reducing average blast-hole deviation and increasing the number of holes drilled within tolerance by 160%. The increased accuracy reduced stope dilution by reducing over-break of subgrade ore: - Stopes drilled using the new technology recorded 62.6% less average dilution. - This contributed to an overall reduction in dilution for the full year (FY18) of 5 percentage points compared to FY17 - from 22% to 17% (a net decrease of 22.7%). A cost-benefit analysis extrapolated from the trials stipulates that if the new technology were in use for a full 12 months, when applied to FY17 full year data, a 10 percentage point reduction in dilution would represent a net 45.4% decrease, and would result in AUD8.2M (USD5.9) additional ore recovered, with AUD4.5M (USD3.2M) less spent on wasted cost of haulage and processing of diluted ore. As a result, return per tonne would increase 22%, from AUD87 (USD63) to AUD106 (USD77.1). INTRODUCTION Dilution – planned and unplanned – remains a significant cost impairment in the mining process. A series of trials were held over a six-month period in FY18 which established the cost-benefit of new technology as it applies to the alignment accuracy of production drilling rigs in underground mining, thus confirming its ability to limit drilling as one of the causes of dilution. The trials identified three underlying factors affecting drilling accuracy, measurable by blast-hole deviation surveys of planned vs actual toe data. These were; rig alignment error, collar location change/error, and in-hole deviation. The trials involved a comparison of existing rig setup processes and technology, with the new technology (Minnovare’s Production Optimiser system). The trials were undertaken in the same environment; an operating underground gold mine - Cracow Gold Mine. The comparison first revealed the extent to which rig alignment impacts blast-hole deviation. Secondly, the new technology was proven to limit rig alignment error, thereby reducing average blast-hole deviation and increasing the number of holes drilled within tolerance by 160%.

Jan 1, 2019

By E. Yigit

Hydrometallurgical production of zinc from concentrates is generally carried out by H2SO4 leaching. For the smooth operation of this process, some harmful components must be removed from the leach solution before the electrolysis stage; MgO is one of these compounds. Zinc concentrate samples from the Mount Isa mines were used in leaching tests. Leaching tests with an aqueous solution of H2SO4 and SO2 gas were carried out at various temperatures, pH levels and leaching durations. While duration and the pH value of the solution were effective parameters in H2SO4 leaching, temperature and pH were more effective in SO2 leaching for the removal of MgCO3 and CaCO3. Removal of MgCO3 and CaCO3 was generally achieved at low pH values. The results show that SO2 gas can be a good alternative to sulfuric acid in the leaching of MgCO3 and CaCO3

Jan 1, 2010

By T. J. DeMull

The business of heap leaching requires accurate forecasting of metal production from the heaps. Business forecasts typically follow a format that project periodic (monthly, quarterly, or annual) product shipments based on anticipated operating results, e. g., tons of ore placed, grade of ore, and rate of leach extraction. Since revenue and cash flow are dependent on the metal production stream, forecasts of metal production are very important for project evaluation and business planning purposes. Nevertheless, production forecasts, particularly for new heap leach projects, have been prone to errors. The present paper identifies some of the pitfalls that would be encountered in preparing production forecasts for new heap leach operations and provides a checklist of considerations to assist in preparing a forecast. Also, the paper presents a case study of copper production forecasting used for the Sanchez Project, a heap leach operation located near Safford, Arizona, that is presently under development by AZCO Mining, Inc.

Jan 1, 1995

By M. Sears, W. H. Su, J. Wickline, M. A. Van Dyke, G. Esterhuizen, Z. Khademian

It is commonly recognized that seismicity can be induced by rock failures or slip along geologic structures around mining excavations. The unpredictable nature of these events and their proximity to the working area may raise safety concerns in underground mining operations. Modeling can be a useful tool for estimating seismic potential for a given mine layout, but the challenge is to detect a seismic event and estimate its intensity in the model. One well-documented approach is to monitor the variation in the energy content of the model and record potentially damaging seismic events when there is a significant release of energy. Researchers from the National Institute for Occupational Safety and Health (NIOSH) employed this approach using 3DEC modeling software to simulate the anomalous seismic events that occurred in a deep longwall mine in Virginia in 2005. A four-panel model of the mine was constructed utilizing a 2D cross section at the location of the mining face at the time of the event. Seismic potentials associated with the development of each panel are evaluated by recording the seismic energy released during the simulation. The results demonstrate the occurrence of two relatively significant events during the mining of the last panel, which are consistent with the historical observations at the mine.

Apr 26, 2022

By J. P. Baur

The sensitivity of radiochemical techniques makes possible the study of the initial stage sulfuric acid leaching kinetics of chalcopyrite and other copper sulfide minerals. High-grade Transvaal chalcopyrite was neutron irradiated in a TRIGA reactor to produce radioisotopes copper-64, iron-59, and sulfur-35. Dissolution rates were measured in the time interval zero to 60 minutes during which time significant anomalies were observed. First, an initial period of rapid dissolution lasting a few minutes; second, an arrest or "plateau" region usually lasting from 6 to 10 minutes; third, a second period of dissolution of lesser rate than the first. The effect of solution variables such as pH, oxygen partial pressure, and ferric ion concentration at different temperatures were measured. The initial rate data were correlated by considering the rapid reaction to be due to the dissolution of surface oxidation products or the formation of an iron depleted surface layer. The data for the second slower reaction have been explained to be due

Jan 1, 1972

By Circe Verba, Scott Montross, Jon Yang

This work is a first-order study to assess the suitability of an organic acid lixiviant to extract rare earth elements (REE) from coal preparation fines refuse sourced from a Pennsylvania mine with a total REE of ~ 300 ppm. The extraction of REE using an organic acid, in this case 0.1Mcitric acid and 0.5Mtrisodium citrate solution, is compared against 0.5M(NH4)2SO4, 1MHCl, 1.2MH2SO4, and 0.5Methylenediaminetetraacetic acid (EDTA). Ashing the coal waste material prior to leaching tests with the citrate solution nominally improved REE extraction. Buffered citrate solution recovered 7% of the total REE in the as-received Isabella Fines as compared to 11% in ashed samples, whereas (NH4)2SO4 extracted 5–6%, respectively. EDTA recovered up to 33%of the total REE, most likely due to the higher coordination chelate bond. Mineral acids, however, outperformed the organic acids on ashed material (16–52%REE recovery), suggesting that organic acids may not be a suitable competitive option for REE extraction from these types of feedstocks.

Jun 15, 2021