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By J. H. Baek, S. Alexandrovskii, D. W. Lee, B. K. Kim

Nano-phase titanium carbide was synthesized by Mg-thermal reduction process using a novel route of Mg-thermal reduction. The processes are based on I) feeding of TiC14+CxC14 x = 1, 2 ) solution into liquid magnesium, 2) Mg-reduction of metal chlorides, 3) TiC formation by the reaction of released Ti and C atoms, and 4) vacuum separation of residual liquid phases of Mg and MgCl2. In this study, the process for titanium carbide production with composition close to stoichiometry and the minimum content of impurities was optimized with the various process parameters such as concentration of initial solution, its feeding rate and reaction temperature, as well as a kinetic study.

Jan 1, 2004

By G. Brooks, M. Hamed, S. Nightingale, K. Coley

The Marangoni effect plays a significant role in slag line corrosion of refractories. Previous experimental studies for various refractory /slag systems and mathematical models are reviewed and show that Marangoni flow is important in slag line corrosion under static conditions. Recent work by the authors is presented which also shows significant slag-line corrosion of MgO refractory in SiO2-CaO-FeOx-MgO slag. The rate of attack of the MgO was marginally slower in the case of slags containing alumina. A semi-empirical model developed by Hrma based on mass transfer control described reasonably well the observed progression of corrosion with time. Further work is proposed to evaluate this model.

Jan 1, 2004

By T. Cutard, H. Marzagui, E. Ouedraogo, M. Roosefid, M. Prompt, C. Deteuf

The present work is achieved in the framework of a French national program on modeling and experimental characterization of the thermo-mechanical properties of refractory materials (PROMETHEREF). This research program is aimed to establish fair models and experimental database and to make it available to industrial partners for numerical simulation of industrial structures made of these materials. The present paper focuses on two silica-alumina refractory castables, an andalusite based one and a bauxite based one. We will present the first rheological characterization results achieved at room on normal and preheated samples of these two refractory castables. Refractory castables are characterized with the help of four points bending tests, compression tests and tensile tests.

Jan 1, 2004

By Paul Stothart

Agenda 1)Key Political and Policy Issues 2)Relevance to the Mining Sector ?All parties vying to be the greenest ?Regulation, indoor air, health issues combined into Clean Air Act ?International carbon markets ?Kyoto Protocol ?legal force ?Spawning clean energy technologies? ?Effectiveness of present approaches?

May 1, 2007

By D. Ferrand, C. Villeneuve, N. Bensalah

"La conciliation entre l’expansion de l’industrie minière et les exigences du développement durable représente un grand défi. Face aux différentes controverses touchant cette industrie, la dernière décennie a été marquée par une plus grande mobilisation de l’ensemble des parties prenantes. Cependant, plusieurs carences persistent en matière d’opérationnalisation du concept de développement durable. Ce défi met en cause la responsabilité partagée entre les parties prenantes. Il exige le renforcement des responsabilités gouvernementales et l’instrumentalisation de bonnes pratiques de responsabilité sociale des entreprises. En aval, s’impose la gestion intégrée de l’usage des produits miniers et la promotion de l’innovation et de la recherche.ABSTRACT Conciliation between expansion of the mining industry and sustainable development requirements represents a great challenge. With regards to the various controversies touching this industry, the last decade was marked by a great mobilisation phase of all stakeholders. However, there are still many shortcomings regarding operationalization of the sustainable development concept. This challenge involves shared responsibility between the stakeholders. It requires strengthening government accountability and instrumentalization of good corporate social responsibility practices. Further down the chain, the use of mining products and the promotion of innovation and research must be achieved through integrated management."

Jan 1, 2015

By T. Melfi, M. James

Attaining required mechanical properties in welds made using the double submerged arc welding (DSAW) process is difficult, and it is becoming more difficult as the strength level of the base materials continues to increase. Producing weld metal with adequate mechanical properties involves factors that are often overlooked and not taken into consideration. Not least amongst these problems is simply finding information to use in selecting the appropriate flux/wire combination. Most of the available data on flux/wire combinations provided by consumables manufacturers is generated using the multiple pass welding procedures required for classification per specifications such as AWS A5.17 and A5.23. This data really gives no insight into the properties that can be expected in a DSAW application. Also, base plate composition plays a very significant role because of the fact that base plate dilution can be as high as 70% in DSAW welds. This means that if any elements are present in the base metal that are deleterious to mechanical properties, they will also be present in significant quantities in the weld deposit. Some of these elements can decrease toughness and increase hardness (increased hardness is a concern if the pipe is intended for sour service). Some of these problems can be mitigated by proper selection of welding consumables. Selection of proper welding consumables means selecting an electrode that provides the appropriate alloying elements to obtain the desired level of impact toughness while also keeping the hardness within any specified limits. In order to attain the necessary impact toughness, selection of a flux with an appropriate composition (in terms of its basicity and its ability to control the nitrogen content of the weld deposit) is required. As with all welding processes, the mechanical properties of DSAW welds are also highly dependent on the welding procedures. This work clarifies how to select appropriate consumables to meet a given set of requirements, and also how to achieve the optimum mechanical properties from those consumables.

Jan 1, 2005

By Lei Pan, Roe-Hoan Yoon

"Sea water flotation is becoming a reality due to shortages of fresh water. To better understand the mechanisms involved in sea water flotation, we have studied the effects of KCl and MgCl2 on the surface forces present in the wetting films of water formed on hydrophobic surfaces. The measurements have been conducted using the force apparatus for deformable surface (FADS), which is capable of measuring both the surface and hydrodynamic forces responsible for bubble-particle interactions. The results obtained with the gold surfaces hydrophobized with butanethiol (C4SH) show that the wetting films of Ultrapure water do not rupture despite the relatively high water contact angle (??= 80o) and the presence of a long-range hydrophobic force with a decay length (D) of 25 nm in the film. The film is metastable with its equilibrium thickness (he) at 140 nm, where the repulsive double-layer force is equal in magnitude to the capillary force as shown in Figure 1. The film loses its metastability and ruptures in a 10-2 M KCl solution, in which the double-layer force decreases substantially due to the decrease in Debye length (?-1) while the decay length of the hydrophobic force remains as large as 23 nm.The effects of MgCl2 has also been studied using a C4SH-coated gold surface with a water contact angle of 87o. It has been found that in a 10-4 M solution double-layer force decreases due to the decrease in the negative ?-potentials and Debye length, which should help destabilize the wetting film. However, the film remains stable due to the decrease in the decay length of the long-range hydrophobic force from 45 nm in Ultrapure water to 14 nm in the MgCl2 solution. Thus, the results obtained in the present investigation support the view that the difficulties in sea water flotation may be due to the presence of MgCl2 rather than the presence of NaCl in sea water (Ramos, et al., 2013)."

Jan 1, 2016

By Richard C. Williams, Herman Pieterse, Ken Thomas, K. S. Fraser, Ron H. Colquhoun

"The Banick Goldstrike Mines Inc. (Goldstrike) operation is located in Eureka County in north-central Nevada on the Carlin geological trend. Gold in the sulphide mill feed, occurs primarily as submicroscopic inclusions or possibly solid solution in a pyrite and marcasite matrix. Sulphide mill feed is pretreated in a pressure oxidation plant allowing gold recoveries of 90 per cent and greater to be achieved. Anticipated 1994 gold production for the sulphide gold facility is approximately 1,500,000 ounces.In January 1989 American Banick Resources Corporation (Banick) announced the US$365 million Betze Development Plan for the Goldstrike property. The Betze plan was based on a three (3) staged expansion of the original 4,500 STPD oxide gold plant. This expansion would involve addition of ore and gold processing capacity and the total conversion of all ore handling facilities to treating Betze sulphide ores.Phase 1 of the Betze Development Plan involved the construction of a pressure oxidation circuit, including a single autoclave and supporting ancillary services. The pressure oxidation circuit was commissioned in February 1990. Currently a throughput of 2,000 STPD is being achieved.Phase II of the Betze Development Plan, commissioned throughout April and May 1992, included the expansion of grinding, leaching, and gold recovery facilities enabling the treatment of combined oxide, and sulphide ore. Pressure oxidation capacity was increased by the addition of two (2) autoclave circuits each treating 2,600 STPD of sulphide ore and other required ancillary services. By June 1992, the Phase II gold facility had achieved a combined throughput of 15,000 STPD of oxide and sulphide ore.Phase Ill, the final stage of the Betze Development Plan, was successfully commissioned in February and March 1993. This final stage of development increased the design throughput of the pressure oxidation plant to 15,000 STPD by the addition of three (3) autoclave circuits with combined capacity of 7,800 STPD."

Jan 1, 1994

By R. V. Typliski, G. J. Labarre

"Hudson Bay Mining and Smelting Co., Limited, Flin Flon, Manitoba, has developed a metallurgical wastewater treatment system employing two-stage lime neutralization, sludge recirculation and conventional mechanical thickening.Laboratory investigations, initiated in 1970, led to the construction of a pilot-scale minewater treatment plant, at Schist Lake Mine, in early 1971. This plant, treating 600 cubic metres /day of wastewater containing 30-60 mg/1 zinc. demonstrated metal extraction efficiencies of 99% under normal operating conditions.On the basis of this pilot work, a second pilot-scale treatment system was established in 1975 at the Flin Flon metallurgical plant to treat zinc refinery process waste water. Through numerous improvements, including automatic con¬trol equipment, the system has evolved to a full-scale operation capable of treating 800 cubic metres/day of wastewater containing 4-11 gm/1 zinc. Treated effluent contains 0.2-20 mg/1 zinc. The hydroxide sludge produced returns to the metallurgical process for the recovery of metals while clarified effluent discharges to waste.With the system, Hudson Bay Mining has achieved its original goal: the reduction of environmental contamination, while realizing a return from metal recovery.IntroductionWith the goal of reducing environmental contamination, Hudson Bay Mining and Smelting began laboratory testwork, during the late 1960's, into the methods and technology for neutralizing and removing heavy metals from acid mine drainage. Based on lime treatment, early tests showed much promise and culminated in the construction of a pilot-scale test plant at Schist Lake Mine in early 1971.This pilot system utilized technology developed in laboratory studies, and related to work then underway by state authorities in Pennsylvania coal mines. The basic operation consisted of a lime slurry tank, baffle reactor and a free-settling basin. Through three summers of operation, the Schist plant, capable of treating 600 cubic metres/day of minewater, produced a heavy-metal extraction of 99% under normal conditions. Although successful in proving the treatment chemistry, the plant displayed deficiencies in sludge densification and handling."

Jan 1, 1980

By V. Pouyafar

Semi-Solid metal alloys, as used in SSM processing, have a special microstructure of globular solid particles suspended in a liquid matrix, which makes them behave differently in forming processes. The sensitivity of semi-solid slurries to temperature variations and their history and rate dependant behavior, make process design and control difficult. Precise selection of the process parameters is necessary in part production. Therefore, a numerical analysis and simulation of the process can be a valuable tool in process design. In this work we proposed a structural dependent model to account for the thixotropic behavior of semi-solid metals. The parameters of the model were then determined using rheometery tests. The results show a good agreement between the model and the experiments.

Oct 1, 2011

By M. Hosseinzadeh

By changing the quality of consumed refractory bricks in burner zone of sarcheshmeh copper complex anod kiln removing of carbon precipitation phenomenon was studied. For blister deoxygenation LPG is blowing in anod kiln and cause destoring microsturcture and bonding of refractory bricks. Studies are shown that in a part of the bricks which have a temperature of 800 - 1000 °C , iron content phases in magesia - chromite bricks are like catalist and cause increasing the rate of carbon precipitation reactions . In a way that in comparsion of two bricks with best and medium quality with different analysis, this problem is more critical in best quality bricks containing high iron oxide. Therefore special magesia spinel bricks suggested and installed in burning zone.

Jan 1, 2004

By M. R. Coffin

In recent years, improved operation of the Kidd smelter has resulted in an increase in blister production capacity. Due to manpower and equipment limitations anode production and treatment rates could not be increased without incurring significant additional operating expenses. The option chosen to expand casting and refinery capacity to meet the available blister supply was to increase the anode thickness while maintaining the same anode exchange cycle in the refinery. This has resulted in a cathode production increase of almost 10% for minimal expenditure. Equipment and process modifications required to cast and refine the thicker anodes are discussed in this paper, along with the Six Sigma methodologies used to identify them. Key areas covered are Hazelett continuous caster operation, refining process parameters, plating performance and cathode quality.

Jan 1, 2007

By M. J. Hadianfard

The effect of holding at temperature on fatigue life of a 10 vol% particulate SiC reinforced Titanium alloy has been investigated. The influence of holding time at 600°C on fatigue of this material has been studied by using tension-compression tests, scanning electron microscope and image analysis. The specimens were heated to 600°C by using a controlled atmosphere furnace; hold at this temperature for time ranging from 0 to 100 hours, and then fatigue tested at room temperature under controlled constant plastic strain. The number of cycle to failure found to decrease with increasing of the holding time. In addition the fracture mechanism and number of debonded particles has been significantly influenced by holding time at 600°C.

Jan 1, 2004

By E. Paransky, M. Rigaud, G. Paschek, S. Palco

Some of the negative impacts of carbon addition on the strength of castables are yet to be overcome in order to fulfill its potential benefits for oxidation resistance. This paper reports the results of recent studies conducted at CIREP on the effects of different types of carbon additives on the thermo-mechanical properties of magnesia-based castables. Experimental techniques included measurements of the hot modulus of rupture (HMOR), hot modulus of elasticity (HMOE), as well as the wedge-splitting test (WST). The comparison of evolving microstructures was carried out employing scanning electron microscopy with microanalysis attachment (SEM/EDS) and X-ray diffraction (XRD). HMOR values of 12 MPa at 1300°C have been reached in MgO-Si02-C castables containing up to 7% carbon.

Jan 1, 2004

By W. Lo, M. Brothers, G. Oprea, G. Richard, T. Troczynski

Magnesia-chrome and chrome-magnesia are the most used refractories in contact with iron-rich non-ferrous smelting slags. The corrosion by slag always brings chromium oxide into the slag, causing the precipitation of crystalline phases at the process temperature. This secondary effect of the chromium-bearing refractory dissolution was studied in this work, emphasizing the effect of the other chemical components of the slag at various temperatures. The experimental results showed that the presence of chromium and lead contribute, although in different ways, to the formation of complex spinel phases and their precipitation at temperatures in the range of 1250-1400°C. The XRD and SEM/EDS results were discussed for refractory-slag mixes containing 0-20% Cr2O3 and 0-11% PbO.

Jan 1, 2004

By D. Allen

Faced with decreasing ore grades and harder ores, many mines today are forced to become more efficient with their approach to processing. Variability in ore hardness, mineral liberation, reagent consumption, sliming, and leach responses are all a function of the minerals present and their concentration. Modern semi-automated X-ray Diffraction (XRD) analyses using Rietveld refinement techniques, in conjunction with high speed quantitative Near Infrared (NIR) analyses, provide reliable quantitative mineralogical ore profiling. By the implementation of XRD with NIR, mining, milling and leaching operations no longer need to be dependant on visual estimates for GeoMetallurgical Modeling and are provided with a valuable forecasting and production control tool. This paper will illustrate the development, plant implementation and application of XRD and NIR at several copper operations.

Jan 1, 2007

By Richard Hurteau

Design and validation of an integrated guidance system for articulated ground vehicles is investigated. The development of an autonomous industrial vehicle must take into the account the specific geometry of these vehicles; they can be composed of a tractor with 1 or 2 trailers or of articulated type like LHD. Moreover the tractor-trailers type vehicles can have on-axle hitch configuration or positive/negative off axle configuration. The path-tracking of a tractor-trailer vehicle in restricted space is presented and discussed in this paper. Recent results obtained in simulation and validated by experimentation are also presented. These studies can lead to better ways of maneuvering an articulated vehicle in a restricted space or automatically executing of docking and parking maneuvers

May 1, 2002

By S. D. Logan

This presentation describes a lightweight automobile body structure concept developed at DaimlerChrysler to support a high fuel-efficiency vehicle project. This body structure consisted primarily of large thin-wall magnesium castings and resulted in a more than 40% weight reduction with a minimal cost increase over a conventional steel structure while achieving significantly improved structural performance as evaluated through CAE simulations. One concept vehicle was built for the purpose of demonstrating concept feasibility. Several slides showing the prototype build process are presented. The presentation also describes several large thin-wall die casting body applications that are in current production or have been used in recent production automotive applications and identifies areas where further development could improve the chances of a magnesium intensive body structure becoming a production reality at a later time.

Jan 1, 2006

By R. Ham-Su, J. P. Healey, S. P. Farrell, R. S. Underhill, M. A. Gharghouri, C. V. Hyatt, L. M. Cheng

Magnetic shape memory alloys (MSMA's) are a class of materials where magnetic energy can be converted into mechanical energy and vice versa. NiMnGa-based MSMA's have attained magnetic field induced strains up to approximately 10% and have a relatively wide operating temperature range, from well below 0°C to above RT, making them very attractive for a variety of applications. However, these materials also suffer from low toughness. Using these materials in a composite could mitigate this shortcoming, and also overcome limits imposed by inertia and eddy current losses. In this work, we describe the manufacture and characterization of such composites. Composites with 30% by volume MSMA were fabricated under a magnetic field resulting in anisotropic magnetic properties. Damping properties were evaluated by dynamic mechanical analysis.

Jan 1, 2004

By S. Orzecki

The KGHM Copper Refinery Plant, Glogów 1, has operated for 35 years and -increased its capacity almost ten times.Cathode quality, expressed in terms of the total impurity content, has undergone a five-fold improvement. The present refining capacity is equivalent to 240,000 metric tonnes of copper cathode, with a total impurity content of 20 ppm, inclusive of 10 ppm Ag. These accomplishments result from combined implementation of current technological progress in electrolytic refining and KGHM's own solutions applied to the Glogów Refinery. The quality improvement measures feature both lowering actual current density, despite an increase in nominal current density, and diminishing the role of non-ion mechanisms which transfer impurities to cathodes. The paper contains a detailed discussion of these issues and outlines possible measures aimed at further production and quality improvements.

Jan 1, 2007