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By S. Luidold, A. Poscher, H. Antrekowitsch

"The rare earth elements (REE) are nowadays mainly used for permanent magnets, catalysts, hydrogen storage alloys in rechargeable batteries, for glasses, ceramics, and polishing agents. Other important areas of application are phosphors in different types of lamps (fluorescent tubes, energy-saving lamps, etc.). These lamps are often collected and treated at their end of life by disintegration and sorting. However, the obtained fine fractions comprise not only REE-containing phosphors but also small amounts of mercury and are therefore disposed till today in special landfills. Due to the enormous price increase of the rare earths during the last two years, a lot of activities started for extracting these elements from secondary resources such as for example phosphors. All recycling concepts for this task mainly work with hydrometallurgical methods. The large number of different compounds in phosphors with sometimes very different behaviors with respect to their solubility in aqueous phases forms a major challenge to achieve good yields as well as acceptable purities of the produced rare earth concentrates by a process with a reasonable number of operation steps. Therefore, this paper gives at first a brief overview about the compounds, used as phosphors and about existing concepts or investigations. It further describes our own process design and the results, obtained on laboratory scale. INTRODUCTIONThe rare earth elements (REE) have a central position in the industrialised world despite their marginal production volume in comparison to common metals such as aluminium, copper, zinc etc., because they are essential for many applications. They often cannot be substituted without a considerable loss on functionality and quality. This group of metals comprise the lanthanoids (f–block elements, lanthanum–lutetium) as well as scandium and yttrium.The estimated world mine production of REE amounted to 133,000 t rare earth oxide equivalent in 2010, whereat China accounted for 130,000 t or 98 % (Cordier, 2012). The European Union (EU-27) imported 23,013 t in 2008 to cover its demand. The figure 1 shows the fraction of the European member states in terms of the total imports of rare earth compounds from outside the EU-27 (Schüler, Buchert, Liu, Dittrich, & Merz, 2011)."

Jan 1, 2012

By Louis Frost

MINE ventilation has for many years been the subject of intensive study by numerous investigators who have presented their findings in forms that are understandable to the average mining man, and all this writer hopes to do is to review those findings in relation to the 'manager's' problem in mine ventilation. It would not, perhaps, be wholly correct to acclaim practical mine ventilation as an exact science, because of the many variables entering into the problem. Each mine has its own particular problem and ventilation characteristics. Fan design, in contra distinction to mine ventilation, is an exact science, but the designer cannot always take into proper consideration the practical variations to which each mine is subject. Fan designers, accordingly, are forced to base their design on such data as the mine manager or engineer is able to supply, and, when it is borne in mind that the mine characteristic is constantly changing, it is not at all surprising that fans do not always show efficiencies hoped for. In many instances, fans work far beyond the de-signer's limitations, and, in consequence, are an economic disability in the colliery cost-sheet, and it is of paramount importance that the colliery manager evaluate all the factors involved in relation to fan performance for the colliery to receive full benefit from its investment.

Jan 1, 1941

By John Dasher

The analyses reported on in this paper indicate that there are hydrometallurgical routes from sulphide concentrates to copper that are potentially competitive with smelters which are not permitted to emit sulphur oxides. The various hydrometallurgical processes, and their economics, are discussed.

Jan 1, 1973

By K. A. Foxford, D. A. Polya, R. P. B. Hebblethwaite

"Abstract-A variety of techniques for interpreting systems of mineralized echelon veins is discussed using examples from Panasqueira and SW England. As aids for exploration and mine planning, and as a tool for ore reserve evaluation, particular emphasis is placed upon establishing vein morphology in the third dimension, and upon understanding vein dilation and propagation histories. Special attention is also placed upon investigating vein thickness and spacing relationships, and upon understanding vein segmentation. The relevant data for these techniques are all readily obtainable from stope and core sources.The vein systems described were produced in host-rock sequences that underwent incremental dilation in response to fluid overpressures, and individual veins display evidence for mineral infilling synchronous with their propagation. Echelon vein geometries resemble those reported from igneous dikes and sills: vein walls are stepped and veins are divided into segments arranged in echelons. Changes in vein geometry, from arrays to composite structures, reflect both the evolution of the vein system with time, and the changes occurring between the margins (arrays) and core (composite structures) of the system. These characteristic morphologies can be used to infer vein propagation and fluid injection trends, proximity of neighboring veins, and the shape of the system as a whole. The techniques are applicable to systems of echelon veins produced under tensile conditions in rocks where faults were absent at the time of vein formation, and where subsequent deformation has been minimal. Further work is required to assess the application to echelon vein systems formed within more complex tectonic regimes."

Jan 1, 1995

By W. G. Hatch

Introduction In November, 1927, a paper was presented at the Annual Meeting of the British Columbia Division by H. A. Pearse(l), in which he described the milling practice at Britannia and set forth the metallurgical results which were being obtained at that time. In the intervening four years, various changes and additions have been made in equipment and practice, which have resulted in marked improvements in efficiency and costs. These changes and their effects are discussed in the present paper. During the past few years two major changes have been made in plant equipment. The first of these was the. elimination of an intermediate crushing stage by discarding two gyratory crushers in favour of two Symons cone crushers. The latter installation-now effects in one stage a greater reduction than was formerly accomplished in two, that is, by the gyratories together with a set of rolls. The second important change in equipment took place when the original M.S. flotation machines were replaced by six Forrester pneumatic machines, so that now the flotation department consists entirely of machines of this type. A number of minor changes and some further additions to equipment have also been effective in raising plant capacity and concentrate grade, while making noticeable reductions in tailing losses and costs of ore treatment.

Jan 1, 1932

By S. P. Lowe

Flotation testing of Flin Flon ore was started in the Denver laboratory of Complex Ores Recoveries Co. in March, 1926. There had been a considerable amount of flotation testing previously which had shown possibilities of success, and it was felt that, with the increased knowledge of flotation and the comparatively new reagents then available, flotation held out the best prospects for a successful commercial treatment of this ore. There remained available for this experimental work a small amount of the rejects from a thorough sampling of the mine and some ore from the mine dump.

Jan 1, 1930

By D. L. Koch, J. W. Tester, L. K. Sinclair

"In this study, hydraulic conductivity (K) geostatistics were used to predict residence time distribution of well-to-well flow. Flow profiles, fracture density measurements, and pumping tests were available from the highly fractured Florence Copper in situ leaching site. The flow profiles were used to establish the statistical distribution and spatial autocorrelation of K. Two tests were used for validation. The first test confirmed that fracture density and K are autocorrelated over similar length scales. In the second test, Monte Carlo flow simulations successfully recreated the results of pumping tests. Flow sim¬ulations were used to stochastically model well-to-well residence time distribution. RÉSUMÉ Dans cette étude, nous utilisons la géostatistique de la conductivité hydraulique (K) pour prévoir la distribution des temps de séjour (DTS) de l’écoulement entre les puits. Des profils de l’écoulement, des mesures de la densité des fractures et des essais de pompage existaient pour le site fortement fracturé de lixiviation in situ de Florence Copper. Les profils de l’écoulement ont permis d’établir la distribution statistique et l’autocorrélation spatiale de K. Deux essais ont servi à la validation ; le premier a confirmé que la densité des fractures et K sont autocorrélés sur des échelles de longueur similaires ; quant au second, des simulations d’écoulements de type Monte Carlo sont parvenues à reproduire les résultats des essais de pompage. Les simulations d’écoulement ont servi à établir un modèle stochastique de la DTS de l’écoulement entre les puits.INTRODUCTION In situ leaching is the circulation of a dilute acid or base solution in the subsurface, via a series of injection and recovery wells, to dissolve a target metal. In situ leach modelling requires forecasting the residence time distribution (RTD) of flow between wells. In fractured formations such as copper porphyry deposits, order-of-magnitude variations in hydraulic conductivity (K) can result in highly channeled flow, resulting in a heavy tailed RTD (Becker & Shapiro, 2003; Kang, Le Borgne, Dentz, Bour, & Juanes, 2015). Channeling through preferential pathways has impacted copper recovery at several past in situ leaching field tests (Cathles, Glenn, Lenzi, Nigrini, Deans, & Huff, 1978; Ahlness & Pojar, 1983; Schmidt, Earley, & Friedel, 1994; Sinclair & Thompson, 2015). The aim of this work is to combine multiple types of hydrogeological measurements to stochastically forecast the well-to-well RTD in fractured rock for the purposes of copper in situ leach modelling."

Jan 1, 2018

By J. E. Gill

"The name 'Canadian Shield' is used for a vast area; largely in northeastern; Canada; underlain by Precambrian rocks. The part in Canada has an area; of about 1; 790; 000 square miles. Extensions in Greenland; Labrador; Newfoundland; and the United States bring the total area to around 2; 800; 000; square miles. The boundaries of the Canadian part are shown in Fig. 1.; At its margins; the Precambrian rocks can be seen at many places to; extend beneath a cover of flat-lying Palxozoic or later sediments. Information; from borings in the Plains and natural exposures in mountain-built belts; show that similar rocks form a large part of the continental platform. The; Shield; therefore; is a large exposure of what may be regarded as the foundation; of the continent."

Jan 1, 1954

By K. A. Foxford, D. A. Polya, R. P. B. Hebblethwaite

"A variety of techniques for interpreting systems of mineralized echelon veins is discussed using examples from Panasqueira and SW England. As aids for exploration and mine planning, and as a tool for ore reserve evaluation, particular emphasis is placed upon establishing vein morphology in the third dimension, and upon understanding vein dilation and propagation histories. Special attention is also placed upon investigating vein thickness and spacing relationships, and upon understanding vein segmentation. The relevant data for these techniques are all readily obtainable from stope and core sources.The vein systems described were produced in host-rock sequences that underwent incremental dilation in response to fluid overpressures, and individual veins display evidence for mineral infilling synchronous with their propagation. Echelon vein geometries resemble those reported from igneous dikes and sills: vein walls are stepped and veins are divided into segments arranged in echelons. Changes in vein geometry, from arrays to composite structures, reflect both the evolution of the vein system with time, and the changes occurring between the margins (arrays) and core (composite structures) of the system. These characteristic morphologies can be used to infer vein propagation and fluid injection trends, proximity of neighboring veins, and the shape of the system as a whole. The techniques are applicable to systems of echelon veins produced under tensile conditions in rocks where faults were absent at the time of vein formation, and where subsequent deformation has been minimal. Further work is required to assess the application to echelon vein systems formed within more complex tectonic regimes."

Jan 1, 1995

By A. -M. Lafront

The corrosion resistance of die-cast and freely-solidified and electromagnetically-stirred thixocast AZ91D alloy has been studied using electrochemical noise technique in a 0.05M NaCI solution at pH 6.1 and 25°C. Specimens polished at different depths were immersed for a period of 75 min in order to assess the influence of the microstructure on corrosion kinetics and morphology. At depths between 10 and 50 µm (skin), all specimens showed general non-uniform corrosion with the lowest corrosion resistance. Between 100 and 200 µmn (interior skin), the observed corrosion was accompanied by superficial undefined pits due to metastable pitting. The corrosion form for 100-200 µm gave the best corrosion resistance. Stable pitting corrosion was observed beyond 400 µm deep on the bulk specimens. The skin of all thixocast specimens prepared billets showed a more corroded surface than that of die-cast. The interior skin as well as the bulk specimens showed better performance than that of the die-cast specimens.

Jan 1, 2007

By K. Soldenhoff, M. Fainerman-Melnikova

The use of strong base resins for uranium recovery is severely affected by the presence of chloride ions in solution. In areas where high-quality process water is not readily available, the use of saline water would extend the potential application for ion exchange in uranium processing. This study presents measurements of uranium uptake, using a wide range of commercially available weak base anionic exchangers, from solutions with chloride concentrations ranging from 2.5 to 22 g/L Cl. Out of 14 weak base anionic resins tested, 3 were identified that were not severely impacted by the presence of chloride and significantly outperformed a gel strong base resin typically used for uranium recovery in high-chloride environments. The uranium loading was sufficiently high for the consideration of development of the application of uranium recovery from uranium ores leached with seawater.

Jan 1, 2012

By F. K. McKean

Abstract A discussion of the difficulties involved in the production of a clean molybdenite concentrate introduces the paper. There is a brief description of the various methods for producing molybdenite that will fit marketing specifications, and it is shown how these methods are nor suited to the milling of ores containing small quantities of bismuth and copper. A process that was developed in the ore testing laboratories of the Bureau of Mines at Ottawa for the La Corne mill of the Molybdenite Corporation of Canada is described in derail and some results from pilot plant operation of this milling scheme are tabulated. A description of the La Corne mill, where the writer supervised the introduction of the process on a commercial scale, adds to the interest of the paper. In conclusion, there is a review of the conditions necessary for proper operation of the flowsheet. An attempt is made to show how the process might be satisfactory in other problems similar to that at the La Corne mill. Introduction The production of a molybdenite concentrate, free from impurities and high in grade, has been a difficult task when milling some types of ore. Whereas ordinary flotation techniques will produce acceptable concentrates of the baser sulphides, in many cases they will not serve in the treatment of molybdenite, for this mineral must be of optimum grade and purity to bring the best prices, or to find a market at all . Faced with the necessity of meeting stringent specifications, the mill operator has been forced to employ expensive processing methods, and to be satisfied with low recoveries, in order to make grade with his product. The most objectionable and common impurities found with molybdenite are: (a) gangue minerals and iron sulphides, which lower the grade; and (b) copper, bismuth, or antimony, which are deleterious in the final uses of the molybdenite products. It is difficult, and sometimes impossible, to market a concentrate with over 0.5 per cent of any of the latter impurities, or with a grade much below 90 per cent MoS2. Various methods, which have been highly successful in specific applications, have been developed to meet the problem of producing a suitable concentrate. All of them, however, have certain defects precluding their use when treating ores of a nature different from the one for which they ? were designed. The writer has developed a process for molybdenite ores having an objectionable impurity content. A description of the procedure involved, and of the La Corne mill of the Molybdenite Corporation of Canada, where the process has been adopted, should be of interest to flotation operators.

Jan 1, 1947

By T. Ivankina, T. Lokajícek, H. Kern, T. Svitek

The knowledge of 3D velocity distribution of P- and S-waves in rocks is very important parameter for interpretation and understanding the nature of seismic anisotropy observed in the earth’s crust and upper mantle. A new high-pressure measuring head was designed and constructed to enable ultrasonic sounding of spherical rock samples in 132 independent directions under up to 60 MPa of acting hydrostatic pressure by means of simultaneous longitudinal and transversal sounding. New measuring system enables ultrasonic sounding of spherical rock samples by using a pair of P-wave sensors and two pairs of perpendicularly polarized S-wave sensors (TV and TH) see Fig.1. Shear wave sensors polarization is oriented according to rotation axis of the sample. Special shear wave gel was used to transfer shear waves between the sample and sensors under acting hydrostatic pressure. An isotropic glass sphere was used to check and calibrate the new measuring setup. A spherical sample of a biotite gneiss from the Outokumpu scientific drill hole was used for testing measurement. There is shown that both, P- and S-wave velocities, can be measured simultaneously up to 70 MPa, respectively. We report data of the 3D velocity distribution of P- and Swaves measured for the first time on a sample sphere of biotite gneiss. We rely, in particular, on the directional dependence of compressional and shear wave propagation and their relationship to the crystallographic (CPO) and shape preferred orientation (SPO) of major rock-forming minerals. The 3D seismic measurements revealed a strong foliation-related directional dependence (anisotropy) of P- and Swave velocities. Ultrasonic measurements were compared with 3D velocity calculations based on neutron diffraction measurements of crystallographic preferred orientation (CPO) of major minerals. Comparison of 3-D velocity distribution (P, S1, S2 and S1-S2) determined by two completely different methods ultrasonic sounding and neutron diffraction is presented. Measurements showed that the intrinsic bulk anisotropy is basically caused by the CPO of biotite constituting about 23 vol.% of the rock.

Jan 1, 2015

By J. Lu, D. G. Ivey, H. Henein

Microalloyed steels are widely used in the oil and gas industry. They are a class of high strength, low carbon steels containing small additions of niobium (Nb), titanium (Ti), molybdenum (Mo) and/or vanadium (V). These steels have good strength, toughness and excellent weldability, which are attributed in part to the presence of nano-sized carbides, nitrides and carbonitrides. In the pursuit of developing higher strength microalloyed steels, it is of great interest to quantify the size, distribution, volume fraction and chemical speciation of these precipitates. However, characterization techniques suitable for quantifying fine precipitates are limited. Possible characterization techniques include SEM, TEM and matrix dissolution. A comparison is presented of the various techniques.

Jan 1, 2005

By H. Marquis

This paper is concerned with an analysis of a number of failures of large-size, hypervelocity light gas gun chambers and barrels. A brief description of the light gas gun principle and of the various types of guns is first given. The failures and the investigations carried out are then described in detail, with the failures divided into two groups. The first group comprises those failures caused by certain conditions to which the guns may be submitted, and includes, for example, severe local heating of the bore surface causing hardening and cracking of the steel. These conditions were accidental and steps were taken to prevent them. The remaining failures were due to faults in the material or in the heat-treatment, manufacturing or assembling procedures. Specific problems, such as hydrogen embrittlement, and the use of high strength gun barrels above their ductile-brittle transition temperature by preheating prior to firing, are briefly considered. Some interesting observations are also presented on the use of surface markings, and angles of fracture of large fragments, as an

Jan 1, 1962

By M. Zamalloa, P. J. Mackey, P. Coursol, Y. Prévost

"Over the last decade or so, the availability of commercial thermodynamic modelling packages, such as FactSageTM, have been utilized to help the plant optimize slag chemistry and to minimize slag handling issues that can arise, such as those due to a process upset, for example, by undue feed variability. This paper illustrates an extension of the application of this software in examining a large range of NCV operating parameters, such as the %Fe/SiO2 ratio in the slag and the level of minor gangue components in the slag including CaO, Al2O3, ZnO, MgO, and PbO. The conditions influencing the slag liquidus range of NCV slag are discussed with respect to the overall process chemistry.Given that a sufficiently low %Fe/SiO2 ratio is used in NCV slag, most components such as CaO-ZnOPbO- Al2O3-MgO, in small concentration, all contribute to lowering the NCV slag liquidus. Considering the present level of these minor components, the NCV can operate consistently at 1200°C if the %Fe/SiO2 is between 0.6 and 0.8 in the slag. Using the type of phase diagrams presented in this paper, it is possible to develop different Noranda reactor/Noranda converter operating strategies adapted to the feedstocks available at Xstrata mines/plants or from other sources. The NCV is unique in that a fayalite-based slag is employed for high-efficiency continuous converting with excellent operating results."

Jan 1, 2007

By Da-Qiang Cang, Qingde Wang, Wei Wang, Wen-Bin Dai, Min Guo, Yu Li

Utilization of both slag and its heat for hot slag is a great challenge for iron and steel industry. Many methods of hot slag modification for directly converting hot slag into value-added materials were researched in recent years, and waste heat of hot slag could thereby be transformed into inner energy or chemical energy of the materials. In this paper, an experiment of converting hot slag directly into glass ceramics by hot slag modification method was conducted. A cooled modifiers mainly composed of fly ash were firstly heated though a cyclone furnace and then fell into a molten bath to mix with hot steel slag. Half of hot slag was used as raw materials and accordingly about half energy consumption, about 5MJ/kg for melting raw materials was saved in the process compared with that of traditional producing method. Frit quenched from the modified hot slag had a higher basicity of 0.6-0.7 than traditional frits in order to reduce the needed amount of cold modifiers and accordingly utilize more hot slag and its waste heat. Glass ceramics were further prepared from the frit and a heat treatment of one-stage method is more suiter to such frit than that of two-stage method. The glass-ceramics with basicity of 0.6 and heat-treated by one stage method had the best performance with bending strength of 146.46 MPa, Vickers hardness of 6.79 GPa, water absorption rate of below 2% and shrinkage rate of around 10%.

Jan 1, 2015

By Dorothy Walters

As an increase in the number of producers alters fact ors affecting supply, long-term prospects in traditional markets for many minerals weaken. At the same time, conflicts between national and international objectives undermine existing competitive elements in mineral markets and Canadian costs escalate. Such changes may dramatically alter the environment in which the mining industry operates.

Jan 1, 1979

By Mahmood Alemrajabi, Ake Rasmuson, Kerstin Forsberg, Kivanc Korkmaz

"In the present study, the recovery of rare earth elements (REE) in the nitrophosphate process of fertilizer production is investigated. The apatite has been recovered from iron ore tailings by flotation. After digestion of apatite in concentrated nitric acid, Ca(NO3)2.4H2O is first separated by cooling crystallization and then the REEs are recovered by precipitation. Optimum conditions in these steps have been determined in a previous study. The precipitate mainly consists of CaHPO4.2H2O and REE phosphates.In the present study, selective dissolution and re-precipitation have been studied in order to obtain a precipitate that is more concentrated in REEs. The precipitate was selectively dissolved in nitric and phosphoric acid at different acidities (pH 6 to 0) with the liquid /solid ratio of 100 mL/g. It is shown that most of the CaHPO4.2H2O and other calcium containing compounds will be dissolved at pH 2 while the REE phosphates are not dissolved above a pH of approximately 2. Thus, by partial dissolution of the REE precipitate at pH 2.5 most of the solid calcium phosphates will be dissolved and the remaining solid phase, which is more concentrated in REEs, can be filtered off as a fairly concentrated REE solid mass and the liquor can be recycled back to recover more P nutrients. Alternatively, the REE enriched precipitate was dissolved completely in nitric acid and re-precipitated again by addition of ammonium hydroxide to pH 1.2. A chemical equilibrium software, MEDUSA (Puigdomenech, 2013) has been used to evaluate the experimental results and to estimate the optimum conditions for selectively dissolving the precipitate."

Jan 1, 2016

By R. L. Bruening, N. E. Izatt, S. R. Izatt

The need for selective metal separations has increased as the mining industry encounters more complex ore bodies and demand for higher performance end products expands. The Molecular Recognition Technology (MRT) process uses highly selective SuperLig® resins to remove desired metals from a variety of solutions in the mining and metals processing and recovery industries. MRT separation processes efficiently produce high purity metal products. In this paper, applications of MRT to metal recovery at mg/L to multiple g/L concentration levels are presented and discussed. Specific examples in the precious metal, nickel, cobalt, zinc, copper, and rare earth industries are given.

Jan 1, 2014