Convert Hot Slag Directly Into Glass-Ceramics by Hot Slag Modification Process

Utilization of both slag and its heat for hot slag is a great challenge for iron and steel industry. Many methods of hot slag modification for directly converting hot slag into value-added materials were researched in recent years, and waste heat of hot slag could thereby be transformed into inner energy or chemical energy of the materials. In this paper, an experiment of converting hot slag directly into glass ceramics by hot slag modification method was conducted. A cooled modifiers mainly composed of fly ash were firstly heated though a cyclone furnace and then fell into a molten bath to mix with hot steel slag. Half of hot slag was used as raw materials and accordingly about half energy consumption, about 5MJ/kg for melting raw materials was saved in the process compared with that of traditional producing method. Frit quenched from the modified hot slag had a higher basicity of 0.6-0.7 than traditional frits in order to reduce the needed amount of cold modifiers and accordingly utilize more hot slag and its waste heat. Glass ceramics were further prepared from the frit and a heat treatment of one-stage method is more suiter to such frit than that of two-stage method. The glass-ceramics with basicity of 0.6 and heat-treated by one stage method had the best performance with bending strength of 146.46 MPa, Vickers hardness of 6.79 GPa, water absorption rate of below 2% and shrinkage rate of around 10%.