Search Documents

By Y. Q. Li, X. H. Long

In this work, structural and electronic properties of smithsonite (ZnCO3) and cerussite (PbCO3) as the typical lead-zinc oxide minerals is simulated by means of DFT. The calculated results could be concluded as: (1) The density of states (DOS) of Zn atom in ZnCO3 is nearer to the Fermi level than that of Pb atom in PbCO3, suggesting that the Zn atom of ZnCO3 is more active and easier to interact with water molecules and hydroxyl ions. Smithsonite, therefore, could be more readily depressed in the flotation process. (2) The bond population value of Zn-O (0.23) and C-O (0.92) in ZnCO3 is obviously larger than that of Pb-O (-0.01) and C-O (0.85) in PbCO3, indicating that the covalent characteristic of ZnCO3 is stronger than that of PbCO3. (3) It is shown that the charge of Pb (+1.32e) in PbCO3 is more positive than that of Zn (+1.22e) in ZnCO3, suggesting that cerussite is easier to interacting with HS- compared with smithsonite in the flotation process. In summary, the structural and electronic property of smithsonite is completely different with cerussite, leading to the difference of their flotation behaviour.

Jan 1, 2015

By Q. Han

A modified cast-on method has been developed to reinforce aluminum castings with steel insert. Defect-free bond between the steel insert and the aluminum casting has been consistently obtained. Data obtained from a push-out experiment indicated that the bond strength was much higher than that obtained using the Al-Fin approach. This paper introduces this modified method in four sections: the coating of the steel pins, the cast-in method, microstructure characterization, and the bond strength. The section on the coating of the steel pins contains coating material selection, electro-plating technique for plating Cu and Ni on steel, and diffusion bonding of the coatings to the steel. The section on cast-in method deals with factors that affecting the quality of the metallurgical bond between the coated steel and the aluminum castings. The results of microstructure characteristics of the bonding are presented in the microstructure characterization section. A push-out experiment and the results obtained using this method is described in the section of bond strength/mechanical property.

Jan 1, 2015

By Barbara Kirby

Mining Industry Human Resource Council Who we are: National Sector Council for the Minerals and Metals Sector 18-person Board of Directors Over 100 Industry Volunteers PPP - Funded by HRSDC and industry What we do: Identify national HR challenges and opportunities for the Canadian mining industry Create national solutions through collaboration, partnerships and Synergy

Oct 1, 2010

By D. C. Rance

"The Quintette Coal Limited property is located in the north east coal area of British Columbia. A basic agreement with the Japanese steel industry was ex ecuted on January 27, 1981 for the sale of 69.5 million tonnes of Quintette metallurgical coal over a 14.5-year period. This contract period can be extended by Jive years by mutual agree ment. Sale agreements have also been signed for the sale of 19.4 million tonnes of oxidized coal over a 15-year period. Work started on site development in the late summer of 1981, and at present, two of the four eventual pits-the McConkey and Frame-are under development. The pits are currently in a pres/ripping phase. These pits are notable for the stripping volumes that have to be removed from relatively small pit areas. in order to provide for the required detailed rapid short-range planning of these pits, engineering will be computerized, as will the truck dispatch system. The mining area lies 21.1 km from the plant site by road and the transport of raw coal LO the plant is by means of a highspeed conveyor system which has a total length of 13.4 km with a vertical drop of 740 m. The surface plant facility was designed on a modularized basis to facilitate maintenance, and is designed to enable the use ofgravity flow ofraw coal and heavy media in the plant to minimize the use of pumps. The construction of the plant and mine site facilities is on-going, and the first coal production is scheduled for early December 1983. Introduction Quintette Coal Limited is a Canadian company incorporated in the province of British Columbia in 1971. Denison Mines Limited is the manager of Quintette's activities. Equity in Quintette Coal Limited is held by several shareholders, with interests as follows: Denison Mines 'Limited, 500Jo; Charbonnages de France International S.A., 120Jo; and Japanese interest, 38%. The project will develop almost 120 million tonnes of coal for marketing during its first 20 years of production. All of the planned production tonnage has been committed to Japanese markets. Most of the coal will be metallurgical grade, and the remainder will be a high-quality thermal coal. The Mcconkey and Frame pits, which will initially provide the mine's production, will commence production in early December 1983 and will, in 1985, reach the full annual production of 5 million tonnes clean metallurgical coal and 1,380,000 tonnes of clean thermal coal."

Jan 1, 1985

By D. B. Dreisinger, M. Rasouli

"Developing technology to address the environmental hazards associated with selenium in mine-impacted waters has been a serious challenge. Ion exchange (IX) has been identified as a potential treatment technology. This paper begins with a review on selenium adsorption with commercially-available basic anionic exchangers (BAS). It then looks at the use of resins for selenium removal via modification with the addition of -O, -N, or -S-containing chelating ligands and chelating polymeric ion exchangers pre-loaded with immobilized metal cations. The synthesis of chelating exchangers requires a final product with a highly stable metal in the ligand-metal complex. The nature, oxidation state, size, and affinity of the metal for the target oxyanions and the size, degree of protonation and space configuration of the oxyanion are among critical factors affecting the oxyanion uptake. There is a limited number of studies on the critical parameters affecting the selenium affinity for chelating exchangers. Such a study could fill in the gaps of our understanding of selenium-metal-chelating ligand interactions and assist in developing a new ion exchanger. In addition to commercial IX resins, layered double hydroxide materials (LDH) have received attention for oxyanion removal from waste water. The adsorption capacity of the LDHs are affected by the crystallinity of LDH, the nature of metal components, the ratio of metals, charge and type of anion, and the space between the layers. In particular, the Friedel phase (FP), a member of the LDH family, showed high adsorption capacity for selenate removal from synthetic solution. A study is currently underway at the University of British Columbia to investigate the effect of different synthesis methods and aging on the suitability of FP for selenium removal from mine waste water."

Jan 1, 2017

By F. Baczek, S. S. Rocks, D. Chaiko, C. Eyzaguirre, S. Asihene, T. Walters

The majority of efforts to improve primary copper sulfide leaching have focused on solution chemistry, temperature, O2 pressure, ultra-fine grinding, the use of catalysts, etc. Historically, very few studies have focused on the solid/solution interface. A new, patent pending approach to catalyzed, copper sulfide leaching has been discovered by FLSmidth that enables manipulation of the 2-D semi-conductor properties of chalcopyrite surfaces to the benefit of higher electrochemical reactivity. Copper dissolution rates are then further accelerated by incorporating a Stirred Media Reactor (SMRt) into the process. By using minute amounts of Cu2+ to "pre-activate" chalcopyrite, leach times have been reduced from >20 hours with incomplete Cu dissolution to <2 hours with 98+% Cu dissolution at 80°C. The pre-activation process takes only minutes to complete at temperatures of 80°C or less. The total atmospheric leaching process, incorporating the pre-activation and Stirred Media Reactor is compatible with existing SX/EW processes. Results of batch leach testing are presented and possible mechanisms are discussed.

Jan 1, 2015

By E. Sharifi, B. Komishke, R. Heffel, D. Schwartz

"The oil sands resources in Canada are one of the world’s largest hydrocarbon deposits. Processing of oil sands uses hot water to extract bitumen. The process generates tailings slurry that must be settled for final deposition. The tailings contain fine material, with poor water release characteristics which makes water recovery challenging. Polymer flocculants are added to assist in settling and dewatering the fine tailings. The amount of polymer addition is dependent on tailings characteristics, including the particle size distribution (PSD). If the PSD of the tailings is unknown, an excess amount of polymer needs to be added in the dewatering stage to flocculate the particles. Over flocculation also has a detrimental effect on the water release characteristics. Measuring the particle size distribution using an on-line analyzer could have major benefits over common laboratory methods as it provides online and fast insight into the process enabling the operators to implement required changes to minimize the reagent consumption, while achieving optimal flocculation. Online measurement of PSD using laser diffraction has long been used in base metals beneficiation processes. A series of test work using Outotec PSI500® particle size analyzer on oil sands samples from different operations have been conducted. Tests were performed by recirculating the slurry in closed circuit to simulate real plant conditions. This paper presents a summary of the results.INTRODUCTION Canada’s oil sands are the third largest reserves of crude oil in the world, with an estimated 165.4 billion barrels of recoverable oil (Government of Alberta 2016). Oil sands are a mixture of sand, water, clay and bitumen. Bitumen is a form of oil that is too heavy or thick to flow or be pumped without being diluted or heated. About 20% of bitumen reserves are close enough to surface to be mined. In mining methods, oil sand is transported from an open pit mine to the processing plant and bitumen is separated from solids and water. The separation process involves ore preparation, such as addition of hot water, steam and caustic (NaOH), followed by gravity separation and froth treatment (Masliyah et al. 2004). A general scheme of the extraction process is presented in Figure 1."

Jan 1, 2018

By B. van Beek, T. Goff, P. Gebski, P. Szyplinski, W. L. Ying

"Monitoring the refractory lining integrity is essential to assure the safety of the operators and to determine the remaining campaign life of a furnace. Early detection of refractory lining degradation is essential to avoid sudden furnace failures and prevent unscheduled shutdowns. In the mid-1990s a stress wave propagation technique was developed and since then it has been utilized by Hatch Non-Destructive Testing (NDT) Group to evaluate furnace linings. For the last 17 years the AU-E technique evolved in terms of hardware, software and signal acquisition and interpretation. Most importantly, based on more than a decade of commercial applications, an extensive database of various failure modes, refractory deterioration trends and material properties has been created. This knowledge base is an integral part of AU-E which progressed from a NDT technique towards a comprehensive approach for furnace condition monitoring. All of the improvements introduced over the last several years have greatly improved the accuracy of the measurements. The data analysis process has also become more time efficient making the critical results available to the furnace operators in a more timely manner. Today the AU-E technology is used on a variety of process vessels in non-ferrous, glass, chemical and iron and steel industries.In this paper we are reviewing the available techniques for furnace refractory lining measurement and discussing the pros and cons of each method. The need for continuous improvement and development of new techniques for refractory monitoring is also emphasized. Finally, we are presenting a number of case studies and comparisons between the physical verifications and the AU-E measurements."

Jan 1, 2015

By W. van der Merwe

With the gold industry looking to process more complex ores, the online measurement and control of cyanide addition to the gold leaching circuit has become more crucial. This paper compares the two commonly employed "free" cyanide online analysis methods (amperometric and potentiometric end-point silver nitrate titration) with the common site laboratory rhodanine endpoint silver nitrate titration and ion selective electrode methods. Measurement differences between these methods are presented and discussed for cyanide solutions containing copper and zinc with varying cyanide to metal ion ratios. The resulting cyanide available to leach gold is also compared with these measurements.

Jan 1, 2011

By G. L. Zhu, Y. F. Wu, H. Nagaumi

A novel eutectic-type alloy Al12Si-HTC with high thermal conductivity has been developed by strict chemical composition control and heat treatment. The thermal conductivity of the alloy is about 30 % higher than that of current commercial Al12Si alloy. The Al12Si-HTC alloy has a silicon content of 10~12 wt.%, which provides excellent castability. Trace element strontium or calcium is added to modify eutectic silicon, and contents of transition elements such as copper, manganese are controlled in a low level. By appropriate heat treatment, thermal conductivity of the castings increases by 7.5 % and finally reaches 172 W/(m·K). It is found that eutectic silicon modification which makes average particle size finer than 2µm plays a dominant role in improving thermal conductivity, as well as further spheroidization of eutectic silicon and reduction of lattice defects in a-Al microstructure in subsequent heat treatment process. The alloy is successfully applied to produce a certain communication enclosure with complex finned structure by die casting process in industrial scale. The results of numerical simulation and thermal analysis experiments show that when manufactured by Al12Si-HTC alloy, the surface temperature of chips in the enclosure is reduced by 2.0~4.5 ? and the temperature distribution is more homogeneous compared with traditional Al12Si alloy.

Jan 1, 2015

By E. C. Sanford

A laboratory-scale batch extraction unit and operating procedure for studying the hot-water separation of bitumen from Athabasca tar sands are described. The extractor evolved from earlier units and has been in use by Syncrude Research for the past 10 years. By using a unit such as this, it is possible to study tar sand feed quality and the effects of chemicals on the hot-water extraction process, while process variables are held constant. Data are presented to demonstrate the importance of surfactants to the process and the interrelated role of inorganic bases and surfactants.

Jan 1, 1979

By Al Goodier

"This paper discusses the experience of Noranda Mines Limited, Matagami Division, with the vertical crater retreat (VCR) method in the mining of narrow-vein stopes. Although limited to only one stope, the viability of this method at the Radiore No.2 Mine has proven that further use of VCR in narrow-vein mining will be made.IntroductionThe Radiore No.2 property is located east of the Bell River in the southeast quadrant of Isle-Dieu Township, approximately 4.5 km east of the town of Matagami. The new James Bay Highway is 2.5 km north of the property and access to the mine is by a 2.5-km logging road.The property was staked by Radiore Uranium Mines in March 1961 and the sulphide body was first indicated by an E.M. survey. Diamond drilling commenced in the fall of 1961 and was completed by the end of 1962. As per an agreement in 1970, the claims were sold and assigned to Orchan Mines Limited. Subsequently, the property was transferred to Bell Allard Mines Limited, a wholly owned subsidiary of Orchan Mines. Early in 1979, Noranda Mines Limited acquired the property and it is now part of Noranda&apos;s Matagami Division.Geology and MineralizationThe deposit is in a band of volcanic rocks north of the Bell River complex. The lens of massive sulphides dips almost vertically and strikes almost east-west. The north contact is essentially sharp against andesite material; the south contact is less well defined, as the massive sulphides tend to grade into more disseminated material.The orebody varies from 5 to 20 feet in width, by 350 feet long and 200 feet in height. The overburden is composed of sand, gravel and clay, varying from 0 to 26 feet in depth. The ore reserves were 153,340 tons grading 1.97% copper and 1.01% zinc including 10% of dilution at zero grade."

Jan 1, 1982

By R. B. Allen, B. S. W. Buffam

"The property of Chesterville Mines, Limited, is in McGarry township, Timiskaming district, Ontario, about 25 miles east of Kirkland Lake. It consists of a group of fifteen claims that extend northeast from the KerrAddison mine for a distance of 2 miles.In June, 1906, two groups of prospectors left the town of Chesterville, Ontario, to prospect in northern Ontario. Silver had been discovered 3 years before at Cobalt and the large profits of this young mining camp were the principal incentive to extending the field of exploration northward. One group consisted of Dr. Reddick, Edward Flynn, John Hummel, William Knott, and Colin Cameron. The other group comprised J. T. Kearns, Herman Hummel, W. G. Barkley, and J. Elliott.The two groups travelled north by train to Haileybury and thence to Larder lake by canoe. Camps were pitched on the northeast arm of the lake, and within a short time a discovery was made by Edward Flynn of the first party, who found gold on the property now owned by Kerr-Addison Gold Mines, Limited. Herman Hummel and J. T. Kearns shortly afterwards made the second discovery, on what is now the Chesterville property. These discoveries, made some years prior to those at Porcupine and Kirkland Lake, are believed to be the first in that part of northern Ontario.The Hummel-Kearns claims were incorporated in the following year under the name of Chesterville Larder Lake Gold Mining Company, Limited. It was not, however, until 30 years later, in 1936, following the increased premium on gold, that sufficient capital was placed in the treasury of the Company to carry out an extensive diamond drilling programme. This exploratory drilling was started early in 1937 under the direction of Leo. J. Kearns, and a large body of ore was intersected in the first drill hole. Underground work was started in 1938, a mill was built, and the first gold brick was poured on July 29th, 1939."

Jan 1, 1954

By A. Mosqueda Martinez, L. C. Trytten, R. P. Kofluk, J. J. Budac

The Corefco ammonia leach nickel refinery treats Ni-Co mixed sulphides from the high-pressure acid leaching of Moa Bay nickel laterite. Due to the low iron content of the feed, the ammonia leach process generates a leach residue with ~10% Ni+Co. Since commissioning a leach residue pressure filtration circuit in 2002, this residue has been stockpiled, dried, and sold commercially. For several years, the residue was sold to nickel smelters overseas. In 2014, re-processing of the residue in the high-pressure acid leach was tested. Lab test work was completed showing excellent extraction of the contained nickel and cobalt, and additional beneficial effects in the high-pressure acid leach circuit. A plant test in Moa confirmed the results, and preparation for shipment of the valuable leach residue for re-processing has begun. This paper outlines the test work and results, and some commercial considerations.

Jan 1, 2015

Despite the claims of energy efficiency and the considerable development that has gone into dramatically extending rolls? life and facilitating rolls? change-out, in the six years since the last SAG conference, only a few HPGR operations have entered the realm of mineral processing. Risk barriers to the take-up of new equipment or processes are: a massive increase in materials handling issues as well as in the number of pieces of equipment required, low total circuit potential energy savings, and similar or higher capital costs. An alternative route is to make use of the complementary strengths of the HPGR and SAG in hybrid circuits. Minimising materials handling issues, providing an ideal balanced feed to the AG or SAG mill, and improving controllability through shifting grinding load as the RoM feed changes, are all potential major advantages to this approach. Conceptual circuit layouts, based on real measured ore and equipment data, are presented here to illustrate the potential production upside, the reduction in operating costs and the reduction in the physical and energy footprints.

Jan 1, 2012

By A. Koster, V. Maurel, S. Dezecot, Szmytka. F.

The aim of this work is to clarify the role of microstructure heterogeneity in the initiation and growth of cracks in a lost foam cast A319 for low cycle fatigue (LCF) loading condition. Because 2D analysis fail to establish the scenario of damage events, this study is based on 3D in situ analysis using synchrotron X-ray tomography during LCF test performed at 200°C. If X-ray tomography is now an established technique to study damage development in 3D, its application for relatively high temperature cyclic tests has never been done so far. Initial 3D observations of damage show that the cracks that lead to fracture initiate near large pores and propagate into the hard particles 3D network of the eutectic regions.

Jan 1, 2015

By C. Blawert

The corrosion properties of the skin and the bulk of semi-solid processed and high pressure die cast AZ91 alloy were studied in 5% NaCI solution by (a) analysing the corrosion morphology, (b) measuring electrochemical polarization curves, (c) performing electrochemical impedance spectroscopic measurements, and (d) immersion tests at constant pH-values. Using XRD, LM, SEM and EDX to evaluate the microstructure of skin and bulk specimens, the corrosion results were related to the microstructures of the particular alloys. However, microstructure and corrosion performance were found to be similar for both production processes, and only slight but distinct differences were found. Generally, the skin corrosion properties are inferior to those of the bulk, with the exception of the high pressure die cast AZ91 alloy, where the finer microstructure of the skin layer exhibits a better performance as showed by impedance studies and confirmed in long term immersion tests.

Jan 1, 2004

By A. P. Paiva

The solvent extraction properties exhibited by some /V,N&apos;-tetrasubstituted malonamides to efficiently and selectively recover iron(III) from concentrated chloride leaching solutions can be found in the recent literature. The iron(III) extractive chemistry exhibited by some of these derivatives is revisited, in order to compare their chemistry with that shown by a few of the new malonamide compounds. The generally good extraction efficiency towards Fe(III), from >4 M hydrochloric acid solutions, and the relative ease of Fe(III) stripping by distilled water are remarkable findings that are confirmed for the malonamide derivatives described in this work. Furthermore, additional data regarding their selectivity towards Fe(III) extraction over several base metal ions and their behavior when subjected to successive Fe(III) extraction-stripping tests are also presented and discussed.

Jan 1, 2006

By G. Chahal, L. C. So, S. Faucher, S. Mostaghel, S. -Y. Oh, S. K. Lee

Slag dumping and water granulation are the most commonly used slag treatment methods in the metallurgical industries. In both processes, water is present (by desire for cooling and dispersion or as a result of rain accumulation) and thus equipment and operations are designed to minimize and mitigate the risk of steam explosions resulting from the inappropriate contact of slag with water. Slag handling practices have, therefore, never been inherently safe; even good design, operation, and maintenance are not sufficient to prevent explosions or other related injuries from occurring. For slag handling to become inherently safe, our industry must eliminate the potential contact of water with molten slag. This is today feasible with the advent of dry granulation technologies, a review of which is presented, and it thus falls to us, in the metallurgical sector, to lead the way in their final stages of development and adoption. Furthermore, while slag dumping and water granulation offer some metallurgists the means of valorizing their slag as a by-product, for most, this is not the case. The energy in slag is lost through dumping and water granulation processes, and where slag is sold as a by-product, it is for its chemical content only. Here, dry granulation processes also offer advantages including the production of by-products which hold value in both their chemical content and physical properties and heat recovery. Dry granulation, therefore, augments the methods by which slag may be valorized over traditional processing methods.

Jan 1, 2015

By A. E. McIlhinney, I. E. Puddington, C. E. Capes, A. F. Sirianni

"Two main problems are associated with the removal of pyritic sulphur from coals. The first is due to the fine state of dissemination of pyrite, which requires grindin1 to a very fine size to accomplish liberation. The second problem is caused by the similar surface chemical characteristics of coal and pyrite, which complicates separatio11 methods based on this property. In the work described here, the problem of fine particle size was overcome by using the selective oil agglomeratioa method developed at the National Research Council of Canada. Recovery of more than 90% of the combustible values was possible, even with particles only a few microns in diameter. Experiments using conventional chemical depressants for pyrite met with little success. It was found, however, that pyrite may be rejected during coal agglomeration through treatment with the iron.oxidizing bacteria, thiobacillus-ferrooxidans. The conditions for maximum pyrite separation are described and possible mechanisms by which the bacteria act are discussed."

Jan 1, 1973