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By R. Khanna, M. Dubikova

A variety of carbonaceous reducing materials are being used for the production of ferroalloys. Reductant materials include not just carbons such as coke, coal, char but also bio-carbons in form of charcoal produced from different types of wood. This paper discusses critical properties and reactions of carbonaceous materials and their significance in dictating reductant performance. Main considerations include among others, gasification of reductant, dissolution of carbon into molten metal, and direct reduction of slag by solid carbon. These are discussed in relation to material properties such as structural order, mineral matter content, composition, physical characteristics etc. A brief review of both conventional and novel approaches towards characterisation of carbonaceous materials has been included. Due to complexity and heterogeneity of carbonaceous reducing materials and a wide range of process requirements, the selection of the most appropriate reducing agent will depend on a number of considerations such as the availability of raw material and associated costs, product and process requirements and environmental aspects of waste gas emissions.

Jan 1, 2004

By John C. Machisak

THIS CHAPTER of the Minerals Yearbook (Volume III) contains overall injury experience for coal mines, both anthracite and bituminous, coke plants, petroleum and natural gas, peat, and asphalt and related bitumens (native); metal mines, their metallurgical plants, including ore-dressing plants and primary nonferrous reduction plants and refineries; nonmetal mines; nonmetal mills; sand and gravel operations; slag (iron blast-furnace) plaints; and stone quarries and their related pants. Volume I of the yearbook contains a chapter showing injury experience and employment data treated separately by metal mines, nonmetal mines, quarries and their related plants, metallurgical plants (ore-dressing plants and primary nonferrous reduction plants and refineries are shown separately), nonmetal mills, sand and gravel plants, and iron blast-furnace slag plants. Volume II contains injury and employment experience in the fuel industries (coal, coke, petroleum and natural gas, asphalt and related bitumens (native), and peat. Injury and employment data are submitted voluntarily for the mineral operations through an industry canvass made by the Bureau of Mines, except for the coal industry, whose reports are mandatory. Information published in this chapter is the result of this canvass. Figures presented in this chapter for 1961 are preliminary except for anthracite, peat, coke, petroleum and natural gas, asphalt and related bitumens, and slag. These preliminary data, with the exception of bituminous coal, are a summation of reports received by May 31, 1962, from the operators showing their injury and employment experience. Estimations of injury and employment experience are not included in these preliminary data.

Jan 1, 1962

This Bureau of Mines publication presents an overview of mine electrical power systems research currently being conducted by the Bureau. The papers, given at a Technology Transfer Seminar, emphasize the increasing importance of research related to the safety considerations of underground coal mine electrical systems. Selected topics are included that summarize results of research in the areas of electrical shock prevention, explosion-proof enclosures and load centers, discriminating circuit breakers, and trailing cables. Other topics discussed at the seminar are published as separate sections of the Bureau of Mines Hand- book "Application Notes--Mine Electrical Power Systems."

Jan 1, 1982

There are many ways to classify structural slurry wall elements, but the DFI committee chooses to limit these descriptions to three functional requirements, namely: design function, plan configuration and type of panel reinforcement. (See Figure 1 in Part IV for panel classification). Slurry walls can function as: 1. Curvilinear or linear elements for temporary and/or permanent structures to resist lateral forces transferred from the ground, water, earthquakes and various surcharge loads. 2. Load bearing elements in various plan shapes to resist vertical forces. 3. Combination Elements to resist combined forces under conditions 1 and/or 2. For example, elliptical shafts with various openings for tunnels and conduits have been commonly used for deep excavations.

Jan 1, 2005

By D. Grabowski, Z. Pokryszka

A study carried out in the iron basin of Lorraine (North-East of France) highlighted the existence of under-oxygenated and noxious gas emissions (carbon dioxide, radon…) in vast built-up areas related to former mine workings. Site investigations showed that the gas flow was mainly due to natural thermal air circulation between old mines and external atmosphere. The main hazards associated with this flow of gas and its potential accumulation in confined volumes in buildings are asphyxiation and intoxication. A further study is in progress in order to better understand the origin of the gas generation within the old iron mine workings. Following the first hypothesis, the carbon dioxide emission is mainly due to the specific hydro-geo-chemical process associating the pyrite oxidation with the acid dissolution of carbonates. KEY-WORDS : gas, emission, iron mine, pyrite.

Jan 1, 2003

The extraction and processing of minerals from surface mines and quarries can produce significant fugitive emissions as a result of site activities such as blasting, unpaved road haulage, loading, primary crushing and stockpiling. Uncontrolled fugitive dust emissions can present serious environmental, health, safety and operational issues impacting both site personnel and the wider community. Simulation technology is finding increasing use for the purposes of advanced warning of potential problem emissions in addition to providing a basis for future planning applications where demonstrable compliance with regulatory requirements are necessary. The initial re-entrainment and subsequent dispersion of fugitive dust presents a process complicated by the combination of the in pit topography, the surrounding natural topography and the dynamic nature of emissions from these sites. These factors impact upon the accuracy and reliability of the conventional Gaussian plume based computational prediction methods employed for regulatory compliance and IPPC applications. This paper proposes that optimal modelling of open pit emissions may be more accurately achieved by the use of a multi-scale predictive modelling approach utilizing computational fluid dynamics (CFD) methods for high resolution near source dispersion and conventional Gaussian based methods for far field dispersion modeling. This paper presents a numerical based flow and dispersion analysis of a typical UK based open pit utilizing CFD in conjunction with a conventional Gaussian plume based methods. Typical operating emissions and meteorological conditions are obtained from long term data records collected at a large operating quarry extraction operation in the UK. Emissions are modelled using a Lagrangian framework within conventional atmospheric boundary layer (ABL) profiles expressed as functions of turbulence and velocity parameters under assumed neutral conditions. Results are presented in terms of the impact of site topography on in pit retention as compared to the Gaussian based method.

Jan 1, 2009

By R. H. T. Garnett

N.B. This paper provoked much (positive!) discussion in later issues, with responses from the author (and thanks also for the many private contributions he had received) - see under Garnett R.H.T. Expanded version of a paper originally presented at the Alluvial mining conference, London, 11-13 November 1991 and published in Alluvial mining, Barking: Elsevier Applied Science for IMM, 1991, p.115-156. The usual measure of performance in gold and tin dredging is the R/E factor. It compares actual production or recovered grade for a given period with that estimated from the original sampling. The factor is a multiple of four component factors, each ideally approaching 1.00. The factors are concerned with estimation, selection, excavation and treatment. The estimation factor reflects the errors involved in determining the grade and depth of single drill-holes or pits. An optimum selection factor is achieved by a higher drilling density. The excavation factor is affected by failure of the dredge to excavate the total volume contained within its course. The required dredge throughput rate influences not only the success in digging recovery but also the treatment factor. No two alluvial deposits are the same, but, in general, the greatest divergence from 1.00 is invariably demonstrated by the estimation factor. A major divergence in one of the other factors may also be the cause of the R/E factor being significantly different from 1.00. The component factors are examined in detail and historical trends in R/E factors are discussed

Sep 1, 1991

Mineral formations, accumulated during technogenic activities greatly influence an economic and ecological situation in the Kola North. On the one hand, the dumps from extraction of mineral resources, tailing ponds of beneficating plants, ash dumps, wastes of metallurgical and mechanical engineering productions destroy the regionÆs environment and require taking certain measures and costs to bury or protect from weathering, oxidation, etc. On the other hand, technogenic mineral formations contain a lot of valuable scarce components. The amount of solid wastes increases annually, causing damage to ecology and economy. Researches conducted in recent years showed a possibility and economic expediency of comprehensive processing of wastes from different enterprises in Murmansk region and their use for production of new competitive commodity output, possessing high consumer properties. Thus, involving mineral wastes from Khibiny apatite deposits into hydrometallurgical industrial processing provides the basis for setting up a large beneficating-metallurgical complex. In this case ores and wastes from other deposits on the Kola Peninsula, containing titanium, rare, rare-earth and other valuable elements, may be involved into processing. Establishing such a complex will allow to organise a deep processing of natural resources, utilise some production wastes, improve ecological security and supply production with competitive output. Expanding the complex implies not only involving new mineral raw material into processing, but mainly deepening raw material processing, maximum utilisation of local natural resources and obtaining a wider variety of prime products.

Jan 1, 2002

By A. G. Starliper

The Bureau of Mines made laboratory investigations to determine the feasibility of utilizing fine tungsten wires to reinforce a number of nonferrous metals and alloys and a superalloy, S-8l6. The composites of tungsten filament and metals were chosen to attain elevated temperature strength and corrosion resistance. Oriented clean or precoated tungsten wires were incorporated with the other metals by extrusion, swaging, and infiltration casting. Although widely varying characteristics were found in the composites, none were considered satisfactory for high-temperature use, chiefly because of reactions between the matrix metal-tungsten surface. Diffusion, solution, and chemical reactions between matrix and tungsten wires were sufficiently slow for some combinations, such as 15 v/o 8-816, to exhibit increased high-temperature strength for a limited time. A few metals failed to wet or bond to the tungsten surfaces, while a few responded after precoating with a third metal.

Jan 1, 1968

By Gunnar Persson

The borehole pressure/time history of blasting practice is simulated in a twin pendulum apparatus, where the expanding shotfiring gases force two steel slab swingers apart. A pilot installation built at SveDeFo is described. The relevant factors, that govern the use of this test method as a means of classifying explosives with respect to their toxic fume potential, are described.

Jan 1, 1996

By M. J. Sapko

A moderately scaled apparatus was developed by the Bureau of Mines to determine the fire resistance characteristics of mine conveyor belts and similar type materials. The design of the apparatus was based upon data obtained in full-scale fire tests and features a radiant panel to preheat the belt and a methane-oxygen ribbon burner to ignite the sample under ventilating condi¬tions in a rectangular duct. The test method overcomes the limitations of existing laboratory-scale methods and provides a measure of both ignitability and flammability in quantitative terms. Flame propagation depended upon such variables as air velocity, ignitor heat flux, and belt width and height in the test chamber. Data are presented for nine belt materials and fire resistance ratings are proposed in terms of the flame spread rate, heat release rate, and the critical ignitor heat flux. The ratings discriminate between the fire hazard posed by different fire-resistant belts and tend to be in reasonable agreement with those obtained in full-scale fire tests.

Jan 1, 1981

By C. Y. Liu

This paper principally deals with the application of caisson foundation in the Chinese bridge building industry, the different types of caisson foundation adopted, and their spheres of application. Caisson foundation has been used and speedily developed for bridge works in New China, and a number of new innovations have been made in its design. Especially in deep water foundation, the Nanjing Bridge over Changjiang has attained one of the deepest bridge foundations in the world. There are six types of deep caisson foundation being now in use in China, namely:

Jan 1, 2010

By Dennis L. Paisley, Thomas P. Turner

Laser slapper detonators are the next generation detonator under development at the Detonations Systems Group at Los Alamos National Laboratory and function very similarly to an electrical slapper. A fiber optic transmits a laser pulse to ablate a thin metal film. This film, or flyer as it is commonly called, is launched through a short barrel to km/s speeds. The flyer shock loads or slaps a high density pressing of secondary explosive, setting off a detonation therein. Laser slapper detonators afford a number of safety advantages over other conventional detonators. Most important they require very high peak laser powers to operate, orders of magnitude larger than possible sources of natural or man-made accidental stimulus. Because light is transported over fiber optics, laser slappers avoid many of the electrical hazards associated with detonators. Use of insensitive, secondary explosives makes these detonators safer to handle, manufacture, transport, and deploy.

Jan 1, 1994

By J. Kerr

The first stage of the development of a new modified 201-type low nickel austenitic stainless steel is described in this paper. The alloy is intended for use as a structural alloy, and so requires a yield strength >400MPa as well as acceptable weldability and toughness. The low nickel content will give a lower material cost in comparison to more conventional austenitic grades, and the processing route is required to be similar to that of Type 304 to keep the processing cost low. The base alloy was designed using empirical methods developed for stainless steel, and the properties of the base alloy were verified using a range of small-scale melts. The base alloy had a 0.2% proof strength of ~320-400MPa, and so it is planned to use V additions of ~0.15% to bring about precipitation strengthening in the hot rolled condition, so raising the alloy?s proof strength above the 400MPa minimum.

Jan 1, 2004

By Thomas Varley

During the past few years, since flotation has become the paramount treatment method for most all kinds of ores, the Bureau has gathered the data on consumption of reagents used in the flotation treatment. The first report was issued in 1916. A brief review of such reports snows the progress made in the art of flotation, and each year brings forth the development of new reagent a or combinations of reagents that seem sure to survive, but research and progress spell their defeat, if not by entire elimination, at least subjects them to considerable modification.

Jan 1, 1928

By MacDonald B. Johnson, Douglass P. Bacon

"W ith the advance of science, rise of public interest in environmental matters, and continuing erosion of air quality, federal and state regulators are demanding an increasing complex array of data concerning emissions produced by burning and detonating energetic materials. The U.S. Department of Defense, one of the world’s largest consumers of energetic materials, now must characterize combustion products resulting from open burning/open detonation disposal operations. The catch-all phrase “below detection limits” no longer satisfies the regulators who nowwant testing to delve into the ppt level for volatile organic compounds and ppt level for semivolatile organic compounds."

Jan 1, 1995

By R. Mark, R. Richards

The Washington National Cathedral is one of the largest masonry structures in the USA, and like many of its European Gothic counterparts, it required nearly a century to construct. The design was altered during this period, resulting in greater loadings than were originally anticipated on the soil beneath the foundation. When signs of continuing differential settlement were observed in the early 1990's, the Cathedral approached the US Bureau of Mines (now the National Institute for Occupational Safety and Health (NIOSH)) for assistance in monitoring the movements of the massive towers and walls. An array of dual-axis tiltmeters was installed about 40m above ground level to measure wall and tower inclination, with the data sent over a dedicated phone line to the NIOSH Pittsburgh Research Laboratory for processing. Mechanical gages and string-potentiometers are also being used to measure motion across cracks and joints, and differential pier settlement is being monitored with optical-level surveying. Data have now been collected for almost 7 years, and they show a long-term settlement trend masked by dramatic diurnal and seasonal thermal movements. The paper discusses the major findings of the study, implications for the future of the Cathedral, and conclusions regarding the use of geotechnical monitoring at major national monuments.

By A. Holeyman

The displacement compaction piles described in the paper are installed using a heavy casing or tube and an internal drop hammer. The casing which initially is closed at the bottom by a sand plug displaces the surrounding soil during the driving. Additional sand is rammed down through the casing during the extraction of the casing. The applications and limitations of the method are reviewed in the paper. The importance of checking the sand compaction piles during and after the installation is stressed. Indications of the compaction of the surrounding soil during the driving can be obtained by comparing the initial and the redriving logs of the casing as well as from the volume of sand added. A method to estimate the increase of the mean cone resistance as measured by CPT tests in sandy and silty soils is presented. The governing parameters are the volume of the added sand, the granulometric index and the initial cone resistance.

Jan 1, 2010

By Seoul National University, Ki-Ho Kim, Jong-Pyo Kim, Sung-Min Joo, Hee-Chan Cho, Hyung-Seok Kim

Aragonite was synthesized in addition of Mg2+ ion and SrCO3 seed by carbonation process, and the best condition and mechanism of the synthesis was studied by analysis of continuous pH change, ICP, XRD, and SEM. As MgCl2•6H2O addition increased, aragonite phase increased at condition of CO2 flow rate of 100 mL/min and stirring rate of 250 rpm. It was the dissolution of Mg(OH)2 that determined overall reaction time. As SrCO3 seed addition increased at 0.2 mole MgCl2•6H2O, the amount of aragonite increased and the aspect ratio was from 5 to 9. And it was thought that Mg2+ ion prohibited calcitetransformation of aragonite formed by SrCO3.

Jan 1, 2003

By John Chipman, Wayne L. Worrell

Using recent thermodynamic data for the carbides and oxides of tantalum, columbium, and vanadium, the stable solid phases aboue 1300°K and at 1 atm CO(g) pressure in each M-C-O system have been determined. Pourbaix-Ellingham diagrams have been constructed and are used to estimate the minimum temperatures necessary to obtain these metals by carbothermic reduction under reduced pressures. TANTALUM, columbium, and vanadium react with carbon to form the M,C and MC carbide phases. The M,C carbides have narrow homogeneity ranges, but the MC phases possess considerable ranges of homogeneity.' The free energies of formation of the MC carbides were recently measured, and those of MC and M2Ccarbides have been estimated., (The notations MC and MC denote, respectively, the carbide compositions at the carbon-rich and at the metal-rich boundaries of the homogeneous MC phase.) In this paper, these carbide data are combined with thermodynamic data for the oxides to predict the stable phases in the Ta-C-O, Cb-C-O, and V-C-O systems at specified temperatures and oxygen pressures. M-C-O PHASE DIAGRAMS The solid phases in equilibrium above 1300°K for each M-C-0 system are shown in Figs. 1, 2, and 3. Above 1300°K, the vapor would consist entirely of carbon monoxide; and these phase diagrams were obtained by specifying the vapor pressure of CO(g) to be 1 atm. The temperature at which any two solid phases become unstable is specified along the two-phase equilibrium lines in each diagram. To simplify the diagrams, all solid phases in the Ta-C-O and Cb-C-O systems are represented as stoichiometric compounds. However, the homogeneity ranges of VO and VC are indicated, because they form a complete series of solid solutions.3 It also should be noted that the homogeneity range of

Jan 1, 1964