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By A. Hekmat-Ardakan

Conventional hypereutectic Al-Si alloys such as A390 are used principally for the casting of components used in wear applications requiring abrasive resistance such as in engine or compressor blocks. A comprehensive study was undertaken to investigate the potential of improving the mechanical properties of these alloys by the addition of magnesium. A thorough thermodynamic study of the effect of the addition of Mg to the conventional A390 alloy showed that Mg2Si starts to form as a primary phase at 4.2% Mg as well as in the products of the binary and ternary eutectic reactions forming the matrix. Experiments were carried out in producing castings with different cooling and solidification rates of alloys with up to 10% Mg. Mg additions were found to increase the hardness over the as cast alloy due to solid solution strengthening. Also, T6 heat treatment greatly improved the tensile properties of these alloy compositions due to the strengthening effect of the theta-Al2Cu phase. The elongation of these alloys generally decreases marginally with Mg content. The most significant property improvement of the alloys with higher Mg content is the substantial increase in wear resistance. This is attributed to the dispersion of smaller particles of Mg2Si and their coherence with the matrix as compared to the large Si particles in the conventional alloy. A new rheoforming process for A390 is presented that improves the processing of the semi-solid slurry. Structure modification elements were also added to refine the primary and eutectic silicon greatly improving the processing of the semi-solid slurry.

Jan 1, 2011

By V. ?. Chanturiya, I. Zh. Bunin, M. V. Ryazantseva

"Surface changes in naturally occurring metal sulfides (pyrite, arsenopyrite, sphalerite, chalcopyrite, galena, and molybdenite) due to treatments from high-power electromagnetic pulses (HPEMP) at varying times were studied using X-ray photoelectron spectroscopy. Analysis of the obtained results revealed common patterns and differences in surface transformations. The transformations were found to include two main stages. The first stage was observed at low treatment intensities (up to n ~103 pulses). At this stage, formation and accumulation in the surface layer of the nonstoichiometric sulfide phase, oxides and hydroxides, as well as elemental (polysulfide) sulfur and/or metastable sulfur species (thiosulfate, sulfite) was observed. The second stage (N = 3·103 pulses) is characterized by thermal removal of sulfur species and renewal of the mineral surface (sulfidization).It was found that the chemical changes of the sulfur on the surface layer of pyrite, arsenopyrite, chalcopyrite included accumulation/formation of S0 (Sn 2-) at the first stage of the transformation, followed by its removal. An increase in the surface concentration of elemental sulfur for pyrite and chalcopyrite was 10–12% while arsenopyrite was approximately 5%. A more complicated chemical change was observed for sphalerite and galena, that included formation/accumulation of metastable sulfur species (thiosulfate, sulfate) at the initial stage (up to 103 pulses) and during longer treatment times, the sulphur is reduced back to its initial state (sulfide or disulfide). The increased concentration of S0 sulfur, compared to the original sample, was only 3% in galena and sphalerite.The application of HPEMP treatment to improve flotation selectivity is supported by singlemineral flotation tests. Changes in flotability as a result of HPEMP treatment are principally explained by surface phase changes that resulted in higher adsorption activity."

Jan 1, 2016

By S. Heusermann, S. Fahland, J. Behlau, A. Schäfers, J. Hammer

In the course of the deep subsurface use, the Federal Institute for Geosciences and Natural Resources has been carrying out extensive geological and geomechanical research and practical project work on domal salt structures, to prove their suitability e.g. for the disposal of radioactive wastes. Recent work on disposal sites has been taking into account the 3-D geological and geomechanical modelling of the underground structures. The geological models are generated using the special-construction openGEOTM code to improve the visualisation and interpretation of the geological data basis, e.g. borehole, mine, and geophysical data. For the geomechanical analysis of underground structures the JIFE finite-element tool has being developed to analyze large 3-D structures and to consider coupled THMC processes. The results of finite-element calculations, i.e. stresses, strains, displacements, and dilatant zones, are basic values for the evaluation of the stability of the structures and the long-term integrity of the geological barrier. As an example, the results of geological and geomechanical investigations of the Morsleben repository are presented including three-dimensional modelling of the entire geological structure of the central part of the mine as well as three-dimensional geomechanical model calculations to provide the necessary results for a long-term safety prediction.

Jan 1, 2015

By N. W. Xu, M. D. Wei, F. Dai, B. Li

"Chevron notched samples achieve general acceptance for measuring the Mode-I (opening mode) fracture toughness of rocks. The cracked chevron notched semi-circular bending (CCNSCB) sample, which is developed from the International Society of Rock Mechanics suggested the cracked chevron notched Brazilian disc method, has recently received much attention. However, these chevron notched methods have not been fully mastered, some ideal assumptions based by their theories and formulas, such as the straight-through crack assumption (STCA), have not been verified detailedly. Fractures of CCNSCB specimens were numerically simulated considering different heterogeneities, geometrical and mechanical parameters. The results show that, the real fractures of CCNSCB specimens are never satisfied with the STCA. In fact, micro fractures not only occur in the notch tip but also the two chevron edges. Consequently, the crack front features prominently in a shape of parabolic curve, far from being straightthrough. Moreover, curvature of the crack front is only affected by shape of the chevron ligament. Cracks usually start from two sides of the notch tips rather than center of the notch width, and propagate deviating from the postulated fracture routes. These fracture mechanisms induce errors with the measurements, and thus more attentions should be paid to the real fractures of the chevron notched samples for measuring fracture toughness more accurately. INTRODUCTIONWith the increasing requirement of people for resources and energies, frequent rock engineering activities have been conducting, such as underground excavation, oil exploration and deep burial of nuclear waste. Many problems appear in rock fracture. Consequently, there are more and more attentions paid in rock fracture mechanics due to its broad application prospects for solving these engineering problems. Since Mode-I (opening mode) fracture is the most common failure mode in rocks, Mode-I fracture toughness is a primary parameter to predict rock mechanical properties in actual engineering, and thus its accurate values are necessary to the researches of rockburst, rock mass slope stability, rock cutting, hydraulic fracturing, tunneling, et al. Therefore, it is thus significant to evaluate and study relevant methods to obtain the reliable value."

Jan 1, 2015

By M. N. Vu, G. Armand, A. Noiret, D. Seyedi

Extensive experimental observations have been performed around drifts and shafts at the Meuse Haute-Marne (North-Eastern France) Underground Research Laboratory (URL) to assess the extent and pattern of the induced fracture networks in Callovo-Oxfordian claystone. Two types of fractures can be distinguished, namely; shear (mode II) and extension unloading (mode I) fractures. The main goal of the present paper is to provide insights on the extent of damaged zone around the drifts by numerical simulations. A two-step approach is considered. First, 2D elastic calculations are performed for simulating the excavation of a drift following the direction of the major in situ horizontal stress. The evolution of the stress and strain tensors around drifts are calculated by applying an elliptic convergence function on the drift wall. Two failure criteria are then verified for the induced damage. An equivalent strain and an elastic energy based damage criteria are considered. The obtained results show that the employed simplified approach provides rather good results for the extent of the damaged zone for drifts parallel to major horizontal stress. However, post-processing elastic results leads to overestimating the vertical extent of the damage zone and underestimating its lateral extent, where the in situ stress state is quasi-isotropic in a section of drift. Nevertheless, the obtained results show that an energy based damage criterion could be considered as a potential way for reproducing the extent of the damaged zones if a convergence function can be defined for the drift.

Jan 1, 2015

By Jerry Handford

Investing in the Development of our Future Workforce ?Collaborative partnerships with educational institutions, industry associations, governments and other businesses. ?Programs: »Co-op / Discipline Student Program »Trades Development Initiatives »Operator Training Programs »General Student Program »Careers Next Generation / Community Careers Co-operative

May 1, 2006

Open pit production planning is a procedure consisting of multiple stages. Although all the planning stages rely on the geostatistical block models, long- to short-term plans each require their appropriate resolutions and levels of details. The main motives behind using different resolutions are the tractability of the models and the practicality of the generated schedules. The current approach in the mining industry is to use nested pits generated by Lerchs-Grossman as the basis for long-term planning and to use manually generated polygons, within those pushbacks, as the units of production control in mid- and short-term planning. However, the nested pits generated by Lerchs-Grossman algorithm and the polygons drawn by mining engineer do not provide control over the value and tonnage of ore and waste inside the planning units and therefore cannot lead to optimum solutions. In this paper, we first present a pushback determination approach which maximizes the profit of the mine with control over the tonnage of ore and waste within each pushback. We then propose a clustering approach with size and shape control that determines aggregates within those pushbacks; and finally, we introduce a mathematical programming model which uses the generated pushbacks and aggregates as the planning basis and generates production schedules that maximize the net present value of the operation and are practical from the operation?s point of view.

Aug 1, 2013

By P. Zhang, K. Liu, L. Ou

"The strength and mechanism of Portland cement prepared from stone coal vanadium slag were studied in this paper. Initially, the slag was used as silicon raw materials to prepare clinker. By blending the prepared clinker with gypsum, waste, and fly ash, a series of different grades cement got well prepared. All of performances of the cement were up to the requirements of China’s national standard. The hydration products and microstructure of cement were identified and analyzed by X-ray diffraction and scanning electron microscopy. With the comparison of cement hydration characteristics at different ages, the strength formation mechanism of cement was clarified. The experimental results suggested that adding the fine materials (mainly waste and fly ash) to replace part of clinker would accelerate cement hydration, as it provided additional surfaces for the nucleation and growth of hydration products. And the hydration products were similar to ordinary Portland cement, mainly containing the amorphous calcium silicate hydrates (C-S-H), acicular ettringite (AFt) and portlandite (CH). With hydration time increasing, the hydration products continuously covered the cement particles, resulting in a thicker surface layer. As a result, it gradually condensed into a dense structure block with small pores and smooth surfaces, which led to higher strength. In conclusion, using the vanadium slag to prepare Portland cement can realize the utilization of solid mineral wastes, which will bring huge ecological and economic benefits.INTRODUCTIONWith the development of China’s mining industry, more and more mineral waste residue is discharged every year. These solid wastes cause varieties of resources and environmental problems on people’s living area. While at the same time, the demands of cement are increasing with the remarkable development of the construction industry. Thus, in recent years, utilization of proper solid waste to prepare cement has become an efficient way to deal with the solid mineral wastes problems (Boncukcuoglu, Kocakeri?M, & Tosunoglu, 2002; Simatupang, Hanafi, Purwasasmita, Imran, & Pane, 2012; Tsakiridis, Papadimitriou, Tsivilis, & Koroneos, 2008; Yun, Yong, Choi, Lee, & Lachemi, 2009)."

Jan 1, 2016

By M. Kermani

This paper presents and compares the physical properties of Gelfill and cemented hydraulic fill (CHF) obtained by lab experiments. Gelfill has an alkali activator such as sodium silicate in its materials in addition to primary materials of cemented mine backfill which are deslimed tailings, water and binders. The CHF and Gelfill samples with various mixture designs were cast and cured for 28 days. Initially, the influence of sodium silicate concentration on the mechanical properties of samples was evaluated using the unconfined compressive strength (UCS) test. Consequently, the effect of curing temperature on CHF and Gelfill samples cured in various curing temperatures ranging from 5?50 °C was studied using the UCS test. Microstructure of selected samples was studied wirth the mercury intrusion porosimetry (MIP) technique. This study concludes that: (i) The mechanical properties of CHF can be improved by the addition of appropriate amount of sodium silicate. (ii) The rate of strength acquisition in Gelfill samples is faster than CHF samples over 28 days of curing period. (iii) Curing temperature strongly influences the mechanical and microstructural properties of CHF and Gelfill samples. (iv) The microstructure analysis revealed that the addition of sodium silicate can modify the pore size distribution and total porosity of Gelfill which can contribute to the better mechanical properties of Gelfill. (v) The MIP tests suggested the microstructure of specimens were changed by adding sodium silicate in a way that the Gelfill samples had a higher percentage of fine pores than CHF samples.

Aug 1, 2013

By D. Want

In titanium-lined autoclave design the most critical point of its mechanical reliability is its titanium batten strips present at the circumferential and longitudinal barrel-weld seams. Recently an Australian Company, W.E. Smith Hudson (WESH) P/L, has developed a fully flush batten strip and is building autoclaves with this design. Significant research and development has been performed in the process. In this presentation, design aspects of these batten strips are presented that cover topics such as residual-stress magnitudes during fabrication, affect of preheat during batten-strip welding and residual stress in respect to fatigue life. There has been little research done regarding the affects of residual batten stress in relation to fatigue life. Considerations of this 'grey' area of design will be discussed based on the author's research data and finite element analysis.

Jan 1, 2005

By Nirmal Weerasekara

Mill liners serve the dual purpose of protecting the shell from wear and transferring the rotary motion of the mill to an effective grinding action. As the liners wear, the efficiency of energy transfer changes, so there is balance between liner profile for wear and for milling efficiency. A tool that can simultaneously predict the evolution of the liner profile and the associated change in milling efficiency should prove most useful in optimal liner design. This paper presents such an approach, based on measured 3D liner profile data informing 3D DEM simulations of charge motion and liner wear modelling.

Jan 1, 2012

By Fatemeh Saeidi, Luis Marcelo Tavares, Malcolm Powell, Mohsen Yahyaei

"Understanding a single breakage mechanism is fundamental to the development of breakage testing techniques appropriate for mechanistic modelling of any breakage equipment. In the light of this insight, it is also possible to compare any two breakage events in a mechanistic manner. This paper presents a new method to compare breakage mechanisms of two-point impact with compression, different in their applied strain rates. This approach regards a single breakage event as a process affected by three sub-processes; first fracture, capture and spatial distribution of fragments. Spatial distribution is influenced by the kinetic energy of fragments and their brittleness. Using this methodology allows us to examine how each sub-process is influenced by applied strain rate and its impacts on progeny size distribution. For this purpose, two rock types of widely different strength, magnetite and silicate, were tested at various energy levels using the impact and compression mechanisms. To isolate the effect of spatial distribution of fragments, particles were forced to remain in the breakage zone. In this condition, similar progenies were generated from compression and impact mechanisms at similar energy levels. However, allowing natural distribution of fragments, coarser progeny was produced from compression of silicate. Additionally, using this approach provides a physical meaning and explanation for rock strength parameters such as A×b in the t10-Ecs relationship. INTRODUCTIONComminution models are rapidly progressing toward a destination that enables us to explain the complete physics of a breakage process as well as the properties of the ores. Eventually, they will be able to take into consideration the micro-events that take place during the comminution process (Bourgeois and Banini, 2002). Thus, considerable efforts have been made in the last few years in the area of ore breakage characterisation to comprehend and unlock a single breakage process that has been treated as a black box event in the majority of conventional methods. In this paper, an attempt is made to explain the effect of applied strain rate on the breakage properties of rock by using the knowledge that has been gained by understanding a breakage event. This is particularly important due to its application for various comminution devices that operate within a relatively broad range of speed."

Jan 1, 2016

By L. Gutierrez, M. Pawlik

The rheology artificial mixtures of bitumen with fine quartz of varying bitumen content, as well as actual oil sand ores, was investigated under different physicochemical conditions (pH, temperature). All rheological measurements were conducted using a Haake Rotovisco VT550 rotational viscometer, connected to a fixture specifically designed to measure properties of settling suspensions. It was found that at low bitumen contents (1 %, wt.) the pH of the slurries was the most important parameter that controlled the rheology of quartz-bitumen slurries. At higher bitumen contents (10%, wt.), it was a combination of high temperature and high pH that gave the lowest apparent viscosities and yield stresses of the model mixtures. These model observations correlated well with the rheology data obtained for slurries of actual oil sand ores. The overall results were discussed in terms of aggregation-dispersion phenomena between bitumen and mineral particles.

Jan 1, 2009

By E. P. Wiechrnann, C. M. Castro, G. A. Vidal

In copper Eta plants the optimal current density setpoint depends on the electrolyte composition and temperature. However, conventional plants operate with large standard deviations. A value of 14% with current densities offsets up to ±50% is typical. For worst, during opencircuit or shortcircuit events this variation can be from -100% to +200%. Naturally, energy consumption and copper quality are compromised. Several devices have been successfully employed to reduce set point deviations. Last developments include; Optibar Segmented Intercell Bars, Outotec Electrodes Arranging Method and NTC Selective Electrodeposition Enhancers. This paper researches and compares these technologies. It is shown that short circuits can be effectively reduced in occurrence and magnitude. Moreover, 95% of the electrodes can be forced to operate within ±10% of the set point. The specific energy consumption is reduced from 2,000 KW per Ton to values close to 1,900 KW per Ton.

Jan 1, 2011

By K. Esmaieli

ABSTRACT We conducted a series of numerical experiments to investigate the influence of rock mass foliation on impact-induced damage on ore pass walls. The 2D Particle Flow Code was used to simulate three distinct rock masses surrounding an ore pass, characterized by foliation angles of 60°, 90°, and 120° (clockwise from horizontal). Subsequently, we projected a rock fragment against the ore pass walls at a constant impact angle and velocity. The resulting damage increase

Jan 1, 2014

There are many inherent risks in creating a mine plan for a new ore zone in an underground mine; one of such risks is the redistribution of stresses that could be a cause of instability. Using numerical modelling tools, it is possible to model the planned stope extraction sequence and evaluate the influence of mining induced stresses on the stability of remnant pillars, and use this information to remedy potential setbacks. This paper demonstrates this approach through a case study of the short-term mine plan of the Lapa mine of Agnico Eagle Mines Ltd., an underground gold mining operation near Val d?Or. Three-dimensional boundary element modelling is used to compute the stresses induced by the stope extraction sequence as planned with a longitudinal retreat mining method. The proposed methodology can be generalized to other mines that require an understanding of the stress concentrations at the pre-feasibility stage of mine design.

May 1, 2009

By Nn Li

Energy consumption in commercial buildings has been increasing rapidly in the past decade. The knowledge of future energy consumption can bring significant value to commercial building energy management. For example, prediction of energy consumption decomposition helps analyze the energy consumption patterns and efficiencies as well as waste, and identify the prime targets for energy conservation. Moreover, prediction of temporal energy consumption enables building managers to plan out the energy usage over time, shift energy usage to off-peak periods, and make more effective energy purchase plans. This paper proposes a novel model for predicting heating, ventilation and air conditioning (HVAC) energy consumption in commercial buildings. The model simulates energy behaviors of HVAC systems in commercial buildings, and interacts with a multiagent systems (MAS) based framework for energy consumption prediction. Prediction is done on a daily, weekly and monthly basis. Ground truth energy consumption data is collected from a test bed office building over 267 consecutive days, and is compared to predicted energy consumption for the same period. Results show that the prediction can match 92.6 to 98.2% of total HVAC energy consumption with coefficient of variation of the root mean square error (CV-RMSE) values of 7.8 to 22.2%. Ventilation energy consumption can be predicted at high accuracies (over 99%) and low variations (CV-RMSE values of 3.1 to 16.3%), while cooling energy consumption accounts for majority of inaccuracies and variations in total energy consumption prediction.

Aug 1, 2013

By R. W. Seedsman

In 1984 and 1985, two 7.6m diameter TBM tunnels were driven from the Donkin-Morien peninsula in Nova Scotia to access the Harbour coal seam. The design of the ground support was based on identifying zones of rock failure through the application of the Hoek Brown failure criterion and the early use of finite element analyses. In 1992, the mining project was abandoned and the tunnels allowed to flood. Monitoring data from the tunnel was subsequently used as a case study in the development of the concepts of brittle rock behaviour. In 2007, the tunnels were pumped out as part of a feasibility study into the reintroduction of longwall mining into the coalfield. There is a good match between observations of the collapse zones in the roof and sides of the tunnel and a simple elastic analysis using brittle parameters, a spalling limit of 5, and a low independent shear modulus. The brittle analyses form the basis of the design for the resupport of the tunnels.

May 1, 2009

By Kirsten Corin, Margreth Tadie, Cyril O’Connor, Jenny Wiese, Wonder Chimonyo

"Relating flotation performance to the electrochemical characteristics of a pulp remains a complex issue both in fundamental research and in practice. For example, in the case of thiol collectors different Eh values can result in the formation of the dimer or the metal thiolate which may or may not enhance the hydrophobicity of the mineral. Reducing or oxidizing conditions in a flotation system, viz. changing the Eh value, are usually manipulated to achieve an optimum flotation response by the control of pH and dissolved oxygen levels in the system. It is also possible to vary the potential by the addition of modifiers such as sodium hydrosulphide (NaHS), sodium hypochlorite (NaClO) or hydrogen peroxide (H2O2). The objective of the present study was to investigate the effect of the addition of the oxidising agents, NaClO and H2O2, on valuable mineral recoveries and grades in the flotation of sulphides from a PGM bearing Merensky ore. Batch flotation tests were conducted at pH 9.2, the natural pH of the system, in the absence and presence of a xanthate collector and Eh modifiers, viz. NaClO or H2O2. Most importantly in this way it was possible to vary Eh at constant pH and DO levels. The results indicate that in the absence or presence of xanthate the addition of H2O2 reduced both the recovery and grade of copper and nickel. In the absence of xanthate, the addition of NaClO improved the recovery of copper slightly and both the recovery and grade of nickel significantly, but in the presence of xanthate NaClO addition resulted in unchanged copper recovery and grade, but those of nickel were reduced. Based on anecdotal evidence that the addition of trace amounts of a potential modifier could improve flotation performance further tests were conducted the results of which suggest improved flotation performance.INTRODUCTIONIn the Merensky Reef, platinum group minerals (PGM) are commonly associated with base metal sulphides (BMS) and this has an effect on the way in which these minerals can be concentrated by flotation (Vermaak, Venter & Pistorius, 2004; Wiese, Harris & Bradshaw, 2005; Schouwstra, Kinloch & Lee., 2000). A major problem stemming from this association has been reported to be the loss of valuable minerals (PGM) associated with the loss of BMS (Wiese et al., 2005) during flotation. Shackleton (2007) suggested that PGMs behave in a similar manner to sulphides during flotation. Therefore, in order to recover the PGM, base metals are targeted. There is thus a need to investigate ways to improve the flotation performance of the sulphide minerals. The electrochemistry of the flotation of sulphide minerals has been studied for over half a century and there is consensus that sulphide minerals float only under a suitable redox environment (Heyes & Trahar 1979). This implies that reducing and oxidizing conditions during flotation of ores such as Merensky can be manipulated/varied to achieve an optimum flotation response.During flotation, sulphide minerals interact with thiol collectors in an electrochemical reaction to form hydrophobic species at the mineral surface (Finkelstein & Goold 1972; Rand & Woods 1984). The sulphide minerals are semiconductors and their interaction with collectors involves transfer of electrons. As such, a potential difference results which is responsible for driving electrons between reacting species (Fuerstenau, Jameson & Yoon, 2007). The magnitude of the potential difference affects the relative energies of charge carriers (electrons) at the mineral/solution interface hence controlling the direction and rate of charge transfer or rate of reaction (Bard & Faulkner, 2001). In a mixed mineral system the mineral/solution interface potentials account for the mixed potential which is critical to the process of flotation (Chander, 2003; Woods, 2003)."

Jan 1, 2016

By K. Forsberg, A. Rasmuson, R. Rodriguez Varela, J. Martinez De La Cruz

"This study analyzes the separation of rare earth elements by means of a supported liquid membrane (SLM) with the final objective of recovering REE from an apatite concentrate (Alemrajabi, Forsberg, & Rasmuson, 2015; Mohammadi, Forsberg, Martinez de la Cruz, & Rasmuson, 2015). In this study, the feed phase consists of an aqueous phase containing REE, the membrane phase contains the organic solvent and carrier (D2EHPA and EHEHPA), and the stripping phase is a hydrochloric acid solution. An evaluation of mass fluxes, separation efficiency, and membrane performance is conducted. In order to analyze the suitability of liquid membranes in the extraction of REE, a deeper insight into the mechanisms causing instability is needed. In this study, surface tension is considered as the key factor of Marangoni instabilities and spontaneous emulsification.INTRODUCTIONThe demand of REE and their compounds has increased considerably due to their special physicochemical features that make them crucial elements for numerous high-tech applications, including wind turbines, hybrid cars, mobile phones, and defense technologies. They are also extensively utilized in traditional industries such as nuclear energy, petroleum, metallurgy, agriculture, and textiles (Xie, Zhang, Dreisinger, & Dyole, 2014; Zhang, Wu, Bian, & Zeng, 2014).Solvent extraction is widely used for the separation of REE (Xie et al., 2014; Zhao, Huo, Pan, Li, & Liu, 2014). Di-(2-ethylhexyl)-phosphoric acid (D2EHPA) and 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (EHEHPA) are two of the most effective extractants for the separation of rare earth elements among organophosphorus extractants (Gupta & Krishnamurthy, 2005). However, the difficulty in stripping loaded D2EHPA extractant, especially for heavy REE, has limited its utilization. Yttrium can be stripped at lower acidities in EHEHPA systems compared to D2EHPA systems (Gupta et al., 2005), but the extraction efficiency is lower. Conventional solvent extraction by mixer-settlers is restricted by its large solvent inventory and loading limits, and suffers from phase disengagement, emulsification, loss of solvent, and flooding problems (Swain, Jeong, Lee, & Lee, 2007). In this context, supported liquid membranes (SLMs) present a potential alternative due to their advantages, being low solvent inventory, process simplicity, low energy and operational costs, great enrichment ratio, and combination of extraction and stripping into one single step. A SLM is a system in which two aqueous phases are separated by an organic liquid membrane suspended in the pores of a porous support by capillary forces. One of the aqueous phases is the feed solution with the solute and the other is the stripping or receiving solution. The solute diffuses through the liquid membrane and then is extracted into the stripping solution (Kislik, 2010)."

Jan 1, 2016