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By Xuanxue Mo, Kaihui Yang

"Abstract- The Laochang mine, located in the Sanjiang area of southwestern Yunnan Province of China, is a volcanogenic massive Pb-Zn-Cu sulfide deposit. It is hosted by a pyroclastic sequence of Barly Carboniferous age, namely the lower member of the Yiliu Group, which was intruded by syenite and rhyolite porphyry . The volcanic suite is basaltic or basaltic-andesitic in composition, has alkaline affinities, and is associated with the initial rifting along the margin of the Baoshan-Shanstate continental rnicroplate (Yang, 1989). The ores are typically Pb>Zn>Cu in composition, averaging 3.820Jo Pb, 3.51% Zn, from 0.01% to 1.85% Cu (0.107% av.), a high average content of Ag (113 g/t) and recoverable amounts of Au, Tl, Gd, Ga, Ge, In. A massive sulflde zone, in which lenticular and stratiform orebodies are localized in a sulflde-carbonate-silica shale unit or sulfldic tufflte horizon that usually overlies coarse-grained pyroclastic rocks, is underlain by a stringer sulflde zone developed in a subvolcanic intrusion or volcanic sequence. The sulfide mineral assemblages, from the top to the bottom of the deposit, are: realgar + orpiment - galena + sphalerite + pyrite- chalcopyrite + pyrite + pyrrhotite + arsenopyrite. Oxide and sulfate minerais occur rarely in the massive ores. The massive ores are generally fine-grained and banded, but coarse-grained ore, colloform and framboidal texture, and growth-zoned pyrite and sphalerite are common. Sedimentary features such as graded bedding, brecciated and deformed ore clasts, and chaotically emplaced blocks, are well preserved, indicating that the massive orebodies have undergone slumping and dis­ placement. Alteration is weak in the hanging-wall rocks, but strong in the stringer zone. Two dis­ tinctive alteration zones have been identified: the upper zone, characterized by an assemblage of quartz, carbonates, chlorite, albite, zeolite and sericite, and the lower zone containing diopside, trema­ lite, actinolite, gamet, clinozoisite, and epidote.The general features of the Laochang deposit are in accord with the descriptive mode! of VMS deposits (Lydon, 1984). However, it falls into neither the Zn-Cu group nor the Zn-Pb-Cu group chemically (Franklin et al., 1981). The depositional setting of the Laochang deposit is quite different from Cyprus or Besshi-type massive sulfide deposits. Laochang is hosted by alkaline lavas that were erupted in a submarine continental rift. Although some features of the Laochang deposit are similar to those of Kuroko-type deposits, there are remarkable differences in the alteration mineral assemblage, the proportion of ore-forming elements (lead enriched) and the amounts of oxides and sulfates. These suggest corresponding differences in ore fluid composition and the associated ore-forming environment. Thus, the authors suggest that the Laochang deposit may be a distinct type of VMS deposit."

Jan 1, 1993

By K. D. Watson

"THE Mindamar zinc-lead-copper mine, owned by Mindamar Metals Corporation Limited, is at Stirling in Richmond County, near the south-eastern shore of Cape Breton Island, Nova Scotia (Figure I). It is connected by several roads with the Canadian National railway at Sydney and St. Peters.The deposit is said to have been discovered around 1895 as an outcrop in the bed of Copper brook, but the details are obscure. Not until 1925, when it was optioned by American Cyanamid Company, was it developed underground. Between 1927 and 1938, the 1-nine was operated intermittently by The British Metal Corporation (Canada) Limited, and yielded approximately 200,000 tons of ore averaging about IO per cent zinc, 2 per cent lead, I per cent copper, and small quantities of silver and gold. In December 1950, Dome Exploration (Canada) Limited made an agreement with Mindamar Metaî Corporation Limited, which was exploring the old mine, to assume management and prepare the property for production. Production started in April 1952 with a new mill and a new four-compartment shaft, and between that time and the end of 1954 it has totalled 545,347 tons of ore averaging 5·89 per cent zinc, 1·35 per cent lead, 0·66 per cent copper, 0·032 oz. gold, and 2 151 oz. silver.The Mindamar orebodies are irregular lenses and large veins lying within a wide, almost vertical shear zone of remarkable persistency. The shear zone consists mainly of well-foliated sericite schist derived from siliceous siltstone, and it contains a vast amount of dolomite and magne-site of hydrothermal origin. Most of the ore is extremely fine-grained and some of the high-grade material has a conspicuous thinly layered structure. The metallic minerals, in order of decreasing abundance, are pyrite, sphalerite, chalcopyrite, galena, and tennantite; the gangue minerals, in the same order, are dolomite and magnesite, quartz, sericite, talc, chlorite, barite, albite, and alunite.The geological setting of the deposit is shown in Figure 2. Except along streams and lake shores, almost all of the bedrock is concealed by glacial drift. The group of rocks in which the deposit occurs consists principally of greywacke, siltstone, tuff, brecoia, and Javas, and has been correlated lithologically with the Bourinot group of Middle Cambrian age. A short distance west of the mine, these rocks are in contact along the Stirling fault with conglomerate, arkosic sandstone, and quartzite belonging to the Middle River group of Silurian or Devonian (?) age, which elsewhere in the area overlies the Bourinot group unconformably. The large bodies of granitic rocks in the region, and the large lenticular masses of diorite and quartz diorite associated with them, have been assigned by Weeks (5, pp. 68-69) to the Devonian."

Jan 1, 1949

Eagle Plains Resources? Exploration in the Northern Cordillera ?Eagle Plains Resources Ltd. (EPL) is actively exploring for Zn-Pb deposits in the northern Cordillera in both carbonate-hosted and shale-hosted (sedex) environments. ?This presentation will review some of the significant carbonate-hosted Zn-Pb showings occurring in the Mackenzie Mountains, NWT and make limited comparisons with sedexdeposits in the adjacent Selwyn Basin.

May 1, 2006

By Adam Moore, Ryan Gillespie, Jarrett Quinn, Audrey Walters, Peter Radziszewski

"Vale Long Harbour Processing Plant (LHPP) was designed to process Voisey’s Bay nickel concentrate into finished nickel and associated copper and cobalt products. The plant includes a secondary grinding circuit comprising two Stirred Media Detritors (SMDs) operating in parallel. The ultrafine grinding circuit was designed to process concentrate at a rate of 33 t/h and produce a ground product (P80) of 20 µm to feed the leach circuits. Start-up of the grinding circuit at LHPP was undertaken in December 2014.The objective of this paper will be to describe the design, commissioning, start-up and performance of the secondary grinding circuit with a focus on the two Metso SMD-355-C mills. Following a brief overview of Vale’s LHPP and the SMD technology, the paper will review the design of the SMD secondary grinding circuit from lab tests through to scale-up performance prediction. This will be followed by the results of circuit commissioning outlining some of the issues raised and addressed after which SMD performance will be outlined. Specifically, the SMD circuit grinding performance will be examined since start-up which will include the effect of media size and wear on grinding. Furthermore, impeller wear will be examined by determining initial “shear volume” and worn “shear volume” as well as its effect on mill power and the means to maintain it. The paper closes with a discussion on grinding performance."

Jan 1, 2016

By Marcondes Lima Costa

Abstract-The Amazon region is characterized by the development of deep chemical weathering represented by widespread lateritic covers and soils. Two distinct periods of laterite formation can be distinguished: mature laterites from the Eocene-Oligocene (and locally from the end of the Cretaceous), and immature laterites from the Pleistocene. The older laterites occur on plateau landscapes, and the younger ones on widespread hilly to flat lowlands. Both types show complete or truncated profiles, generally covered by deep yellow to brown topsoils. The mature laterite profiles contain high concentrations of gibbsite and/or aluminum phosphate, whereas the immature ones are poor in these minerals. The Amazon region is rich in mineral deposits related to lateritic profiles. Some mineral deposits are of primary origin but were concentrated to economic grades by lateritic processes. The most important ore deposits are of iron, aluminum (bauxite), kaolin, manganese, gold, nickel, copper and phosphate. These are mainly related to mature profiles. The wide spectrum of ore deposits and mineralogical and geochemical complexity of the Amazon laterites has been promoted by: (1) the prevalence of ideal conditions for laterite formation throughout much of the Tertiary; (2) the presence of varied basement lithologies due to contrasting geological environments; and (3) a variety of epigenetic alteration types. The lateritic profiles show a well-developed ore zonation which is related to specific lateritic horizons. Iron and gold deposits occur in the ferruginous horizon, which is nearest the surface; the central aluminous horizon hosts bauxites, aluminum phosphate, strontium and gold; and the lower clayey horizon contains deposits of manganese, nickel, copper and kaolin. Resistate phases which residually accumulate throughout entire profiles include titanium (as ilmenite and anatase), chromium (as chromite), tin (as cassiterite), yttrium (as xenotime), and niobium (mainly as ilmenorutile). Epigenetic alteration, caused by swamp environments developed above truncated lateritic profiles, has led to the formation of high-grade kaolin and refractory bauxites. The laterites in the Amazon region contain most of all known kinds of ore mineralization related to laterite processes.

Jan 1, 1997

By Marcondes Lima Costa

The Amazon region is characterized by the development of deep chemical weathering represented by widespread lateritic covers and soils. Two distinct periods of laterite formation can be distinguished: mature laterites from the Eocene-Oligocene (and locally from the end of the Cretaceous), and immature laterites from the Pleistocene. The older laterites occur on plateau landscapes,and the younger ones on widespread hilly to ?at lowlands. Both types show complete or truncated pro?les, generally covered by deep yellow to brown topsoils. The mature laterite pro?les contain high concentrations of gibbsite and/or aluminum phosphate, whereas the immature ones are poor in these minerals. The Amazon region is rich in mineral deposits related to lateritic pro?les. Some mineral deposits are of primary origin but were concentrated to economic grades by lateritic processes. The most important ore deposits are of iron, aluminum (bauxite), kaolin, manganese, gold, nickel, copper and phosphate. These are mainly related to mature pro?les. The wide spectrum of ore deposits and mineralogical and geochemical complexity of the Amazon laterites has been promoted by: (1) the prevalence of ideal conditions for laterite formation throughout much of the Tertiary; (2) the presence of varied basement lithologies due to contrasting geological environments; and (3) a variety of epi-genetic alteration types. The lateritic pro?les show a well-developed ore zonation which is related to speci?c lateritic horizons. Iron and gold deposits occur in the ferruginous horizon, which is nearest the surface; the central aluminous horizon hosts bauxites, aluminum phosphate, strontium and gold;and the lower clayey horizon contains deposits of manganese, nickel, copper and kaolin. Resistate phases which residually accumulate throughout entire pro?les include titanium (as ilmenite andanatase), chromium (as chromite), tin (as cassiterite), yttrium (as xenotime), and niobium (mainly asilmenorutile). Epigenetic alteration, caused by swamp environments developed above truncated lateritic pro?les, has led to the formation of high-grade kaolin and refractory bauxites. The laterites inthe Amazon region contain most of all known kinds of ore mineralization related to laterite processes.

Jan 1, 1997

By B. McHenry, A. E. Wraith, P. J. Mackey

The Wallaroo smelter on the Yorke Peninsula, South Australia commenced smelting operations in 1861 treating ores from the nearby Moonta and Kadina mines. The plant expanded and modernized on several occasions and was a leader in the successful introduction of new technology to improve operations. It operated continuously until 1923 when local mines became exhausted; in the closing stages of the 19th century it was the largest copper smelter in the world outside of those in Swansea, Wales. In 1892 a small electrolytic refinery was established at Wallaroo, the first in Australia, based on principles developed by Elkington at Pembrey, Wales in 1869. The Wallaroo refinery was specifically built to recover gold and silver from copper produced by smelting gold-containing feed materials shipped from Western Australia. This first venture into electrolytic refining was replaced in 1903 by a somewhat larger refinery which, although modest in size for its time, with a capacity of about 1000 tonnes of cathode copper per year, was very productive in precious metals. Anode copper was produced by an updated version of the reverberatory-based Welsh process until 1910 when barrel-type pneumatic converters were introduced based on American practice; subsequently, anodes were cast by tapping the precious-metals rich "bottoms" portion of converter copper as produced at about one-fifth into the copper blow. The present paper describes the Wallaroo refinery, its anode supply and products, supported by initial observations on a sample of a Wallaroo cathode held in the collection of the South Australia Museum, Adelaide SA, Australia. INTRODUCTION Australia ranked 6th in the world for copper mine production in 2018, with an output of 918,000 tonnes of mined copper, after Chile, Peru, Congo, China and the USA; about 40% of Australian mined copper was smelted in the country. Interestingly, the world ranking of Australia in mined copper has, with a few variations, remained about the same for more than 100 years – of interest, it was also the 6th largest country for copper production at 21,089 tonnes in 1899. At that time, all or most of the copper was smelted in the country (Mackey, 2016). Copper was first discovered in Australia in 1842 in South Australia not far from Adelaide; additional copper discoveries in the region soon followed. At first, copper ore was shipped to Swansea, Wales for smelting (Bampton, 2003). However, in addition to the long, 150 day one-way sea passage, it seems Welsh smelters preferred higher grade of ores – these aspects and likely a mood in the new colony to be independent of Swansea (Evans, 2014) evidently encouraged local smelting at the mine sites using small, Welsh-type reverberatory furnaces fired with hardwood as fuel and operated by Welsh and Cornish migrants. The first large copper smelter in Australia commenced in 1848 at Bremer, near Callington some 60 km east of Adelaide. With larger discoveries on Yorke Peninsula, the Wallaroo copper smelter at Wallaroo Bay on the west coast of the peninsula commenced operations in 1861 (Bell & McCarthy, 2008). Thus began one of the most successful, and in its day, one of the most advanced and innovative plants in Australia if not the world. In the late 1860s, it was considered one of the largest copper smelters in the world (Bell & McCarthy, 2008)

Jan 1, 2019

By G. C. Lipsyy

ALL mineral production? of Can11.da is transported in a mine car at some stage during its extraction. There are as many types and varieties of mine cars as there are of mines. Many of the cars in use were developed in the blacksmith shop. Others were designed by engineers and improved by the mine foremen and the mechanics. Every mine car has the ideas of miner, blacksmith, mechanic, and engineer incorporated in it. Many of these ideas are not generally known. This paper was written to make at least some of this information available to the mining industry. In drawings, tables, and notes, it gives all the important details pertaining to the cars. It .does not recommend any particular type of car for any particular piece of work, nor does it present drawings from which a car can be built. It gives the engineer or master mechanic information on many cars which he can apply to his own particular problems. It is hoped that this information will be of use to mine operators. If a few new ideas are conceived as a result of the paper, the author will feel that the effort of compiling it has been worth while. In order to obtain the data for the preparation of the paper, a questionnaire, copy of which is here reproduced, was sent to all the operating mining companies in Canada. An accompanying letter briefly explained the purpose of the paper and asked for co-operation in furnishing as complete information as possible.

Jan 1, 1945

By Sylvain Castonguay, Sylvain Pilon

"Operator competency is an important factor in the safe and successful operation of today’s complex processes. Competent process unit operators deliver superior performance and results. In greenfield projects, operator competency is particularly critical, as the lack of specific operations experience must be offset with proven practical knowledge and skills to avoid mistakes that can cost millions in terms of start-up delays, production losses and equipment damage. It is, therefore, important to know precisely what competencies are required for a project or site, and what any gaps in operator competency need to be addressed and improved. The success of plant commissioning, start-up and sustainable operations is directly tied to operator competency. The significant investments required for new projects, the exploitation of more challenging ore bodies, and the increasing complexity of plant operations have placed renewed emphasis on the need for competent operators. Furthermore, many large capital projects are being developed in remote regions, often with ties to the delivery of social benefits for the local population in terms of jobs, training and other development opportunities. While automation and processing technologies have helped do more with less, indicators now point to a bottleneck in human performance limiting operational results.Automation industry development in managing abnormal situations, including solutions for simulation and operator training, has produced applications to provide customized and flexible training methods. This paper will discuss tools to automate the operator competency process in order to guide trainers to effectively teach, measure, control, provide feedback, and monitor operator skills. Today’s competency management solutions can be effectively applied throughout the course of an operator’s professional life, as a guide to hiring new operators, for developing competencies to support operations, and also to develop and refine best practices and share lessons learned."

Jan 1, 2016

By W. Abdellah

Underground mine developments, such as haulage drifts and cross cuts, play a vital role in providing access to ore extraction areas for mine production. The stability of mine developments is thus of crucial importance during the life of a mine plan. Many Canadian mines use longhole mining methods or one of its variants. These methods require access to the orebody through mine developments such as haulage drifts and cross cuts on multiple levels. This paper examines the stability of mine development access intersections with respect to the planned mining sequence. A case study, the #1 Shear East orebody at Vale?s Garson Mine in Sudbury, Ontario, is presented. A three-dimensional, elastoplastic, finite difference model (FLAC 3D) was created for a development intersection situated 1.5 km below ground surface. The stability, or performance of the intersection, is evaluated in terms of the strength-to-stress ratio. The ratio threshold is set at 1.4 for temporary openings. Unsatisfactory performance is defined as a strength-to-stress ratio less than this threshold value. The performance of the intersection stability is evaluated at various modelled mining stages and the probabilistic method of analysis is then invoked to study the probability of unsatisfactory performance of the intersection. The results are presented and categorized with respect to probability, instability, and mining stage.

Aug 1, 2013

By R. O. Burt

The original flowsheet of the TANCO mill consisted of a simple two-stage gravity circuit for the recovery of the tantalum concentrates. With decreasing grade and grain size of the tantalum minerals, considerable modifications to the circuit have been required. This paper discusses the various recent improvements carried out 011 all stages of the flowsheet, which have resulted in a 10% increase in recovery. Future improvements, including on stream analysis, and the possibility of tantalum flotation , are also discussed.

Jan 1, 1979

By Ron Zevenhoven

In Finland one opportunity for large-scale CO2 capture, utilisation and storage (CCUS) is CO2 mineralisation, i.e. mineral carbonation. A process route under development towards industrial application involves production of magnesium hydroxide or sulphate from serpentinite rock (serpentine = 3MgO·2SiO2·2H2O), followed by conversion either in a pressurised fluidised bed (PFB) reactor, giving magnesium carbonate, or in an aqueous solution process giving magnesium hydro-magnesites. Iron present in the rock is typically obtained FeO(OH). Results obtained with these process routes and progress towards industrial demonstration is addressed, process heat integration and operation on flue gases (without CO2 pre-separation!) being key features for economic viability. A process route utilizing calcium-containing slag by-product from iron- and steelmaking under development towards large-scale application is the so-called slag2pcc concept. It converts an industrial by-product into valuable material, reduces use of natural material and streams to landfills while binding CO2 produced by the process generating the slag. Using ammonium salts, calcium is extracted from steel converter (BOF) slags and subsequently carbonated in a two-stage aqueous process (at ambient temperatures and pressures). Precipitated calcium carbonate (PCC) is produced while regenerating the ammonium salt. Process performance and scale-up while guaranteeing a certain PCC quality are presented.

Jan 1, 2015

By Noel W. Kirshenbaum

Difficulties and costs of transport markedly affect Canadian mineral producers because of distance from markets, weather conditions and rugged terrain. The chemical and physical nature of sulphide concentrates presents additional difficulties in handling and transport, resulting in higher costs which are ultimately borne by the mineowner. Troublesome properties include the thixo-tropic character of wet concentrates, freezing, susceptibility to autogenous heating, and fine particle size causing spillage and dusting losses. Canadian mineowners and shippers must contend with these problems and with stringent regulations governing the maritime shipping of concentrates. A "systems approach," in which complementary techniques in materials preparation, handling and transport are integrated, could reduce freight costs and losses for those selling concentrates, facilitate operations for those carrying and handling them and, in some cases, improve metallurgical processes in smelters receiving them.

Jan 1, 1969

By K. Thuro, H. Käsling, F. Menschik

"With increasing data volume, due to enhancing requirements for ground investigation programs for large construction projects, the demand for more efficient filing systems is more and more growing. Depending on the project we also have to use flexible systems to cope with varying data out of different lab and field tests.The chair for Engineering Geology at TUM is developing a web-based database solution to handle all project relevant data in a more appropriate way. We aim to optimize our data management to achieve a fast and easy way of collecting, documenting and analyzing our gained data. The second objective is to provide an easy access to our data for project partners across broadly distributed locations.This Database system consists of a PHP web interface and a MySQL database core. The current setup allows an online access via Internet (www). We are able to grant and constrain access to all data or only arrays of data with our user management system to guarantee the safety of project data and respect all rights and proprietorship. The database system is of modular design and consists of the following three base modules: module of general project data, module of laboratory data and user management module. At the current stage we are able to save and work with all usually generated specific values from unconfined compressive strength tests, brazilian tensile strength tests, point load tests, CERCHAR and LCPC abrasivity tests and ultrasonic tests. The user is able to perform a simple statistical analysis within our database (e.g. average calculation of one sample) and export data as csv or xls files for further analysis.For specific questions within projects we are able to deploy and integrate further modules in our database system. At this moment, we are developing an add on to use this database for different drill test analyses. One of the tools correlates drilling performance and drill head wear measured in the field with rock mechanical properties, and extrapolates the data to estimate the performance and wear in new projects. Today we are managing 90 projects with 550 samples and almost 1350 lab tests with the base module.In our contribution we aim to demonstrate an efficient way of data structuring using a relational database for laboratory and field testing data."

Jan 1, 2015

By Himanshu Dehra

The pre-fabricated outdoor rooms are often utilised near the mines and construction sites for office purposes. The paper has presented modelling and simulation results of the integration of commercially available glass coated photovoltaic (PV) energy technology and solar ventilation technology into a pre-fabricated outdoor room. The pre-fabricated outdoor room has been setup at Concordia University, Montréal for full scale testing of the glass coated PV modules with solar air ventilation. The computer simulation model has been developed for PV modules installed on a double wall wooden frame in an outdoor room based on its preliminary field testing. The testing apparatus was a wooden frame assembly of double wall with solar air ventilation: two adjacent glass coated PV modules, air column and plywood board filled with polystyrene. The measurement data collected from various sensors were: solar intensity, ambient air temperature, room air temperature, electric power, surface temperatures of PV modules and plywood board, air velocities and air temperatures in the air column. The enhancement in the air velocity of the air column was achieved with an exhaust fan fixed in an outdoor room. The simulation model is used to perform the two dimensional energy analyses with applied one dimensional solution of steady state heat conduction equations. The simulation model is based on conjugate heat exchange paths with network boundary conditions of convection, radiation heat exchange and solar air ventilation heat transport. The model parameters are based on measured values of ambient air temperature, room air temperature, air velocity at outlet of air column in double wall, electric power and available solar intensity. The model has predicted fairly well energy performance of glass coated PV modules with solar air ventilation installed on a wooden frame. The model is also useful for predicting heating, ventilating and air-conditioning (HVAC) requirements for the pre-fabricated outdoor rooms.

May 1, 2007

By Juergen Antrekowitsch, Stefan Steinlechner

"Within the last decades, mainly the base metals, like zinc, copper and lead were recycled from different industrial residues without taking into account that accompanied minor side-elements are often also present. A high supply risk for critical raw materials derives mainly due to the high share of the worldwide production in a limited number of countries. Examples include indium and germanium in China, PGM in South Africa and Russia or cobalt and tungsten in the Democratic Republic of Congo. By taking the market of critical metals into account, the recycling of potential residues does not only contribute to an economic treatment but also to the European strategy to decrease the supply risk of certain metals. Depending on the metal discussed, political unrest, decreasing primary resources leading to supply risks in different countries or also simply economic interests moved these mentioned side elements and with this the residues where they are present in, into the focus of the recycling industry.Because of this, the typical routes of lead, zinc and copper production are evaluated concerning generated residues and their typical contents of contained minor elements. Finally, the paper tries to answer the questions how a possible treatment of these wastes could contribute to the overall supply of for example silver but also other minor elements."

Jan 1, 2016

By T. M. Ruff

A GPS-based traffic awareness and collision avoidance system has been implemented at mines with long, narrow access roads to help avoid accidents involving two approaching vehicles or vehicles following too close. A simple display in the cab of each outfitted vehicle gives an indication of oncoming traffic and a voice announcement indicates the type of vehicle that is coming as far out as 300 meters. Advanced warning of approaching vehicles is increasing driver awareness, especially around blind corners and in adverse weather such as heavy fog, snow, or rain. Speeding alarms have also been implemented and are especially critical as a vehicle approaches reduced speed areas near single-lane bridges or tight curves. A description of the system, safety improvements seen since its introduction, and implementation challenges will be discussed.

Aug 1, 2013

By Jan Kvinge, Aina Opsal Bakke, Yanjun Li, Jan-Ove Løland, Svein Jørgensen

"Compound casting is a very attractive approach to reduce the weight of components for some specific applications while keep both the functional and the mechanical property requirements. In this work, Al-7Si-Mg alloy /copper compound castings were produced through a low pressure die casting process. To reduce the oxide present in the interface, flux coating of the copper pipes was tested. The interface layer formed between the two alloys was investigated using Optical Microscopy (OM), Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray Spectroscopy (EDS). Vickers Micro-hardness was also measured across the interface. Results showed that the flux coating prevented the formation of the metallic bond between copper and aluminum. Instead, high concentrations of potassium, magnesium and fluoride, coinciding with formation of KMgF3 and MgF2, were detected in the interface. In the castings without surface treatment, a continuous metallurgical bond was achieved. In the bond layer, various Al-Cu intermetallic phases have been detected. In addition, formation of primary silicon particles in the reaction layer was observed in all castings. The mechanism for the formation of the intermetallic phases and the strength of the interface layer have been discussed.INTRODUCTION Recent development in the automotive industry has focused on producing lightweight components, which can reduce CO2 emission and increase the efficiency. Often, one material alone is not able to meet the requirements for a specific use. The need for lightweight bimetallic components has therefore increased. Aluminum-copper bimetallic components can be used in wires and bus bars where conductivity is an important factor (Lee, Bang, & Jung, 2005). Compared to Al-Cu alloys, Al-Cu bimetallic components can reduce both weight and cost without reducing electrical and thermal conductivity (Sheng, Yang, Xi, Lai, & Ye, 2011). A challenge is, however, that aluminum and copper have high affinity to each other, especially at elevated temperatures. This causes formation of brittle intermetallic phases with high electric resistance (Liu, Wang, Sui, Wang, & Wenjiang, 2016). In addition, both metals are subjected to oxide formation on the surface. Copper is especially exposed to oxidation at elevated temperatures (Pinnel, Tompkins, & Heath, 1979), while a thermodynamically stable oxide layer will spontaneously form on the aluminum surface (Papis, Loeffler, & Uggowitzer, 2009). Oxides are known to be passive substrates, which will reduce wettability and will thus prevent the formation of metallic bonding between aluminum and copper (Papis, Hallstedt, Löffler, & Uggowitzer, 2008)."

Jan 1, 2018

By P. A. Riveros, R. Molnar, F. J. Baša

"An acidification circuit was installed and operated at the Agnico-Eagle Silver Division refinery in Cobalt, Ontario, for treating ~300 m3 of a concentrated cyanide waste solution with the purpose of recovering its cyanide and metal values. The acidification circuit was designed from parameters determined experimentally at CANMET. Available refinery equipment was assembled according to a flowsheet developed by Agnico-Eagle Mines. The process produced a regenerated cyanide solution containing >15 g/L of free cyanide, which was used for leaching gold ore at another Agnico- Eagle operation. It was estimated that the value of the recovered cyanide offset the treatment cost. BackgroundThe Silver Division of Agnico-Eagle Mines needed an economic and effective method for disposing of ~300 m3 of a concentrated cyanide waste solution that had remained in the plant after the operation was shut down in 1989. As a result of extensive recycling and evaporation, the solution had become practically saturated with metals, cyanide, thiocyanate, sulphate and other components, and was, therefore, an environmental liability for the company. A partial analysis of the solution is presented in Table 1. Initially, the use of cyanide destruction methods was considered by Agnico-Eagle, but the estimates indicated a considerable cost with no credits to be gained. A research project carried out by CANMET showed that a simple procedure consisting of acidification, filtration and reneutralization was the most attractive option, because it enabled the recovery of a substantial portion of the cyanide. Furthermore, the metals would be recovered in the form of a solid precipitate. The research showed that conventional AVR was not applicable because of excessive cyanide degradation and low HCN volatilization obtained with this particular solution (Riveros et al., 1996). This paper describes the procedure used to treat the concentrated cyanide waste solution and the operating practices of the large-scale acidification circuit run at the Agnico-Eagle refinery."

Jan 1, 1998

By C. R. Fast, G. C. Howard

The loss of fluid to the formation adjacent a fracture governs the areal extent of the fracture and the success of hydraulic fracturing as a production stimulation technique. The three flow mechanisms which control this loss are the result of the viscosity of the fracturing fluid and the permeability of the formation to the fracturing fluid, its wall building properties, and the combined effects of viscosity and compressibility of the reservoir fluid. The effects of these flow mechanisms can be evaluated in terms of a fracturing fluid coefficient, the fundamental concepts of which are developed in the paper. The fracturing fluid coefficient, which may be used in calculating the areal extent of fracturing, affords a direct measure of the effectiveness of fracturing fluids. The area of hydraulically created fractures is in-creased as the coefficient is de-creased. The fifteen-fold variation noted in this coefficient for the commercially available fracturing fluids tested resulted in a six-fold difference m the calculated areal extent of the fracture system.

Jan 1, 1961