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By Md. Nafiul Haque, Murad Y. Abu-Farsakh, Chris Nickel

"This paper presents the results from a pile load testing program for a bridge construction project in Louisiana. The testing includes two 54-inch open-ended spun cast concrete cylinder piles (OECP), one 30-inch open-ended steel pile (OESP), and two (30-inch and 16-inch) square prestressed concrete (PSC) piles driven at two locations with very similar soil conditions. All the test piles were instrumented with vibrating wire strain gauges to measure the load distribution along the length of the test piles and the skin friction and the end bearing were derived from strain gauge measurements. High strain dynamic load tests (HSDLT) were performed on all test piles at different times after pile installations to quantify the amount of setup with time. Static load tests were also performed on the PSC and open-ended steel piles. Due to expected large pile capacities, the statnamic test method was used on the two open-ended cylinder piles. The pile capacities of these piles were evaluated using various CPT methods (such as Schmertmann, De Ruiter and Beringen, LCPC, COFS methods). The result showed that all the methods can estimate the skin friction with good accuracy; but not the end-bearing capacity. Setup was observed for all the piles, which was mainly attributed to increase in skin frictions. The setup rate parameters “A” [The “A” parameter is defined as the rate of increase of pile capacity ratio (Rt/Rto) per log cycle of elapsed time] were back-calculated for all the test piles and the values were between 0.31 and 0.41.INTRODUCTIONDue to greater efficiency (capacity to weight ratio) of the pipe piles, open-ended piles are a viable option to solid piles. However, the behavior of open-ended piles is more complicated compared to the close-ended piles owing to possible formation of “soil plug” inside the open-ended pile. Many researchers have analyzed the behavior of both types of piles for different purposes; however, very few studies in the literature offer the side-by-side comparison of the close-ended and open-ended piles."

Jan 1, 2017

By Nancy Estrada, Jane Nowell, Cathy Jennings, Debra Yniguez, Carol Lavery, Kristin Harrer

Pilots of the MH-60S helicopter are exposed to continuous whole body vibration (WBV). Pilot fatigue is a growing operational concern due to the increased frequency of extended durations of missions (6-8+hours) in support of Operations Iraqi Freedom and Enduring Freedom. Endurance aspects of the currently used rotary wing seating systems were not optimized for the longer missions and wide range of pilot anthropometric measurements, which is now typical of naval aviation. The current seating systems were designed primarily to meet crashworthiness requirements, not for the wide range of pilot anthropometry or to mitigate WBV. Albeit, an issue, pilot fatigue and reduced mission effectiveness are also critical concerns. Current Hazard Reports indicated that pain in pilots’ legs and backs begin two to four hours into the flight and increase with time. Mission readiness also decreases with an increase in flight duration due to the constant distraction of pilots shifting in their seats while trying to get comfortable. Froom, et al [2] reported a dose-response relationship between the length of military helicopter flights and back discomfort. He also concluded that this pain is typically dull, over the lower back, and its prevalence and intensity are dependent on the total flight hours of exposure. Methods This study evaluated WBV produced in the pilot seating systems onboard the MH-60S. The purpose of the study was to test and compare the effectiveness of two different seat cushions, the current seat cushion versus an anti-vibration seat cushion. Both seat cushions were measured for acceleration levels averaged over five-minute intervals using a triaxial seat pad accelerometer. The recordings were completed for a 3-hour straight and level flight. A frequency analysis from 0-80 hertz (Hz) was conducted on all acceleration measurements to determine the dominant axis and frequency of the pilots’ vibration exposure. The results were then compared to the applicable Threshold Limit Values (TLVs) established by the American Conference of Governmental Industrial Hygienists (ACGIH) [1] and the International Organization for Standardization (ISO) 2631.1 [3] to determine the MH-60S pilots’ permissible exposure time for both seat cushions. Results The results of the study showed that for both seat cushions the vibration levels of the z-axis at 16 Hz had the shortest allowable exposure duration, according to the ACGIH TLVs. In the z-axis at 16 Hz, the MH-60S’s current seat cushion’s acceleration levels indicated an exposure time limit of approximately 6 hours, while the anti-vibration seat cushion’s acceleration levels pierced the 8-hour exposure time limit curve. This is shown in the graph below.

Jan 6, 2006

By Gerald H. Luttrell, Mohammad Rezaee, Roe-Hoan Yoon, Rick Q. Honaker, Aaron Noble, Abhijit Bhagavatula, Michael J. Kiser

A field study was undertaken to experimentally measure the concentrations of rare earth elements (REEs) contained in the process streams generated by a group of 20 coal preparation plants located in the eastern USA. For each site, representative samples of clean coal product, coarse refuse, and fine refuse were collected. Each sample was then partitioned into preselected size and density classes by wet screening/sieving and float-sink testing. The resultant products were dried and subjected to laboratory analyses to determine ash contents and rare earth element concentrations including Yttrium and Scandium. A detailed analysis of the database generated by this exercise showed that coal-based products from these preparation plants contained significant quantities of rare earth elements. In particular, the coarse refuse streams currently discarded by the 20 plants examined were found to contain a sufficient tonnage of REEs to satisfy the current domestic demand for these important elements. The data also showed a strong positive correlation between ash content and REE concentration, which suggested that the primary association of REEs in eastern USA bituminous coal sources is likely within fractions containing inorganic impurities. This association was well described using a simple power equation relating ash content and REE concentration. The ratio of heavy-to-light rare earth elements was discovered to be significantly higher in organically rich fractions of clean coal, suggesting that mineral impurities intimately associated with carbonaceous matter have elevated concentrations of heavy rare earth elements. A similar trend was observed for a grouping of rare earth elements (Y, Nd, Eu, Tb, and Dy) that are likely subject to near-term supply shortages. Finally, the database showed that a linear correlation existed between La for many REEs of interest, although there were several notable exceptions for some high-value REEs (Lu, Pr, and Tb).

By Xun Luo, Yi Duan

A field trial of by distributed optical fiber sensing (DOFS) technique was conducted at a longwall coal mine in Australia. This investigation was designed to assess the applicability of DOFS for microseismic monitoring in mining. The experiments used commercially available optic fiber cables, geophones and associated data acquisition instruments – a fiber interrogator and a seismic recorder. The fiber cable was deployed in a 300m deep hole and in trenches of approximately 3.5 km long on the ground surface around and across the longwall panel being mined. The results obtained from the experiments have shown that DOFS is able to acquire microseismic data with quality that is comparable to geophones. It has been proven that DOFS can achieve higher spatial resolution for seismicity sensing and higher accuracy for locating events than a geophone network. These characteristics are particularly useful for using DOFS to monitor ground vibrations associated with ground caving processes and rock fracturing events induced by mining and civil engineering. It was also found that far more additional seismic events were recorded by the fibers than by the geophones. Automated data discrimination and processing methods must be developed in order to utilize DOFS for real-time applications.

Apr 26, 2022

By B Reid

"Since the commencement of mining operations at the Cowal Gold Operations (CGO) in 2005, reverse circulation (RC) drilling has been the preferred method for grade control (GC) sample collection. This method was selected because it allowed:for multibench drilling (20 m hole depths for two benches of mining) to aid mine planning increased data density for comparison against the wide spaced ore reserve model angled drill holes to intersect perpendicular to the strike and dip of the shallow dipping mineralisation ability to take two metre sample intervals to enhance the understanding of the mineralisation’s short-scale variability and provide the ability to flitch mine.From June 2008 to December 2013, RC GC was performed using a UDR rotary cone splitter. The field duplicate data over the period displayed strong precision, with a correlation coefficient of 0.94 and an average relative per cent difference (RPD) of 21 per cent for gold. Up to 66.1 per cent of field duplicate data greater than 0.1 g/t fell within ±20 per cent RPD. This is within limits of industry best practice. The Mine to Mill reconciliations over the same period showed the estimated GC grade was 7.7 per cent lower than the calculated head grade (CHG).In December 2013, the Progradex sampling system (PGX) was introduced at CGO due to its advertised ability to capture 100 per cent of the drill cuttings for the complete sample interval, inclusive of fines. Analysis of field duplicate data indicates that since the introduction of the PGX, the sample precision has drifted. From January 2014 to February 2016, the correlation coefficient was 0.92 and up to 51.2 per cent of field duplicate data, greater than 0.1 g/t fell within the ±20 per cent RPD. Over the same 26 month period, the Mine to Mill reconciliation improved to one per cent lower than the CHG. Granulometric analysis of the RC samples collected from the PGX indicated the fines material(<212 µm) averaged up to 22 per cent of the samples mass and following assay determination, the fines material represented a weighted average of 31 per cent of the total gold content within the sample.This paper highlights the:importance of the complete capture of all drill cuttings during an RC drill programinfluence of fines material on the sample quality and accuracyimpact sampling of the fines material has on the Mine to Mill reconciliation performancechallenges experienced in commissioning a PGX system.Citation:Reid, B, 2016. A Fine Looking Sample - the Importance of Fines in Grade Control Sampling to Mine to Mill Reconciliation, in Proceedings Ninth AusIMM Open Pit Operators' Conference 2016, pp 28–38 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Nov 15, 2016

By J. C. Vreugdenburg, B. A. Dippenaar, J. Muller, T. L. de Vries

Iron ore fines are agglomerated to produce sinter, which is an important feed material for blast furnaces worldwide. A model of the iron ore sintering process has been developed with the objective of being representative of the sinter pot test, the standard laboratory process in which the behaviour of specific sinter feed mixtures is evaluated. The model aims to predict sinter quality, including chemical quality and physical strength, as well as key sinter process performance parameters such as production rate and fuel consumption rate. The model uses the finite difference method (FDM) to solve heat and mass distributions within the sinter pot over the height and time dimensions. This model can further be used for establishing empirical relationships between modelled parameters and measured sinter properties. Inputs into the model include the feed material physical properties, chemical compositions, and boundary conditions. Submodels describe relationships between applied pressure differential and gas flow rate through the bed of granulated fine ore particles, combustion of carbonaceous material, calcination of fluxes, evaporation and condensation of water, and melting and solidification. The model was applied to typical sinter test conditions to illustrate the results predicted, and to test sensitivities to parameters such as feed void fraction, feed coke percentage, and the fraction of combustion heat transferred to the gas phase. A model validation and improvement study should follow, ensuring sinter test results are free from experimental errors by conducting repeated tests.

Jan 1, 2015

By R. Ratnagiri, B. Minaie

"In order to expeditiously produce defect-free metallic components in materials processing applications, the relationship between the process parameters and the product properties needs to be well understood while minimizing the production engineering iterations. To achieve this goal, a realistic mathematical formulation of the process should be carried out and an appropriate numerical modeling of various phenomena occurring in such process should be implemented. The materials processing of transforming the molten material into a finished metallic component involves fluid flow and solidification/melting. In the present paper, a finite element based analysis of the fluid flow ·and solidification/melting phenomena in cavities is presented and the various issues in modeling these phenomena are discussed. These transport phenomena play an important role in determining the final characteristics and material properties of the part by affecting the formation of defects and microstructure. A realistic numerical modeling of these phenomena can significantly reduce the rejection rates during the process and can increase the quality of the final product.IntroductionDuring the intelligent materials processing of various metallic components, it is often required to have a thorough knowledge of the behavior of the transport phenomena involved in this process. This is due in large to the coupling that exists between the transport phenomena and the final material properties of the components produced during materials processing. This interrelationship demands that the pertinent transport phenomena in the form of fluid flow and solidification/melting be studied and predicted accurately. In many materials processing applications, the fluid flow is in the form of either a forced convection free surface flow intended to fill a cavity or a natural convection flow resulting from the gravity when the cavity is filled. In either case, the phase change in the form of solidification/melting is also involved in order to complete the process. However, the thermal history during this phase change has a direct impact on the material properties of the final part and the possible defect formation that may be involved. This thermal history itself is dependent on the nature of the fluid flow during the earlier stages of the process. As such, there is a coupling between the fluid flow, phase change, microstructure, and defect formation in the resulting component. It is therefore necessary to analyze these phenomena in order to find optimum methods to produce good quality parts by minimizing the defects that may be generated. Such an analysis can result in the development of appropriate numerical models for the process that can facilitate the economical and timely manufacturing of various components with high consistency. The present paper discusses the issues related to the transport phenomena encountered during materials processing of components engineered largely by using various combination of convective fluid flow and solidification/melting in cavities."

Jan 1, 1994

By W. A. Gericke, B. Olmstead, I. Mc Dougall, C. F. R. Smith

A finite element model was generated of a Søderberg electrode in a ferromanganese smelter. In this model, the casing and fins were modelled explicitly, and temperature-dependent material properties were included. A two-stage analysis procedure was used, the first part being a coupled thermal-electrical analysis using an applied DC current. As the casing material was non-magnetic, the DC current was deemed sufficiently accurate for this initial analysis. The proximity effect was not considered. Thermal boundary conditions based on assumed temperature distributions in the furnace were applied. Calculated temperatures agreed well with measured values. The joule heat calculated in this step was applied as a load to a coupled thermalstress analysis. The model was applied to a comparative study of alternative materials for the casing and fins. A number of different combinations of materials for the casing and fins were evaluated in a comparative study. The position of the baking zone was used as the criterion for evaluating the potential of each material combination. Based on this analysis, some material combinations were discarded as being entirely unsuitable, whilst the two most suitable combinations will be tested experimentally in the furnace. The stress analysis was performed on the most suitable option. The practical advantage of this analysis was that a number of what-if scenarios could be evaluated and discarded prior to embarking on expensive experimental work, thus limiting the amount of experimental effort required. A mathematical model allows for the comparison of options under controlled conditions, where parameters of interest can be varied individually, with all other parameters remaining the same, a condition which is difficult to achieve in an operating furnace.

Jan 1, 2004

By V. K. Risinggård, M. Sparta

We report on the development of a finite-element method model for a pilot furnace for the production of manganese alloys. The model is a multiphysics model that addresses material flow, electrical conditions, heat transfer, and physical and chemical transformations. It is capable of studying both quasi-steady and transient states in time-dependent simulations. The model includes common charge materials and fluxes and can simulate production of both ferromanganese and silicomanganese alloys with acid and basic slags, as well as changing charge compositions. The model output provides access to the material distribution in the furnace during furnace runs, temperature profiles, current paths, energy balances, and alloy and slag production rates and compositions.

Apr 16, 2024

By Thomas Barczak

Roof support systems are designed for roof control to prevent unplanned falls. It sounds logical and has been the conventional thinking in support design since supports were first installed. In order to determine which support system should be used or which would be the most effective, the degree of control provided by the support system must be known. This question embodies the concept of a ground response curve, which is a measure of support control by assessment of the convergence in the mine entry as a function of the support capacity. In this National Institute for Occupational Safety and Health (NIOSH) study to optimize standing roof support design, ground response curves were developed for longwall tailgate conditions from numerical models of Pittsburgh Coal Seam geology. The models were calibrated against tailgate convergence measurements that were made in two Pittsburgh Coal Seam mines as the depth of cover varied during the panel extraction. Ground response curves were developed for four loading conditions: (1) development, (2) side abutment, (3) front abutment near the longwall face, and (4) full extraction inby the face. In general, the tailgate convergence and required support capacity increase through each of these loading stages. It was concluded that prior to failure of the rock mass, the support system regardless of its capacity has relatively little impact on tailgate convergence. Recognizing that the support cannot prevent much of the (pre-failure) convergence that is occurring is an important part of support design. Supports that exhibit high loading stiffness but cannot sustain that loading through a displacement compatible with the ground response curve will not provide adequate roof control because they can fail prematurely. The required capacity depends on the loading plus yielding characteristics of the support and the amount of rock failure that has occurred. The loading plus yielding character establishes where the support loading intersects the ground response curve. Design criterion for support capacity based on the identifying the onset of strain-soften rock response leading to ?damaged roof? is proposed as a foundation for assessing support design requirements. The capacity without accounting for the loading and yielding character of one support should not be used to assess the capacity requirement of an alternative support design, particularly when the loading and yielding characteristics are significantly different. A sensitivity study was made to evaluate the impact of mining height and overburden depth. As expected, the results show that convergence increases with increase in mining height and increase in overburden depth. Some specific support examples are also analyzed. Although this is a first step and the two-dimensional numerical models have limitations, these initial studies provide valuable insight into the control provided by the roof support system and will ultimately lead to optimizing support design based on specific mine site conditions.

Jan 1, 2008

By James A. Finch, Jason S. Doucet, Cesar O. Gomez

"Exercising control over the physical environment of flotation as a step towards process optimization is the driving force for characterizing gas dispersion in flotation cells, a subject of considerable research and still not fully understood. From an operational standpoint, however, there are just a few variables that can be manipulated to manage gas dispersion on a cell-to-cell basis, the most important being gas rate (superficial gas velocity Jg). Measurements in eight plants demonstrate there is often no strategy for distribution of gas to cells in a bank, i.e., there is no particular Jg profile. Two exercises where Jg profiles were set allowed metallurgical performance to be manipulated and an optimum Jg profile to be selected. To facilitate setting Jg profiles, a multi-unit device based on McGill Jg sensor technology is introduced. Possible directions for gas dispersion management are discussed.INTRODUCTIONThe earliest patents regarding the flotation process ignored the importance of air and in certain cases, steps were taken to eliminate bubbles from the system (Nelson and Smit, 2005). Rickard (1916) described a keen metallurgist who observed better than expected performance and hypothesized that entrained air was enhancing the process. Within a few years of this observation, the basic concept of modern froth flotation was developed whereby air is dispersed into slurry to induce bubble particle contact.As research into flotation advanced, the link between performance and the flow-rate of air entering the cell was established. In the first volume of the International Journal of Mineral Processing, Harris (1974) described the importance of airflow-rate and derived parameters such as the superficial gas velocity (then called the superficial airflow velocity) as being important parameters for cell design and scale-up. Mehrotra and Kapur (1974) presented research suggesting that the rate of flotation was strongly correlated to the aeration rate. McKee et al. (1976) continued to demonstrate the importance of airflow-rate linking it to the entrainment rate of hydrophilic gangue material."

Jan 1, 2006

By Russell Frith

A review of published literature reveals case histories whereby the entire periphery of a coal pillar has “burst” out as a single event during first workings, the associated energy and material release causing significant damage to adjacent roadways and any equipment/infrastructure located within said roadways. Such events are distinct from coal burst events during first workings such as that at the Austar Mine in 2014, or those linked to overburden bumps related to either horizontal stress-driven slip along major faults and/or thick, massive strata units in the overburden or floor of the coal seam.

By R. H. McCorkell

"Sample drops were evaporated on Lexan disks on which fission tracks were etched and counted after neutron irradiation. [U] = 0.01 ppb could be measured. This method is rapid, cheap, simple and accurate when sufficient control and checking is possible, but several types of error were encountered in its use, the natures and sources of which were investigated but not always determined. The most troublesome were ""annealing"" processes which sometimes altered the fission tracks so that they were not fully revealed, or acquired varying appearances, after etching. Several different annealing processes seemed to exist and seemed to be produced by alteration of the Lexan surface by dissolved components in the solutions and, perhaps, by radiation and local heating during neutron irradiation. The appearances of the etched tracks varied with the natures of the droplet solutions even when annealing appeared to be absent, and for this reason, standards are best prepared by additions of known amounts of U to sample solutions. Contamination of sample droplets by U-containing dust from the air is best avoided by preparing the disks away from areas where other U-analysis is being carried out.IntroductionFission tracks are regions of radiation dam age produced in solids by the fission of atoms such as 235U. They can be enlarged to sizes visible through optical microscopes by etching surfaces through which they pass with solvents in which the solids are slightly soluble. A sample to be analyzed for U may be placed against a film of a solid of negligible uranium concentration (the track detector) and irradiated with thermal neutrons in a nuclear reactor to fission 235U. The track detector is then etched and the number of tracks per unit area, ?, which is proportional to the uranium concentration of the sample, c, and the neutron do se, n, is found by counting through a microscope. Uranium in solutions ha s been measured by evaporating drops on track detectors, irradiating, etching and determining the number of tracks per drop, T(2,3,4,5). Extensive test s of this method are reported here."

Jan 1, 1983

By T. L. Joseph

A DEMAND for specialized knowledge has directed engineering curricula towards competency in some particular field or occupation. Preparation for life in a broad sense of completeness has received little consideration. Ways and means are needed for weaving some of the threads of liberal education into the fabric of engineering education. Any effort to develop a humanistic-social stem of engineering education will depend largely upon the content of the courses and the type of instruction offered. Many of the courses in college curricula are intended to lay a foundation for more advanced courses to be taken later by those. who specialize in some particular field. Students in other fields lack the background necessary to take the advanced courses and have too much detailed information, soon forgotten, forced upon them if they pursue the foundation courses. To develop a humanistic-social stem for engineering education existing catalogue courses selected should follow some general plan aimed towards broad educational objectives. Courses packed with detailed factual information are necessary for the stu-

Jan 1, 1947

By Takiuchi T, Kurita M, Owada S

This paper describes the possibility of the application of flotation to the separation of monazite from xenotime and of columbite from ferberite, which have been said to be difficult with generally used physical beneficiation methods. For Malaysian monazite and xenotime samples, a great difference is observed between the flotation recoveries at pH 7.5 using 1.0 x 10-4mol/1 dodecylammonium chloride (DAC). The grade and recovery of columbite in the binary flotation with both minerals result in 85 per cent and 67 per cent in the cleaning froth and 91 per cent and 51 per cent in the re-cleaning froth, without adding any scavenging stages. For monazite samples from various localities, the flotability is dominated by the electrostatic interaction between mineral surface and collector ion using DAC as collector, but the singular decrease of flotation is observed in the sample of which the crystallinity is low and the surface structure is rugged and complex. Otherwise, ferric ion in the flotation system probably dissolved from mineral is found to activate the flotation using sodium dodecylsulfate as collector. For columbite and ferberite, the separation is judged possible at pH 3.0 using 1.0 x 10'3mo1/l sodium oleate (NaOl) from the single flotation results of each mineral. In the binary flotation, however, columbite recovery in the froth is greatly diminished below that expected. This would be because NaOl is prevented from adsorbing on the columbite surface of which the charge is transformed more negative side by the specific adsorption of the tungstate ion dissolved from ferberite.

Jan 1, 1993

By A. G. Roach

MILLING of Nova Scotia gold ores began in 1862 with arrastras and wooden stamps and has progressed to heavier stamps followed by tables and other forms of concentration for the recovery of the sulphides. Chlorination and cyanide leaching of the concentrates has been practised, and in 1936 the combined amalgamation and all-sliming cyanidation plant of Seal Harbor Gold Mines was built. It has since been found that it is not necessary to cyanide the full tonnage and now only the concentrates are being so treated. From his experience in this enterprise, the writer presents the accompanying flow-sheet and supporting comments. While he has not the temerity to maintain that it is the best or only flow-sheet for Nova Scotia gold ores, he feels that it warrants thoughtful consideration by members of the milling fraternity of the Province. THE ORE The gold in Nova Scotia ores occurs both free and intimately associated with sulphides-chiefly arsenopyrite. Much of the free gold is quite coarse and crystalline. This is especially true when it occurs in white quartz. When in the slate, it is usually in thin plates and scales, frequently coated and discoloured. The values bound up in the sulphides are not amenable to amalgamation and must be recovered by other methods-concentration, followed by smelting or fine grinding and cyanidation. While high freight and treatment charges apply on concentrates shipped from the Province to smelters, a considerable quantity has been so disposed of in the past. However, it is hoped that a customs cyanidation plant will soon become available to producers of these auriferous concentrates in Nova Scotia.

Jan 1, 1938

Operating CIP/CIL gold recovery plants in the arid regions of Western Australia face unique challenges due to water and ore quality issues. The presence of cations of Mg, Fe and Cu metals in water supplies and leached sulphide ores can have considerable effect on plant consumption of lime and cyanide, due to pH buffering and complexation effects. Reagent costs are critical to many of these operations. In this paper, computational modelling is used to analyse a number of process options to mitigate such issues. This requires careful consideration of the chemistry of the process system, and the ability to predict accurately the response of speciation and precipitation reactions to changing process conditions. The Mg-Fe-Cu-CN-H20 system is specifically modelled in this application. The Gibbs Free Energy Minimisation thermodynamic framework has been selected to model equilibrium phenomena. Furthermore, this approach has been extended to the process flowsheet level, incorporating multiple unit operations and recycle streams in a steady-state mass balance model. The Gibbs equilibrium composition module of HSC Chemistry software has been successfully integrated into the commercial flowsheeting package SysCAD. Consideration of the Gibbs Energy Minimisation capabilities of other flowsheeting packages has also been given. This approach has been successful in simulating the aqueous process chemistry typical of such plants. It has resulted in a predictive capability where equilibrium states respond appropriately to process changes. Potential cost savings may be identified by examining alternative process conditions to minimise overall reagent consumption.This methodology may be extended to other hydrometallurgical plants where issues of solution ideality, temperature and other equilibrium processes are sufficiently understood.

Jan 1, 2005

By Z. Lin, M. Isac, R. I. L. Guthrie

The kinetic and thermodynamic efficiencies of chromium recovery from the slag in an AOD process during the slag de-oxidation period with ferrosilicon is a complex process affected by slag basicity, temperature, the dissolution kinetics of the reducing agents, and intermixing of the slag/metal/alloy addition phases within the vessel. The present work focused on a study and simulation of the fluid dynamics and mixing behaviour of ferrosilicon additions in the AOD process for the production of stainless steel. In order to visualize the mixing behaviour, a two dimensional slice model of an AOD vessel was first built and filled with ZnCl2solution and then covered with silicone oil in order to represent the bulk liquid steel and slag phases, respectively. The injection of argon/oxygen process gases was simulated using air or helium. Particle trajectories and intermixing of the phases was monitored with a high-speed camera. To simulate the 75FeSi additions, glass spheres were used. A three-dimensional version of the AOD model was then constructed in order to confirm the adequacy of the slice model. Similar particle mixing behaviour was observed. Both models demonstrated that the ascending gas/liquid plume created two asymmetric mixing zones: a smaller rapidly re-circulating mixing zone adjacent to the side-wall locating the tuyere(s), and a larger mixing zone in the main part of the vessel. The process efficiency during the reduction period is governed by the thermal behaviour of ferroalloy as well as the mixing efficiency in the main large mixing zone. To enhance the recovery efficiency for chromium, small Fe-Si particles are suggested, given their wide distribution within the slag phase, and their large interfacial areas and rapid melting times for Cr2O3reduction from the slag. Keywords; modelling, ferrosilicon, chromium oxidation, AOD steelmaking.

Jan 1, 2004

By K. Muehlenbachs, J. U. Stemler

"Abstract - The Boston deposit is a recently discovered Archean lode-gold deposit located approximately 700 km northeast of Yellowknife, in the southern portion of the Hope Bay volcanic belt. Primary H2O-CO2-NaCl fluid inclusions associated with gold mineralization at Boston are of low salinity (4.6 ± 1.4 eq. wt.% NaCl, n = 182) and contain pure CO2. Homogenization temperatures of liquid-phase inclusions average 270° ± 33°C (n = 141), but some fluid inclusion assemblages contain coexisting liquid- and vapor-phase inclusions that homogenize near critical conditions, suggesting phase separation. In these groups, liquid-phase inclusions homogenized at 299° ± 25°C (n = 24), and vapor-phase inclusions homogenized at 338° ± 28°C (n = 18). These temperatures overlap within error, and a median temperature of ~320°C is taken as representative of trapping conditions within the veins. An approximate pressure of 2-3 kbar was estimated from fluid inclusion isochores at this temperature. Stable isotopic compositions of carbonate minerals from the mineralized zones range from -4.7‰ to -3.1‰ in d13C, and from 11.2‰ to 12.8‰ in d18O; quartz ranges from d18O = 12.8‰ to 14.9‰; and pyrite ranges from d34S = 2.1‰ to 3.5‰. The d18OH2O, d13CCO2, and d34SH2S values of the fluid calculated from these minerals at 320°C are 6‰-9‰, -2.4‰ ± 0.6‰, and 1.5‰ ± 0.5‰, respectively, and are intermediate between metamorphic and magmatic compositions. A unique source for the fluids cannot, therefore, be constrained from these data. Petrographic and geochemical data for the Boston deposit are consistent with data from other Archean lode-gold deposits worldwide, implying that the Boston deposit formed in a similar environment and from similar types of fluids. These results suggest that the Hope Bay volcanic belt may represent a major new mesothermal gold belt in this part of Nunavut. Sommaire - Le gîte Boston a été récemment découvert à environ 700 km au nord-est de Yellowknife dans la partie sud de la ceinture volcanique de Hope Bay, il s’agit d’un gîte d’or filonien d’âge Archéen. Les inclusions fluides primaires de H2O-CO2-NaCl associées à la minéralisation aurifère du gîte Boston présentent une faible salinité (4.6 ± 1.4 eq. pds.% NaCl, n = 182) et contiennent du CO2 pur. La température d’homogénéisation des inclusions à phase liquide est en moyenne de 270° ± 33°C (n = 141), mais certains assemblages d’inclusions contiennent des phases liquides et gazeuses coexistantes qui s’homogénéisent dans des conditions quasi critiques, suggérant qu’elles résultent d’une séparation de phase. Dans ces groupes, les inclusions de phase liquide s’homogénéisent à 299° ± 25°C (n = 24) et les inclusions de phase gazeuse s’homogénéisent à 338° ± 28°C (n = 18). Ces températures se recoupent à l’intérieur des limites de l'erreur de mesure, et nous considérons qu’une température médiane de ~320°C est représentative des conditions de piégeage dans ces veines. Les isochores permettent d’estimer une pression d’environ 2-3 kbar à cette température. La composition des isotopes stables des carbonates dans les zones minéralisées s’étend de -4.7‰ to -3.1‰ pour d13C et pour de 11.2‰ à 12.8‰ pour d18O; les valeurs de d18O pour le quartz varient de 12.8‰ à 14.9; et les valeurs de d34S dans la pyrite vont de 2.1‰ à 3.5‰. Les valeurs de d18OH2O, d13CCO2, et d34SH2S du fluide calculé à partir de ces minéraux à une température de 320°C est de 6-9‰, -2.4‰ ± 0.6‰, et 1.5‰ ± 0.5‰ respectivement, reflétant des conditions intermédiaires entre des compositions métamorphiques et magmatiques. Il n’est donc pas possible d’identifier une source unique pour ces fluides à partir de ces données. Les données pétrographiques et géochimiques du gîte Boston sont similaires à celles d’autres gîtes d’or filoniens ailleurs dans le monde, ce qui implique que le gîte Boston s’est formé dans un environnement similaire à partir des mêmes types de fluides. Ces résultats suggèrent que la ceinture volcanique de Hope"

Jan 1, 2006

By Pandey H. D.

The paper describes a fluidised bed ion exchange method for simultaneous removal of phenols and cyanide from the effluent. Use of an eluant enables regeneration of the resin in the continuous operation mode. The breakthrough experiments conducted both on the laboratory scale and on a pilot plant scale have shown that while the level of phenol can be brought down from 462 ppm to about 6 ppm, the free cyanide is almost totally removed. An examination of data indicates that the method can serve the twin objectives of pollution control and phenolic compounds recovery.

Jan 1, 1992