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By H. H. Fields

The Bureau of Mines conducted research to determine the effectiveness of long holes drilled in solid virgin coal in degasifying an area of the Pittsburgh coalbed showing that horizontal holes drilled into a virgin coalbed from the bottom of any shaft will effectively remove methane gas in commercial quantities from the Pittsburgh coalbed. The in situ pressure at a depth of 214 feet into the coalbed and the average gas and water flows from the five degasification holes were 3 lb/in2 gage and 860,000 ft3/d and 1.7 gal/min, respectively. On June 19, 1975, after 593 days of degasification, a compressor was installed and pipeline quality gas was introduced into a commercial pipeline. As of June 1, 1976, after 1,022 days of degasification, over 753 million cubic feet of gas had been drained and 117 million cubic feet of gas had been purchased by the gas company for use in the local community of Wadestown, W. Va. The gas drained to date is six times the gas estimated to be in the area subtended by the holes. Methane emissions at the working face of 1 West mains, Federal No.2 mine has been reduced by 50 pct, proving the value of methane drainage by horizontal degasification holes drilled from shaft bottoms ahead of mining.

Jan 1, 1976

By W. Beckering

In characterizing tars obtained by the low-temperature carbonization of North Dakota lignite, infrared spectra have been an invaluable aid in both qualitative and quantitative examination. Quite, early in the tar-research program of the Federal Bureau of Mines it became evident that the small number of published spectra available for hydroxy-aromatics would be inadequate for comparative purposes when dealing with the wide range of compounds present in coal tar; therefore, compiling a catalog of spectra was begun as a continuing part of the tar program. Because these spectra should be valuable to other investigators in this and related fields, they are being presented in these reports. This supplement to the original publications presents the spectra (figs, I to 32), representing 32 compounds, largely phenolic materials. The major problem of this project has been the availability of materials for examination. Most of the compounds included in this supplement were synthesized at the Bureau of Mines Lignite Research Laboratory. Some were obtained from commercial sources, whereas the compound 2'-hydroxy-l-phenylnaphthalene was synthesized at the Bureau of Mines laboratory in Bruceton, Pa. The spectrum of 2-ethyl-4-methylphenol, figure 32, is a correction of the spectrum presented as figure 26 in the original reports

Jan 1, 1961

By W. N. Marchant

The Bureau of Mines performed chemical research to elaborate details of sulfur chemistry pertaining to the citrate flue gas desulfurization process in which sulfur dioxide (SO2), absorbed (as bisulfite ion) in a buffered sodium citrate solution, is reduced by hydrogen sulfide (H2S) according to the overall reaction 2H2S + HSO3 + H+ ? 3S + 3H20. The rate-limiting step in the process was shown to be the reduction by H2S of thiosulfate (S2031-) that is formed as an intermediate. Pseudo first-order kinetic measurements were made at room temperature to retard the reaction sufficiently that adequate analysis was possible. These measurements showed the rates of the following net processes to be -d [S02]/dt (pH 4.5) = (0.409±0.050)min-1 [S02]; d [S2032-]/dt (pH 4.5) = (0.199±0.017)min-1 [S02]; -d [S2032-]/dt (pH 4.0) = (0.0437±0.0265)min-1 [S2032-]~1; -dH2S/dt (pH 3.9) = (21.6±3.0) mmoles/min-atm [H2S]g1.4, where [H2S]g is the partial pressure of H2S in the gas phase, in atmospheres, and the rate describes the consumption of H2S, in millimoles per minute; d[S]/dt (pH 4.0) = (38.0±3.4)min-1 [H2S]1, where [H2S] is the concentration of H2S in solution. Hydrogen ion consumption during the slow phase of regeneration was shown to occur at (2.1±0.5) times he rate of thiosulfate consumption, which is interpreted as evidence for the following as the rate-limiting reaction: 2H2S + S2032- + 2H+ ? 4S + 3H20 A scheme consisting of five sequential general reactions is proposed to account for sulfur formation.

Jan 1, 1981

By C. M. Frost

The hydrodesulfurization characteristics of a residual fuel prepared from Wilmington, Calif., crude oil were determined at temperatures from 600° to 900° F, pressures of 200 to 800 pSig, and space velocities from 0.2 to 2.0 Vo/Vc/hr, using cobalt molybdate type catalysts. A prediction equation, developed from the experimental data, satisfactorily predicts the fraction of total sulfur that can be removed under any combination of operating conditions within the ranges investigated. Yields and properties of the low sulfur product are correlated with the fraction of total sulfur removed. Kinetic calculations show that the apparent reaction order and activation energy change with space velocity and temperature.

Jan 1, 1970

By Edward L. McHugh

Twelve properties in the Riverside Mountains have moderate to high potential, for silver, gold, copper, and molybdenum. Six properties in the Big Maria Mountains have moderate potential for zinc, lead, copper, silver, iron ore, and limestone. The Big Maria Mountains also have occurrences of building stone. Four properties in or near the study area have low-grade gold-silver-copper resources totalling more than 300 thousand tons (270,000 t). An estimated 29 million tons (26 million t) of limestone and dolomite, and 620,000 long tons (630,000 t) of iron ore are in the Big Maria Mountains section of the study area. INTRODUCTION The Big Maria Mountains Wilderness Study Area covers about 50,538 acres (20,453 ha) near the Colorado River in eastern Riverside County, California (fig. 1). The study includes portions of both the Big Maria and Riverside Mountains. It lies north of Blythe, California and south of California Highway 62 in the Mojave Desert province of the California Desert Conservation Area. The study area consists of two mountain ranges surrounded mostly by broad alluvial slopes or bajadas. It extends for 25 mi (40 km) from the Riverside Mountains on the north, to the south end of the elongate Big Maria Mountains.

Jan 1, 1982

By R. L. Benner

A compound stability diagram was constructed by the Bureau of Mines for the Zn-Fe-S-O system to show the phases that should be thermodynamically stable at various temperatures, oxygen pressures, and SO2 pressures. The diagram was demonstrated to have good qualitative value for predicting stable phases that may, in turn, be related to the recovery of zinc in the leaching phase of the electrolytic zinc process. The study showed that roasting temperature is the most Significant variable in preventing roaster formation of zinc ferrite, which is directly related to subsequent extraction of zinc in the leaching step.

Jan 1, 1966

By C. J. Chindgren

Two air classification systems were built and tested as separatory devices for recovering the nonferrous metal values from shredded automotive nonmagnetic reject scrap. A horizontal air system with a capacity up to 16 tons per hour was used to obtain preliminary separations, and a smaller capacity vertical system was used as a cleaning device. Shredded automobile reject material containing aluminum, copper, and zinc values of about $55 per ton were air-classified in the horizontal elutriator. Ninety-six percent of the metal was recovered in a 74-percent metal concentrate. Tandem operation of both classifiers recovered 92 percent of the metal in an 80-percent concentrate while rejecting 87 percent of the nonmetallics. Heavy media separation of the air-classified concentrate produced an overall recovery of 91 percent of the metal in the form of a 99-percent metal concentrate.

Jan 1, 1971

By J. V. Batty

Various ores from deposits in the Boulder Dam Recreational Area, Clark County, Nev., were submitted for ore-dressing tests as part of the Bureau of Mines studies of western manganese ores. The Virgin River manganese deposit is situated on the Virgin River arm of Lake Mead, 5 miles from Bonelli's Point, which was formerly the junction of the Virgin and Colorado Rivers. It is 20 miles from Overton, Nev., and 26 miles from Boulder City, Nev. The ore body, composed of wadlike manganese in a tuffaceous gangue, is a flat-lying bed overlain with beds of gypsum and basalt. Two ore samples were submitted by engineers of the Bureau for ore-dressing investigation. Low-grade sample 1 was a composite of channel samples cut from outcrops of the ore body; sample 2, of intermediate manganese grade, was taken from the dump-at the exploratory shaft sunk by the Bureau. The Boulder City manganese deposit is situated in the Boulder Dam Recreational Area -3 miles southwest of Boulder City. The ore body is a manganiferous gypsum bed 32 feet thick, slightly inclined from the horizontal. The ore sample submitted-by engineers of the Bureau for-testing was taken from channel cuts in the walls of the shaft, which cuts through the bed vertically.

Jan 1, 1948

By A. J. Kraemer

This report on the physical and chemical properties of typical crude oils of California is the eighth in a series which will cover the producing districts of the United States, and is supplementary to Serial 2595 of the Bureau of Mines, which includes discussion of results, summary tables, and selected typical analyses of California crudes. The present report contains additional individual analyses of crude, oils from the fields of Fresno, Kern, Los Angeles, Orange, and Ventura Counties.

Jan 1, 1924

By Loren R. Anderson

This is an Appendix of Volume I. It contains the results of the electric cone penetrometer soundings from the first phase of the testing program.

Jan 1, 1982

Since its creation in 1910, the Department of the Interior's Bureau of Mines has pioneered in the development of mineral technology, through research. From the very beginning, research on mine health and safety has been a dominating concern, and a responsibility that expanded markedly as a result of the Coal Mine Health and Safety Act of 1969. Until the mid-1970's research on fuel technology and coal production also was an important part of the Bureau's work. But in the four years following the 1973 oil crisis, Congress established a reorganized Federal energy research apparatus in which all fossil fuel research-encompassing extraction, use, and conservation-was centralized. Today, the Department of Energy houses Federal research on coal mine production technology, while research on coal and noncoal mine health and safety and environmental technology, and on noncoal mine production technology, remains in the Interior Department as a continuing responsibility of the Bureau of Mines. In carrying out its authorized research programs, the Bureau conducts both short- and long-term re-

Jan 1, 2012

By Y. Miron

'This report presents a U.S. Bureau of Mines study to identify the causes of self-heating events beneath the floor of a deep underground coal mine. Mine samples from both heated and unheated areas were examined by various techniques, including visual, microscopic, thermal, chemical, and instrumental tests. The combined results led to the conclusion that pyrite (FeS2) oxidation was the prime cause of the beatings. However, adiabatic oven tests of selected samples did not indicate the effect of the pyrite on the self-heating process, probably because of the experimental conditions. A fast, simple procedure to assess the concentration of pyrite in the mine samples was developed, g the reactivity of the sample with an aqueous solution of hydrogen peroxide (H2O2).

Jan 1, 2010

By J. B. Littlefield

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Jan 1, 1938

By J. B. Littlefield

[A rulp has i~c+:r. ilrsi i,nsd Lo O~JPY:L~ e the mid~ol Llf;pin.5cr rll~!-t-.cxny)lin:: apparatus recently c',ov~-lo.pe;t by tL1e '.liro:ul of !dines- For th-is pilryoac, a po?.-iti~rs-nct.i?~. pvrni? t:,.;~t v:i.l.'l. :.-,,- #?,n c-noot'fl ;L flow nc possiY,].c? is dcni?.oYle. Flota.lS:r vnnc\-t:rre 1jl:~l~l: zrt iln~;xtJsY:or (2s thc:; n1lr.t ke tvrned at h ityh spet.d for rT:oot,c, o;?ey,;ltiori., ~nd at hi:,h s~ee(' the c8n:xcity oi' the s-n:r.llest piqt ott:~ir?:zk?e Is too la~-~:c. nir crrn'rle bler! in nt the intn?~, but t,he mm;nt o nor.;: l.o'q7r ir.:,l soon t ire:. the oyernt or, ]

Jan 1, 1938

By C. R. Nisewanger, F. W. Brown

"The velocity of detonation of an explosive is one of its most important properties, because its performance depends markedly on the rate at which it releases its energy. Fortunately, the velocity of detonation is one of the few properties of an explosive that can be measured precisely. However, the velocity of detonation of an explosive may depend on several factors other than its chemical composition, such as density, physical state, degree of confinement, nature of confinement, and magnitude of initiating impulse. Presumably for an explosive of fixed chemical and physical properties there are certain limiting conditions of confinement and initiation under which the explosive will detonate at a maximum constant and uniform velocity. This velocity is its ""ideal"" velocity of detonation. It is obvious, however, that in order to evaluate performance properties of an explosive in all of its applications it may be necessary to measure its velocity of detonation under a number of conditions in which the velocity of detonation is far from the maximum ""ideal"" velocity.. Under certain-conditions the velocity of detonation may even,be,different at different points in the explosive.It is .relatively simple to determine the velocity of detonation of an explosive under a. standard set of conditions if one is free to use large quantities of the explosive and to form it into a convenient shape. Under these circumstances; one can use a thin column of explosive a meter or more in length. The time required for an explosion to travel the length of the column will not be less,of the order a few ten-thousandths of a second and can be readily and accurately measured .by means of the standard spark chronograph or by photographing the explosion with a rotating-drum camera. However in many applications the explosive charge may be of relatively small dimensions arid may not be in a form convenient for making velocity measurements and often may be enclosed in a case or other confining medium. It may be necessary to determine the velocity of detonation over distances of the order of a few centimeters, in which case the time intervals to be measured will be extremely small. For example, the time required for an explosion to traverse 1 centimeter of tetryl is of the order of 1.5 microseconds.Since no satisfactory method of determining time intervals of the order of magnitude of a few microseconds within an explosive charge was available,, at least not for all conditions that might be encountered in practice, it was necessary to develop a special electronic chronoscope which is capable of measuring time intervals as small as a microsecond with a fair degree of accuracy. This report describes the chronoscope and its application to measurements of velocities of detonation in explosives."

Mar 1, 1946

By W. H. Tomlinson

Although the thoughts and efforts of the great majority of people in many parts of the world are today directed toward killing each other, the purpose of this paper is to discuss means of conserving human life. In a world of turmoil and strife, we find time to discuss and make plans to achieve our objective -prevention of the "sacrifice" of life through avoidable accidents. The word" sacrifice" is used here advisedly, as one meaning of the word given in the 1942 edition of Funk and Wagnalls New Dictionary of the English Language is "the act of giving up some desired or valued object for the sake of *** future good." As everyone agrees that life is man's most priceless possession, one wonders if past sacrifices have been in vain. It appears that life is cheap in America; it is cheap because some of the industrialists are too much concerned with making a profit to devote much time and thought to conserving human life; it is cheap because some labor leaders apparently are interested solely in personal power and prestige; it is cheap because a great many workmen fail or refuse to cooperate energetically with the various organizations interested ill; their safety and welfare; it is of little value because, individually and collectively, we are indifferent to our responsibilities toward our fellow men.

Jan 1, 1944

By H. H. Schrenk, W. P. Yant, P. H. Mautz

"In a study of the chemistry and pathology of chronic benzene poisoning, which was conducted cooperatively by the United. States Bureau of Mines, the Barrett Co., and the producers of benzene, it was necessary to make quantitative determinatious of the abzorption, distribution, and: fate of benzene in the organism. Although methods for determining benzene in relatively large amounts were available no satisfactory method was found for removing and determining the small amounts that are present in the tissues or excretions after exposure to conditions which ultimately cause chronic poisoning. This no doubt accounts for the lack of information in the literature on this particular phase of benzene poisoning.The writers have found in work that will be described in a subsequent publication that the amounts of benzene present in the tissues and excretions under conditions of exposure which produce chronic benzene poisoning arc of the order of a fraction to a few milligrams per 100 grams of tissue. This report describes a method developed and found satisfactory for these determina¬tions.RÉSUMÉ OF PERVIOUS METHODSA method for the determination of benzene in tissue was developed by Joachimoglu. 5 In the Joachimoglu procedure the ground organs are mixed with water and acidified with diluted sulphuzic acid, and the benzene is distilled into a receiver containing carbon tetrachloride. The benzene is nitrated in the carbon tetrachloride, the carbon tetrachloride evaporated, the acid mix¬ture neutralized, and the dinitrobenzene extracted with ether. After removal of the ether the dinitrobeuzene is determined gravimetrically. Joachimoglu reports that this method is about 55 to 60 percent quantitative."

Aug 1, 1935

By Henry M. Harris, John E. Kelley, Thomas D. Roberts

A penetrometer apparatus for measuring viscosity of glass at temperatures up to 1,450 ° C was developed for use in establishing the viscosity coefficients required for high- temperature forming of ceramic materials . The major advantage of the method is that it can be used with samples of almost any shape or size without the necessity of forming or measuring shapes to close dimensional tolerances . Also , it has proved accurate in the range of 106 to 109 poises , a gap between the normal limits of other methods . The device , which operates on a single penetrometer principle , was used to determine the absolute viscosity coefficient of substances in centimeter - gram- second units of poises instead of relative penetration - rate units as with other penetrometers . Penetration of the viscous sample was sensed with a linear , variable differential transformer . The output of this transformer was recorded versus time , and the penetration rate was used in calculating the viscosity coefficient . The general equation relating penetration rate and viscosity coefficient was found to be 11 = F ( ln L/a 0.72 ) 2 π UL · where is the viscosity coefficient in poises , F is the penetrator load in dynes , L is the penetration depth in centimeters, a is the penetrator radius in centimeters and U is the penetration rate in centimeters per second . The penetrometer was tested using a standard viscosity sample of sodalime - silica glass obtained from the National Bureau of Standards ( NBS ) . Values obtained at several temperatures all agreed within 10 percent with comparable data calculated from the Fulcher equation derived by NBS for this glass . Equivalent accuracy was obtained with other glasses used to evaluate the apparatus .

Jan 1, 1964

By John Jordan, Tesarik, Steven J. Knoll, Theodore J. Williams, David K. Denton, Douglas F. Scott

Highly stressed rock in stopes continues to be a primary safety risk for miners in underground mines because this condition can result in failures of ground that lead to both injuries and death. Personnel from the Spokane Research Laboratory of the National Institute for Occupational Safety and Health studied two methods for identifying stress in rock. A seismic tomographic survey, finite-difference analysis, laboratory measurements of compression wave (ultrasonic) velocities in rock cores, and site geology were integrated to evaluate the use of seismic tomography for identifying induced pressures in an underground pillar at the Edgar Mine, Idaho Springs, CO. Electromagnetic (EM) emissions were also investigated in the Galena Mine, a deep underground mine in Idaho, in an effort to determine if these emissions could be used as indicators of impending catastrophic ground failure. Results of this research indicated that (1) seismic tomography appears to be a useful tool for determining relative stress in underground pillars, while (2) EM emissions do not appear to be significant precursors of impending catastrophic ground failure.

Jan 1, 2004

By Gary P. Sames

The Bureau of Mines recently initiated a study of geologic features that contribute to roof instability in western U.S. underground coal mines. The purpose of the study is to provide information for use in ground control planning and safety hazard reduction in that region, where mining activity has been increasing. Hazardous geologic conditions were surveyed in selected underground coal mines in Utah and Colorado, and both depositional and structural features were identified as potential ground hazards. Although the conditions found do not differ in kind from hazardous geologic conditions in the Eastern United States, they do differ in intensity of occurrence and relative importance. Three depositional features dominate where unstable roof occurs in western underground coal mines: paleochannel deposits, crevasse splay deposits, and flood basin deposits. Three structural features identified as hazardous, but not so widespread or common as the depositional hazards, are faulting, jointing, and igneous intrusions. This survey establishes a foundation for future studies aimed at reducing and preventing ground control accidents in western coal mines.

Jan 1, 1988