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By Jorge Blanco, Joaquin Gotor, Enrique Delgado, Carlos Frias

Since 2009 Cobre las Cruces (CLC) has successfully operated a sustainable mining business near Seville, Spain, applying the most advanced hydrometallurgical technologies to process secondary copper sulphide ores through atmospheric leaching in ferric sulphate media and using oxygen sparging in a cascade of ten reactors. In comparison to conventional copper smelters, the CLC hydrometallurgical process does not generate SO2 gas, airborne emissions or slags. The copper ore is ground and sent directly to atmospheric leaching reactors; flotation is not required, and consequently, copper extraction is maximized at 93-95%, while producing 72,000 t/y copper cathodes of the highest purity (99.999 wt.% Cu, Grade A). Reserves for the CLC deposit were estimated at 16 million tonnes of ore averaging over 6 wt.% Cu and containing principally a chalcocite mineralization. Other copper bearing species include digenite, covellite, chalcopyrite, bornite and enargite. Pyrite represents over 70 wt.% of the ore. In the CLC leaching process, chalcocite reacts with ferric sulphate at approximately 90 ºC and copper is released into solution while ferric ions are reduced to ferrous ions. The ferric sulphate leachant is regenerated continuously by oxygen injection and consumes sulphuric acid. It is remarked that pyrite plays a crucial role to yield high copper leaching rates. When pyrite is oxidized, a small proportion of iron is co-leached and some sulphuric acid is generated. The CLC leaching technology has been designed to allow a certain level of pyrite oxidation, which is positive in many ways: (i) to maintain a Fe/Cu ratio in solution; (ii) to facilitate Fe(II) oxidation; (iii) to produce a high redox potential; and (iv) to counterbalance a bleed solution that removes some iron. Moreover, galvanic interaction between pyrite (cathode) and chalcocite (anode) can substantially increase atmospheric leaching kinetics and efficiency (copper recovery).

Jan 1, 2016

By G. Labonté, J. Truskoski, A. Kerr, A. Bouchard, J. Barrett

"Improving mill grade recovery relationships is always good business. Inco’s Clarabelle mill has just undergone a $16 M process upgrade that was designed to improve nickel recovery by 2%. The “Mill Redesign Project” was completed on time, under budget and delivered the promised improvement in recoveries.This paper describes the methodology of the Mill Redesign Project team, details of the process improvements and the critical success factors that helped the team deliver on its promises.With a payback of under one year, the Mill Redesign Project will play a key role in ensuring a competitive edge as Inco embarks on its second century of operation. IntroductionIt is not uncommon in milling operations to encounter a crisis. That is the point when the process does not behave as expected and fails to respond to the increasingly desperate efforts of the metallurgists and operators. Flowsheet and process changes are attempted and abandoned. With luck, one or more of the changes achieves some mitigation of the original problem or more usually, the original cause of the problem disappears. Regardless, the metallurgist can sit back and bask in the apparent success of his or her endeavours.Less common is when a problem is carefully diagnosed, a team put together to explore all avenues and recommend a path of action that is implemented on time, on budget and immediately delivers on the promises which are sustained over time. This is one such story. It is the story of the Mill Redesign Project at Inco’s Clarabelle mill in Copper Cliff, Ontario."

Jan 1, 2003

By E. Poiate, P. A. L. P. Firme, D. Roehl, M. A. Carrion, A. M. Costa

Drilling high-pressure/high-temperature wells in salt rock formations is still a challenge for the energy industry. Creep and solubility is part of the salt rock physical-chemical behaviour, which must be considered in the design of the wells. The stress redistribution caused by drilling, in addition to thermallyactivated processes, triggers creep deformation, leading to borehole closure and the imposition of loads on the casing. The drilling fluid is designed by computer modeling in order to control the creep strain rate to a limit which allows the drilling operations and the casing setting. Depending upon the composition of the drilling fluid, chemical reactions on the salt wall may occur, especially in case of water-based fluids in highly soluble salt rocks. In those cases, cavities by dissolution (washouts) can be generated and the casing column remains uncovered by the cementation and laterally unconfined along the cavity length. This scenario is propitious to the loss of integrity of the casing due to phenomena such as plastic collapse, buckling and non-uniform loading on the casing provoked by the closure of salt formation around it. The casing should remain intact during the wellbore life-time. In this work, a section of a typical well crossing salt formation composed by halite and carnallite is considered. An idealized-cylindrical washout cavity inside a highly soluble salt layer is assumed. The purpose here is to evaluate the effect of the dimensions of the cavity on the integrity of the casing. Several typical diameters and lengths of the cavity are adopted. Numerical analyses are carried out with an in-house finite-element system composed by the pre-processor MTOOL 3D®, the simulator ANVEC 3D® and the post-processor POS 3D®. Salt rocks are modeled as visco-elastic materials. Creep is simulated by the Double Mechanism Creep Law, widely employed in Brazilian salt rock mechanics research. Cement and casing (steel) are modeled as elasto-plastic materials described by the Mohr-Coulomb and the von Mises criteria, respectively. Casing integrity is evaluated with respect to vertical and horizontal displacements. Vertical displacements imposed to the casing can provoke the failure of the column by plastic collapse or by buckling. Besides that, horizontal displacements of salt due to creep closure shall lead to the undesirable contact with the casing. Failure envelopes based on displacements are generated. The results of the simulations have shown that the casing failure by plastic collapse occurs preferentially in short columns, as well as buckling occurs in long and slender columns. The occurrence of both failure modes is more frequent in large-diameter cavities. Additionally, failure caused by contact between salt and casing occurs preferentially in short-diameter cavities.

Jan 1, 2015

By H. R. Manouchehri

"It is well understood that, apart from particle hydrophobicity, the flotation process is strongly influenced by the cell hydrodynamics. Once the chemical conditions were optimized and fixed, the flotation rate is essentially determined by impeller speed and the air flow rate.The collection efficiency in flotation is a product of collision, attachment and stability/detachment efficiencies. The collision efficiency for a given particle diameter is increased by decreasing the bubble size and bubble velocity as well as increasing the power input to the cell. The attachment efficiency, however, is defined by bubble size and its velocity. The detachment/stability depends on the relative magnitudes of the attachment force between the bubble and particles and the detachment force acting on the bubble-particle aggregates. For the particles having specific contact angle, the stability decreases as the energy input increases. Therefore, there must be an optimum energy dissipation to maximize recover of defined size fraction.A comprehensive laboratory study was devoted to determine the effect of power input in recovery of finely grind Cu-Ni bearing ore. Several flotation tests were conducted to define the hydrodynamic parameters for a laboratory scale Runge cell under different impeller speeds. An increase in flotation recovery of finely ground ore was observed when the impeller speed was increased from 450 to 1,200 rpm. The experimental results have shown increasing in water recovery and improving in flotation kinetics of fines by increasing the power input to the flotation cell. Implementation of the Wark flotation model to the experimental data revealed a good correlation between the experimental data and the model. For the particles having enough hydrophobicity the flotation rate increases by increasing the impeller speed due to a higher value for collision efficiency within the cell."

Jan 1, 2016

By Peter Van-De-Velde

"The results of applying Japanese pumping technology to North American reclamation projects will be discussed.IntroductionEconomic high-density mineral reclamation and subsequent transportation of solids through a pipeline presents many formidable engineering problems.In North America where space has rarely been a facto r, industry has generally relied upon the traditional dumping of material into various waste ponds, etc . In Japan, where confined geographies and stringent environmental regulations are enforced, alternative solutions for disposal or reprocessing of waste material had to be found.High-density mineral reclamation system designed by theoretical formulas is almost impossible because solids composition, i.e. concentration, velocity, moisture content, solid size, etc. can only be controlled within a broad pumping range.Traditionally this has restricted dredging of material to relatively dilute slurries whereas it is usually preferred to reduce water usage with its associated power and reclamation costs to a minimum and reclaim as high a concentration as possible.At Toyo Pumps North America we recognized these pumping limitations and began to develop and manufacture a range of standard and auxiliary equipment that would exceed these technical restrictions."

Jan 1, 1985

By W. G. Hatch

Introduction Classified equipment originally installed in 1923 in the Britannia mill consisted of eighteen Model C Dorr Simplex classifiers, each in closed circuit with a pebble-mill. These machines were only three feet wide and of light construction, so that their raking capacities were necessarily limited, the maximum being about 20 tons per hour for each classifier. On conversion from pebble-mills to ball-mills, in 1924, attempts to increase circulating loads with higher rake speeds resulted only in overflowing a coarser product to the flotation cells. The elevator type of classifier was developed locally in 1935 and during that year two units, each having a sand carrying capacity of from 30 to 40 tons per hour, were installed. With such loads, a material increase in the grinding capacities of the ball-mills was noticed, and, after further development work on the elevator classifier, fifteen of the small Dorr classifiers were replaced by units of this type, capable of handling approximately 75 tons of sand per hour, with later alterations increasing this capacity to well over 100 tons per hour. In the meantime, the three remaining ball-mills had been placed in circuit with Dorr FX classifiers, one of which was six feet wide and the others five feet wide. Impartial and exhaustive tests conducted on the Dorr FX versus the elevator classifier showed the average results on these machines at Britannia to be substantially the same. A large amount of testing was carried on to determine the effect of circulating load on the output of the grinding units. This work indicated a rapid increase in the grinding rate as the ball-mill feed increased up to about 60 tons per hour, after which a relatively slow increase took place up to 100 tons per hour. No benefits were derived from higher circulating loads. A 300 to 500 per cent circulating load, depending on the nature of the ore treated, is considered to be within the economical range for the grinding of Britannia ores.

Jan 1, 1946

The article presents an outline of methods and certain results of laboratory tests, underground tests and model tests, aimed at assessing performance of a powered shield support on the floor of low strength parameters. The tests were conducted within the framework of GEOSOFT project co financed by Research Fund for Coal and Steel (RFCR-CT-2010-00001). The described research works were conducted by Central Mining Institute (Glówny Instytut Górnictwa), Janina coal mine and Becker-Warkop

Aug 1, 2013

By Yan Qun, Chen Xiao-ming, Ma Pei-long, Luo Xian-ping, Luo Cai-gui, Feng Bo

The effect of leach promoting reagent LPF on the leaching process of a weathered crust elution-deposited rare earth ore has been investigated and the mechanism is discussed. The result shows that the leach promoting reagent LPF can enhance the leaching extraction of rare earth ore effectively. With the addition of LPF to the lixiviant at a concentration of 0.1%, the leaching extraction increased by more than 8%, the ammonium sulfate concentration could be decreased by 25%, and the leaching liquid/solid ratio reduced by 34%. The mechanism analysis shows that LPF can react with rare earth ions and form soluble coordination compounds, thus reducing the activity of the leached rare earth ions, increasing the concentration difference for ion diffusion, and promoting the rare earth leaching process. These results will hopefully help point to a new approach to making the leaching process of low-grade weathered crust elution-deposited rare earth ore more efficient and with lower lixiviant consumption.

Jan 1, 2014

By D. H. Whiting, A. J. Sinclair

"The San Antonio gold mine, in the Archean Rice Lake Greenstone Belt, was in continuous production from 1932 to 1968, during which period the mine yielded 1.35 million ounces (41 985 kg) of gold and 195,000 ounces (6065 kg) of silver from 4.88 million tons (4.44 Mt) of ore for average grades of 0.28 ounces per ton (9.0 g/t) gold and 0.04 ounces per ton (1.3 g/t) silver. After the 1968 closure, several publications appeared implying that gold grade of ore decreased with increasing depth.Recent observations by the authors show that the relatively low grades in the middle levels of the mine are controlled geologically. However, the reduced average are grade in the lower levels of the mine was due to inadequate mining control that led to a high level of dilution. The similarity of geological factors such as vein styles within structural domains, variations in mining control, recent ore muck sampling results and lithogeo chemical profiles all indicate the similarity of ore in both upper and lower levels.Strict mining control should yield improved grades of gold for future production from the lower levels at San Antonio, in contrast with the production grades of the late 19605that represented extensively diluted ore. High-quality production records are an essential component in re-evaluating a past producer, particularly where workings are accessible. Poorly founded conclusions which cannot be checked by access to workings can have a negative impact on the evaluation procedure."

Jan 1, 1990

By Henry Smith, Stu Brown

"The Williams Mine is Canada's largest gold producer, with annual production of some 500 000 ounces of gold from two million tonnes of ore. Highly mechanized and automated underground mining practices are utilized at the property in order to help achieve high levels of productivity and the most cost-effective mining possible.Planning and design parameters for the underground ore handling system at the Williams Mine are described in this paper. Particular reference is made to the considerations that were built into the system to provide maximum operating flexibility through the use of multiple orepass systems, portable low profile jaw crushers, underground conveyors and automated hoisting equipment.IntroductionThe Williams Mine is situated in the Hernlo area of northwestern Ontario, approximately 40 Ian east of the town of Marathon (Fig. I). It is operated by the Williams Operating Corporation, which is owned equally by Teck Corporation and Corona Corporation, and is one of three adjacent properties forming the HernIo gold camp.The mine commenced operation in October 1985 at a nominal production rate of 3000 tpcd. Through an ongoing capital development program, winch was completed in late 1989, the production rate at the property was increased to its current level of 6000 tpcd. This paper describes the mine planning process and the evolution of current mining strategies with particular reference to the underground ore handling system .HistoryGold mineralization was discovered in 1944 in the Hemlo area of Northern Ontario, near the north shore of Lake Superior. A year later, 11 claims were staked over the showing and subsequently patented by the late Dr. Jack Kerr Williams.Over the next 35 years, other claims were subsequently staked, explored and abandoned in the immediate area of the 11 patented claims . In 1980 a predecessor of the Corona Corporation acquired claims adjoining the Williams property to the east. Drilling on this claim group started early in 1981 and intersected the Hemlo orebody in May of that year. In December 1981, Corona Corporation entered into an option agreement with Teck Corporation to explore and develop the property.A drilling program by LAC Minerals on the II patented claims discovered the Williams orebody in March 1982. The mine started production in 1985, pouring its first official bar of gold on December 6 of that year. Corona Corporation was awarded ownership of the Williams Mine conclusively by a decision of the Supreme Court of Canada on August 11, 1989. The court's ruling ended a legal dispute with LAC Minerals over the property initiated eight years earlier."

Jan 1, 1991

By Alok Porwal, E. J. M. Carranza, M. Hale

Abstract- Approaches to mineral potential mapping based on weights of evidence generally use binary maps, whereas, real-world geospatial data are mostly multi-class in nature. The consequent reclassification of multi-class maps into binary maps is a simplification that might result in a loss of information. This paper describes results of using multi-class evidential maps in an extended weights-of-evidence model vis-à-vis results of using binary evidential maps in a simple-weights-ofevidence model. The study area in the south-central part of Aravalli province (western India) hosts a number of SEDEX-type base metal deposits in Proterozoic supracrustal rocks. Recognition criteria for base metal deposits were represented as both multi-class and binary evidential maps. The known mineral deposits were divided into two subsets, viz., the training and the validation subsets. The training subset was used to calculate, for the evidential maps, the weights, contrasts, and posterior probabilities and their variances. The distributions of expected frequencies of base metal deposits estimated from the posterior probabilities and the observed frequencies were compared using standard goodness-of-fit tests to verify conditional independence of the input evidential maps. The posterior probabilities from both the models were mapped and interpreted to classify the study area into zones favorable, permissive, and non-permissive for base metal deposit occurrence. As compared to the simple weights-of-evidence model, the extended weights-of-evidence model results in more robust and finely differentiated posterior probabilities in favorable and permissive zones and has a better prediction rate. The results also reveal that the statistical properties of the weights of evidence, the contrasts, and the posterior probabilities are not significantly degenerated by using multi-class evidential maps in weights-of-evidence modelling.

Jan 1, 2001

By L. Fernandes

A two level factorial study was undertaken to investigate the relative impacts of factors affecting the kinetics of polytetrafluoroethylene, PTFE, assisted pressure oxidation of chalcopyrite. A copper flotation concentrate, principally composed of chalcopyrite, was leached in 850 mL of leach solution under conditions similar to those of the CESL process. The factors manipulated were: the amount of 1/8" PTFE beads added (100 g or 650 g), oxygen pressure (690 kPa or 1030 kPa), and concentrate addition (10 grams or 65 grams). Copper extraction data, which indicated complete leaching under certain conditions, were fit using a shrinking core model from which rate constants were estimated and further used to generate a statistical model containing only the factors of significance and their interactions. Results indicated a strong positive effect of PTFE addition and a strong negative effect of increasing pulp density. A weak negative interaction between increasing PTFE addition and pulp density was attributed to PTFE/concentrate agglomeration.

Jan 1, 2014

By P. W. A. Mayer

"As the push toward the northern regions of Canada steadily increases to exploit the rich mineral reserves, interest is steadily rising in respect to accessibility and climatic conditions and the problems posed thereby. In twelve years of operation, the Iron Ore Company of Canada, and associated companies, have found, through advanced technology, ingenuity and, most of all. need, some of the answers to the running of a profitable year-round open-pit mining operation."

Jan 1, 1966

By G. Diaz

Técnicas Reunidas (TR) has been involved for over 30 years in the development of process technologies for the recovery of zinc from different primary and secondary feed materials, such as the ZINCEXTM process. Because of the complexity of the feed mineral resources, solvent extraction (SX) is an invaluable technique to concentrate and purify zinc solutions. When applied to a pregnant leach solution, solvent extraction can produce an extremely high quality zinc electrolyte, suitable for obtaining SHG zinc ingots, after electrowinning and melting and casting processes. However, the high affinity of most organic extractants for Fe(III) poses a serious problem, which may adversely affect the zinc extraction process. Different methods may be applied to deal with the negative effect caused by Fe(III). An acid regeneration step and electro-reduction stripping have been considered as the most viable techniques to remove the iron from the organic phase. This paper describes some findings of Técnicas Reunidas in the area of zinc solvent extraction, especially on removing Fe(III) from the organic phase.

Jan 1, 2006

By J. H. Rickard, D. H. Watkinson

"Abstract - Detailed petrographic and quantitative (electron microprobe, SEM-EDS) mineralchemical analyses of sulfide ore from the 100 orebody at the Copper Cliff North mine, Copper Cliff, Ontario, reveal numerous stages of ore development. Sharp contacts between weakly mineralized quartz diorite and blebby to massive sulfides indicate multiple intrusive events within the Copper Cliff offset dike. A spatial association of sulfides and hydrous minerals, such as amphibole, biotite, chlorite and epidote, suggests that most primary ore has been affected by later hydrothermal fluids. Sulfides are often enclosed or bordered by these secondary silicate phases. The ore consists primarily of pyrrhotite, pentlandite, chalcopyrite, with trace michenerite, cobaltite/gersdorffite, irarsite, hessite, tsumoite, and bismuth tellurides.Geological and petrological comparison of the 100 orebody and the adjacent 900 and 890 orebodies has revealed distinct similarities in ore distribution. Data show that the 100 orebody is depleted in platinum-group elements (PGE) relative to the 900 orebody. Platinum-group elements from the 100 orebody may have been hydrothermally remobilized and partly emplaced in the 900 orebody, in adjacent veins, or in magmatic breccia. Analysis of Cu, Ni, and PGE assay data of ore samples has characterized their distribution among the eight different ore textures in the orebody. There is a strong association between Pt and interstitial sulfide, and to a lesser extent massive sulfide, but little correlation between chalcopyrite-rich ore and PGE in the 100 orebody, unlike many other deposits in the Sudbury region."

Jan 1, 2001

By P. M. Dranchuk

"SINCE their inception, the mineral industries have, from time to time, been confronted by various and sundry problems. These have been identified, attacked and solved by means of a slow methodical process peculiar to these industries. During the past decade, these industries have experienced increasing difficulty in attracting and retaining an adequate supply of manpower. This poses a situation which seems to be unlike those that came before it in that it appears to be immune to those methods of attack which were successful in the past. Despite various attacks upon the problem, its seriousness appears to be increasing at an increasing rate. The point has now been reached where the President of AIME recently expressed the opinion that this is the most serious problem facing these industries at this time (1). Another observer has gone so far as to state, ""Given the motivation and the determination, the crisis in mineral education in Canada, can, in time be met. But it will take a generation if we Start DOW (2)"".Part of the difficulty arises out of the identification and assessment of the problem itself. For, although the manpower shortage has been developing over a fairly long period of time, there still appears to be no unanimity concerning its seriousness and the nature of the threat which it poses. Some observers continue to maintain that the current situation is not new at all, but is merely the reappearance of something old which is cyclic in nature. They observe that in the past there were numerous periods where the mineral industries encountered manpower shortages but that, in each instance, the situation eventually rectified itself. Furthermore, they draw attention to the fact that the current problem is not confined to the mineral industries but that in fact all industries are experiencing an increasing manpower shortage. They are therefore confident that if left alone the present problem will eventually disappear."

Jan 1, 1967

By G. R. Haiden, E. Henderson

"An LHD teleoperation and guidance system, developed at the Ontario Division of Inco Limited, has been demonstrated in operation at Copper Cliff North Mine (CCNM) since late September, 1993. The tests performed to date have evaluated the feasibility and production viability of multiple LHD operation, from surface by one operator.The systems technology required to accomplish this consists of an electronic monitoring and control package mounted on the LHD; a high bandwidth mining computer network capable of providing radio frequency coverage; and an operator control console which provides an operator workstation for multiple LHD operation.This paper discusses the systems required to accomplish the task of LHD teleoperation and guidance, the benefits of multiple machine operation and future research and development directions. IntroductionSince underground mining began, persolU1el have entered the mine workings to mine ore. Today, however, the rapid advancement of modem telecommunications, computer hardware and software technology has opened the door to remote mining technology that was considered unfeasible a few years ago. This paper discusses the ingredients of remote mining technology that have been developed at Inco Limited.Figure I represents an historical view of the application of electronics to LHD operation at Inco Limited. In 1980, the first radio remote controls for the operation of LI-IDs in large open stopes were tested. The successful application of this technology at Inco went hand-in-hand with the development and application of the Vertical Crater Retreat mining method. The combination of these two advances had a very positive effect on the productivity in the mid-eighties at Inco. In 1991, the Mines Research Department of the Ontario Division advanced remote control technology by developing a high capacity underground mining telecommunications system. This system is capable of moving voice, data and video information throughout the mine workings. The system is based on broadband communication technology found in most automated factories, with the added benefit of providing the information to and from mobile equipment through radio interfaces. The first test of the system consisted of an operator teleoperating a single LHD (on the 3000 ft level) from the surface. The next test on September 13, 1993, demonstrated the first production application of multiple LHDs being run from surface with a single operator."

Jan 1, 1994

By Serge Perreault

Le cuivre est un métal fascinant qui joue un rôle essentiel dans le développement des différentes civilisations depuis 7000 ans. Le cuivre est aussi un métal polyvalent et essentiel qui est très présent dans notre vie quotidienne. L’un des premiers métaux utilisés par les humains, il est un élément chimique qui se trouve à l’état natif, ce qui est rare pour les métaux. Il apparaît principalement dans des minéraux, notamment sous forme de sulfures, en raison de son caractère chalcophile (c’est-à-dire son attraction pour l’élément soufre). Le cuivre se trouve dans la croûte terrestre sous forme de minéraux de cuivre, tels que dans les sulfures dont la chalcopyrite, la bornite, la covellite et la chalcocite. Il est également présent sous sa forme native ou dans des minéraux oxydés comme la cuprite et dans des carbonates hydratés, comme la malachite et l’azurite. La formation de gisements de minerai de cuivre implique des processus géologiques complexes, notamment l’activité hydrothermale, les intrusions magmatiques et l’altération des roches. Les gisements de minerai de cuivre se trouvent dans divers types d’environnements géologiques, dont les gisements porphyriques, les gisements de cuivre encaissés dans des roches sédimentaires, les gisements de type skarn, les gisements de sulfures massifs volcanogènes, les gisements magmatiques de type nickel-cuivre, les gisements de cuivre oxydé, et d’autres [1].

May 2, 2024

By Erica J. Wanless, Ghislain Bournival, Seher Ata, Jose Hamilton Tavares

In froth flotation valuable particles are captured by bubbles and transferred to a froth layer where bubbles are in close proximity. Bubble coalescence frequently occurs in flotation, especially in the froth layer. The coalescence of two bubbles causes a release of energy, which may expel particles from the bubble surface. A series of experiments were carried out to determine the effect of bubble interfacial properties on the detachment of particles upon the coalescence of capillary-held bubbles of 2 mm in size. The interfacial properties of the bubbles were changed by the addition of low molecular weight alcohols, namely 1-pentanol or methyl isobutyl carbinol (MIBC). Using esterified glass particles (? = 43 °) with a 10 % and 90 % cumulative passing diameter of 47.2 and 92.5 µm, respectively, as model particles, it was found a certain concentration of frother, different for each additive, is needed in order to observe a reduction in the detachment of particles. In the presence of frother, the detachment was evaluated at approximately 65 % which was a considerable reduction in the detachment compared with the value of approximately 85 % found in the absence of frother. Frother molecules changed the properties of the airwater interface. Upon the coalescence of two bubbles, the release of energy caused the merged bubble to oscillate; effectively resulting in the detachment of particles. The addition of frothing agents augmented the elasticity of the bubbles, which appeared to be related to the detachment of particles. Whereas frothing agents are generally used to prevent bubble coalescence and stabilise the froth phase, only transient stability is imparted. The results suggested that an additional role of frothers in flotation is to decrease the detachment of particles from bubble surfaces. The type and concentration of frother can be strategically selected to improve metallurgical recovery as an economic incentive.

Jan 1, 2016

By J. Shibata, N. Murayama

"Rare earth elements are present in more than 100 minerals, of which monazite, bastnaesite and xenotime are typical. Rare earth elements have excellent chemical and physical properties for industrial use in functional materials such as phosphors, magnets, electronic components, abrasives and catalysts. China produces more than 90 % of the world’s rare earths, and Chinese trends significantly influence the demand and price of rare earths. From the viewpoint of resource securement, it is desirable to separate and recover rare earth elements from low-grade resources and wastes. Phosphate gypsum, which is a by-product of wet phosphoric acid manufacturing, contains low concentrations of rare earth elements. In this research, the separation and recovery of rare earth elements from phosphate gypsum were investigated. A series of recovery methods including washing of phosphate gypsum, leaching of the rare earth elements with sulfuric acid, adsorption and desorption of rare earth elements by using ion-exchange resin, and precipitation of rare earth oxalates were carried out. The separation of rare earth elements from Ca2+ simultaneously leached from phosphate gypsum was also investigated."

Jan 1, 2014