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By Yvon Trudeau, Deni Raymond

"The Orion gold mine, located 7 Ian northeast of the town of Malartic, Quebec, was discovered in mid-1985. Underground exploration was undertaken in 1986 leading to commercial production in 1988. The upper part of the orebody was exploited above the 125 m level and a total of 131 090 t at an average grade of 5.31 g/t gold were extracted.This paper describes the authors' current knowledge and interpretation of the geology, gold distribution, and structure of the Orion No.8 ore zone deposit. The deposit is an epigenetic lode gold occurrence somewhat unique in that both quartz-vein type and pyritic type of gold ore occur side-by-side. It is located within the Marban-Noriartic Deformation Corridor (MNDC) formed during a first deformation stage (D1) The MNDC is a well-defined regional structural feature in the Val d'Or - Malartic mining camp. Primary gold mineralization is associated with the D1 event and is represented by pyritized, silicified and brecciated basaltic lavas enclosed by ultramafic flow units. The ore zone is concordant with the MNDC. Felsic intrusions are spatially related with the ore zone, but their role in the genesis of the ore has yet to be dermed.A second deformation event (D2) resulted in local folding, a second schistosity (S2) and reverse faulting. Gold remobilization, the formation of the gold-bearing quartz breccia and the emplacement of the main quartz vein at the No. 8 zone deposit were associated with this event."

Jan 1, 1992

By C. R. Hocott

"IntroductionRESEARCH in petroleum production consists primarily in investigations related to the drilling for and recovery of oil. As an organized activity of individual oil companies, production research is now 30 to 35 years old, and the petroleum industry may point with justifiable pride to the achievements of this third of a •century. Emphasis on research has grown through the years until at the present time many of the larger companies operating in the United States •have well-organized production research staffs.In addition to the efforts of the oil companies, significant research and development in petroleum production technology have been performed by oilfield service companies and others. Valuable contributions have been made through fundamental research carried on by the U. S. Bureau of Mines and by various colleges and universities, both in their own programmes and in programmes sponsored by industry, such as those of the American Petroleum Institute. However, the total effort of these groups is small when compared to the sum of the effort devoted to research by the individual .oil companies. In contrast to some industries which conduct the major portion of their research through co-operative, sponsored research at universities or research institutions, research by the petroleum industry is done predominantly by individual company research staffs. These industrial research groups have usually been organized in such a way as to provide liaison and co-ordination with operating technical staffs. In this way, the research groups are kept aware of the major problems confronting the operating departments and, correspondingly, the operating technical people •are able to keep informed on research activity and progress. This type of close contact generally results in prompt testing of research developments in actual operations."

Jan 1, 1953

By W. H. MacLean

The Matagami district lies directly west of Chibougamau on the north side of the Abi tibi greens tone belt. Ores at Matagami are volcanogenic massive sulphides and occur in the dominantly rhyolitic Watson Lake group surrounding the Bell River Igneous Complex. Rhyolites and basalts of this group, and basalts of the overlying Wabassee group in the central part of the district, are tholeiitic; calc-alkaline Wabassee rocks occur in the western part. Massive sulphides occur associated with rhyolite domes that can be delineated by paleotopographic and isopach mapping. They are mainly distal deposits that formed over an extended period of time while several volcanic units were being deposited,

Jan 1, 1984

By Malcolm Black

Introduction Before beginning to write this paper, I decided that I should first find suitable definitions of the words Sample and Sampling. The dictionary gives: "Sample.-A portion indicative of the whole"; and according to Baillie (1), sampling is "That process whereby a representative and comparatively small portion of material is selected from a large bulk, and preserved under such conditions as shall prevent contamination or avoidable alteration, with a view to the formation of valid conclusions regarding the suitability of the bulk for specified purposes". These comprehensive definitions are alike in substance, and indicate that unless a truly representative portion is taken, it is not a sample. Ore 'as mined' generally varies a good deal in composition, and, in crushing, segregation takes place. Some of the minerals present, due to differences in hardness and friability, break into smaller pieces than others, and, on reaching the bin, the coarse particles roll away, leaving the fines behind. The result of this segregation is generally quite noticeable on the conveyor feeding the mill, especially when the bin is nearly empty and the crushing plant shut down. Should the sampling period synchronize with either the coarse or the fines, the sample obviously would not be representative. I agree that this is rather far fetched, but I maintain that such a condition is possible. Assuming that a representative sample may be procured from the feed conveyor, the method of cutting it down for assay has considerable influence in maintaining the original condition of the sample. The finer the material is ground after each cut, the more uniform the sample will remain. To illustrate this point, let us take a quantity of fine sand and add, say, three grains of rice to represent metallic particles. We may mix this sample by any of the known methods, then cut it into four equal portions. It is obvious that at least one of the portions will be without a rice grain. But let us grind the three grains of rice into flour and proceed as before. Now there will be a much greater chance of including some of the rice in each portion.

Jan 1, 1935

By D. Chadwick, J. W. Matousek

Between 1860 and 1890 -- from the time of the American Civil War to the last decade of the 19th Century -- nickel production in North America was dominated (even monopolized) by the output of the industrial complex of the Gap Nickel Mine near Lancaster, Pennsylvania and the American Nickel Works in Camden, New Jersey. In some years, from one sixth to one third of the world's metallic nickel supply came from this enterprise. Mining and smelting were conducted at Lancaster; a matte of high iron content was shipped to Camden for pyrometallurgical and hydrometallurgical refining to produce nickel metal, copper sulfate, and cobalt oxide. The high purity nickel product was rolled into sheet for marketing, primarily for coinage, as nickel had few other uses at that time. The undertaking experienced all of the problems that face the mining and metallurgical industries of today: declining reserves, high labor and fuel costs, high transportation costs, fluctuating demand and prices, pollution concerns, and foreign competition. The technical features of the geology; the mining, smelting, and refining operations; and some of the economic aspects are assessed. The view is taken from that of the present time -- seeking those lessons from history that we are supposed to learn or face the prospect of repeating the mistakes of the past.

Jan 1, 2005

By W. M. Armstrong, John A. H Lund

The paper describes an investigation of some of the tensile properties of single crystal vanadium, poly-crystalline vanadium and polycrystal-line tantalum, in the range of: W°C to -196°C. Techniques employed in the preparation and testing of specimens are discussed in detail. Some results of determinations of the temperature dependence of yield stress and ductility are given, and discussed in terms of the Cottrell-Bilby Theory of yielding. At subnormal temperatures, all the body-centred cubic transition metals in the Periodic Table exhibit; a) the "yield phenomenon" in tension, b) a strong temperature and strain rate dependence of yield stress, and c) a large decrease or complete loss of ductility. The yield phenomenon (existence of an upper and lower yield point) has been explained by Cottrell and Bilby ( 1) in terms of the dislocation-locking effect

Jan 1, 1961

By J. W. Bingay

The expansion of the mining industry, with other industries, of course, is dependent upon a supply of fresh capital from year to year. Mining is a speculative form of investment, though there is a wide range of risk as between indiudual undertakings. All of the leading financial writers, nowadays, agree that expansion is being seriously interfered with by the unprecedented load of taxation Canadians are carrying. Individuals have less for investment and corporations are obliged to defer necessary expenditures in order that the demands of the taxing authorities may be met. Naturally, speculative investments such as mining exploration suffer first. Undoubtedly, a great deal of cash raised by taxes, if left in the hands of individuals and corporations for investment and expansion, would have been far more beneficially used and would have developed the country more than any use made of it by the government, in the way of bonusing new industries, or the undertaking of large schemes of development. Government undertakings of this nature are often entered into without a proper knowledge of cost and probable return. Expert expenditure of the same sums by business men or corporations undoubtedly would generally produce more prosperity for the country as a whole. The absolute necessity for lower taxation is being increasingly known to the public at large, and eventually it is hoped that our governments will see the economic impossibility of continuing the present rate of expenditure. The successful Finance Minister of the near future will not be the one who can borrow the most money.

Jan 1, 1924

By D. J. Farmer

Mining hoists are major components of any underground mine, however, the detailed design work required to get the actual power required for a particular hoist is outside the scope of preliminary feasibility studies. Nonetheless, a hoist is costly. Therefore, an accurate estimate is needed for the design parameters and the power required. There are two methods available, namely, the O’Hara method and the Society of Mining Engineers’ method. Tests were done for both methods employing nine friction hoists and 19 drum hoists currently in use at Canadian mines. The O’Hara method provided unacceptable results for both friction and drum hoists. While, the SME method was designed for American regulations and factors of safety which often differ significantly from Canadian ones, good results were obtained. The two relationships deter-mined were simply to add 5% to friction hoist design and to add 4% to drum hoist design. Modifying the SME method by these two factors will allow the hoisting system determined by the SME method to be within the error for a prefeasibility study.

Jan 1, 1997

By A. W. Jolliffe

DESPITE the widespread occurrence of scheelite in Canada, domestic production of this strategic mineral is still quite insufficient to meet wartime needs. Two difficulties have invariably arisen in prospecting for or developing scheelite deposits: scheelite is a difficult mineral to identify, and secondly, its distribution is commonly so erratic that the value of a deposit cannot be determined without arduous and expensive methods of sampling and wet assay. Scheelite's property of fluorescing under certain ultra-violet lamps overcomes the first difficulty and is the basis for a quantitative method developed to overcome the second. It is found that, by use of an ultra-violet lamp, the value of many scheelite deposits may be accurately and speedily determined. The method requires neither elaborate apparatus nor exceptional skill on the part of the operator, and is most applicable to those deposits where the bulk of the scheelite occurs in fairly pure aggregates that are at least one-tenth of an inch across. It has been used in grading some two hundred scheelite-bearing veins in the Yellow-knife-Beaulieu region, Northwest Territories, and various occurrences in the Porcupine district, Ontario. The method requires the measurement of the total area of scheelite exposed in any reasonably large measured cross-section of a deposit. From the areal percent of scheelite so obtained, the tungstic oxide (WO,) content of that part of the deposit may be calculated by means of equations of simple derivation.

Jan 1, 1942

By O. B. Horne, R. O. Morgan, C. E. Anderson

"Air-photo interpretation and photogrammetry are two of the most effective and versatile tools available to the petroleum industry. The techniques have proven successful in providing solutions to many of the problems encountered in the design and construction of oilfield projects.Although most technical personnel are aware that air-photo interpretation and photogrammetry are useful in the selection of routes for roads and pipelines, few realize the true scope of the techniques or the wide variety of areas in which they are applicable.This paper briefly describes the principles involved, and reviews a number of typical applications of particular interest to petroleum companies. Excessive detail is avoided, rather the emphasis is placed upon the wide spectrum of possible applications. It is stressed that on-the-ground examination generally is a necessary adjunct, and that there are certain limitations to the techniques discussed.Properly applied, however, air-photo interpretation and photogrammetry can offer significant advantages in terms of time, flexibility, secrecy and economy."

Jan 1, 1968

By L. K. Mireku

"Abstract - The Halfmile Lake South Deep zone, Bathurst Mining Camp, New Brunswick, was discovered by Noranda Inc. (Exploration) as a result of a 3-D seismic survey in 1998 and the subsequent drilling of ten diamond-drill cores. The deposit consists of massive, breccia, and stockwork Pb-Zn-Cu sulfide minerals, and is hosted by a volcano-sedimentary sequence belonging to the overturned Ordovician Tetagouche Group. Epiclastic rocks and interbedded fine-grained felsic pyroclastic rocks dominate the stratigraphic footwall. Locally, crystal-rich felsic tuffs and subordinate epiclastic rocks comprise the immediate stratigraphic hanging wall. The entire stratigraphic sequence was intruded by quartz-feldspar porphyritic intrusions, and cut by intermediate and basic dikes. The volcanic and sedimentary rocks can be discriminated geochemically using trace element ratios such as Zr/TiO2 and Nb/TiO2, despite intensive alteration and cleavage development. These ratios indicate that four protolith volcanic compositions exist: rhyolite, dacite, andesite, and basalt. The aphyric and feldspar- and quartz-phyric volcanic rocks are dacitic and rhyolitic in composition; epiclastic rocks have trace element ratios consistent with dacitic compositions. Pearce element ratio diagrams, general element ratio diagrams, and petrographic observations demonstrate that the rhyolitic volcanic rocks exhibit evidence of albite, potassium feldspar, and quartz fractionation, dacitic volcanic rocks exhibit little evidence of any fractionation, and epiclastic sedimentary rocks exhibit evidence of quartz sorting only. Hydrothermal alteration is best represented by the presence of phengitic muscovite and daphnitic chlorite. Minor calcite occurs in the stratigraphic hanging wall, deep in the stratigraphic footwall, and in post-mineralization dikes, and thus is not interpreted to be part of the causative hydrothermal event. Element additions and losses during alteration have been used to determine net alteration reactions, and these have been used to identify alteration parameters that are independent of other forms of alteration and fractionation/sorting, and which can be used to guide exploration. These parameters include: a bulk hydrolysis measure, (2Ca+Na+K-2CO2)/Al; a muscovite alteration measure, K/Al; an albite destruction measure, Na/Al; a chlorite alteration measure, (Fe+Mg-S/2)/Al; a chlorite composition measure, (Fe-S/2)/Mg; a sulfidization measure, S/Ti; and a carbonatization measure, CO2/Ti. With the exception of the carbonatization measure, these alteration parameters define a distinct lateral and vertical zone of intense hydrothermal alteration in the stratigraphic footwall of the deposit, and demonstrate that the epiclastic rocks are predominantly chlorite altered, and the volcanic rocks are predominantly muscovite altered. Within the alteration halo, element additions of Fe and H, and element losses of Na are characteristic. Potassium was added to muscovite-altered rocks, but subsequently removed from chlorite-altered rocks. The results from this study demonstrate that metamorphism and deformation have not significantly obscured hydrothermal alteration signatures."

Jan 1, 2006

By D. Groenveld, M. Rozou

"Recent trends move towards automation, smart sensors, internet of things, powerful DCS, and more data. Are those trends already utilized in a real time production environment? Today operators still have to monitor several complex processes at the same time and predict their behavior based on an overwhelming amount of data available.The fact of the operator being overloaded and humans being unable to process multivariable problems shows the need of a tool merging essential data and providing consistent, sound decisions for long-term profitability.This paper shows a successful execution of ABB’s process improvement services in Aitik (Boliden SA), a copper mine located in Sweden. Soft sensors, fuzzy rule blocks and model predictive control were seamlessly integrated in the control system of the grinding area, resulting in proper control of mill loads and particle size without violation of any constraints.INTRODUCTIONDepending on the ore characteristics and the targeted plant capacity, the design of the grinding circuit may vary significantly. Typically, the circuit consists of several mills (rod, ball, SAG, AG) in series and/or parallel with a number of classifiers and sumps at appropriate locations. The goal of the grinding section is to reduce the ore particle size to a level that enables efficient separation between gangue and precious metals in the subsiding processing step. The trade-off between quality and quantity has to be made. It is also crucial to execute this process step at the lowest possible energy and grinding media consumption.An optimal grinding process controller must manage to maintain a given fresh feed level while keeping the product size within a given range without violating any constraints such as power, torque or load limits. To accomplish the aforementioned, it is necessary to manipulate the ore feed rate, water feed rate and the mill speed. The most significant disturbances adding another degree of complexity to this control problem are ore hardness and the amount of circulating load."

Jan 1, 2016

By A. Manouchehrian, M. Cai

"Rockburst, which often occurs around underground openings in highly stressed hard rocks, is a sudden and violent unstable rock failure and is associated with energy release. Rockburst is very dangerous to workers and mining equipment, and it has been a major concern for deep underground construction and mining. Before excavation, rocks are loaded under a true-triaxial condition. Upon excavation, the rocks at the excavation boundaries are loaded in the maximum principal stress direction and unloaded in the minimum principal stress direction and this provides a necessary condition for unstable rock failure to occur. Understanding rock behavior under true-triaxial unloading condition is critical for developing measures to control unstable rock failure in underground construction.In this article, an explicit FEM tool is used to simulate rock behavior under true-triaxial unloading condition, with a focus on analyzing stable and unstable failure and the released energy during failure. Firstly, a uniaxial compression test was simulated. The results indicated that the adopted numerical tool was able to simulate stable and unstable failure by varying the Loading System Stiffness (LSS). In this research, Loading System Reaction Intensity (LSRI) was proposed as an indicator to identify stable and unstable failure. Secondly, unstable rock failure under true-triaxial unloading condition was simulated. A rock specimen was loaded in three directions; the lateral pressures (s3 and s2) were kept constant and the vertical stress (s1) was increased to a pre-defined stress. The specimen was suddenly unloaded in the minimum principal stress direction (s3) and loading in the s1 direction was continued until failure occurred. Different LSS values were considered and the results showed that the LSS influenced the failure mode; a soft loading system resulted in more violent failure and released more energy than that in a stiff loading system. The influence of specimen height to width ratio on rock failure was also investigated. It was found that failure in taller specimens was more violent than that in shorter specimens. Insights gained from the simulation are useful for better understanding of the influencing factors on the released kinetic energy during unstable rock failure and to find means to control rockburst damage in engineering practice."

Jan 1, 2015

By Errol Ladner

The application of large-diameter bore holes in underground operations at Heath Steele was first tried in February, 1975. Since that time, 90,000 feet of 6-l/2-inch holes have been drilled, primarily in open blasthole stoping, for a total of 1.4 million tons, 37% of underground production. This paper deals with a review of drilling with conventional percussion longhole drills, a practice which is still utilized at Heath Steele, and the changeover to accommodate the use of larger blastholes in underground operations. The discussion will include layouts for 2-inch-diameter blasthole stope blocks, 6-inch-diameter stope blocks, trials for I. T.H. (in-the-hole) stope rooms, and drill pat/ems, drilling and performance. The complexity involved in the development, drilling and blasting of 2-inch blastholes is overcome by the over-all simplicity of drilling and blasting in I. T.H. stopes. This has made the practice of open blasthole stoping more economical and efficient. The future indicates an increase in the company's I. T.H. program. Investigations are being undertaken regarding longer holes to decrease development costs. A VCR stope is also being developed for trial.

Jan 1, 1979

In this study, flotation of fine galena, chalcopyrite and pyrite was performed after grinding with different extent of oxidation-reduction condition adjusted by grinding media. Sodium dithionite and iron ions were added in mill to simulate pulp potentials and iron oxidation species produced by grinding media, respectively. The types and quantities of the metal oxidation species on mineral surfaces were determined by EDTA extractions, while the surface electrical properties of minerals and interaction of different types of metal oxidation species were studied by zeta potential measurements. It was found that the nature and concentration of the absorbed metal oxidation species were dependent on oxidation atmosphere controlled by the iron amount of grinding media. These species interacted with each other and had an important role in determining flotation of fine galena and chalcopyrite as well as activation of fine pyrite by lead and copper.

Jan 1, 2006

By J. H. Sokolowski, R. I. MacKay

The level of Si and Cu in the 3xx series of alloys affects the volume fraction of the a-Al dendritic phase and the Al-Si eutectic phase. The volume fraction of these phases in turn affects the feeding conditions during solidification and ultimately the Area Fraction Porosity and Mean Pore Diameter measured in the as-cast structure. This work sets out to establish the relationship between the volume fraction of the a-Al dendritic phase and the Al-Si eutectic phase and the resulting porosity that forms on the Monotonic and High Cycle Fatigue properties. The alloys in question are the Al-9%Si-l %Cu and a Al-7%Si-4%Cu alloys which were cast into V8 performance engine block castings and then heat treated to achieve desired mechanical properties. The engine block castings provided the mechanical and metallographic test samples analyzed for this work.

Jan 1, 2006

By E. G. Langille

"The Premier mine; owned by Silbak Premier Mines; Limited; is 14 miles from Stewart at the head of Portland canal. Development of the property began in 1918; and since chat time a very large amount of gold and silver as well as some lead and copper have been produced from the mine.The area in the vicinity of the mine is underlain by greenstones tuffs, and sediments of Mesozoic age, belonging to the Bear River formation of the Hazelton group. These rocks are intruded by a stock 2 miles in diameter, composed of orthoclase porphyry and called the Premier porphyry. It sends numerous sill-like and dyke-like tongues into the Bear River formation, and is intruded in turn by a granodiorite outlier of the Coast Range batholith. The orebodies occupy fractures and fracture or shear zones. Primary ore consists chiefly of pyrite, galena, and sphalerite, with some chalcopyrite. The upper 300 feet, or locally 600 feet, contained presumably secondary silver minerals."

Jan 1, 1954

By Jehan Rondot

Les trois intrusions alcalines de Suzorite en haute Mauricie, bien que non datees, son! sans doute d ,attacher aU)( nombreuses autres intrusions alcalines dispersees sur les blocks Grenvillia et Laurentia et datees de I 050 Ma =t= 10%, done reliees d l'orogene grenvilien. L 'utilisations de la Suzorite est liee d sa forte proportion de phlogopite (>50%). Le rapport Mg/Fey varie de 3 d 7. Sa mineralogie et sa composition particulieres (forte proportion de Mg, Ket H20) en font son attrait.

Jan 1, 1984

By G. Q. Liu

"The application of oxygen-enriched cyanidation to three Canadian gold ore samples has been investigated. The results showed that the use of oxygen can improve gold dissolution kinetics, reduce grinding time, and lower cyanide and lime consumptions. To obtain the same gold extraction, the required cyanide leaching time was reduced from 48 hours in slurry containing 8 ppm O2 to 12 - 24 hours in 20 ppm O2 slurry. Reagent consumptions were reduced by 23 - 37% for cyanide and by 35 - 54% for lime. There was little advantage to further increasing the dissolved oxygen to 32 ppm from 20 ppm. Gold extraction from the +200 mesh fraction improved 4 - 14% in oxygen-enriched slurry. A general kinetic model derived from the cyanidation of three ore samples can be described by the following equation: <equation>where E is the gold extraction (%) at time t (hours), EI is the ultimate gold extraction (%) , and &apos;P and k are constants depending on cyanide concentration, level of dissolved oxygen, and the characteristics of the ore samples. Comparative studies of conventional carbon adsorption and carbon adsorption in oxygen-enriched slurry have also demonstrated that oxygen enrichment resulted in more favourable conditions for gold adsorption."

Jan 1, 1995

By M. Maeda, H. Sasaki

"Precious metals such as platinum, palladium, and rhodium are commonly used for automotive catalyst converters. To recover these metals with lower environmental load and cost, exposure to zinc vapor was proposed as a pretreatment prior to acid leaching. Alloying with zinc is expected to enhance dissolution of precious metals and reduce the amount of toxic chemical agents required for the leaching. This study examined the effect of the alloying pretreatment using model catalysts. Catalysts were immersed in leaching solutions for a predefined time with or without zinc vapor pretreatment, and the amount of dissolved metals was then evaluated. INTRODUCTIONAutomotive catalysts account for large portions of the world consumption of platinum (Pt), palladium (Pd), and rhodium (Rh) (Butler, J., 2011). Because of their limited production and high prices, recovery of the precious metals from spent catalysts is obviously an important issue. A representative structure of an automotive catalytic converter can be described as a monolithic ceramic support with a honeycomb structure which is coated with porous oxides such as those of aluminum (Al2O3), cerium (CeO2), and zirconium (ZrO2) (Heck & Farrauto, 2001; Matsumoto & Shinjoh, 2007). Small particles of precious metals, originally several nanometers or less, adhere to the oxides.Typical recovery processes for precious metals from scraps are shown in Figure 1 (a)-(c) (Habashi, 1997; Yoo, 1998; Shibata & Okuda, 2002). Precious metals can be recovered by using non-ferrous smelters as Figure 1 (a) shows. Smelted along with metals such as copper (Cu), precious metals and ceramics in the scraps are absorbed into the metal phase and slag phase, respectively. Because the metals separate from Cu as anode slime in successive electro-refining, such a process can recover precious metals as co-products of Cu. However, in order to prevent negative effects on the principal process, a specialized procedure is needed. Figure 1 (b) is a specialized approach in which scraps are melted at elevated temperature with Cu called the Rose process. Here Cu works as a collector metal, and the absorbed precious metals are then concentrated by oxidation of Cu. Such a process can separate precious metals from ceramics constituting catalyst converters. Smelting at high temperature, however, requires extensive equipment as well as a high amount of energy. On the other hand, hydrometallurgical processes may be effective to separate precious metals from ceramics into an aqueous solution, because chemical agents can act on these metals selectively (Figure 1 (c)). Leaching of precious metals, however, requires strong acid and oxidizing agents because of their corrosion resistance; this makes liquid waste disposal and the large environmental load controversial. To solve the problem, a metal vapor pretreatment was proposed (Okabe, Yamamoto, Kayanuma, & Maeda, 2003a, 2003b; Kayanuma, Okabe, Mitsuda, & Maeda., 2004; Kayanuma, Okabe, & Maeda, 2004; Itoh, Kayanuma, Miyake, Kimura, & Maeda, 2005). A flow diagram of the process using zinc (Zn) vapor is shown by Fig. 1(d). Exposed to Zn vapor, precious metals are expected to form alloys which dissolve more easily than pure precious metals, thus reducing the use of chemical agents and environmental load involved with successive leaching. In previous research (Sasaki, Miyaki, & Maeda, 2010; Sasaki & Maeda, 2010, 2012), dissolutions of precious metal alloys formed by Zn vapor treatment were examined in hydrochloric acid (HCl) using an electrochemical method, and it was confirmed that these metals dissolved at higher rates from the alloys than from their pure states (Figure 2). In this study, the availability of the alloying pretreatment was demonstrated by testing on model catalysts in leaching solutions."

Jan 1, 2012