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By M S. Henderson, R D. Alorro, L G. Dyer

An alternative leaching system for rare earth element recovery from monazite is under development. The initial stage utilises oxalic acid to convert the rare earth phosphate into an oxalate salt through dissolution and reprecipitation and it is the efficiency of this stage that governs the overall recovery achieved. It has previously been proposed that lixiviant consumption is the primary limitation in this process. This work further investigates a range of conditions in an attempt to further elucidate the factors influencing the achievable conversion in this stage. It has been shown that the pH may be governed by multiple reactions both consuming and producing acid (thus the mild change over time). The importance of proper mixing and potential to operate at lower temperature with only moderate impact on kinetics has also been demonstrated. Staged/sequential leaching is more effective in fresh solution as opposed to restoring the lixiviant concentration with subsequent reagent addition, suggesting some impact of solution composition. However, contrary to previous findings, subjecting the leach residue to fresh solution resulted in significant decline in leach rate and overall dissolution. This may be because a greater proportion of conversion was achieved in stage 1 in this work than in previous investigation. This may indicate that eventual passivation or the presence of some more refractory REE minerals limits dissolution. Iron dissolution was relatively consistent upon exposure to fresh solution, displaying the ability of the solution to continue to leach the goethite component of the concentrate.

Aug 24, 2022

The design of mine ventilation systems for the BHP Steel Division Collieries is based on the acquisition of ventilation survey data for the establishment of a realistic computer net- work model. The branches which form the net- work for the computer models are calculated from a range of resistance factors incorporat- ing both a frictional and shock loss component. Since shock losses can account for up to 30 per cent of the total energy losses in mine airways the use of friction factors alone without accounting for shock losses will result in the choosing of an insufficiently performing fan. Published tables of friction factors have in- variably been taken from metalliferous or single entry studies and consequently are not reliable for Australia's mining conditions where multiple entries with regularly spaced cut-throughs are the normal practice. Typical resistance factors for roadways of rectangular cross-section 5.5 m x 2.0 m, with coal sides, have been found to vary from 0.11 Ns2/m8/km where no timber supports are used, to 0.98 Ns2/m8/km where double centre legging together with wooden chocks is used. In addition to the range of resistance factors due to varying support methods, the nature of use for a roadway is very significant because of the condition of repair and upkeep maintained.

Jan 1, 1983

The Canada Centre for Mineral and Energy Technology (CANMET) /Calgary Coal Research Laboratory and the National Research Council in Ottawa established a joint working research group with industry to develop and test various computer models for application in surface coal mining operations in western Canada.The first part of the paper deals with the problems the group experienced during the past two years especially having model specification and requirements defined and understand site management practices.The second part of the paper deals with site specific development of general mine model for TransAlta Utilities' Highvale Mine in Alberta. Described here are the development of an interactive truck/shovel model for their three pit operation, selection and application of dragline model for tandem operation with the extended bench method, criteria for operational model of the five seams operation with selec-tive mining approach.

Jan 1, 1985

By L Cooper, J Sharma, M J. Hendry

Thick clay tills below potash mine tailings and brine ponds are important natural barriers protecting fresh water aquifers in Saskatchewan. Centrifuge modelling was applied to assess geochemical processes and impacts of dilute brine (0.1 M NaCl) migration through clay till core samples obtained from non saline, unoxidised clay till at a mine site. At accelerated gravity of 876 + g, during each day of centrifuge modelling, flow driven through a 52 mm length core simulated transport through a 45 m thick clay over ~2100 years. Hydraulic conductivity, monitored continuously before and during brine permeation, was low and relatively constant (8.5 + 10-12 m/s), confirming that confining stresses prevent permeability increase. Core density and porosity measurements confirmed that reactive transport occurred under realistic in situ conditions. Breakthrough (defined by C/C0 = 0.5) of non-reactive Cl- occurred at 25 days. The slight delay for Na+ breakthrough, associated with small increases in Ca2+ and Mg2+ concentrations in the effluent were attributed to ion exchange, but carbonate reactions were relatively unimportant. Cation exchange analysis of core samples was inconclusive without corrections for porewater Na+ and carbonate dissolution. Geochemical processes that were observed during centrifuge modelling were successfully simulated using the 1D geochemical transport code PHREEQC. Solute transport was dominated by diffusion with limited ion exchange to delay Na+ migration. Brine would not break through a 45 m thick clay for tens of thousands of years. Based on these findings, the thick clay till at this site, if laterally extensive and undisturbed by drilling activity, is likely to act as an effective natural barrier to vertical brine migration over the long term.

Jan 1, 2003

This paper considers two particular empi- rical models for the processes of the generati- on of hydrochemical zoning and epithermal near- surface mineralization of mercury-antimony-arse- nic formation in the discharge area of the Uzon Caldera ore generating hydrothermal system in Kamchatka. Vertical and horizontal hydrochemical zo- ning is caused by mixture of infiltration waters of the surface formation with fluid of chloride- sodium composition which are supplied up the-zo- ne of deep fault. Ore formation is caused by simultaneous existence of two geochemical barriers, namely oxidizing and reductive. The first barrier is determined by the-level of ground waters. The second one forms under the clay-opal screen un- der the influence of two factors, namely the inflow of deep reduction sulphur compounds (which are transported together with arsenic, antimony and mercury) and the generation of hyd- rogen sulphide as a result of sulphur- and sul- phate reduction. X-ray-amorphous phase of orpi- ment composition and realgar phase are formed, respectively, on the oxidizing and reductive Barriers.

Jan 1, 1987

By L M. Foster, J R. Kellett, G A. McMah

The Great Artesian Basin (GAB) contains one of the largest reserves of fresh water in the world. The volume in storage is enormous, being estimated at nearly 65 000 million megalitres (ML). Development of this resource, dominantly for the pastoral industry, began in the late-1800s and quickly accelerated. With exploitation of the resource, artesian pressures declined almost as rapidly. This loss of head is a result of the total discharge from the basin and much of this discharge is waste of water. The waste through uncontrolled bores and inefficient distribution systems still amounts to about 75 per cent of all discharge. However, the volume in storage has hardly been depleted. The major concern is the effect of withdrawal on artesian pressures. Due to the size of the Basin, the relatively flat gradients and low permeability, the movement of water through the aquifers is extremely slow and independent of recharge. Hence, the normal concepts of sustainable yield (ie discharge should equal recharge) cannot be applied to the Basin as a whole as travel times do not allow for the effect of recharge to be seen away from the outcrop areas within management timeframes. The large volume in storage, though, can provide an extensive buffer to the impacts of temporary water needs. This effect should be considered when assessing the acceptability of fixed life projects such as mines and the extracted volumes from their operations. Identifying a sustainable yield involves balancing the acceptability of the economic, environmental and social costs with the associated discharge and fall in head, to arrive at an acceptable balance.

Jan 1, 2003

By Dhawan AK

On 8 July 1993, a landslide of about one million cubic metres of rock blocked the river Satluj near Sanjay Vidyut Pariyojana - Bhaba project and caused flooding into the Bhaba Power House (120 MW) resulting in suspension of power generation. The concerned authorities desired an early removal of the blockade by an underwater blasting operation into the over topping water to reduce the water level at the blockade and resume power generation in the power house. In the absence of underwater drilling, it was essential for the blasting technique to be used where no cavity to confine the explosive was required. For this reason mud capping and plaster shooting with directional throw were used and additional specially fabricated mild steel pipe charges were used under high current for an underwater trenching operation. By employing these techniques the river blockade was removed up to the required depth and on 8 September 1993 the Power House resumed the power generation.

Jan 1, 1995

By Coppock BW

Sintering of lead and zinc concentrates is practised by Sulphide Corporation Pty. Limited to provide both desuiphurised lump sinter feed, for simultaneous reduction to zinc and lead in the Imperial Smelting Process blast furnace, and sulphur dioxide gas for sulphuric acid manufacture. From November, 1969 a 20 percent increase in production rate has been obtained through improvements in operating technique. A gradual increase in bed permeability was achieved by modifications to the feed mix conditioning equipment and by improving moisture control. However advantage could not be taken of the higher permeability to increase sulphur elimination because the hardness of the lump sinter decreased. Higher throughput, better quality sinter and more stable sintering conditions were however made possible by simultaneously: 1. reducing segregation and compaction in the sinter bed, by narrowing the discharge opening of the main layer feed hopper, 2. reducing the sizing of sinter returns to give a closer size spectrum of particles in the feed mix, and 3. increasing the sulphide sulphur content of the feed mix to give higher bed Temperatures.

Jan 1, 1972

A simulation of the fluid flow, minera- logical and chemical aspects of in situ leaching is being developed for application to the recovery of metals from unbroken, naturally jointed rock. The fluid flow aspect has been developed. The rock is assumed to have a double-fracture property. A major joint set is responsible for bulk flow of solution, while a minor joint set, intersecting with the major set, allows the solution to contact the reactive minerals. The two-dimensional fluid flow through the major joint set is analysed by a streamline model for a particular well pattern. The other important components of the model are described briefly.

Jan 1, 1984

By Motyka J, Adamczyk AF, Witczak S

A case study of migration of a paper factory fluid wastes, on the distance of 5 km from an underground disposal site to an ore mine is presented. The ore mine in question, situated in SW Poland is pumping 3.5 m3/s (ca 300 000 m3/day) of groundwater, producing a cone of depression about 150 m deep and several kilometers wide. The migration of wastes (pollutant) occurs within the carbonate karstic aquifer of Triassic age. The aquifer is about 100m thick and is characterized by the coefficient of hydraulic conductivity equal to 8 m/day on the average. The results of systematic measurements carried out for 13 years enabled to estimate the mean breakthrough curve of the pollutant. On this basis and taking into account the coefficient of hydraulic conductivity as well as the mean hydraulic gradient between the disposal site and the ore mine, the migration parameters of the polluting material, i.e. the real flow velocity, the effective porosity and the longitudinal disper- sivity have been calculated. As the measurements considered a long migration distance of the pollutant, the obtained hydrodynamic dispersion constant (dispersivity), in the authors opinion, is reliable enough to be applied for regional groundwater calculations, regardless of the "scale effect".

Jan 1, 1988

By R Higashi, D Maruoka, T Murakami, Y Iwami

The ironmaking industry consumes a large amount of fossil fuel derived carbon as heat source, reducing agent of iron ores and carburising agent of reduced iron. Although the demand for drastic decrease of carbon dioxide emission, carbon is an essential element for smelting process of molten iron. The carbon recycling ironmaking process by circulating CO has been already proposed to achieve carbon neutrality. However, the production of molten hot metal is not considered in this process because sufficient amount of carbon does not dissolve in reduced iron by CO. Therefore, our group has suggested a new carbon recycling ironmaking process which can produce hot metal. In this process, free carbon and iron carbides produced by carbon deposition reaction using metallic iron as a catalyst are used. It is known that only Fe3C is obtained as iron carbide by using CO gas, however, Fe5C2 is also produced by adding H2 gas. The composite agglomerated with these carbonaceous materials and fine iron ore (Deposited Carbon-Iron oxide Composite: DCIC) is reduced and melted in a furnace. It is reported that Fe3C in DCIC accelerates the reduction reaction and melting of the composite. In this study, the effects of iron carbides and free carbon on the melting behaviour of DCIC are investigated. Fe3C, Fe5C2 and free carbon were produced by vapour deposition using porous iron whiskers and CO-CO2-H2 gas. These were agglomerated with hematite reagent at a certain ratio to prepare DCIC samples with and without Fe5C2. The samples were heated up to 1300°C in inert atmosphere. The DCIC containing Fe5C2 completely melted and iron nuggets were obtained after the experiment. This behaviour was not observed in the composite without Fe5C2. This indicates that using Fe5C2 is more preferable than Fe3C for molten iron production using DCIC.

Jun 19, 2024

The difficulty in creating and obtaining a competitive edge in the mineral industry is rapidly increasing. The Kiruna Iron Ore Mine in the far north of Sweden is currently thriving on the world market through firm managerial strategy. LKAB believes in upgrading its raw material to produce a high quality iron ore product for sale to steelworks throughout the world. It is vital that this product is also of uniform quality and quantity to provide quality assurance to customers. The first link in meeting these product requirements starts in the underground workings. Mining methods and operations are of large-scale. Automation and continuous production streamline operations and reduce operating costs. These factors have built Kiruna Iron Ore Mine into the world's biggest, most modern, underground iron ore mine. To remain competitive on the world market, LKAB relies heavily on research and development. The mine is currently in a phase of upgrading its operations. A 25-tonne Toro electric loader is being tested to improve the rate of output of ore from the mine. Long hole drills are being improved to increase accuracy and efficiency. An electronic detonating system will improve detonator delay precision. Projects are underway to better understand ore flow mechanisms from a caving orebody. Benefits include improved ore recovery along with better rock quality control at the caving front. The continued updating of mining operations at Kiruna will enable LKAB to continue to maintain its competitive advantage on the world market in the production of high quality iron ore products.

Jan 1, 1997

By Lee H. G, El-Rahaiby S. K

The literature relating to reduction of sulphides by carbon using lime as sulphur-absorbent is reviewed. A stage-wise thermodynamic model is employed to evaluate the practical feasibility of the direct reduction smelting of galena (PbS) concentrates with a carbon reductant in the presence of lime; a coke-rate of 65 kg/ton Pb is predicted by the model. The experimental data on the reduction of PbS:4CaO:4C mixtures under nitrogen were correlated by means of a finite difference numerical method and the values of the intrinsic rate constant I1 were derived. The results for the uncatalysed reduction are represented satisfactorily with log I1 = 1.247(±0.522) - 5540(±610)T-1.The catalysed PbS:4CaO:4C mixtures contained 2.5 wt% of ternary (K, Li, Na)2CO3 catalyst. For the catalysed reduction it was found that log I1 = 3.981 (±0.301) -7790(±353)T-1, where I1 (in both relations) is expressed in moles.(g.C.)-1.atm-1.s -I. The catalytic enhancement faclor was found to be quite large in the 1068 to 1262°K temperature range investigated here.

Jan 1, 1991

By Sjaw WJ

Conditional simulation is a set of geostatistical tools that is becoming popular as powerful personal computers make the use of these tools less costly. The more familiar set of tools for spatial estimation has a number of varieties (eg Ordinary Kriging, Simple Kriging, Multiple Indicator Kriging, etc) each suited to particular solutions of the problem of estimation, for example predicting the average grades of blocks in a region from more or less sparse data. Similarly, conditional simulation has a number of varieties, discussed in this paper, which in various ways address the problem of characterising the variability of a deposit between the known data locations.Conditional simulation can provide a number of equiprobable images of a deposit, at a finer resolution than would be economic or practical to sample, and that can be constrained by various criteria (which may be geological, statistical and geostatistical), to ensure that the images reasonably represent the deposit. These images can then be used to assess the risk involved in various practical mining decisions. Examples are provided where conditional simulation has been used for validating resource estimate parameters, optimising grade control sampling grids, and for ore block optimisation for mining grade control.

Jan 1, 1997

By Ritchie IM

The Parker Centre was formally established by the Australian Government's Co-operative Research Centre (CRC) Program in 1992 and is one of over 60 such centres encompassing a wide-range of applied scientific and resource based disciplines. Government funding for the CRC Program is currently around $A140 million per annum and the Parker Centre receives $A1.8 million per annum to support its core research and education activities.

Jan 1, 1997

By Mosusu N

Geothermal anomalies of different types occur within distinct geological/structural settings in Papua New Guinea. According to R.F. Herring, geothermal occurrences in Papua New Guinea can be classified into two types, those related to vulcanism (Lihir, Rabaul and other series of islands along the volcanic arc) and those resulting from a regional heat flow probably caused by radiogenic sources, for instance those in the Wau/Bulolo area. The manifestation of this potential source of energy generally coincides with either converging or diverging tectonic plate boundaries. Previous inventories on thermal waters were carried out by vulcanologists from the Rabaul Observatory in the early 1960s. However, these studies rarely included chemical analyses of water and gas emissions and the investigations were carried out in an ad hoc manner, generally as a secondary activity. The most recent investigation on thermal waters was conducted on Lihir Island in connection with the development of the open pit gold mine. These studies included detailed exploratory drilling to a maximum depth of 730 m, and a water chemistry isotopic sampling and analysis programme. The hydrothermal waters were not considered as an energy source but as a hazard during the development stage of the mine. Nevertheless, the geothermal anomaly observed at Lihir includes hot springs emerging along the coastal zones with temperatures that approach 100¦C, steam, and thermal borehole waters with temperatures that exceed 200¦C. Chemical analysis results of thermal fluids from Rabaul, Talasea and other areas in Papua New Guinea generally show high total dissolved solids and low pH. In contrast, recent results from the deepest and hottest thermal source at Lihir shows a neutral pH, a Na-CI-SO4 composition and temperatures above 200¦C. Despite the concentration of chloride being similar to that of sea water, other chemical results and stable hydrogen and oxygen isotopic compositions of thermal fluids imply the source to be mixture of local meteoric water and deep thermal water rather than sea water. Results of geothermal modelling suggests that the total geothermal uptlow is equivalent to 54 MW.

Jan 1, 1997

By Renwick MT

Two innovative ground reinforcement products have been developed for use in the mining industry. One of these products is a high strength polyethylene (HOPE) bar for use as a rib bolt in underground coal mining and as a corrosion proof tendon in open pit mines. The other product is a cable bolt (Ultrastrand) which demonstrates enhanced load transfer and is available in continuous lengths. Ultrastrand's exceptional in- situ performance and versatility makes it ideal for mechanised installation in both underground and surface mining operations. Details of these products are presented and results from labortaory and field trials are discussed.

Jan 1, 1992

By Ghose AK

Design and selection of support systems for longwall faces call for in-depth know- ledge of strata mechanics and in particular of strata-support interactions. The paper presents the results of field investigations and analysis of a difficult-to-cave roof using powered supports under a massive dolerite sill in Central India using a state- of-the-art datalogger system. The mechanised long wall face was equipped with 4/680 tons chockshields operated on the IFS mode using a 300 KW DERD shearer. The datalogger system was capable of storing data simulta- neously in 32 channels. The paper describes the monitoring system and the monitoring programme. The system provided useful information on support behaviour, build- up of leg pressures and face convergence during an intense dynamic periodic weighting phenomenon which destroyed the integrity of almost half of the face supports. At this point, the face had advanced by about 197 metres from the barrier. The paper outlines a post-mortem analysis of this dynamic event and provides a critical evaluation of the data collected for understanding strata support interaction and the behaviour of the massive sill in the overburden.

Jan 1, 1992

A system for rapid on-line determination of weight percentage coal in slurry and weight percentage ash in coal has been developed at the Julius Kruttschnitt Mineral Research Centre, University of Queensland. The gauging system is suitable for use with coal flotation slurries or slurries having a maximum particle size of about 1 millimeter. The system is based upon measurement of gamma ray transmission; radioisotope sources emitting photons of two widely different energies are employed. The inaccuracies of measurement that would normally result from variable amounts of air entrained in the slurry are substantially reduced by pressurising the slurry to approximately 2MPa (300 psi) using a Mono pump. The equipment can be used to make measurements on more than one slurry stream by pumping streams sequent- ially. The system is being tested at the Peak Downs Mine of the Utah Development Company in Central Queensland. This paper describes the theoretical principles of the gauge design, the experience gained to date in the commissioning of the equipment, including the installation of a PDP 11/03 computer, and the progress made in developing satisfactory interpretations of the gauge count-rate output.

Jan 1, 1978

The excavation of sandstone of generally medium strength for the Liverpool Link Line by Dosco Mark 2A Roadheaders has demonstrated the versatility and good performance of road- headers in suitable rock formations. A description is given of the strata traversed by the tunnels together with descriptions of equipment and crews, excavation sequences, operating difficulties and the results achiev- ed. In addition tunnel construction is des- cribed for a difficult section where there was only O.Sm clearance between invert and a four lane vehicular tunnel below, and O.5m clearance between tunnel crown and a century old sewer above.

Jan 1, 1976