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Stripping of Fe (III) from D2EHPA Using Different Reagents The common way to extract Fe(III) from an organic solvent is by using concentrated acidic solutions. The stripping of Fe(III) from organic solvent Di-2-ethylhexyl phosphoric acid (D2EHPA) by hydrochloric acid (HCl) solutions has been found to increase with increasing the acid concentration. However, the use of a concentrated acidic solution such as 6 M HCl can degrade the organic molecules. In this research, to increase the efficiency of Fe(III) stripping from D2EHPA, effect of some acids, salts and buffer solutions was studied. Influence of Tri-butyl phosphate (TBP) as modifier on the Fe(III) stripping operation was also investigated. According to the results, the best Fe stripping recovery was achieved in the presence of low acid concentration and the salts which was 72.4 per cent oxalic acid, 70 per cent ammonium oxalate and 75 per cent buffer of oxalic acid and ammonium oxalate. The results also showed a better recovery in the presence of the buffer rather than the salt. Finally, increasing the concentration of TBP, HCl and H2SO4 resulted in a higher stripping efficiency of Fe(III). However, in the presence of oxalic acid and its salts increasing the reagent concentration did not increase the stripping efficiency and at this condition, the recovery of iron remained constant.

Sep 13, 2010

By Michael W. Oakland

Deer Island is the site of the Massachusetts Water Resources Authority (MWRA) wastewater treatment plant which, when completed in 1999, will serve 43 cities and towns in central eastern Massachusetts. Deer Island is located in the Boston Harbor, as shown on Figure 1. The existing wastewater treatment plant on Deer Island is being upgraded to include secondary treatment to comply with Federal require­ments. The new treatment facilities will process an average of 455 million gallons of sewage per day; total capacity will be about one billion gallons per day. The new treatment facilities will cover virtually the entire island. [ ]

Jan 1, 1994

This report, the third in an annual series, outlines recent trends and developments in the minerals industry. Discussed are new methods, equipment, techniques, and systems used to more, effectively extract and process minerals and fuels. Environmental considerations, reduced ore grades, and the related increased quantities of material handled were the dominent concerns of the minerals industry in 1972. Productivity increased in most mineral commodities as equipment became more mobile, versatile, and sophisticated. Increasingly, equipment designs incorporated health and safety features. There was considerable interest in the field of energy and in pollution-free metallurgy processes.

Jan 1, 1973

Effect of Lattice Impurities on Electronic Properties and Surface Adsorption of Sphalerite - A Density-Functional Theory Study

Sep 13, 2010

By J. Osterberg

A new device has been developed for load testing driven piles and drilled shafts which consists of an hydraulic jack or bellows which has a telltale rod fastended to the bottom. The rod extends upward to the surface through a pressure pipe. When pressure is applied, the jack or bellows expands, applying an equal upward and downward load at the bottom. The downward movement at the bottom is indicated by the rod and the upward movement is indicated by the movement at the top. Thus, upward and downward load-deflection curves can be drawn. As load increases, failure will occur either in end bearing or friction. Results of field installations are described. Total loads of up to 1,100 tons metric have been used. The method obviates the need for the reaction load required for the conventional pile loading test and separates friction and end bearing. It is especially advantageous for use over water, in crowded spaces and for inclined piles.

Jan 1, 1989

By P. S. Heyns, M. Heyns

A computer model has been developed of mine hoisting systems in deep South African gold mines. Particular attention was paid to the contribution of different modelling assumptions for the guides and guide-roller assemblies. Objective functions indicative of guide-roller tyre endurance, slipper-plate forces and perceived vibration levels were introduced to quantify dynamic performance. These objective functions were used to compare models. It was found that the choice of guide and guide-roller models did not influence the forces on the guide rollers significantly for typical shaft and conveyance characteristics at typical levels of viscous damping coefficients. The rigid and finite-element guide models gave the same results as those of the effective-stiffness guide model, and while the latter is suitable for simulation for design purposes, the finite-element model should be used for unusual guide geometries

Jun 19, 1905

A process was developed, on a laboratory scale, for the removal of iron oxides from Weipa pisolitic bauxite. The technique involves the chemical reduction ofthe iron oxides by carbon, followed by selective removal of the iron species by acid leaching or chlorination.To remove more than 90 per cent of the iron it is necessary to reduce the iron oxides substantially to iron metal by heating the bauxite, pre-calcined at 650-800°C, with reactive carbon at 1040-1100°C. Reduction proceeds via the intermediate formation of hercynite (FeO.Al2O3) and difficulties have been encountered in reducing hercynite formed under less favourable reduction conditions.Following reduction, efficient selective removal of iron species is readily effected by acid leaching using dilute hydrochloric acid at 100°C, or chlorination at 500-750°C using Cl2, Cl2/N2, or Cl2/N2/CO mixtures.After removal of unreacted carbon, the final products contain 0·5-1.0 per cent Fe203 and 87-92 per cent Al203.

Jan 1, 1971

By Valentín Choquenaira Bombilla

El presente trabajo describe el proceso de automatización de la planta concentradora BHPBilliton deTintaya desde el punto de vista del usuario final y así proporcionar una visión global sobre los aspectos relacionados con la automatización de nuestro proceso a través de sistemas de control distribuido (Distributed Control Systems, DCS) e inteligencia artificial (Sistema Experto).También se describe la arquitectura del control, las formas de conexión (Hardware) y la función que desempeña dentro del sistema cada uno de los componentes del sistema de control distribuido instalados en la planta concentradora de sulfuros de BHPBilliton Tintaya S.A. así como algunos conocimientos básicos de manejo del sistema composer y conductor NT (Software) para realizar las funciones de configuración, monitoreo y control del proceso desde unidades remotas y estaciones de trabajo.

Sep 12, 2005

By John Lindsay

Outline ??Recovery plant requirements and concepts ??Common recovery plant unit processes ??Recovery plant design considerations ??Peripheral issues Process Design ??Liberation ??Separation ??Recovery Processing ??Density 3.5 g/cm3 ??Luminescent under x-ray ??Hydrophobic (non wettable) surface ??Non-magnetic ??Inert to strong acids / bases

Apr 1, 2005

By Arnis Mangolds

A study of the technical and economic feasibility of using a unique undercut and fill system developed by USBM engineers to mine steeply pitching coal is discussed. A brief resource assessment has indicated that significant reserves exist in most coal regions to justify the development of a safe and economical method of extracting steeply pitching coal. The undercut and fill system combines hydraulic coal cutting with unassisted gravity fluming of the coal slurry. Mining occurs across strike and the extended entry is backfilled to provide uniform strata control and an impermeable water and air barrier. Subsequent mining occurs beneath the previously filled stope such that the roof consists of a solid, controlled back. In addition to providing positive roof and hanging-wall support, the backfill system eliminates subsidence potential, post-mining drainage, and the danger of spontaneous combustion from naturally drafting air currents. A unique through-flowing ventilation system permits passage of return air through the production face via ducting located at the backfill-coal junction. This provides a constant supply of fresh air at the face, eliminates the need for brattice cloths, and provides an additional escapeway for the miners. The preliminary estimates indicate a production rate in the neighborhood of 31.9 tons/ manshift. Capital costs are approximately $3.17/raw ton over a 20-year life with an initial investment per annual ton of $48.29. Total cash-costs for labor, supplies, power and benefits range in the vicinity of $19.59 for a 704,460 ton/year mine, or a total cost of $22.76/ton. These costs do not include federal and local taxes or post-of-money; however, the cost of coal is well within the area selling price.

Jan 1, 1981

By M. S. Klima, P. T. Luckie

Proper analysis of washabiity data can lead to the development of a maximum yield coal preparation plant flow sheet. Simulations, as simple as spreadsheet mass and water balancing, are important in examining yield maximization and middlings liberation. Key to such attribute tracking flow sheet simulations is the distribution model, expressing the probability of a species reporting to the product stream. There are many such models in the literature. This paper examines a functional form that can represent or fit most of the proposed distribution functions.

Feb 24, 1997

Industrial Minerals production in New Zealand is limited in both quantity and range, but imported in quantities that make New Zealand the world's biggest consumer per head of population. The use of industrial minerals is assured as both population and standard of living increase regularly. But to develop these minerals in the New Zealand environment requires the mineral, or its market (both local and export), to have characteristics that negate the remote geographical location. Volume and/or uniqueness can achieve this.

Jan 1, 1997

By J. Dahner

Total milling cost is composed of energy, liner and grinding media costs. In primary high ball load milling, the grinding media play the biggest role in total milling cost. This cost can be drastically reduced by improving the impact condition inside the mill. The impact condition inside the mill is influenced by shell liner design (as well as feed end and discharge design) and the type of discharge. The improvement of the impact condition will result in a significant decrease in grinding media consumption. The softened impact condition allows for better alloy optimization, resulting in a further reduction in grinding media consumption. Optimized liner design can also improve energy consumption as less energy is wasted in the projection of the grinding media. Magotteaux utilizes tools to simulate and show the grinding media trajectories for shell and end liners. This paper will present some practical examples where the media and energy consumption can be or has been reduced by optimizing liner design. Keywords Comminution, grinding, liner design, grinding media wear.

Jan 1, 2011

By A. E. Harak

To determine the retorting characteristics of a column of mine-run, ungraded oil shale ranging in size from fines to 5-ton pieces, a 150-ton batch-type retort was designed and constructed at the Bureau of Mines Laramie Energy Research Center, Laramie, Wyo. The retort vessel is 45 feet high by 11 ½ feet inside diameter, and is supported in a 95-foot-high steel superstructure. Mine-run shale from the Bureau of Mines facility near Rifle, Colo., assaying about 25 gallons of oil per ton, was used as the test shale. To date, 11 runs have been completed, and the results of the last 10 of these are reported. The effects of oxygen content of the retorting gas and the superficial gas velocity of the retorting gas on oil recovery from a column of mine-run oil shale were studied. In one run, the average particle size of the shale was substantially increased to determine its effect on oil yield. Oil recoveries ranged from a low of 39.3 to a high of 65.8 volume-percent of Fischer assay.

Jan 1, 1974

By Bradley Stoughton

(Cleveland Meeting, October, 1912.) [SECRETARY'S NOTE.-To avoid repetition of foot-notes, references to authorities are made in this paper by means of figures, referring to a numbered list in the appendix.-J. S.] INTRODUCTION. THIS paper gives the results : first, of a research into the somewhat extensive literature of titanium; and second, of a series of original tests upon the effect of titanium on iron castings. New investigations have also been made upon the effect of titanium on steel, but I hope to treat this subject in an independent paper at some later date, and, therefore, will not discuss the experiments in detail here. The combined results of this study, which extended over a period of more than two years, can be briefly summarized as follows: 1. Steel or cast-iron, in which the titanium is properly proportioned, and which has been properly treated, is improved in strength, toughness, and durability against wear, such as, for example, the wear of railroad-rails, of steel and chilled-iron .rolls, car-wheels, etc. 2. These improvements seem to be caused, not so much by the direct effect of titanium on the metal, as by its cleansing influence in removing harmful impurities, such as oxygen and oxides, nitrogen, occluded slags, and perhaps also sulphur. It appears also to reduce segregation, which would contribute to the same end. 3. In order that its effects may be fully realized, the treatment of steel or iron with titanium must be correctly performed. There are a few simple, but essential, details to be observed; if they are neglected, the best results cannot be expected. To illustrate by an example : A series of tests on cast iron

Nov 1, 1912

By Zhiyun Li

Room temperature infrared reflection spectra of 2 n-type homo-epitaxial epifilms have been measured in the work. The effect of the refractive index on the determination of layer thickness using traditional calculation measurement is studied and some improvements have been added to the measurement to improve the accuracy and stability of the measured results. Results of the improved method have great agreement with the results from SEM and both variance and mean relative error decrease an order of magnitude.

Jan 1, 2010

By P. H. Williams, D. J. Morris

The co-disposal of coarse and fine coal wastes by combined pumping through a pipeline to subaerial deposition was pioneered in Australia in 1990 by Jeebropilly colliery in Queensland. Significant segregation of fines is found to occur in its co-disposal delta, leading to the formation of distinct mainly coarse upper and fine-dominated lower segments; the upper delta drains rapidly and is able to support traffic on its surface immediately after deposition. An existing theory of subaerial deposition, originally developed for mine tailings alone and later extended to trial co-disposal, is shown to apply also to the upper segment of the full-scale Jeebropilly delta

Jun 19, 1905

By C. Lemmer

The resolution with which the different categories of resources are forecast for Witwatersrand gold reefs should ideally tie in with block sizes that are optimal in terms of the variability structures of the reefs. A tool, called the ?variancegram?, is proposed as a basis for block size choice. A variancegram is intrinsic to the particular reef and mine concerned. A further requirement is the ability to attach global confidence limits to weighted average estimates built up from combinations of local kriged estimates. Approximations to derive global kriging variances based on variables derived from local kriging deliver hugely inflated results if ordinary kriging is used, and markedly better, but not accurate, values if simple kriging is used. These approximations improve as the number of samples used in kriging each block is increased. It is shown that the behaviour of the different components of the global kriging variance with increasing number of samples, all differs, but they all link to the variancegram for the particular reef. The variancegram can thus be used to correct the different components to the values they would have had if all samples were used in kriging each block, and so deliver the ?correct? global kriging variance, even though only a limited number of samples were used in kriging each block. The desirability of having very stable solutions implemented in production systems is taken into account in the proposals. It is anticipated that the same variancegram findings will also hold for other densely sampled deposits, but this remains to be investigated.

Jan 1, 2014

By William E. Lardner

Interlocking caisson walls developed from conventional "soldier pile and lagging" shoring. In the latter, the soldier piles receive directly most of the soil load. Natural arches form in the soil behind the shoring; the lagging supports little more than the segment of soil inside the arch. Fig. 1: A typical layout of a lagged wall [ ] Fig. 2: A typical layout of an interlocking caisson wall [ ]

Jan 1, 1987

By J. C. Fowler

The field testing of the Seismic Mine Monitor System is described. This system consists of nine geophones buried about 40 feet deep over a ten-square-mile area, the amplifiers and electronics needed to get the signals to the mine office, and a central processor unit to detect and locate explosions and large roof falls. Since the problems associated with the original installation were solved, this system has worked for 2 1/2 months. The system has detected roof falls in the pillar areas and has located blasts as small as 114 pound of dynamite. The location accuracy has, in general, been within 250 feet. The system is now being used to gather long-term data on the seismic activity of the mine.

Jan 1, 1974