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By W. G. Davenport

The Cu content of industrial flash furnace concentrates varies considerably. It is usually around 30% Cu (Tables 2.1, 3.1) but it may be as high as 55% Cu and as low as 20% Cu. The mineralogy of flash furnace concentrates also varies. The most common Cu mineral is chalcopyrite (CuFeSz), but many concentrates contain bornite (CuSFeS4), chalcocite (CU2S), covellite (CuS) and even native copper (CUO). Pyrite (FeSz) :is also present in many concentrates. This chapter examines how concentrate composition affects flash smelting -with specific reference to 'low-Cu-grade' FeS2-CuFeSz concentrates. Chapter 14 does the same with 'high-Cu-grade' CuzS-CuFeSz?concentrates.

Jan 1, 2001

By Tiejun Chun, Jian Pan, Deqing Zhu, Vinicius Mendes

"Fine manganese fines are characterized by large amount and low price compared to lump manganese ores. However, fine manganese must be agglomerated as EAF (electric arc furnace) feed. In this paper, high quality fired pellets were produced by simulating grate-kiln process to supply the feed for EAF from some imported manganese ore fines containing high combined water. Manganese ore fines assaying 44.47wt%Mn, 5.89wt%Fe, 12.09%LOI and with 72.7wt% ranging between 0.5mm and 8mm, are pretreated up to the particle size of 84.7wt% passing 0.074mm by HPGR (high press grinding roller) twice in open circuit. The finely ground manganese fines were mixed with 1.2wt% bentonite, balled at 15% moisture for 7min in disc pelletizer. The drop numbers, compressive strength and thermal shock temperature of green balls reach 11 times/0.5m, 11 N/pellet and 360oC, respectively. After the green balls drying in the oven, the dry pellets were preheated at 1050oC for 12 min and then fired at 1300oC for 12 min in electric tube furnace. The compressive strength of fired pellets reaches 2621 N/pellet. Therefore, these pellets are high quality burden for blast furnace or EAF due to high mechanical strength and high Mn grade of 49.11wt% and low detrimental elements.IntroductionManganese, mainly using as deoxidizing agent, desulfurization agent and alloying elements, is widely used in the steel company. With the rapid development of iron and steel industry in China, domestic manganese ores cannot meet the requirement, resulting large quantities manganese ores import to China [1-4]. Compared to lump manganese ores, fine manganese ores containing high combined water are characterized by large amount and low price. However, they must be agglomerated as EAF (electric arc furnace) feed. There are three ways to agglomerate the manganese fine ores, sintering, briquetting and pelletizing [5-6]. Compared to the other two methods, pelletizing technology possesses the following superiorities, such as uniform size distribution of product, stabilizing chemical composition of product and lower energy consumption in producing. Therefore, pelletizing is a superior way to treat the fine manganese ores [7]. The systematic research of producing manganese oxide pellets by fine manganese ores containing high combined water was studied in this paper."

Jan 1, 2011

By Mike Dry

While McCabe-Thiele plots are useful for designing single-component solvent extraction systems, not least because of their simplicity, they are less useful for multi-component solvent extraction. This paper presents a relatively simple method, compared to other approaches, for modelling solvent extraction as chemical equilibrium reactions between the various aqueous and organic species. The essence of this approach is how values for the equilibrium constants can be extracted from standard laboratory data. Synergistic solvent extraction of nickel is used to illustrate the method.

By Frank A. Vonesh

In order to reduce the amount of visible, airborne emissions in the Metals Industry, a new Industrial Gas Technology was developed by Air Liquide. This patented technique is called ALECT?, Air Liquide Emission Control Technology. Demonstrations have been conducted for many cutting and lancing operations as well as for hot metal transfer from vessel to vessel. Fume reductions of 90% and greater have been achieved in actual practice. Air Liquide continues to improve the process and the associated control equipment.

Jan 1, 1994

By Xuewei Lv

An intelligent recognition and quantification system for the micrographs iron ore sinter was developed in the current paper. The average distribution parameters in a gray histogram of minerals by a Gaussian gray distribution model were obtained. The feature curves of the gray histogram of two minerals were achieved by combining the two density functions. The feature indexes, such as the number and position of the peaks and the valleys of two minerals in different ratios, were quantified by differentiating the distribution functions. This algorithm is able to extract the feature of the minerals adequately and accurately for recognizing the composition and phases of the minerals intelligently.

Jan 1, 2009

By Masaaki Naito

The Japanese steel industry has a long history of introducing new and innovative technologies in the field of ironmaking. The new technologies introduced during the past ten years include technologies to use cheaper and lower-grade raw materials and fuels, measures to prolong the service life of blast furnaces and coke ovens, promotion of energy saving, use of wastes and solutions to environmental problems. This report outlines the condition of production and technological trends and technical development themes in ironmaking technologies.

Jan 1, 2006

By Björn Lindquist

Boliden has developed a number of specialised technologies for smelter gas handling and effluent treatment. These technologies will be described. Special attention will be given to the high-pressure venturi, Editube wet electrostatic precipitator, mercury removal processes, and two-stage effluent treatment.

Jan 1, 2002

By James D. Navratil

Neutral bifunctional organophosphorus solvent extractants (such as carbamoylmethylphosphonates and carbamoylmethylphosphine oxides) strongly extract lanthanides and actinides and do not extract more than 40 other elements from mineral acids. Because of their excellent properties they have been found useful for F-element recovery and purification processes. A brief overview of the lanthanide and actinide extraction chemistry of these reagents will be given.

Jan 1, 1990

By Peter Fischer

A demonstration plant for QSL technology with a continuous through-put of up to 10 t/h concentrate has been in operation at the Berzelius smelter, Duisburg, Germany since early 1981. In the QSL-process, both oxidation and reduction steps are performed in a single horizontal long cylindrical reactor. In the present demo-reacior, 2.5 M diameter by 22 M long, these steps are separated by a low partition wall with an underflow opening, to prevent backmixing of slag. -Tests on a variety of concentrates, including high-lead Missouri-type material and lower grades, have shown recoveries and consumables indicating very attractive economics. Investment cost estimates further enhance the economic attractiveness. Environmental protection afforded by the QSL system is a major advantage. The process has proven its reliability and versatility and is now ready for commercialization. Continued test work, including smelting secondary lead materials, is planned.

Jan 1, 1983

By Xiaobing Yang, Animesh Jha, Greg Doughty

"Successful use of inert anodes should reduce the CO2 footprint in aluminum production. The search for a “holy grail” inert anode for metal electro-winning from constituent oxides using molten salt bath as an electrolytic medium is continuing. In this article we demonstrate the engineering approaches for the fabrication of intermetallic anodes, based on a quaternary Al-Ti-Cu-M (M:Ni, Fe) system for primary aluminium production. In particular, we examine the microstructural and electrochemical properties of alloys, based on the quaternary compositions. We explain the aspects of phase stability under anodic potential, which leads to the loss of anodic materials in the temperature range of 850-1050oC. The results are analysed in the context of oxidation reaction and formation of oxide layers which readily dissolve in the cryolite melt and prevent passivation. The paper also describes the conditions under which the reduction of aluminium at the graphite cathode occurs which also strongly depends on the molten salt chemistry for the nucleation of molten aluminium at the cathode.1. IntroductionOxygen-evolving inert anodes are an alternative to the conventional consumable carbon anodes for the production of primary aluminium. In this paper the materials selection criteria chosen for the engineering of anode is based on the understanding of the thermodynamic stabilities of aluminide intermetallic phases, some of which are formed and remained stable in fluoride melts. For example, the formation Al3Ti dispersed in aluminium metal via molten-fluoride flux reaction is well known in the context of aluminium casting and grain refining [1-3]. It is for this reason in our research we concentrated on the engineering of stable intermetallic phase mixture in the Al-Ti-Cu ternary system, shown in Figure 1 [4]. In this figure two compositions in the Al3-0.5zTi1-0.5zCuz family are shown with the substitution of 7 atomic % and 11 atomic % copper. However initial investigations showed that these two compositions were unsuitable due to the formation of low-temperature liquid (~540oC) and intermetallic phase, Al2Cu along the Al-Cu binary edge during solidification. The Al2Cu phase segregated along the boundaries of Al3Ti and Al5Ti2Cu, and dissolved away when electrolysis was carried out using these anodes above 800oC. The presence of consequential porosity in the anode material increased the corrosion of the alloy through local heating due to high current density at 0.8 A cm-2. The early tests were carried out with cryolite melts, shown in Figure 2, having 3 weight percent of Al2O3 in the bath at 850oC."

Jan 1, 2010

By Roma T. Dec

Many industrial wastes may require preliminary processing to change their particle size, density, surface properties or flowability to become more suitable for treatment and recycle. This can be achieved by pressure agglomeration using roll presses. In the following paper an overview of various roll press processing methods like briquetting, compacting, compacting-granulating or densification is presented together with basics of process and equipment design. The emphasis is focused on major factors influencing compaction process and responsible for pressure build up and final product quality. Finally, two examples of roll press application for briquetting of steel plant wastes and compaction of alumina base catalyst tailings are introduced.

Jan 1, 1996

By A. G. Jackson, Rand R. Biggers, John D. Busbee, Iman Maartense, David P. Lubbers, David C. Liptak

"This paper describes the application of Raman Spectroscopy for characterizing superconducting YBCO thin film parameters. Attenuation of the substrate Raman spectrum as a function of material deposited is established. Also a correlation between film quality and Raman spectrum is explored. The identification and discrimination of superconducting and non-superconducting phases of YBCO is presented. The critical temperature (Tc) of a film as a function of its oxygen content is also established using Raman peak ratios. These results provide significant implications toward the use of Raman Spectroscopy for in situ monitoring and control of the PLD process. Film quality can be controlled via optimization of film oxygen content and reduction of improper YBCO phases. Film thickness can be controlled by monitoring the response of the substrate material. Also the PLD process can be studied and modeled using this powerful observation tool.IntroductionSuperconductors are materials that possess unique characteristics when cooled to sufficiently low temperatures. Below a material's critical temperature (Tc) it exhibits zero resistance to current flow. One such material, yttrium barium copper oxide (YBCO) has a critical temperature of approximately 92° K. Due to its high critical temperature YBCO is being aggressively researched for many possible applications, because of high current carrying capability and strong pinning of flux lines.YBCO in the 123 form is a ceramic material that was discovered in February, 1987. Its unit cell structure is shown in Figure 1 [ 1,2]."

Jan 1, 1997

By K. C. Mills, P. N. Quested, A. P. Day, R. F. Brooks

"Methods have been developed to measure the physical properties of molten materials relevant to the fluid flow in high temperature processes. Data for the densities, viscosities and surface tensions of Al-, Ni- and Fe-based alloys are compared with (i) values for the pure metals and (ii) estimated values obtained from models making use of chemical composition of the alloy. Experimental values for metallurgical slags are also given and compared with estimated values.1 IntroductionPhysical property data has proved very useful in improving process control and product quality. For instance, in the continuous casting of steel the viscosity (TJ) of the mould flux is important since it determines (i) the optimum casting conditions, nVc = 2.5±1 dPas (m min-1) where V c is the casting speed and (ii) the level of slag entrapment (which leads to inclusions) in the metal. Thus data for properties like viscosity are exceedingly useful in understanding the process and the problems encountered and the causes of defects and problems.Another interesting development which has helped to increase our knowledge of processes and improve process control and product quality is the development of mathematical models of the fluid and heat flow in the process. These models have been developed to the stage where one of the prime requirements is for good physical property data for the industrial materials involved. Recently, Oxley [1] has shown that the use of reliable, experimental, property values for the commercial alloy in a commercial software package produced a significant improvement in the prediction of casting defects. Thus reliable property data are required for liquid metals but also for (i) liquid slags since many processes involve the use of a slag to refine and protect the metal or to lubricate the mould and (ii) refractories, sand and investment moulds."

Jan 1, 1999

By Guo Chen, Jin Chen, Jinhui Peng

In this paper, solving common problem of electrostatic precipitator (ESP), which was frequently ruptured of the cathode insulation in the production process were studied. The microwave heating airflow technology was introduced, which takes full advantage of its unique properties, solves the output problem of the high temperature air, achieves purpose of energy conservation, important economic significance and environmental significance. The mathematical models and designing of microwave high-temperature hot air system was calculated. The common forms of heat exchangers and comparative analysis were also introduced. The conditions found to be at the temperature of 240 °C. Under optimum conditions, the microwave heating power was 1482 W. Based on the mention results, this microwave heating method can be applied effectively and efficiently way for the production process of electrostatic precipitator.

Jan 1, 2015

By C. G. Bastos Andrade, V. F. Justo, F. R. Valenzuela-Diaz, M. G. S. Valenzuela, C. M. Matos, C. Volzone

For industrial use, the smectite clays are usually treated with inorganic acid of high concentration at temperatures under boiling point, which provide the bentonite´s bleaching power. In the present paper, a sample of brown smectite from Paraiba, Brazil, was submitted to treatment under moderate conditions (90°C, reaction times of 1, 6, 12, 18 and 24hours in close reactor, concentration of the aqueous solution of hydrochloric acid 1.5M, clay/acid solution ratio of 1g/10mL), aiming to reduce impurities, responsible for the color of the clay, without causing significant changes in their structure. The samples were characterized by scanning electron microscopy (SEM), energy dispersive X-ray detector (EDS), stereomicroscopy, Cation Exchange Capacity (CEC), Thermal Analysis (TG/DTA), and X-ray diffraction (XRD). It was observed a bleaching in samples with time of 12h to 18h. With the DRX was possible to monitor the peak intensity of the clay structure and the sample with 12 hours of treatment was not significantly altered its crystalline structure, maintaining the peak clay at d(001). The most pronounced changes in the bleaching occurred within the first 12 hours of acid treatment. Thus, clay can be used in products with high added value.

Jan 1, 2015

By J. J. Rush

Neutron scattering and analysis techniques are extremely powerful, often unique, probes for the characterization of the amount, location, bonding states, and dynamics of hydrogen in all classes of materials. Developments over the past decade at the NIST Center for Neutron Research and elsewhere have greatly increased the sensitivity and dynamic range of neutron methods. In this paper, we provide a flavor of the capabilities of modem neutron instrumentation for the study of hydrogen in a number of technologically interesting systems, including metal hydrides, fuel-cell materials, fullerenes, and disordered carbons.

Jan 1, 2002

By Cailing Zhen, Jian Pan, Deqing Zhu, Xianlin Zhou, Yanhong Luo, Guixiang Huang

The grate-kiln process has been widely applied for oxide pellet production with the quick development of steel industry in China, but ring formation takes place which adversely affects the productivity and properties of fired pellets. Rotary kiln at high temperature seems a black box, and ring formation is difficult to measure directly by current technology. It’s of great importance to monitor ring formation during firing of pellets. Therefore, a method for estimating the thickness of ring formation in rotary kilns was studied, based on working out theoretically the relationship between ring thickness and the outside surface of the kiln, according to steady-state heat transfer across a cylinder, which provides a soft-sensing technique for ring formation at high temperature, and achieves stable pellet production .

Jan 1, 2015

By E. A. Thiers

The causes of structural changes in the markets for high technology alloying metals are discussed in terms of technological, economic, and financial trends. Recent market imbalances have affected producers in developed and developing countries differently. Possible response strategies for suppliers in the two types of countries are examined that may alleviate future market imbalances.

Jan 1, 1988

By Honglei Zhang, Wuguo Xiang, Xinhao Huang, Guotao Xu, Xilai Chen

"The service behavior of refractories used in hot air pipeline for hot air stoves in a 3200 M3 blast furnace of WISCO was analyzed. The damage factors can be concluded as the poor quality of and alusite based bricks, the severe thermal shock damage, the more porosity in structures, loose bonding capability, and the unreasonable choice of materials and design of bricks. By analysis, the service life of hot air stoves can be enhanced by the measurements such as the reasonable choice of materials and their match, the use of light-weight refractories, the improvement of brick type, etc. Thereafter, the normal production operation of hot air stoves is guaranteed.IntroductionThe No.7 blast furnace of WISCO has been used for about 5 years and it was mid-repaired in March, 2012. The top phenomena of worn hot air pipelines are brick drop, breakage, severely local wear and deformation, existing hidden danger, so the worn hot air pipelines were renewed. Investigations have been done on the stove damage and design [1,2]. In order to clarify the wear mechanism, the used refractories for hot air pipelines were sampled and analyzed, the properties and structures of worn materials and reused materials are relatively studied."

Jan 1, 2013

By T. Asahina, M. Nakamura, M. Mabuchi, I. Shigematsu, M. Nakanishi, G. Yamauchi

"Commercial stainless steels (SUS304L and SUS430) were subjected to equal channel angular extrusion (ECAE) at room temperature to a total strain of 2.3 to 9.2. For each type of stainless steel, it was shown that the sample processed by ECAE showed higher room temperature strength than the as-quenched sample. This is probably due to the heavily worked structure. On the other hand, both strength and elongation of the ECAE processed SUS430 were increased by annealing at 773K. It is likely that higher strength is attributed to both the heavily worked structure and fine substructures. It is also likely that higher elongation is attributed to the fine substructures. It is concluded that ECAE is available for improving the room temperature strength of commercial stainless steels.INTRODUCTIONEqual channel angular extrusion ( ECAE ) is a technique that provides the repetitive deformation and allows to high intensity of deformation. With this procedure, a sample is pressed through a channel that has an equal cross section but bent at an angle of ?> [1-2]. Shear strain is introduced when a sample passes through the bending point of the channel. Repetitive processing is feasible because the cross-sectional dimension of a sample has no change during processing. To date, many reports have described that ECAE is available for the fabrication of fine-grained materials [3-14]. On the other hand, an ECAE processed sample can achieve high intensity of deformation through repetitive deformation. According to the equation given by Segal [ 2 ], a strain of about 1 is introduced in each pass through die if the angle ? is 90 deg.It is well known that high tensile strength can be achieved in metallic materials through work hardening [15]. It is also known that metallic materials with fine grain size show high strength [16]. Hence, it is expected that ECAE is available for strengthening method in metallic materials. In the present paper, we will report the mechanical properties of stainless steels processed by ECAE. As samples, SUS304L austenite stainless steel and SUS430 ferritic stainless steel were chosen. Each alloy has a single-phase structure (fee or bee) and shows no phase transformation, so that transformation strengthening cannot be applied. Hence, a heavy cold work such as ECAE may be effective for strengthening of this stainless steel. Annealing was conducted for the ECAE processed SUS430 to vary its microstructure. Then, the effect of annealing on the strength of the ECAE processed SUS430 was also investigated."

Jan 1, 2000