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By R. R. Brown

The solubility and the activity of aluminum chloride hexahydrate, A1C13?6H2O, in aqueous solutions were determined as a part of the Bureau of Mines, U.S. Department of the Interior, research to improve mineral processing technology for recovering alumina from low-grade domestic resources. The solubility of A1C13 in pure water was found to be 31.09 and 31.77 wt-pct at 25° and 85° C, respectively, and decreased drastically to 10 and 0.1 wt-pct when the respective amounts of 20.3 and 37 wt-pct hydrochloric acid (HCI) were added in solution. The equilibrium constant for the solubility of hexahydrate, activities, and activity coefficients of A1C13 and H2O were calculated and compared with the results from the available methods of estimation. The results were shown to be useful in leaching nonbauxitic ores for extraction of alumina by changing the solubilities of component salts upon addition of HC1. Simultaneous solubilities of A1C13, FeC13, KC1, and NaC1 in solutions of HC1-H2O were also determined and their effects on the purity of A1C13?6H20 crystallized from mixed salt solutions are briefly discussed.

Jan 1, 1979

By Jack G. Croeni

A study was made by the Bureau of Mines to determine the influence of high energy-rate deformation on the structures and properties of low-carbon steel, stainless steel, titanium, titanium-6 percent aluminum-4 percent vanadium, beryllium, molybdenum, and tungsten. The purpose of this study was to determine relative formability, the effect of energy and temperature on metalworking parameters and resulting structures, and the properties of materials formed by this technique. Forming techniques were limited to upset forging and direct extrusion on pneumatic-mechanical forming machines. Results show that considerable grain refinement can be achieved by careful control of deformation and forming temperature by high energy-rate techniques. Significant improvements in strength were observed as a result of this refined structure. Approximate deformation resistance as a function of temperature was determined for a variety of materials.

Jan 1, 1966

By John B. Gayle

The probable inadequacy of physical tests of coke for the purposes for which they are made has been a subject for discussion for many years. However, little has been published in this connection, even though most workers in the field believe that the physical properties of coke are of major importance in its utilization in the steel and allied industries. In fact, the reproducibility of the recognized tests is largely unknown or can only be approximated. This situation occasions many difficulties when attempts are made to judge the coke-production qualities of various coals or coal blends. During World War II the Coke Production Committee, composed of representatives from industry and the Solid Fuels Administration, concluded that study of existing testing methods and possible improvements would be of material assistance in answering questions relating to coke quality. Since that time the Bureau of Mines has taken samples of coke produced in industrial slot-type coke ovens in connection with studies aimed at extending coking-coal reserves by adding to the list of sources known to be suitable for this purpose. Testing procedures on these cokes were arranged so that the data obtained would yield information on (1) the degree of precision of tests commonly used in the industry, (2) the causes of the known poor reproducibility in several of the physical tests, and (3) possible improvements or modifications of existing physical testing procedures.

Jan 1, 1953

By P. D. Kovscek

The Bureau of Mines has tested a low-thrust water-jet-assisted rotary drill. This work was performed to evaluate the performance of a water-jet-assisted drill operated at thrust levels typical of a handheld manual-thrust operation. Prior work by the Bureau had indicated that using water-jet assist with high-thrust drilling applications would increase drilling rate. Small-diameter holes were drilled in five different types of rock. Thrust and water pressure were varied as the drill rate was monitored. The test results indicate that drilling rates increase with increasing water pressure and thrust. The water jet has more effect on reducing the specific energy when drilling in the harder rocks than in softer rocks. Variation in drill rate for a given rock sample is attributable primarily to the material heterogeneity within the sample. One rock type (Greenwich sandstone) could not be drilled efficiently with the water-jet-assisted drill.

Jan 1, 1988

By R. Van A. Mills

Crude oils are capable of dissolving quantities of gas under pressure. This fact has been known for some time, but questions have arisen as to the effects of gas in solution upon the characteristics of the oil. Previous investigations4 show that gas in solution in an oil affects the viscosity and surface tension of the oil, but the effect's on the volume and A. P. I. gravity of the oil have not been known. The results given in this report show that there is a decided change both in volume and in the A. P. I. gravity of the oil due to the solution of the gas in the oil under pressure. As gas is dissolved, the volume of the oil and the A. P. I. gravity increase. The converse of this phenomenon is also true: if the gas is released from a saturated oil, there is a shrinkage in volume and a decrease in A.P.I. gravity due to the release of gas from solution. However, various oils show marked tendencies to retain a portion of the dissolved gas upon releasing the pressure to that of the atmosphere. This retained gas has an appreciable effect on the volume and A. P. I. gravity of the oil because the oil does not resume its initial volume or gravity while it retains dissolved gas. In a sense the oil has been "Freshened" and will not return to its original or weathered volume until it loses some of the lighter fractions. Wiggins5 has shown that a fresh oil decreases both in volume and in gravity because of the weathering of the lighter fractions while the oil is standing in storage tanks.

Jan 1, 1928

By Frank J. Wiebelt

In its efforts to maintain production of tungsten during the recent war period, the Bureau of Mines explored certain parts of the properties of the Atolia Mining Co. in San Bernardino County, Calif., by diamond drilling. Owing to past production record and other available data, the area was considered attractive for possible development of new ore bodies. Scheelite occurs in narrow veins ranging in width from a fraction of an inch to several feet. The veins are in quartz monzonite in a zone 2 miles long and 500 feet wide. Production from the district was reported to have been over 1,000,000 units of W03. Twelve diamond-drill holes, totaling 5,056 feet, were drilled by the Bureau of Mines in the vicinity of the Papoose, Papoose No. 5, Amity, and Union mines, the tailings pond, and the "Old Spud Patch." The work began in August 1943 and was completed in June 1944. This publication briefly describes the history and deposits of the district and gives full details of the work performed by the Bureau.

Jan 1, 1950

By E. A. Pelczarski

Initially, the objective of this contract was to develop a PWSCSR that could meet proposed criteria (that were different from 30 CFR 11(Title 30 of the Code of Federal Regulation part II) and that would be less than twice the size and weight of a filter self rescuer. This objective was met. Consequently, the original contract was extended to develop a PWSCSR that would meet existing CFR-30 criteria within the same size and weight constraints. This resulted in the development of a PWSCSR (the SR-100) that received NIOSH/MSHA approval (TC-239). This report presents a historical discussion of the design and development of the SR-100 as developed by CSE Corporation under Bureau of Mines contract number H0368013. The technical parameters and the test results of NIOSH/MSHA 30 CFR 11 certification are also presented.

Jan 1, 1990

By A. A. Sonnek

A simple, portable helium analyzer was developed primarily for field use. Its utility lies in making preliminary surveys before exact analyses are required. The analyzer is based upon chromatographic principles; that is, separation of gas mixtures resulting from variable retention times of the components with respect to a separation medium (column-packing material). It uses thermistors for sensing detectors, a dry battery as source of power, and a micro-ammeter for indicating helium concentration. The absolute accuracy of the instrument depends upon the recency and care with which the instrument is calibrated with a standard gas. The unknown gas should be analyzed immediately after calibration, and another calibration should be made before another unknown sample is analyzed. The instrument is simple to operate, requiring approximately 15 minutes, after calibration, to determine the helium content of a natural gas sample. Although developed primarily for helium determination, the analyzer possibly can be used for other analyses that can be performed at ambient temperatures.

Jan 1, 1965

By John P. Walsted

Because of the absence of an iron-producing industry, the Pacific Northwest is working under an economic handicap. This is particularly apparent in the gray-iron-foundry industry because of the high price of pig iron imported from foreign sources or shipped in from producing ?areas within the United States. The high prices and sometimes short supply of ferrous metal products has put a brake on industrialization, which has been only partly compensated by the availability of cheap electric power. The economic condition of the gray-iron-foundry industry could be improved by establishing a small iron-producing industry based on the locally available ores. Moreover, establishing a local iron smelter would create a market for resources now dormant. Low-grade ores of manganese, chromium, and nickel would become usable in industry when combined with the iron ore from Scappoose. Pig iron produced in even limited quantities would level out the fluctuation in supply. The ore deposits, being small, would not supply enough pig iron to satisfy the entire demand. This condition necessitates designing special pig irons that will carry abnormally high proportions of scrap in the cupola charge.

Jan 1, 1955

By John E. Pahlman

The Bureau of Mines conducted column-leaching tests on 25 domestic Mn ores to determine the feasibility of extracting Mn by in situ or heap leaching with dissolved sulfur dioxide (S02) solutions. The ores tested were obtained from deposits in Arizona, Arkansas, California, Colorado. Maine, Minnesota, Nevada, and South Dakota. Dissolved S02 was found to be effective for leaching Mn; extractions greater than 90 pct were obtained with solution application rates of 1 mL/min from uncalcined, minus 2.5-plus 1.3-cm ore pieces. Leaching these ores with solutions containing only 5-wt-pct S02 and no added H2S04 resulted in Mn being selectively extracted over Fe except when Fe was present as goethite or siderite. Ca solubilization was inhibited by controlling the solution application rate (1 mL/min). The rate of leaching was found to be principally dependent upon the rate at which the leaching solution can penetrate the ore, since the solubilization of Mn upon contact with S02 was observed to be rapid. Despite low water permeabilities of the ores (as low as 10-2 to 10-4 darcy). greater than 90 pct of the Mn was extracted from even the largest ore pieces tested (approximately 10 cm in diameter). It appears, therefore. that leaching Mn opens up the pores, allowing penetration of the leach solution into the ore pieces.

Jan 1, 1988

By Thomas M. Barczak

This U.S. Bureau of Mines report describes methods to enhance the capacity, stiffness, and timber utilization of wood crib supports. Since stiffer supports minimize strata deflections that contribute to roof instability, efforts to maximize crib stiffness while maintaining stability through a wide displacement range should be a design priority. The stiffness and capacity of conventional crib designs, employing alternating layers of wood timbers that are loaded perpendicular to the grain, can be increased by increasing the interlayer contact area or by using higher strength wood. Contact area can be increased by using wider timbers or employing more timbers per layer. Concepts that provide parallel-to-the-grain timber loading will provide substantial increases in crib stiffness and capacity. Two concepts that utilize this principle are examined: (1) an original South African design that constructs wood cribs from preformed layers (mats) of timber where short blocks are oriented vertically between horizontal slabs; and (2) a design that employs full lengths of timber placed vertically in the interior of a conventional crib structure. These designs also provide more efficient timber utilization by providing greater support capacity per volume of wood used in the crib construction.

Jan 1, 2010

By R. V. Higgins

The, large volumes of low A. P. I. gravity oil that will remain in many shallow fields of California when such oils no longer can be recovered profitably by pumping are important potential sources of oil when ways and means are found to remove them from the reservoir sands. Estimated ultimate oil recoveries in many of the "low-gravity fields" of the San Joaquin Valley in California indicate that less than 25 percent (on the average) of the original oil will be recovered. These oils have viscosities of 1,000 or more centipoises at reservoir temperatures and, because of their high viscosity and low intensity of the reservoir pressure, the quantities that will be retained in the sands ultimately are so large and their recovery is such a challenge to petroleum engineers that the Bureau of Mines has made the study of their possible recovery one of its major projects. The fact that a slight increase of temperature materially reduces the viscosity of low A. P. I. gravity oils has 'prompted the use of various means for increasing the temperature of the oil in the reservoir sands and hence the rate of flow and Completeness of recovery of the oil. Hot oil, hot water, heated air, and natural gas, steam, super-heated steam, and the products of combustion have been circulated in wells to raise the temperature of the oil it the sands; electric heaters have been installed in wells, and butane and air have been intermittently exploded and the flames propagated through the tubing to the "pay" zones. None of the methods, however, have been entirely satisfactory for the recovery of large quantities of oil.

Jan 1, 1949

By H. A. Watson

The introduction and use of synthetic materials in various applications may lead to potential hazards from toxic, gaseous, decomposition products if these materials are subjected to conditions abnormal to their intended use, such as high temperatures or burning from accidental causes. This report covers an investigation of such possible hazards from toxic gases produced by the burning or thermal decomposition of some low-density, expanded, synthetic materials, three of which consisted of polyvinylchloride and one of acrylonitrile. In the production of certain expanded plastic materials, Chemical blowing agents frequently are used to produce a cellular structure. One of these blowing or foaming agents contains azo-bis-isobutyronitrile, which is designated in this report as PN. Information indicates that a product of decomposition of this blowing agent, formed in the blowing operation, is tetra-methyl-succino-nitrile, designated as TSN, Which is significantly toxic. Decomposition of the blowing agent, with release of its azo nitrogen, is represented by the following reaction:

Jan 1, 1951

By N. S. Dalal, A. H. Hoffman, X. Shi, D. E. Banks, J. K. H. Ma, Y. Rojanasakul

Excessive production of reactive oxygen radicals by alveolar macrophages is proposed to play an important role in oxidative lung injury. A major product of oxygen radical formation is the highly reactive hydroxyl radical (•OH) generated via a biologic Fenton reaction. In addition to its known ability to induce lipid peroxidation, recent studies have suggested that the •OH may exert its cytotoxic effect through the alteration of [Ca2+], homeostasis. To test this potential mechanism as well as to investigate the relationship between •OH and Ca" overloading in cytotoxic injury, isolated rat alveolar macrophages were exposed to externally generated radical system, H2O2 (0.01 to 1 mM) and Fe (1 mM) and their [Ca2+] levels and cell injury were monitored using quantitative fluorescence microscopy with the aid of the specific Ca" indicator, Fura-2, and membrane integrity indicator, propidium iodide. Electron spin resonance measurements using the spin trap 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) confirmed the production of the .OH radical by this system. Upon the addition of the radicals, the macrophages displayed a rapid initial rise in [Ca2+] which was followed by a slower but more pronounced [Ca2+], elevation that reached a level 3 to 5 times higher than the basal level. This process preceded cell death as evident by nuclear propidium iodide fluorescence. Depletion of extracellular Ca" inhibited both the [Ca2+], response and cell injury. Preincubation of the cells with the Ca" channel blocker verapamil or .0H radical scavenger mannitol similarly inhibited the [Ca2+], rise and loss of viability. Firefly luciferase assay of cellular ATP content demonstrated that the alterations in [Ca2+], following .0H treatment preceded the depletion of ATP. Changes in membrane potential caused by Na* substitution with K* had no significant effect on either the unstimulated or stimulated [Ca"], levels. Taken together, these measurements indicate that .OH-induced injury in alveolar macrophages is associated with the alteration in [Ca2+], homeostasis. The mechanism of •OH-induced [Ca2+] loading is not due to nonspecific membrane damage or energy depletion, but mainly due to an increase in Ca2+ influx through Ca2+ selective channels. This Ca2+ over-load state as well as energy depletion caused by the oxidant may activate certain cellular degradative processes leading to cell injury and death.

Nov 1, 1995

By Doris M. Hyde

Limited geographically by size and geo-logically by origin, smaller countries and territories of the Caribbean are nonetheless engaging in efforts to encourage the initiation of mineral and mineral-related industries. Petroleum dominates the minerals sector, which otherwise consists principally of minor quantities of construction-oriented materials, usually for local consumption. The increased cost of petroleum has adversely affected most of the world, but these islands with their economies precariously balanced on the uncertainties of agriculture and tourism are especially vulnerable to petroleum's direct and indirect costs. In 1975, the Government of Antigua acquired the financially troubled West Indies Oil Company refinery at St. Johns. The refinery ceased operations in 1976. In 1979, negotiations were underway to sell Ashland Oil Co. an interest in the small, 20,000-barrel-per-day refinery for $6.6 million. In 1977, Antigua granted petroleum exploration rights to the Antigua Mineral Exploration Company, which planned to drill in an undefined offshore area, possibly between Antigua and Barbuda. The company expected to spend about $200,000 per year through 1982. There have been no reports on its activity.

Jan 1, 1981

By D. E. Andrus

This paper, which describes the milling practice at the Montana mine concentrator of the Eagle-Picher Lead Co., is one of a series being prepared by the United Slates Bureau of Mines. LOCATION The Montana mine is situated on the eastern edge of the Oro Blanco mountains at an elevation of 4,300 feet. It is in the Oro Blanco mining district, Santa Cruz County, in the southern part of Arizona, about 4 miles north of the Mexican border, 30 miles northwest of Nogales and 80 miles southwest of Tucson. Amado, a station on the Southern Pacific Railroad, midway between Tucson and Nogales, and about 40 miles northeast of the mine, is the shipping point and is reached over an excellent highway.

Jan 1, 1931

By James W. Ballard

The facts are generally accepted that an atmosphere containing large quantities of any dust is objectionable to breathe and that some dusts are more dangerous than others. Therefore, knowledge of the com-position of dusts is important in evaluating the hazard entailed on exposure. At present, free silica, of which quartz is the most abundant form, is considered one of the most significant dusts, from the standpoint of pneumoconiosis, and one State5/ has established permissible limits of air dustiness on the basis of the free-silica content of rock. The amount 06 free silica in materials used for rock dusting also has been limited.6/ Determination of free silica or quartz, therefore, is important.

Jan 1, 1940

By Errol D. Sehnke

This U.S. Bureau of Mines report provides detailed information on worldwide alumina production capacity by plant and country. The information was compiled from a variety of domestic and international sources and was based on information available to the Bureau through December 31, 1993. Capacity data represent announced installed and planned capacities and do not necessarily reflect a Bureau of Mines judgment of actual plant operating levels or timing of planned expansions, The year-end capacity is the ?nameplate" capacity or estimated production capacity, whichever is larger.

Jan 1, 1993

By Irving Hartmann

Rock-dusting of coal mines is a most important safety measure for preventing or limiting the propagation of explosions. The Bureau of Mines has recommended for many years that rock dust be distributed on the top, ribs, and floor of mine entries and other workings of all bituminous coal and lignite mines in sufficient quantities to maintain the incombustible content of the dust above the minimum requirements. Rock-dust barriers constitute a secondary safeguard used occasionally to complement generalized rock dusting at entrances to panels and side entries or at other locations. In general, rock dust can be applied effectively with modern rock-dusting machines. However, in thin coal beds, in certain back entries, and in some other areas, rock-dusting machines cannot be used conveniently. Furthermore, many small mines find the purchase of machines costly. In such cases, rock dust is not used at all, or else it is distributed by hand, a relatively slow and costly procedure. In recent years some coal mines have started applying rock dust with the aid of permissible explosives. This may be done in various ways. One method consists in placing a stick of explosive on the floor of a room or entry midway between the ribs and covering the stick with two bags of rock dust that are slit on top and set crosswise one above the other. The explosive is then fired, causing the rock dust to be distributed on the nearby roof, rib, and floor surfaces. The procedure is repeated at desired intervals until the entire area is rock dusted. The method is claimed to be rapid, safe, and inexpensive.

Jan 1, 1950

By Henry Kreisinger, John Blizard

This preliminary statement presents some of the results of tests carried out at the Lakeside Station of the Milwaukee Electric Railway and Light Co. , by the fuel section of the U. S. Bureau of Mines , in cooperation with the research department of the Combustion Engineering Corporation of New York . The object of these tests was to determine the thermal efficiency , ease of operation , and other particulars of a boiler equipped with specially designed furnace and burners for burning powdered coal . The boiler tested haş 13380 square feet of heating surface , and is one of eight boilers equipped with the Lopulco powdered coal system supplying steam to two 20,000 -Kw . steam turbines in the largest power house burning powdered coal . Twenty- six tests were run at rates of heat transference varying from 4000 to 8000 B.t.u. per square foot of boiler heating surface , and the mean thermal efficiency attained was about 84 per cent , based on the gross calorific value of the fuel as fired . The efficiency varied little with the rate of steaming , and its high value is accounted for by the small loss from incomplete combustion and the small amount of excess air which varied from 5 to 36 per cent . The coal burned had a gross calorific value of about 11500 to 12800 B.t.u. per pound , contained 2 to 5 per cent moisture , 33 to 36 per cent volatile matter and 9 to 13 per cent ash, and was so ground thaf 89 to 95 per cent would pass through a 100- mesh sieve . The ash had a softening point of 2150 to 2450 degrees F. , but did not fuse together at the bottom of the furnace because it was partly protected from the flame radiation by means of a series of water tubes connected to the boiler which were placed between the fumace bottom and the flame, ..

Jan 1, 1923