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By A. Kuriwada

Dolomite is a mineral, which consists of CaCO3 and MgCO3. In this work, a series of experiments were carried out in order to adsorb boron from a boron-containing solution using a calcinated dolomite sample, and then to desorb it from the loaded adsorbent. A particular modification on the surface of dolomite was observed when it was thermally treated at certain temperature, ranging from 750 oC to 1050 oC; in turn, it is the specific surface was increased. In other words, the experimental results suggested that the calcinated dolomite exhibited a high adsorption capacity for boron, indicating its effectiveness in effectively adsorbing boron from drinking water or wastewater.

Sep 1, 2012

By H. Hamza, M. R. MacIver, M. Pawlik, L. Malin

"Size and shape are important properties of aggregates formed in engineering processes and natural systems. Measurement of aggregate size or shape is a challenge when the solids concentration is beyond the gel point, ?? > ??g, when the aggregates are in contact and it is difficult to distinguish or segment individual particles in the network. This paper describes the use of a micro-computed tomography (micro-CT) method for the calculation of the aggregate volume fraction, ??, and a characteristic aggregate length, ??a, based on a 3D chord length measurement algorithm. These parameters can be used to quantify changes in aggregate and pore size during a compressive yield stress test to help understand the impact of flocculation and network structure on dewatering. INTRODUCTION In a thickener, flocculation is often used as a pre-treatment step and the final solids content of the underflow depends on the network strength and permeability of the bed formed by settled aggregates (Usher, Spehar, and Scales 2009). This paper describes the measurement and analysis of micro-computed tomography (micro-CT) of flocculated mineral sediments to obtain a characteristic length, ??a, of the aggregate and pore phases during a staged compressive yield stress experiment. This parameter may be used as an indicator of changes in aggregate and pore size to quantify material behaviour in solid-liquid separation processes that depend on self-weight compression or applied pressure. This analysis was carried out to help understand the effect of flocculation on aggregate structure and the thickening process as part of a broader research on the improved solid liquid separation of tailings produced in the oil sands industry.Aggregate properties The solids phase of an aggregated or flocculated suspension will eventually settle – if left undisturbed – under the influence of gravity. As settling of a flocculated suspension continues, the solids volume concentration, ??, may increase to the gel point or gelation threshold (Landman and White 1994), ??g, above which the aggregates form a network of touching particles, or space-filling structure (Kranenburg 1994). In the sediment bed, the aggregates are surrounded by fluid and occupy a partial volume fraction, ??, according to"

Jan 1, 2018

By Michael. H. Moys, Clayton Bhondayi

An electro-resistive measuring technique developed by the authors was used to study the effects of superficial gas velocity and froth height on froth phase bubble sizes as a function of height above the pulp-froth interface. Flotation tests and the bubble size measurement were carried out in a laboratory mechanical flotation cell that was operated in a pseudo-steady state mode using primary rougher tailings slurry from Lonmin Platinum as feed. The values of intra-bubble impact distances (IIDs) which are the estimates for froth phase bubble sizes obtained from the measurements indicated that as superficial gas velocity was increased, the values of IIDs decreased for the two froth depths tested. Increasing froth height at fixed gas rate resulted in an increase in IID values especially close to the froth surface. Changing froth height and gas rate alters froth residence times; longer froth residence times mean more time for bubbles to coalesce hence larger values of IIDs and vice-versa.

Jan 1, 2014

By K. Saberyan

Zirconium and hafnium are two important elements in nuclear industries. Zirconium is used in fuel rod for its low neutron absorption. Hafnium should be separated from zirconium, because it has higher neutron absorption cross section. In this research, separation process of the mentioned elements from (Zr+Hf)Cl4 mixture produced in the Zirconium production plant (ZPP) of Iran (Esfahan) was studied employing solvent extraction method in the nitric acid medium by using tributylphosphate (TBP) as solvent, and kerosene as diluent. The effects of nitric acid, sodium nitrate and amount of extractant, zirconium concentration in aqueous phase, phase ratio, agitation time, and mixer agitation rate were investigated on the separation process. The process was optimized at 5 M nitric acid, 1 M sodium nitrate, 60% (v/v) TBP. The optimum values for phase ratio, agitation time and agitation rate were 1.5 min and 500 rpm respectively. In this condition, the zirconium extraction efficiency, and separation factor were 65.1% and 205.59, respectively. Finally, we accessed to nuclear grade in this research.

Jan 1, 2014

By G. Granata, C. Tokoro, T. Kato

The rare earth elements (REE) are composed of 17 elements that are 15 elements of lanthanide added scandium and yttrium. REE are divided into light rare earth elements (LREE) and heavy rare earth elements (HREE). Although the supply source of LREE is distributed around the world, the supply sources are unevenly distributed. Thus, the development of a new HREE supply source is required. In this study, we focused on the weathered residual rare earth ore as a new HREE supply source. Since so far this weathered residual rare earth ore could not be treated neither by flotation nor by wet high intensity magnetic separation, it was not considered as HREE resource before. In this study, we investigated the leaching of HREE from the weathered residual rare earth ore and elucidated the effectiveness of planetary milling with sodium hydroxide as a method to enhance their recovery. For this purpose, the weathered residual rare earth ore was first grinded by planetary mill in the presence of sodium hydroxide and then leached by sulfuric acid. The influence of planetary milling on HREE recovery was investigated by assisting the leaching experiments with X-ray absorption fine structure (XAFS) in cerium and yttrium K-edge. Since yttrium was the most contained HREE in the weathered residual rare earth ore used in this study, we focused on yttrium in XAFS analysis. Results clearly showed that the recovery of HREE increased by planetary milling with sodium hydroxide. XAFS analysis revealed that a part of the yttrium in the weathered residual rare earth ore was changed to yttrium hydroxide by planetary milling with sodium hydroxide. It is supposed that all HREE were affected like yttrium due to a similar behavior observed in leaching.

Jan 1, 2018

By M. Ito

Cobalt-rich ferromanganese crust and nodule ores from seamount areas contain volcanic and sedimentary rocks as substrate or nuclei. These ores require mineral processing to remove the sub-strate/nuclei rock before smelting. This paper reviews experimental results of previous investigations. Observations and analysis of 10 samples from different localities were carried out and it was found that the liberation ratio of crushed product was high even at coarse size fraction, 0.5mm to 4mm. Experimental and calculated results in the smelting stage confirmed that the separation product satisfies the standards of the subsequent smelting process if the substrate/nuclei rock is removed from the 0.5mm to 4mm fraction with high separation efficiency. There was a density difference between the substrate/nuclei rock and the ferromanganese component. Thus the coarse sized sample was treated with gravity separation; air table separation was used as a dry method and jig separation as a wet method and high grade values with high recoveries were obtained by both kinds of gravity separation.

Jan 1, 2014

By Erico Tabosa, Meng. Jun, Kym Runge, Matthew Brennan, Weiguo Xie, Dee Bradshaw

Turbulence and its distribution are of great importance in flotation cell design as they affect suspension of particles, air dispersion and particle-bubble collision rates, which in turn determine flotation performance. However, there is no mature technique to measure turbulence in three phase (liquid-solid-gas) systems such as in flotation cells. In this article, the authors present two new approaches that are suitable for measuring turbulence distribution in three phase systems and validate their applicability. The first technique uses a piezoelectric vibration sensor (PVS) to measure fluid kinetic energy standard deviation and the second technique applies electrical resistance tomography (ERT) to measure conductivity variation at a measurement position in a flotation cell. For the PVS technique, calibration of the sensor was performed to determine the values of parameters that were needed to calculate the force applied to the sensor. Then measurement was conducted in a 60L batch flotation cell and the results were compared with LDA measurement. This demonstrated that the piezoelectric sensor signal provides a good representation of fluid kinetic energy standard deviation at the position of measurement. For the ERT technique, conductivity distribution data was processed to give conductivity variations, which were then used to calculate fluid kinetic energy standard deviation at the measurement position. The spatial distribution of turbulence obtained by performing multiple measurements at different positions in the 60 litre batch flotation cell was found to agree with the PVS measurement results. These two techniques are potentially powerful tools for turbulence measurement in flotation environments, enabling a clearer understanding of turbulence’s influence on flotation performance to be determined.

Jan 1, 2014

By A. Güney

Currently, recycling technologies use relatively homogeneous plastics because hand-sorting waste feed is too expensive. Many promising technologies for separating mixed thermoplastics are being investigated, but they are still uneconomical and unreliable. Burning plastics for recycling is not used because of poisonous gases released when their burning. PET and PVC cannot be separated using conventional gravity separation techniques because their specific gravities overlap; PET density changes from 1.33 g/cc to 1.37 g/cc and PVC density is between 1.32 g/cc and 1.37 g/cc. For this reason, plastic recycling needs new techniques. Among these techniques froth flotation, also used in mineral processing, can be useful for its cost and simplicity. In this method, a plastic is selected from mixture, tried to regain its natural property, hydrophobicity. In this study the experiments were applied by using plasticizer reagents to make the selected plastics hydrophobic and us-ing NaOH to render the other hydrophilic. Post-consumed PET and PVC are evaluated by concerning the effects of selected parameters (particle size, concentration of plasticizer reagent, amount of NaOH, conditioning time and the effect of conditioning temperature). At the end of the experiments, optimum parameters for selective flotation of PET from PVC was found as particle size of -4.76 + 3.36 mm, NaOH amount of 30 kg/t, conditioning temperature of 75°C, conditioning time of 30 minutes, reagent amount of 300 mg/L. Consequently, PET was re-covered with 99.7% purity and 57% efficiency.

Jan 1, 2014

By Rintaro Hayashi

The enrichment of useful components from ores and/or wastes has become important with increasing recent worldwide resources demand and the amount of wastes generated from the urban mines, in order to establish real ?sound resource-cycle society? including the activity of resource exploitation. The first stage of the treatment in the process must be comminution and it is important to make good liberation among compositional phases in the targeted resources. Electrical disintegration (ED) is well known to make a selective breakage at phase boundary. However, the detailed mechanism of the phenomena is not clarified yet, in especial, on the influence of electrical properties of compositional materials on the liberation. This paper made a comparison between the liberation degrees of ED products and the results of electromagnetic field analysis using finite element method (FEM). In the experiments, we used several synthetic cement paste based samples in which mineral particles were dispersed to apply the ED, and in the electromagnetic field analysis, we calculated the charge density accumulated and the Maxwell stress at phase boundary. It was found, for highly insulating mineral samples, that higher breakdown voltage was necessary because electric charge was not easily accumulated at phase boundary but that higher liberation degree was obtained after the breakdown (ED). It was also found the tendency that higher liberation was observed for the samples which had higher maximum Maxwell stress calculated by the electromagnetic field analysis. From the results, the electrical charge and Maxwell stress induced at phase boundary could be driving forces of selective breakage. In addition, we also applied the ED to the printed circuit boards (PCBs) in order to concentrate miner rare metals, which were essential for producing electronic devices. It could be demonstrated that the devices installed on the PCB were easily detached from the board and that most of metal elements in the devices was exposed and liberated from the insulating plastic covers, which were broken in the ED, then, it is considered that the subsequent solid phase separation could be effective for concentrating such metal elements. Keywords: liberation, electromagnetic field analysis, printed circuit board, miner rare metal

Sep 1, 2012

By H. Gallardo, J. Yianatos

Flotation is a separation process in which mineral recovery depends on the particle surface properties. The selective collection of particles by air bubbles requires hydrophobic mineral surfaces. Hydrophobicity can be selectively induced on a valuable mineral surface by means of reagents. For this purpose, it is required that mineral grains in the ore become physically liberated or exposed in the particle surface after grinding. The grinding process generates three types of particles according their exposed surface in the floatable mineral: locked particles (0-10%), associated particles (10-90%) and liberated particles (90-100%). Locked particles have low floatability, and they typically show low recovery (<20%), while liberated particles have a high floatability and can be easily recovered (98-100%) at different particle sizes (10-150 µm). The main challenge in the flotation process is the recovery of associated particles. These particles typically have recoveries of 20-80%, but strongly depend on the particle size, particle surface liberation and collector dosage. Recent studies on particle floatability by size-liberation have significantly contributed to improving the characterization of flotation processes. In this work, a study of flotation recovery of associated particles of 10-90% liberation is presented for particle sizes (10-150 µm) and collector dosages (5-40 g/ton). In this work historical data on galena recovery based on particle cross-section composition of galena was used, assuming they represent an acceptable estimate of particle surface composition, as shown by some previous researchers. The results showed that galena recovery can be well represented by a model consisting of the interaction of a linear function and a Gamma distribution function to account for the liberation and the particle size effects. Consequently, an alternative approach for modelling the recovery of associated mineral (10-90% liberation), with a reduced number of parameters, was developed and validated.

Jan 1, 2018

By Cagri Emer

In conventional mechanical flotation cells, when the size of particles exceed a particular value, that is of the order of 100 µm for metal sulphides, the recovery of particles decline rapidly. It appears that the turbulence in the agitated vessel is sufficiently intense to rupture the forces of attraction between the particles and the bubbles, so the large particles are flung off the bubbles in the turbulent field. It has recently been suggested, that a fluidized bed would be a very favorable environment in which to contact bubbles and the particles. In a fluidized bed, particles are supported by rising flow of fluid, which separates them from each other and allows them to move freely while remaining close together. In this novel method, bubbles injected into the fluidized bed are able to rise through it, colliding with hydrophobic particles, transporting them to the top of the column where they can form a froth layer that overflows into a launder. The flow in a fluidized bed is generally slow and nonturbulent, and preliminary experiments have shown, that it is possible to collect mineral particles as large as 1 mm and coal particles as large as 5.5 mm. If the upper particle size limit can be extended, there could be significant reductions in the overall energy consumption in concentrators. Calculations show for example that if the top size for flotation could be increased from 100 µm to 400 µm, there would be a reduction in grinding energy of the order of 40%. It is therefore, important to study the mechanism of coarse particle capture in fluidized beds. In this work, the factors governing the capture rate of particles, particularly the particle and bubble size, the fluidization velocity and the superficial gas velocity have been investigated, and the results will be presented.

Sep 1, 2012

By E. Lee

Cone crushers are widely used within the mining and aggregate industries for the size reduction of minerals, ores, and rock materials. In mining applications for example, the product from cone crushers is often fed to HPGRs or directly to mills in the subsequent grinding circuit. An improved cone crusher performance can therefore result in an overall improved and more efficient comminution process. The objective of this paper is to systematically study a number of different ways of applying compressive crushing. By mathematically modelling these different crushing concepts and then theoretically optimizing crushing sequences accordingly, each concept can be studied and evaluated. In addition, aspects concerning whether or not the results are mechanically or practically achievable are considered. This study thus explores the advantages and disadvantages of different crushing concepts. In this paper, four different theoretical crushing concepts are presented and studied. The results show that in terms of interparticle crushing, optimal crushing sequences with varying compression ratios can be replaced by easier implemented series of constant compressions without significant deterioration. It is also shown that that considerably better performance is obtained for crushing sequences with both breakage modes. The subsequent comparison between such concepts indicates that different approaches can achieve the same results, and that the different concepts are comparable. It is further concluded that interparticle crushing should be kept to a minimum if fines generation or energy consumption is to be minimized, and that each of the studied concepts presents different challenges for implementation. Keywords: compressive crushing, cone crusher, optimization, modeling, crushing concept

Sep 1, 2012

By Cesar Gomez, Jaime Álvarez, Lisette Wen

Laboratory mechanical flotation cells are extensively used in mineral processing for running batch flotation tests with a variety of purposes, for example assessing feed characteristics, determining flotation kinetics, or testing of new reagents and procedures. It is known that the results obtained depend on the operation mode, self-aerated or forced-air, and on the operating conditions selected for the test, in particular impeller speed and gas flow rate. These different results are a consequence of changes in size distribution of the generated bubble population and its remarkable evolution when frother is added; variations in bubble size affect the bubble surface area flux (BSAF), a variable which correlates with particle collection. Results of a two-phase (air-water) test program designed to measure bubble size for a variety of combinations of impeller type and speed, gas flow rate, frother type and concentration, and cell volume, demonstrated the wide range of BSAF with which the cell can be operated. The results obtained in this work demonstrated that gas dispersion in a forced-air lab flotation machine is significantly affected by the characteristics of the impeller/cell geometry combination in use, and the operating conditions selected. Operating conditions must be carefully selected and maintained during the test to ensure consistent results, in particular when frother concentrations below 20 ppm are used, because frother concentration in the cell will decrease as flotation progresses as a consequence of frother partitioning to the concentrate.

Jan 1, 2014

By P. S. Mukherjee

Mineral ilmenite is a major resource for titanium, whose major application is for production of Titanium dioxide (TiO2) for pigment application. The production of pigment grade TiO2 from ilmenite was earlier carried out by acid leaching, which has now been banned due to environmental regulations. Further acid leaching leads to loss of iron metal values as sulphate or chloride which are also treated as effluent. In thermal plasma processing the metal values are recovered as high value pig iron and Titanium dioxide is recovered as Titania rich slag containing 80 to 85 percent TiO2. The Titania rich slag has now been considered as a better input material than synthetic rutile for production of pigment grade Titanium dioxide. On the other hand, high value pig iron goes for automobile industry for specific application. An Inflight-flight Thermal Plasma Processing plant, used for the production of Titania Rich slag and high value Pig iron from ilmenite, with 20kg capacity was designed and fabricated. The reactor has the provision to utilize the flue gas generated for preheating the input of raw materials. Various aspects of designing the furnace operation include viz. Feeding the raw material at a fixed rate, designing the crucible used for melting ilmenite, proper cooling arrangements, an innovative method for tapping the melt, recovery of heat from the gases, various safety arrangements which are some of the important milestone of the present work. The various operations have been carried out through a controller panel. Experiments were carried out to optimize various processing parameters using statistical modeling. Large scale experiments have been carried out at 10 to15 kg scale. The material balance has been calculate, and it has been observed, that about 95 percent recovery could be obtained for both Iron and Titanium oxide from ilmenite. The detailed characterization on Titania rich slag and iron has been carried out. It has also been shown that using the above slag, it is possible to prepare nanosized Titanium dioxide powder containing about 98 percent Titanium dioxide by optimizing leaching conditions. Keywords: titania rich slag, ilmenite, thermal plasma

Sep 1, 2012

By Kazutoshi Haga, Batnasan Altansukh, Shirchinnamjil Nyamdelger, Atsushi Shibayama, Narankhuu Ariunbolor, Gunchin Burmaa

In this study, the authors investigated the capability of an acidic thiourea solution and silicon-organic polymers (PSTM-3c, PSTM-3T) as ion-exchange resins to recover of gold from gold-bearing ore concentrates. Firstly, elemental gold present in flotation concentrates was dissolved by leaching with a solution of nitric acid and thiourea under the optimized conditions. The best result on gold thiourea leaching was obtained under a nitric acid concentration of 2 N, thiourea concentration of 2 %, and oxidant (Fe2(SO4)3) concentration of 3 %, solid:liquid ratio (S:L) of 1:20, leaching time of 6 hours at 20 °C with a gold recovery of 93.7 % for a gold flotation (unroasted) concentrate. For the roasted gold concentrate, the dissolution of gold was 94.8% under the optimized leaching condition as nitric acid concentration of 0.5 N, thiourea concentration of 2 %, and the oxidant concentration of 1 %, S:L ratio of 1:10, leaching time of 4 hours at 50 °C. Secondly, a series of sorption tests was carried out on a pregnant leach solution containing gold complex Au[S=C(NH2)2]2+ using silicon-organic polymers (PSTM-3c and PSTM-3T), respectively. The effects of solution pH, adsorption time and temperature in the sorption process are also studied. As the results, the PSTM-3c and PSTM-3T polymers were adsorbed about 94.4 % and 95.1 % gold from the pregnant leach solutions under the optimum sorption conditions, respectively. It was found that the both PSTM-3c and PSTM-3T polymers were effective for the recovery of gold from the pregnant leach solution of thiourea. Adsorption activity of the PSTM-3c and PSTM-3T polymers was confirmed by new peaks near 1700 cm-1 in the FT-IR spectrum of the gold-adsorbed polymers, respectively.

Jan 1, 2014

By K. A. Natarajan

"Interaction with microorganisms results in significant surface chemical changes on minerals. For example, chemolithotrophs such as Thiobacillus ferrooxidans and Thiobacillus thiooxidans significantly alter the surface chemistry of several sulfide minerals such as pyrite, chalcopyrite, sphalerite and galena. Heterotrophic bacteria such as Bacillus sp. could alter the electrokinetic properties of oxide minerals such as hematite, alumina, silica, kaolinite and calcite. Microbe-mineral interactions could thus be beneficially utilised in mineral beneficiation as different from bioleaching. Microbially induced mineral beneficiation unlike bioleaching deals with interfacial phenomena at mineral-solution-bacteria interfaces and surface chemical changes are brought about at very rapid rates amounting to a few minutes resulting in mineral separations in an aqueous medium.In this paper, the role of acidophilic chemolithotrophs such as Thiobacillus thiooxidans and neutrophilic heterotrophs such as Bacillus polymyxa in the beneficiation of sulfide and oxide minerals is illustrated. Mechanisms of bacterial attachment on various sulfide and oxide minerals are outlined with respect to the influence of bacterial interaction in bringing about mineral surface hydrophobicity or hydrophilicity. The role of bacterial cells as well as metabolic products such as bioproteins and exopolysaccharides in significantly altering the surface chemistry of sulfide minerals such as sphalerite and galena and oxides such as hematite, alumina, silica and calcite is discussed with probable mechanisms. Possibilities of generating mineralspecific bioreagents are outlined with respect to bacterial adaptation to mineral substrates."

Jan 1, 2003

By Robert Dunne

A review of the current ?state of the art? of refractory gold treatment will be provided. This will include a global perspective of the refractory processes that are being practiced, where they are and some discussion on why the processes were selected. Some discussion on the challenges that face the refractory gold industry will also be provided.

Sep 1, 2012

As a leading global company in the mining sector, we are committed to sustainable development. To this end, we invest in the responsible, integrated management of economic, environmental and social issues. Vale?s objective is for our businesses to produce local, regional and global prosperity, enabling the construction of a positive legacy throughout the lifecycle of our activities. This covers everything from talking with stakeholders and preventing failures to complying with legislation, paying constant attention to environmental issues and respecting ethics in business. Keywords: sustainable development

Sep 1, 2012

By D. Szyszka

During passing gas bubbles through mineral suspensions, some mechanical carryover of fine particles to the froth layer always takes place. The entrainment of mineral particles is influenced by many parameters, mostly by the particle size and the concentration of the frother. The paper deals with influence of selected frothers (methylisobutylcarbinol (MIBC), a-terpineol, and hexadecane tricosaethyleneglycol ether (C16E23)), common laboratory flotation frothers, on the mechanical car-ryover of quartz, a typical gangue mineral component of ores. Entrainment tests were carried out in a laboratory Mechanobr flotation machine with quartz particles suspended in aqueous frother solu-tions. The mechanical recovery of quartz in the presence frother was increasing with time and reached plateau after about 20 minutes of flotation. The plateau level of quartz recovery depended on the frother concentration. Initially an increase of the plateau with frother concentration was observed until the plateau reached the highest level called the maximum recovery emax. The emax can be used as a parameter to characterize the ability of frothers to entrainment. In the studied quartz-frother flotation system the maximum entrainment was 32%, 50% and 80% for methylisobu-tylcarbinol (MIBC), a-terpineol, and monohexadecane tricosaethylene glycol ether (C16E23), re-spectively. A comparison of the maximum entrainment factor emax with other, known from literature, indices such as bubble critical coalescence concentration (CCC), dynamic foamability index (DFI), Jw, e =25%revealed, except DFI, their similarity.

Jan 1, 2014

By R. C. Miranda

This paper intends to demonstrate the applicability of tools for advanced process control and online particle size image analysis in crushing and autogenous grinding circuits. In a crushing plant, cameras are installed in the conveyor belts of the circuit products. The vision system continuously processes the acquired images and thus obtains the variation of the size distribution curve. From these measurements, the advanced control system can operate, for example, at the opening of the crusher, in order to keep the P80 in the desired range. In addition, through the power information and level of the crusher&apos;s chamber, it is possible to increase the capacity of the crushing circuit. If the crusher is not equipped with an automatic opening adjustment, a warning may be issued to the operator to provide this setting manually. In mineral processes that use autogenous and semi-autogenous grinding for fragmentation, obtaining online F80 through the vision system allows for manipulating the parameters of rotation speed and solids concentration, through which the amount of material at the critical particle size that is produced can be controlled. In addition, the noise produced in the mill can be measured and controlled. Thus, it is possible to prevent breaches and to optimise the mill capacity for grinding. Image analysis combined with an expert system that translates this information and acts to seek the most appropriate particle size distribution, brings greater stability to the process optimising the capacity of the equipment, which allows for significant gains in production.

Sep 1, 2012