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By K. J. Maggs

The U.S. Bureau of Mines has investigated the chemical vapor deposition of diamond films on tungsten substrates. The effects of deposition parameters on the adhesion of the films was determined. The films were produced using a hot filament chemical vapor deposition system. Parameters investigated were substrate temperature and methane concentration in the feed gas. Film quality, morphology, and composition were characterized by scanning electron microscopy and Raman spectroscopy. Adhesion testing was performed using an indentation technique, and the results were quantified by relating adhesion to interface fracture toughness. Diamond films with well-faceted crystalline morphology with grain size greater than 1 µm had poor adhesion properties regardless of substrate temperature or methane concentration. Diamond films with smooth morphologies consisting of rounded clusters of small (<0.2 µm) diamond crystallites and amorphous carbon phases displayed much higher adhesion, although the conditions that led to the growth of these films are not understood.

Jan 1, 2010

By Kenneth M. Earl

In its investigation of deposits of strategic minerals, the Bureau of Mines did some development drilling at the New Galena Deposit in an endeavor to find an additional source of supply of lead. In Bucks County, lead and zinc minerals have been found in shales over a largo area west and northwest of Doylestown. Considerable mining has been done in the vicinity of New Galena on the North Branch of Noshaminy Creek, 3 miles northwest of Doylestown. It has not been possible to obtain a satisfactory history of the New Galena mine, as there is much disagreement in statements. Most of the mining was done in open pits. Two shafts were sunk to shallow depth; one of these became part of the main pit&apos; which is 256 foot long, 50 to 75 feet wide, and 20 to 44 feet deep. Small pits 8 to 10 foot square wore sunk on the ore zone, which extends some 1450 feet to the southwest. The rock containing the minerals is either black or gray shale. The gray material closely resembles limestone. The following minerals have been reported from the mine: quartz, ankerite, calcite, galena, sphalerite, pyrite, chalcopyrite, and bornite. Some of the galena has yielded 10 to 15 ounces of silver and 10 cents in gold per ton. The average grade of the ore as mined is not known. To investigate the downward extension of the ore shoot, the Bureau drilled two holes aggregating 373.9 feet, No additional ore was developed by this work.

Jan 1, 1950

By Bernard Porter

The solubility of UO2 was determined at 1,250° C. in ternary melts of UF4 and BaF2 with CaF2, LiF, and SrF2. The solubility of Ce02 was measured at 800° and 850° C. in a solution of CeF3, BaF2, and LiF. The amount of La203 which dissolves at 950° C. in a binary mixture of LiF and LaF3 and a ternary of LiF, LaF3, and BaF2 was also measured. In each case, the amount of soluble oxide was mound to be less than 5 weight-percent. A procedure was developed for filtering fused, oxide-saturated fluoride melts in order to obtain a representative sample for chemical analysis. The oxide content of the samples was determined by an inert-gas fusion procedure.

Jan 1, 1961

By J. P. Hansen

The Bureau of Mines has investigated the S02 leaching of MgO from high-MgO-bearing Florida phosphate concentrates. The S02 was effective in leaching some of the MgO from three phosphate concentrates; flow rate of the S02 and leach time were major factors in determining the amount of MgO leached. Calcining the samples, then grinding to minus 200 mesh, and elevating the leach temperature gave only small increases in the amount of MgO leached. The research also showed that some of the MgO was so intimately associated with the phosphate mineral that it could not be removed by S02 leaching. This amounted to about 0.6, 0.7, and 1.0 pct MgO in three leached residues. The calculated heads for the three concentrate samples averaged 1.4, 1.1, and 1.5 pct MgO, respectively, before leaching.

Jan 1, 1985

"The main objective of this research is to identify the mechanisms of control of respirable dust generation in coal mines. Full understanding of the mechanics of crack propagation in coal is of fundamental importance in studies of the generation and control of respirable dust.The main objectives of this fracture investigation are: 1) to determine reliable data on the fracture toughness of coal as a parameter controlling unstable crack propagation; 2) to determine fracture propagation velocity in coal providing data on the terminal velocity at which crack bifurcation occurs and fine fragments of coal material are generated; and 3) to apply the critical strain energy density criterion to model mixed mode crack propagation in coal.The development of the protocol, laboratory procedure and equipment necessary to conduct an extensive mixed mode fracture toughness testing program has been completed. About 80 mixed mode fracture toughness tests, 10 good fracture velocity records and over 50 fracture surface examination with the SME are available. The details of the mixed mode fracture toughness testing are available in a paper titled, ""Development of Mixed Mode Testing System for Geologic Materials"" which is available from the center. The average fracture toughness and critical strain energy density values for the three seams investigated to date are included in the attached Figures 71, 72, 73."

Nov 1, 1988

By S. C. Schaefer

Thermodynamic properties of indium oxide (In203) have been studied with a high-temperature galvanic cell employing stabilized zirconia electrolytes. In the temperature range 790° to 1,230° K the free-energy change for the cell reaction 21n(1) + 3Cu20(c) = In203(c) + 6Cu(c) together with the standard free energy of formation of cuprous oxide gives the standard free energy of formation of indium oxide from the elements as ?Gf° = -218.78 + 75.34 X 10-3T ±0.7 kcal/mole. A third-law analysis yields the standard enthalpy of formation: ?Hf°298.15 = -221.5 kcal/mole.

Jan 1, 1971

INTRODUCTION The pager phones used in many underground coal mines are battery- operated, party-line telephones with provisions for loudspeaker paging. The system is two-wire, non-polarized, and is operated by self-contained batteries. Many of the individual units are certified as permissible. Requirements for installation are specified in state and federal regulations, such as in the Code of Federal Regulations, Title 30, Mineral Resources, Part 75. The major federal regulations that affect communication in coal mines are noted below, with a brief description of the subject matter in each of the relevant paragraphs. Refer to the cited paragraphs of Title 30 for explicit details of these regulations. (This brief description is for reference purposes only.) Minimum Requirements (paragraphs 75.1600, 75.17 13-2, and 75.1003-1) Approved telephone or two-way communication will be provided between the surface and each main shaft landing and each working section ; to the nearest medical assistance; and shall be protected from contact with trolley wires or trolley feeder wires. Installation Requirements (paragraphs 75.5 16-2, 75.52 1, and 77.508-1 ) Communication wires will be supported on insulated hangers, attached to messenger cables, or buried, to protect against mechanical damage ; installed opposite trolley wires; and insulated near power conductors . . . each cable will have lightning arresters within 100 feet of going below ground . . . and arresters will be provided wherever telephone wires enter a building. Wire and Cable Requirements (paragraphs 75.5 16-2, 75.5 17, and 75.52 1) Communication cable means two or more insulated conductors, covered by an additional abrasion-resistant covering; power wires and cables shall be adequately insulated and fully protected; and lightning arresters shall be connected to low-resistance grounds, more than 25 feet from neutral grounds.

Apr 1, 1975

By N. S. Dalal, V. Castranova, K. Van Dyke, V. Vallyathan, J. H. Kang

"We have reported previously that crushing or grinding crystalline silica results in the generation of silica-based radicals on the particulate surface and that these radicals can generate hydroxyl radicals in aqueous solution. Data in the present study indicate that freshly ground silica is more cytotoxic and is a more potent activator of alveolar macrophages than comparably sized aged silica. That is, compared to aged silica, fresh silica is 4.2-fold more potent in decreasing the membrane integrity of macro· phages; is 50% more potent in activating hydrogen peroxide secretion by macro· phages; and is 4.frfold more potent in stimulating cellular chemiluminescence. Prosil 28, an organosilane material, is an effective coating agent for fresh silica. It decreases the cytotoxicity of fresh silica by as much as 78% and decreases the ability of fresh silica to induce chemiluminescence from alveolar macrophages by 58%. The data suggest that surface radicals associated with freshly cleaved dust may be an important factor in the induction of pulmonary disease. Furthermore, treating dust with coating agents may substantially decrease toxicity. INTRODUCTIONThe U.S. Department of Labor estimates that over 1.25 million American workers may be exposed to crystalline silica and that nearly 60,000 may be at risk of developing some degree of occupational lung disease (Parkes, 1982; Peters, 1986). Occupations of concern include miners, stone quarry workers, sand and gravel workers, sandblasters, foundry workers, and glass workers. Acute silicosis is characterized by inflammation, alveolar lipoproteinosis, and the rapid development of respiratory disability (Banks, 1986). In contrast, chronic silicosis develops 20-40 yr after initial exposure and is characterized by the appearance of concentric hyalinized nodular lesions and the progressive development of dyspnea (Parkes, 1982; Ziskind et al., 1976)."

Mar 1, 1992

By King K. Mak

The objectives of this study are to: (1) Assess current signing regulations and practices; (2) Develop effective signing guidelines; and (3) Evaluate the applicability and appropriateness of the proposed signing guidelines through field demonstration at representative mines. A literature search was conducted to determine the state of the art for signing applicable to surface mine haulage roads as well as survey of existing MHSA regulations and review of MSHA accident records. Nine representative mines were visited to gather information on current signing practices. Preliminary signing guidelines were then developed based on the abovementioned data. Field demonstration of the preliminary signing guidelines was conducted in which signing programs were implemented in two selected mines. Signing requirements were first assessed at each of the two participating mines. Subsequently, the necessary signs were designed, purchased, and installed at the two mines. Evaluation of the signing program as to its adequacy, appropriateness, and effectiveness was solicited from both mine management and operations personnel. Experiences gained from field evaluation were then incorporated into the final signing guidelines as presented in this final report.

Jan 1, 1981

By G. W. Jones, I. Spolan

"INTRODUCTION The operation of internal-combustion engines at high altitudes and the general aspects of combustion processes in rarefied atmospheres have created considerable interest in the problem of ignition and flame propagation at low pressures. Nuckolls, Matson, and Dufour 4/ have published results on the effect of low pressures on the propagation of flame in gasoline vapor-air mixtures in vessels of large capacity. The volumes of their test equipment varied in capacity from 0.425 to 125 cubic feet. Various sources of ignition were employed. These authors found that the explosive range of gasoline vapor in air decreases with decreasing pressure at pressures considerably below atmospheric, until a limiting absolute pressure of about 33 mm. mercury at ordinary temperature is reached, at which point no appreciable flame is propagated.Experiments carried out at the Bureau with natural gas-air mixtures at reduced pressures have shown 5/ that the limits of inflammability are but little affected at reduced pressures down to 175 mm. mercury. As the pressures of natural gas-air mixtures are reduced below atmospheric, the mixtures become more difficult to ignite; however, if a suitable source of ignition is employed, the limits of inflammability are as wide at 175 mm. mercury absolute pressure as they are at atmospheric pressure. In view of these observations with natural gas-air mixtures, it appears important to investigate gasoline vapor-air mixtures for possible similar behavior. For this reason the tests herein described were carried-out."

Oct 1, 1946

By D. J. Bauer

A solvent-extraction system employing selective stripping of a pre loaded organic phase was investigated for recovering Sm203 from a light-group rare-earth mixture. The samarium concentrated in the organic phase, and a >99-pct-pure samarium oxide product was obtained at 76-pct recovery in a 20-stage operation using di(2-ethylhexyl) phosphoric acid (EHPA) as the organic phase. The stripping agent was a 1.5-pct hydrochloric acid solution containing 200 g NH4C1/1.

Jan 1, 1972

By H. P. LeVan

The Bureau of Mines has developed a technically feasible continuous single-stage leaching and thickening system for extracting manganese from umber by a sulfuric acid-ferrous sulfate process; the cocurrent leaching and thickening system proved simpler to operate and control than the countercurrent leaching and thickening system developed earlier" Related tests investigated the use of a centrifuge to replace thickeners for separating the product liquor from are residues and compared several chemical agents for removing iron from the pregnant manganese leach solutions. Results of Some exploratory autoclaving tests are also given.

Jan 1, 1972

By R. W. Van Dolah

An important function of stemming used to confine explosives in shot holes in underground coal mines is to minimize the chance of ignition of firedamp or coal dust by the detonation products. Until 1952, the Bureau of Mines approved only the use of fireclay or similar incombustible material for stemming permissible explosives. At least 2 feet of stemming were required except in holes less than 4 feet deep; in such short holes the stemming was required to be half the depth of the hole. Over the years, several special stemming devices have been proposed in the United States as substitutes for fireclay. Many economic and safety advantages were claimed for these devices, but only one approved device has been marketed in this country. Bureau requirements for stemming explosives in coal mines were modified at that time to permit the approved stemming device to be used as a substitute for the required fireclay.

Jan 1, 1961

By Foster Fraas

A separator for minerals of low magnetic susceptibility and fine particle size in a water suspension is described. A ring-shaped matrix of ferromagnetic fragments rotating so as to pass successively through magnetic-field and field-free regions provides for the separation. Application is illustrated in the separation of hematite and ilmenite from quartz.

Jan 1, 1966

By James S. Browning

The Bureau of Mines conducted laboratory batch and pilot plant flotation tests to determine the technical feasibility of recovering commercial-grade mica from a California micaceous schist. Best results in the laboratory batch tests were obtained using sodium carbonate and sodium silicate for pH control and quartz depression, and a combination of fatty acid and cationic reagents as the mica collector. In continuous pilot plant flotation tests, an alkaline fatty acid-cationic method recovered about 70 percent of the mica in a concentrate analyzing 95.6 percent mica.

Jan 1, 1965

By G. R. Hopkins

[Apparent progress in fuel economy at petroleum refineries, as measured by the average amount of .seat units required to refine a barrel of crude oil, received a set-back in 1935, when the average rose to 562,00 B. t. u., compared with 562,000 B.t.u. in 1937 (see fig. l). The primary factor in the rise in average heat requirement&apos;s per barrel of crude oil refined in 1938 wan the decline in total runs to Invariably the average requirement increases when crude ins to stills decline, and vice versa. In other words, annual gains in fuel efficiency at refineries arc masked by the degree to which the capacity is utilized. Additional crude runs give lower average e heat requirements in two ways - first, because they are mane with the c expenditure of comparatively small amounts of auxiliary heat, and, second, because the additional runs generally represent simple topping operations. In 1938 crude runs, to stills declined 1.6 percent (from 1,183,440,000 barrels in 1937 to 1,165,015,000 barrels in 1938), but the total heat consumption declined only 0.4 percent, or from 663,866 billion B. t. u. in 1777 to 660, 56 billion in 1938 .]

Jan 1, 1939

By K. C. Dean

Time and motion studies were made by the Federal Bureau of Mines on the hand and machine dismantling of scrapped auto starter motors, generators, and alternators for recovery of copper, aluminum, and iron. The studies showed that an individual with power handtools and convenient access to a hydraulic press, power bandsaw, acetylene torch, and power lathe could, in an 8-hour day, disassemble about 100 starters, or 150 generators, or 30 alternators. The scrap copper yield would be 280, 390, and 45 pounds, respectively, and the iron yield would be about seven times the copper weight. About 100 pounds of aluminum would be obtained from the alternators.

Jan 1, 1976

By R. G. Sandberg

Many gold-bearing ores throughout the Western United States contain small quantities of mercury. The presence of mercury not only decreases the gold-loading capacity of the activated carbon, but complicates the fire refining of cathodes and creates a potential health hazard. The Bureau of Mines investigated methods to limit mercury extraction during gold ore leaching and to remove mercury from cyanide leach solu-tions. Mercury dissolution was reduced from 40 to 10 pct by decreasing NaCN concentration from 20 lb to 0.34 lb per ton of solution at a pH of <11. When 0.1 lb CaS per ton of ore was added to a leach slurry, mer-cury extraction was reduced from 27 to 0.4 pct. Less than 0.5 pct of the mercury was solubilized when <0.1 lb CaS per ton of are, along with lime and NaCN, was added to a simulated grinding circuit.

Jan 1, 1984

By Rogers F. Davis

The Bureau of Mines developed a new method for the determination of oxides of nitrogen in diesel exhaust gas. The procedure, a modification of the Saltzman method, uses a NO2 absorbent for the diesel exhaust gas; the colorless absorbent becomes purple on contact with N~. When used properly this procedure gives satisfactory results in 2 hours, whereas the standard phenoldisulfonic acid method required approximately 8 hours. The new method is not satisfactory for determination of oxides of nitrogen in the overrich fuel to air ratio range.

Jan 1, 1966

By Phillip Allender, Wolf Karo, Knox Van Dyke, Lixin Wu, Ali Ardekani, Jorge Garcia, Jaime Gutierrez

"We report that two different micropolystyrene round beads linked to either luminol or lucigenin have been developed. The 1-µ.m-diameter beads arc useful reagents that allow one to perform chemiluminescent (light producing) phagoeytic reactions without opsonization. It is known that luminol reacts with peroxidases (e.g., myeloperoxidase) while lucigenin reacts mainly with superoxide anion. Luminol and lucigenin beads produce cellular chemiluminescence (CL) with neutrophils, macrophages, monocytes, and differentiated human promyelocytic leukemic cells (HL60). When myeloperoxidase (MPO) is present luminol beads evoke higher CL from neutrophils, but when little or no MPO is present, lucigenin beads produce higher amounts of light. Lucigenin beads appear to be active inside these cells where unbound lucigenin does not enter freely.INTRODUCTIONA variety of cells, e.g., neutrophils (Ns) and macrophages (Ms), can engulf foreign particles (1). This engulfing or phagocytic activity is used by the body to kill bacteria and to eliminate foreign particles such as respirable dusts, e.g., coal, silica, or cotton. The neutrophil engulfs or phagocytizes bacteria which are coated with plasma antibodies and/or complement proteins (Fig. 1). The coating or opsonization allows the neutrophil to recognize foreign substances. Usually the absence of opsonization prevents the cell's recognition of a foreign particle and the particle is not phagocytized. Macrophages, particularly the alveolar Oung) cells, do not require opsonization for phagocytosis. Ms should not be selective toward individual dusts because they serve a major role in eliminating a variety of these.Particle size can also be a factor. Usually a particle with a diameter of 0.5-5 µ.m is considered in the respirable range. Larger particles are trapped before they reach the alveoli Oung spaces where oxygen exchange with blood occurs), ·and smaller particles do not generally settle, and are not engulfed by macrophages (2). Tabato and Ikada (3) found that maximal phagocytosis of microspheres takes place when their diameter is in the range of 1.0 to 2.0 µ.m. In addition, they found that beads with hydrophobic surfaces were more readily phagocytized than hydrophilic surfaces."

Jan 1, 1990