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By Rick Ellman, Ian Chaney

"The Hampton Roads area encompassing the Norfolk, Virginia Beach and Newport News metropolitan region experiences some of the worst traffic congestion in Virginia. With continued growth of the ports and increasing demand, the Virginia Department of Transportation (VDOT) initiated the Downtown Tunnel/Midtown Tunnel/MLK Expressway Project, a complex undertaking critical to addressing the Hampton Roads area’s transportation needs. The project is a $2.1 billion Design/Build/Finance/Operate (DBFO) endeavor most notably involving the construction of a new two-lane vehicular tunnel utilizing the Immersed Tube Tunnel (ITT) method. The tunnel will pass under the Elizabeth River parallel to the existing Midtown Tunnel between Norfolk and Portsmouth, Va. It will be the largest design-build project constructed in the history of the Hampton Roads District.The New Midtown Tunnel will extend approximately 6,450 ft (1,966 m) along the north side of the existing tunnel where it ties into the existing Midtown Tunnel approaches in Norfolk and Portsmouth. It is being installed in a pre-excavated trench of which approximately 2,250 ft (686 m) required bracing on the Portsmouth side and approximately 1,000 ft (305 m) required bracing on the Norfolk side. The remaining 3,200 ft (975 m) of trench excavation was open cut dredging with laid back side slopes, optimized to reduce dredging, disposal and backfill quantities while also reducing the risk to the existing tunnel. The braced excavation portions of the tunnel alignment were divided into distinct segments which include: Portsmouth Approach Boat Section, Portsmouth Approach Cut-and-Cover Section, Portsmouth Dredge Section, Norfolk Dredge Section, Norfolk Approach Cut-and- Cover Section and the Norfolk Approach Boat Section. All “approach” excavations were performed in the dry and all “dredge” excavations were performed in the wet. Eleven ITT segments are being fabricated in the Sparrows Point Dry Dock facility in Baltimore, Md., and each 14,000 ton (12,700 tonne) segment is being towed approximately 220 mi (354 km) to the site. The ITT segments will extend under the Elizabeth River, with the deepest crossing 90 ft (27 m) at the Federal Navigation Channel. Once beyond the channel limits the ITT rises at an approximate 4.5% slope. Controlled screeding and element lowering operations will be performed primarily from floating barges."

Jan 1, 2014

By Fang Wu

The paper designs an extraction flow for the total recovery of nickel and cobalt and removing magnesium simultaneously from the cadthodic materials of the spent hydrogen-nickel and cadmium-nickel batteries. The separation of Co, Ni and Mg though P507 extraction .The extraction equilibrium pH is 4.5~5.0, ßNi/Co is 140~180, and ß Ni/Mg is 20~25; nickel and magnesium are scrubbed in two steps, in which the equilibrium pH of nickel and magnesium scrubbing is controlled at 5.0±0.1 and 4.4±0.1 respectively. The stepwise scrubbing technique is adopted to remove 94.5% of magnesium and to recover 99.45% of nickel and 95.35% of cobalt. During the integrated extraction and precipitation process the total recovery fraction of nickel and cobalt are 99.99% and 99.95%, and the recovery fraction of magnesium is 94.02%.The recovered NiSO4 and CoSO4 solution are enriched and crystallized.

Jan 1, 2009

By E. F. Divers

This Bureau of Mines report describes the results of a program to develop small, rugged mechanical dust collectors (scrubbers) with high dust collection efficiency and low energy comsumption for controlling dust in coal mining operations. All of the scrubbers described are similar in configuration and are powered by 6-hp, 2,000-ft3/min vane axial fans. Air pressure differential is less than 6 inches water column. Height of the scrubbers? including fan is less than 14 inches, width is less than 16 inches, and length is less than 45 inches. The flooded fibrous-bed scrubber achieved respirable (less than approximatey 7 µm) dust collection efficiencies of 95 percent. The small-diameter-cyclone scrubbers showed about 92 percent efficiency and can be best where excess water is a problem. The wetted brush scrubber showed 88 percent efficiency at low cost, and the wetted fan scrubber showed a slightly lower efficiency (87 percent) but offered the smallest size and cost. A suitable water droplet eliminator is described.

Jan 1, 1978

By P. Conrad

Experience has shown that, since the passage of the Surface Mining Control and Reclamation Act, over-compaction of spoil during the reclamation process has severely limited tree growth on reclaimed land. Researchers at the University of Kentucky have conducted a ten-year investigation at a surface mine in eastern Kentucky that monitored the changes in selected spoil physical characteristics for various reclamation and compaction alleviation methods. More specifically, research plots were developed for reforestation that employed three different levels of compaction and two different methods of ripping for overly compacted spoil. Each year measurements were made in the field of dry bulk density, using a nuclear density gage, and maximum penetration depth, using a recording cone penetrometer. In addition to good correlation between tree growth and selected spoil characteristics, the data demonstrated a gradual convergence of the measured spoil characteristic data over the study period.

Jan 1, 2008

By J. F. Shea, O. F. Tangel

Battelle Memorial Institute participated in a program for the General Services Administration aimed at developing a nickel-cobalt separation process that could be integrated in the Nicaro nickel plant. At the time the programwas being carried out, the Nicaro process was a straight-through operation, in which the ore was reduced and leached, after which the pregnant solution was boiled to produce a so-called "bulk precipitate" which contained virtually all of the nickel and cobalt which had been dissolved in the leaching step. The weight ratio of nickel to cobalt in Nicaro ore is approximately 15 to 20:l. The weight ratio of nickel to cobalt in the finished product had to be 100:l or higher to meet specifications. Because the Nicaro process embodied no nickel-cobalt separation step, the only way that a bulk precipitate of the specified nicke1:cobalt ratio could be produced was to so adjust roasting and leaching conditions that nickel would be selectively leached and most of the cobalt would be rejected with the tailings. The required selectivity, however, was achieved at the expense of nickel recovery, which was 5 or more per cent less than might have been obtained with the existing equipment, utilities, man power, etc., had selectivity been no object. The over-all purpose of the program was to develop a separation step that could be fitted into or onto the Nicaro facilities and which would permit the manufacture of a product that would meet the desired specifications and still permit the recovery of a maximum amount of nickel. Battelle suggested that this might be accomplished by reprocessing off-specification bulk precipitate and specifically suggested the process based on ammonium sulphate leaching followed by hydrogen reduction of the leach solution according to techniques developed commercially by Sherritt Gordon Mines Limited. Such a process would not only satisfy the objectives of the research but would present two additional advantages. (1) It would produce a separate cobalt product which could be further processed into metal, alloys, oxides, or salts. (2) It would yield nickel in metallic form which might be more generally marketable and command a slightly higher price per unit of nickel than the Nicaro oxide product. DESCRIPTION OF THE PROCESS Figure 1 is a flowsheet of the process. The essential features are: (1) Extraction of about 97 per cent of the nickel and about 85 per cent of the cobalt from bulk precipitate by a principal leach with ainmonium sulphate solution (Step A). Extraction of virtually all of

Jan 1, 1961

By Yoginder P. Chugh

This study has appraised available deeper soil loosening equipment in the 1-4 ft. depth range, in the U.S. and abroad which has potential for Illinois prime farm-land reclamation. The appraisal was based on written and/or oral contacts with equipment manufacturers, reclamation experts, and visiting with selected equipment manufacturers. The results indicate that several manufacturers in the U.S., West Germany, and England market static and vibratory deeper soil loosening equipment which may have potential for application in Illinois. The pertinent information concerning each equipment with potential is presented in this report.

Jan 1, 1983

By Mehmet Canbazoglu, Kaarlo Haavanlammi, Hannu Laitala

Cobalt is currently a critical metal because of the increasing number of electrical vehicles forecast for production. Copper and zinc are base metals that are used in many everyday applications, including vehicle production. Eti Bakir Co. Mazidagi Phosphate Plants in the Mazidagi district of Mardin, Turkey is a multi-product facility that produces cobalt, copper, and zinc, as well as fertilizers, from the roaster calcine. Roaster off gas is treated in a sulfuric acid plant (SAP) and the acid itself is utilized in fertilizer production. The comminution circuit, roaster, SAP, and calcine leaching process were developed by Outotec and integrated with the fertilizer production process implemented by Eti Bakir A.Ş. This paper describes the hydrometallurgical calcine leaching process used at the plant, with a focus on the oxidative pressure leaching of the cobalt, zinc, and copper-containing calcine. The cold and hot commissioning phases of the pressure leaching autoclave start-up are discussed together with experiences from the ramp-up period. The production processes of the copper cathode and cobalt and zinc-containing salts are also presented together with some of the plant’s operating parameters. INTRODUCTION The ETI Bakir A.S. fertilizer plant, Turkey, is located in Mardin Province near the border with Syria, (Figure 1). The leaching plant project was started in 2012. The purpose of the plant is to separate the valuable metals from the calcine produced by the pyrite roasters, which are used to produce a SO2 containing gas for the new sulfuric acid plant. Fertilizer production requires sulfuric acid, and for this reason a sulfuric acid plant was built; customer already had access to pyrite concentrate, which is used as the roaster feed. During the engineering phase of the roaster and acid plants it was noticed that the roasted calcine contained considerable amounts of valuable metals like cobalt, copper, and zinc. To recover these metals, a calcine leaching process was developed at the Outotec Research Center in Pori, Finland. The main process connections of the Mazidagi site are shown in Figure 2.

Jan 1, 2019

By Shahriar Vandani, Andy Herlache, Andrew Bro, Wei-Yu Chen

"The Presidio Parkway Project will reconstruct approximately 1.6 miles (2.6 km) of highway, including seven new bridges, three new cut-and-cover tunnels, and a new undercrossing connecting the Golden Gate Bridge to the City of San Francisco, California. The project site is approximately 5.6 miles (9 km) from the San Andreas Fault, capable of producing magnitude 8 earthquakes. Seismic hazards include strong ground shaking, soil liquefaction, ground settlement, and lateral spreading. The Main Post Tunnels (MPT) are two parallel cut-and-cover concrete tunnels approximately 1100 feet (335 m) long. The MPT site underlain by loose sandy soils susceptible to liquefaction and lateral spreading. Excessive racking and permanent displacement due to lateral spreading are identified as the main seismic vulnerabilities. Analyses showed that without ground improvement, tunnel racking of over 5 inches (13 cm) and permanent lateral tunnel displacement of up to 15 feet (4.6 m) could be anticipated. Cement Deep Soil Mixing (CDSM) is proposed to mitigate slope displacements and increase lateral stiffness of the foundation materials to reduce tunnel racking. A series of 2-D fully dynamic time domain analyses were performed to evaluate the performance of CDSM, confirm that performance criteria are met, and optimize the CDSM geometry and replacement ratio. The use of CDSM reduced the permanent tunnel displacement from over 15 feet (4.6 m) to less than 1 inch (2.5 cm). Tunnel racking was also reduced significantly. The adopted analytical approach presented herein can be considered for future tunnel design projects in seismically active areas.Introduction The Main Post Tunnels (MPT) are an integral component of the Presidio Parkway project which will replace the existing facility with a new multi-lane roadway between the Golden Gate Bridge and the City of San Francisco. The MPT are two parallel cut-and-cover concrete tunnels approximately 1100 feet (335 m) in length. As shown on Figure 1, the project site is located in a seismically active area, about 5.6 miles (9 km) east of the San Andreas Fault and 12.5 miles (20 km) west of the Hayward Fault. The San Andreas Fault can generate magnitude 8 earthquakes while the Hayward Fault is capable of producing magnitude 7.3 earthquakes. The design Peak Bedrock Acceleration (PBA) is 0.46g for the upper level design earthquake. The project alignment is shown on Figure 2."

Jan 1, 2014

By W. L. Dare

Tri-axial strains in pillars, created by pillar robbing, were measured in an experiment at the Dysart No. 1 uranium mine near Grants) New Mexico. At this mine, room-and-pillar stoping is used on the advance, and pillars are recovered on the retreat. The are deposit is, for all practical purposes, horizontal. Measuring devices were installed in pillars approximately 90 to 200 feet from the break line, and strains were recorded over a 4-to 6-week period. The measurements indicate that, in general, the algebraic magnitude of vertical strains increased, and the horizontal strains decreased, in turn, indicating that vertical (or near vertical) loads on the instrumented pillars lessened as pillars were recovered.

Jan 1, 1962

Thallium is an uncommon heavy metal that may be found in concentrations that exceed regulatory limits in mining influenced water associated with processing cadmium, copper, gold, lead, and zinc ores. This study evaluated cost-effective modifications to lime precipitation treatment to reduce thallium concentrations to below the EPA drinking water MCL of 2 ppb. The oxidative precipitation of Tl+ to Tlß+ by potassium permanganate was explored for thallium removal at low concentrations (1 ppm initial thallium). Laboratory batch tests were performed to evaluate the removal of thallium from synthetic solutions. Three ratios of potassium permanganate to oxidizable metals in solution were used (one-half, one and two times stoichiometry). Thallium was removed to less than 1 ppb for all stoichiometric ratios evaluated within 10 minutes of reaction. The efficacy of oxidative precipitation for thallium removal is presented.

Jan 1, 2011

By A. E. Raddatz

In an attempt to develop technology to use domestic resources in place of imported bauxita, the Bureau of Mines investigated sulfurous acid leaching to extract alumina from kaolin. The process consists of leaching the calcined kaolin with a 30 wt-pct S02 solution at 60° C and 160 psig for 17 hours, fil¬tering the leach slurry, precipitating monobasic aluminum sulfite from the filtrate at 110° C and 60 psig, a& decomposing the sulfite in the spent liq¬uor at 150° C and 55 psig to produce crude alumina. Purification of the crude alumina was accomplished using a modified Bayer process. Results from closed-circuit tests employing the sulfurous acid process showed that overall extraction of alumina from kaolin was 67 pct. Production of 1 ton of alumina would require 3.6 tons of calcined kaolin, 0.7 ton of sul¬fur dioxide, and 8.4 tons of water. After purification by a modified Bayer process, the alumina product contained the following; impurities, expressed in weight-percent: Fa203, 0.009; S, 3.6; Si02, 0.07; Ti02, 0.002; K20, 0.017; and P205, 0.03.

Jan 1, 1981

By M. Kane, B. Bissonnette, D. Hodouin

"A laboratory cell has been designed for a careful investigation of gold ore cyanidation using mathematical modelling of the process kinetics. The cell is a stirred vessel with continuous monitoring and control of pH, oxygen and free cyanide contents. Samples are automatically extracted for gold analysis. The instruments are connected to a microcomputer which records all the measured variables and calculates the reagent consumption (air or oxygen, cyanide, lime). For cyanide control a sample is automatically extracted and filtered and the solution analyzed, using a specific electrode, by a flow injection technique. The rate of gold dissolution is modelled using a kinetic model the parameters of which are calculated by a non linear least-squares technique. The parameters of an empirical model of reagent consumption are also estimated. The resulting model is used in a simulator for gold cyanidation plant design, tuning and control.INTRODUCTIONThe leaching of gold ores in a cyanide solution is the usual method for gold extraction from raw ores. This process requires long reaction times and leads to very significant consumption of cyanide. The optimization of the cyanidation plant operation is a very important aspect of gold ore processing for increasing gold recovery and decreasing operating costs. The key parameters to the improvement of gold extraction are the selection of an efficient solution chemistry, the design of the size and the arrangement of the equipment and the correct tuning of the operating variables. Automatic control strategies can then be applied to maintain industrial operations at their optimum setpoints.Two approaches can be used for optimizing design and control of cyanidation circuits, either empirical trials for improving process performances or mathematical modelling of the process kinetics for subsequent analysis, simulation and optimization. The advantages of the second approach, which is used in this study, is that it gives a systematic pattern to interpret data and reliable tools, in as much as the models are good, to improve operation performances. In order to determine the structure and the coefficients of cyanidation models, well controlled measurement and calibration procedures must be used. The purpose of the paper is to present an equipment and a test procedure for modelling the kinetics of gold ore cyanidation."

Jan 1, 1990

By A. Mainza

It is common practice in the mineral processing industry to use hydrocyclones for particle classification. However, classification in the UG2 platinum circuits using the hydrocyclone poses major challenges due to the differences in density between silica and chromite, the two major components of this ore. Silica, the PGM carrying component, has an average density of 2.7 and the barren chromite component has an average density of 4.5. When conventional and flat bottom cyclones are used there is a misplacement of particles due to differences in density leading to inefficiencies in the classification by size. As a result of the density effect, coarse silica reports to the overflow, resulting in loss of recovery, and fine chromite reports to the underflow, resulting in loss of milling capacity and unnecessary production of fine chromite. A classifier based on a different concept was required in the classification of UG2 platinum ore. The three-product cyclone, which is a hydrocyclone with two concentric vortex finders to produce three distinct products, has been tested in the UG2 ore application and indications are that misplacement of particles due to differences in the component densities can be minimized through the use of this unit. Industrial and pilot plant trials were conducted and indications are that the three-product cyclone can be installed to selectively produce a middlings stream that can be screened using Pansep screens to provide a screen oversize, which is predominantly coarse silica that can be preferentially reground to recover the PGM values contained in the coarse silica.

Jan 1, 2005

By A Kurniawan, A Sjadat and M Akhasyah

PT Freeport Indonesia’s Deep Ore Zone (DOZ) is a block cave mining operation that has been in production for 15 years. DOZ is located approximately 900 m below surface and has an average production rate of more than 5000 t/d. The footprint of the extraction level will ultimately be 900 m long and average more than 200 m wide. The undercut level is located 20 m above the extraction level.While developing Panel 1K on the northern portion of the extraction level, a major geotechnical problem was encountered when there was a change in lithology and an associated fault intersection. A large collapse of the hanging wall of the extraction level drifts occurred in the area of the fault intersection between February and March 2011. This was followed by a collapse of one of the undercut level drifts directly above the extraction level in May 2011.It was suggested that the best approach to mitigate risk during rehabilitation was to systematically open up the failed area under the protection of a steel set support system. To achieve this, approximately 60 t of grout was injected from the undercut level to fill the voids created when the rock mass between the two levels failed. A ground penetrating radar system was used to survey the condition of the rock mass between the two levels before and after the injection of grout. After the grout injection phase was completed to a satisfactory level of confidence, rehabilitation activities started on the extraction level by taking out the now consolidated material from inside the drift in 2 m advances from under steel sets initially constructed in secured ground.Controlled blasting was the key aspect to the success of the initiative to open up just enough of the drift to systematically support the rock mass before the next set was installed. The systematic support consisted of in-cycle shotcrete sprayed over mesh pinned to the exposed rock, as effectively as possible, with splitsets before spiling the next advance’s protection canopy with rebar. Once secure, a combination of steel set and pumped concrete was installed as the final support. This final support provided a safe platform to repeat the process until the failed zone was safely traversed.CITATION:Kurniawan, A, Sjadat, A and Akhasyah, M, 2016. Rehabilitation of the collapsed panel 1K north in the Deep Ore Zone block cave mine, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 763–768 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

By S. K. Bradford

(Pittsburg Meeting, March, 1910.) FOR years past I have traveled in quest of promising mining-properties, over almost impassable mountain-trails to remote places in the mining-regions, usually, many miles from an assay-office. If, upon examination, the formation and the ore-deposit appeared favorable, a quick determination of the value of my samples was necessary, in order that I might take intelligent action with reference to the acquisition of the property. A journey with my samples to civilized regions often meant weeks of delay, and perhaps loss of opportunity. How many, under similar circumstances, have returned with their assay-results from such a journey, only to find that some audacious speculator had " optioned" the property ! True, a first payment could have been made and the chances taken on the results; but experience has taught that rich-looking ore is not of necessity valuable. Personally, I would not hazard a ten-dollar bill on any property without first determining by assay the value of the ore. To carry the usual complete assay-paraphernalia over such mountain-trails was impracticable by reason of the loss of time involved, the great expense of transportation (charged according to weight), and the fact that a few such trips would almost certainly wreck the outfit. For these reasons I began a process of elimination and substitution which finally enabled me to carry, in an ordinary 26-in. valise, sufficient apparatus and supplies for, say, 100 assays of adequate commercial accuracy. My final outfit was as follows: APPARATUS. Small hammer; steel mortar (2.5 in. wide, 3 in. high, with stand sawed off flat, so that it can be used as an anvil and for

Jan 1, 1911

By David A. Larson

Preliminary laboratory experiments have been conducted by the Bureau of Mines to define the influence of bit geometry on methane ignitions as a step toward establishing safer mining-machine operating parameters. The experimental system was designed to simulate the operation of a continuous mining machine, using a drum-type cutterhead of normal diameter with a narrow cross section, permitting full-diameter drum cutting tests to be run on material representative of sandstone lenses (or inclusions) in coal seams. Two conical bit types were tested at shallow depths of cut with three drum speeds. Bits that rotated in the mounting block during testing did not produce ignitions. The ignition frequency for used bits was three to four times greater than for new bits at the same kerf depth.

Jan 1, 1983

By G. L. Smith

As the Platinum mining industry expands in the Eastern Limb of the Bushveld Complex it is increasingly evident that a major constraint to development is a lack of appropriate infrastructure. Of critical concern are water resources and spatial development / infrastructure. This paper identifies the context for infrastructure development in the Eastern Limb and two solutions that have evolved in the areas of water supply and spatial development. INTRODUCTION In an economics context, infrastructure is considered to be the structural elements of an economy which allow for the production of goods and services, without themselves being part of the production process. Despite the lack of a specific definition, infrastructure has largely become understood as to comprise road and rail transport systems, public transport systems, airports, public educational facilities, water supply and water resources, wastewater management, solid waste treatment and disposal, electric power generation and transmission, telecommunications and hazardous waste management systems. Critically it is important to understand that infrastructure not only comprises these physical elements but also the operating procedures, management practices and developmental policies that facilitate the effective utilization and development of the infrastructure in response to societal demand.

Jan 1, 2008

By John Starkey

"During the period June 2007 to March 2007, John Starkey of Starkey & Associates (Starkey) worked in Russia for High River Gold, supervising the engineering design work that was being done at the IRGIREDMET Research Institute, in Irkutsk Russia. The work entailed moving the Newmont No. 4 mill from Elko, Nevada to Berezitovy, a mine site north and west of the city of Skovorodino, in the Amur Region of Siberia. This was a grass roots project and required construction of all phases of the infrastructure and process facilities that are associated with a 5000 t/d open pit mine and CIP mill.During the course of this engineering design exercise, many aspects of doing business in Russia were encountered, with regard to laws, norms, and business practices. This paper discusses many of these findings. Also by living in Irkutsk, many observations on Russian life and social customs were made and these merit discussion from a general interest point of view.Prior to going to Russia, another engineering and ore testing firm (TOMS) had approached Starkey to find out if Starkey could assist them in upgrading their SAG ore testing procedures to Western standards in order to offer their clients turnkey projects, that included reliable SAG and AG grinding. TOMS was aware that Starkey had invented the SPI test but did not know that the SAGDesign test had by then been fully developed and was being offered commercially as the most accurate way in the world to design new grinding mills. They were also unaware that this new testing method had been patented by Outokumpu (now Outotec) and that this method allowed them access to a design method, through Starkey, that would lead to a manufacturer’s guarantee (by Outotec) of throughput and grind for any new semi-autogenous or autogenous grinding circuit, with or without ball mills.When Starkey started working at IRGIREDMET in June 2005, they also made a request to add a design method for SAG mills that would be considered acceptable to Western clients. From these requests, presentations were made in Russian to both institutes and each decided to join the SAGDesign Consulting Group as satellite members and buy a SAGDesign test mill to use with their Bond Ball Mill Work Index mills, to provide SAGDesign testing services. To complete the service, contracts have been put in place for Starkey to use these results to design new grinding equipment and to train engineers at TOMS and IRGIREDMET how to do this work.Starkey also undertook to train engineers at both labs to go into the field and to take the samples for SAGDesign testing programs. It is here where the SAGDesign testing service upgrades other grinding test programs because the samples to be used for design are professionally chosen, and the results will be much more likely to produce a satisfactory design. Starkey is a mining engineer and is uniquely qualified to do this task. This and the SAGDesign test are the key components that lead Outotec to offer a performance guarantee for mills designed by Starkey."

Jan 1, 2008

By F. C. Gennari, D. M. Pasquevich

With the gradual exhaustion of natural rutile, there has been extensive research into its synthesising from lower-grade titanium minerals. The removal of Fe from pseudobrookite (Fe2TiO5) by chlorination was studied, using both isothermal and non-isothermal thermogravimetric measurements. Correlation of the results obtained from element distribution maps, scanning electron microscopy, energy-dispersive X-ray analysis and phases detected by X-ray diffraction in the chlorinated samples showed clearly two associated processes. First, the pseudobrookite particles reacted with chlorine and iron was removed selectively as FeCl3(g), leaving a solid residue rich in the TiO2 phases anatile and rutile, separated from an inner layer of unreacted pseudobrookite by a distinct interphase boundary. Second, chlorine allowed TiCl4(g) to form in the reaction bed, where it removed iron from the Fe2O3 crystals as FeCl3(g) and substituted Ti through a pseudomorphic reaction

Jun 21, 1905

Acid soluble calcium is depleted in drainage sediments from hydrothermal alteration centres in the Coromandel Peninsula. The routine analysis of acid-soluble calcium on drainage samples is an economical and effective technique for outlining hydrothermal alteration centres in volcanic terrains.

Jan 1, 1979