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AustraliaÆs record-breaking drought, efforts towards environmental best practice and the current commodities boom is demanding water use and reuse as never before. Mining practices, processing, the remote communities and support industries require vast amounts of specific quality water. Sustainability of water use has been a key factor in mine development, expansion of existing operations and increasing profitability of processes involving water. Developments in water treatment technology have enabled the use of a range of processes to produce this water reliably at ever decreasing costs. This increasing acceptance of new technologies has seen seawater desalination, recycling of plant wastewater streams, municipal wastewater reuse and others to become commonplace. Processes including seawater and groundwater reverse osmosis (RO), low pH RO, thermal desalination, high rate clarification, brine water treatment, ion exchange and other advanced treatment technologies are now used as part of mining operations. This paper surveys the trends in water treatment for the mining industry both in Australia and internationally with a review of technologies and case studies of operating plants. The key technologies are explained with an emphasis on the specific requirements for mining operations û unusual raw water, process and operations limitations, environmental concerns, as well as harsh climate. Case study information from several mining operations is included.

Jan 1, 2006

By T Tran, F Lucien

Supercritical fluids (SCFs) have gained recognition as solvents for the extraction of a wide range of organic materials. Their principle advantages over conventional organic solvents are that they possess much more favourable transport properties and that such properties can be easily altered by adjusting the system temperature and/or pressure. More recently, SCF solvents have been employed in the extraction of metal ions. The direct extraction of metal ions using SCFs such as CO2 is normally not possible due to the charge neutralisation requirement for solubilisation. However, extraction can be achieved with a SCF solvent containing an organic complexing agent as a cosolvent (Laintz et al, 1992; Laintz and Tachikawa, 1994; Dehghani, 1996). The role of the SCF is therefore similar to the role of a diluent in conventional liquid-liquid or solvent extraction processes. In this regard, SC-CO2 is a particularly good diluent since it exhibits good solubility for many organic complexing agents. The extraction of metals with SCF solvents has been examined mainly in the analysis of environmental samples and the treatment of metal contaminated wastes. Nonetheless, some interesting results have been reported recently on the extraction of rare earth metals, which highlight the potential of SCF solvents in mineral processing applications (Laintz and Tachikawa, 1994; Dehghani, 1996).

Jan 1, 2000

By R G. Barker, N Mortimer

In New Zealand, platinum group metals (PGM) occur in three main geological environments of economic interest: layered mafic igneous complexes, the Dun Mountain Ophiolite Belt, and in association with placer gold deposits. Most of the layered mafic complexes with PGM potential occur in the Median Batholith. These include the Longwood (Permian), Bluff (Permian), Riwaka (Devonian) and Rotoroa (Jurassic) igneous complexes. Exploration of the Longwood Complex discovered PGM associated with gabbroic rocks. Best assays to date include a 1 m drill intersection of 1 g/t Pt + Pd and float rock with 3.0 ppm Pt and 3.3 ppm Pd. The Greenhills complex at Bluff consists of basal dunite overlain by wehrlite and gabbro. PGM occur with chrome spinel in the basal dunite and Pt geochemical anomalies have been identified associated with the wehrlite-gabbro contact zone. The Greenhills complex has some similarities to Alaskan-Ural type complexes.Reconnaissance exploration in the Dun Mountain Ophiolite Belt has identified PGM geochemical anomalies, but no follow-up work has been carried out. During the late 1800s and early 1900s, PGM were recovered as a byproduct of placer gold mining in Southland. Placer gold prospects with PGM potential include the Waiau River, deposits flanking the Longwood Complex and some Southland beaches.

Jan 1, 2002

Most of the copper deposits in the Lachlan Geosyncline fall within areas having either a common host rock, mineral assemblage, form of ore body or time and method of emplace- ment. On this basis a Cobar-type ore has been recognised in the deposits of the Cobar -- Mt. Hope - Melrose region. The copper ores in the Tottenham-Girilambone area to the east have a different mineral assemblage. In the more rugged Central Highlands nearer the coast copper deposits are generally concentrated either in one of several Ordovician andesite belts, particularly between Wellington and Woodstock, or within Silurian acid volcanics developed in irregular fashion over a considerable portion of this region. In only a few instances is copper known in the granite batholiths which adjoin these volcanic belts. Native copper and magnetite are characteristic of the deposits of the andesite province and it is possible that future mineragraphic studies will indicate significant differences in the base metal sulphides of both the andesitic and the more acid volcanic belts. Ores having similar mineralogy and form to the Captain's Flat deposit are known at various localities in the eastern segment of the latter belt. In the Gundagai area several small copper deposits with associated nickel minerals have been developed in the Coolac Serpentinite belt.

Jan 1, 1969

We often read and hear, especially in the United States, that we are running out of critical metals. These are vague forebodings of stagna- tion or winding down of our civilization. Our technological progress has been rapid in the last 50 years and is still advancing at an accelerated rate, and predictions of its long-term impact on consumption and production of metals are more hazardous than ever in the light of the great economic and political shifts that are bound to continue. There are many factors that will have a hardly predictable but profound effect on pro- duction and consumption of metals over a time span of, say, 25 years. Among such factors are recycling, substitution, availability of capital, direct involvement of governments in financing and production, and the capability of producing much lower grade ores at possibly much higher prices relative to costs in the event of scarcity. I must state at the outset that my discussion of this topic does not take into account the role that deep-sea nodules containing copper, nickel, cobalt, and manganese may play, because I don't believe production from these deposits will be of much significance within the 25 year span I will be discussing.

Jan 1, 1978

In southeastern China, offshore Tertiarybasins are buried underneath the broad continental shelf areas from Taiwan to Hainan Island. These basins bear relatively similar characteristics of structure, stratigraphy and tectonics. Based on age and tectonic framework, these Tertiary basins are divided into two groups of Paleogene basin and Neogene basin (Fig.1 and 2). However, observations of extensional structures indicate that the Paleogene basins are rift basins; and the predominant structural features are NE-SW trending half grabens and fault blocks. In a regional scale, these half grabens and adjacent uplifts represent a horst-and-graben structural style. Neogene basins are downwarp basins lying on the tilting continental shelf. Late Tertiary sequences are relatively undeformed but locally with minor folding and thrusting during the Pliocene-Pleistocene.Seismic stratigraphy and well data indicate that the Early Tertiary strata are commonly tilted and disturbed as nonmarine to marginal marine facies deposited in the wedge-shaped half grabens; the Late Tertiary strata are generally parallel undisturbed marine facies accumulated in the enlarged downwarp basins overlying the infilled half grabens. In general, three major regional unconformities formed during the Late Cretaceous, the Late Eocene and the Middle Miocene. Widespread extrusive basaltic flows are commonly associated with these unconformities.

Jan 1, 1990

By Peck RC

The ore body at Elura contains fine grained galena and sphalerite in a matrix which is mostly pyrite. A differential flotation circuit concentrates lead and silver in the first section and zinc in the second. The lead section, shown in figure 1, was sampled in detail previously and the metallurgical performance assessed on a size by size basis. That assessment took no account of liberation and given the fine grained nature of the ore body, this could lead to an incomplete picture of the flotation performance. Liberation measurements were made using the QEM*SEM system on four size fractions of samples taken from seven different streams in the lead section. Using the mineral flows obtained from the mass balance around the lead section an excellent liberation balance was obtained which enabled the effect of liberation on the flotation performance to be assessed. The measurements indicated that only 17 per cent of the galena and 28 per cent of the sphalerite in the flotation feed was liberated. On the other hand 31 per cent of the gangue iron sulphides were liberated. The final concentrate was largely composed of locked galena and locked iron sulphides with 85 per cent of the product being locked. There was a small but significant fraction of liberated pyrite.

Jan 1, 1991

Secondary steelmaking (or ladle metallurgy) has been developed as a post- steelmaking ladle treatment to produce steel of superior quality. Its rapid growth has resulted from quality improvements, productivity increase, operational flexibility and process route economics. Advances in secondary steelmaking are very impressive during the past decade, and many commercial systems have been developed for performing one or more of the following unit operations: degassing, atmosphere regulation, reheating, refining with synthetic slag, rinsing gas treatment, injection of solid materials and alloying. The metallurgical requirements imposed by the current competitive steel market include more precise analysis tolerances, minimum level of detrimental elements, improved cleanness, demanding service performance and better processability. In most cases, these requirements could only be realized by the application of appropriate secondary refining facilities. Continuing developments in simplicity of design, cost advantage, quick cycle time, improvements in peripheral services such as refractories, instrumentation and in-situ analysis, extensive exploration of new applications, and the use of computer, can be expected. An exciting future is predicted for the widespread adoption of secondary steelmaking to perform most of the major refining functions over a variety of steel quality. It will also become a vital link in the total steelmaking process for production of tonnage steel at the large integrated steelworks and the mini-steelmills.

Jan 1, 1986

A good blasting result is largely achieved by putting the right amount of explosive in the right place and firing it in the right sequence. The best blast design in the world will not break the rock if the planned blast layout is not achieved in the field. One of the critical inputs into a blast design is the diameter of the blasthole. An assumption that the actual blasthole diameter is equal to the nominal drill bit size is generally made. However, a small deviation in the actual hole diameter from that assumed will have a dramatic effect on the hole's volume and, consequently, where the explosive is placed in the blasthole. Any discrepancy in actual blasthole volume from that assumed will be reflected in 'overloading' or 'underloading' of the blasthole with the calculated explosive quantity and, thus, reflect in explosive distribution and stemming lengths. When loading to a 'collar' in an oversized hole extra explosive will be used, resulting in higher than planned powder factors and explosive costs. A blasthole diameter assumed from a nominal drill bit size is an incorrect assumption. This paper will present some actual blasthole diameter measurements illustrating the variation in hole diameters seen in the field and proposes a practical method for achieving a useful blasthole diameter measurement.

Jan 1, 1990

By Klenowski

Rational design of layouts for longwall operations is greatly facilitated by use of an accurate and economical method for predicting stresses and displacements. The displacement discontinuity method (a form of boundary element method) is based on replacing actual excavation geometries by thin slits of the same plan area. This approach allows three-dimensional stress- analysis at a fraction of the cost of alternative methods. The analyses can be readily performed on economical microcomputers, putting the analysis capability within the reach of mine-site personnel. This paper describes investigations associated with the German Creek Central Colliery, the first longwall operation in Queensland's Bowen Basin. The material properties used in the model, in particular the rock mass and goaf properties, have been 'tuned' to fit stress measurements obtained during extraction of the first and second longwall panels at the mine. The study shows that model predictions based on suitably scaled anisotropic rock strata properties are in good agreement with the stress measurements made to date. This model predicts average chain pillar loads significantly higher than predicted by models based on United Kingdom conditions. A working chain pillar design method is proposed using average pillar loads predicted by the numerical model and ultimate strength characteristics given by Bieniawski's formula.

Jan 1, 1988

Intensive exploration for iron ore in the banded iron-formations (BIF) of the Pilbara region of Western Australia began in the early sixties and almost immediately established the Hamersley area as a major iron province. The early genetic models for the BIF-hosted ores were based mainly on macroscopic examinations of ores from the "hardcap" zone, and generally accepted a direct relationship with weathering effects on a Mesozoic to Tertiary land surface. Brandt (1964) was the first to suggest a difference in age between the high-grade hematite ores and the more common hematite-goethite types. He initially accepted a supergene origin for both, but later opted for a hydrothermal origin for the hematite ores. Apart from MacLeod (1966), the published views of the next decade reflect a largely parochial interpretation of individual ore bodies, centred mainly on supergene models but with some support for hydrothermal concepts. Except for Ayres (1971), none of the models were backed by detailed mineragraphic data. In 1976, an AMIRA-sponsored CSIRO group began a Province-wide investigation of the wide variety of ore types and BIF, with emphasis on geochemical and textural studies. The resulting conceptual model for a world-wide unified supergene and supergene-metamorphic hypothesis is generally accepted in the Hamersleys.

Jan 1, 1986

A synthetic gold-silver telluride material (mainly sylvanite) has been prepared and its physical and chemical properties checked. Flotation tests using a Hallimond tube were conducted using commercial xanthate collectors. At collector concentrations of 10-3M with the addition of 5 × 10-4 M CUS04, no obvious differences in the mineral recoveries were seen irrespective of whether amyl, secbutyl, isobutyl or isopropyl xanthates were used. However, when the concentration of xanthate was reduced to 10-4 M or in the absence of the copper sulphate activator, the effectiveness of the collectors was in the order: amyl > secbutyl > isobutyl > isopropyl > ethyl. Changes in the slurry pH appeared to have little effect on the recovery of the telluride mineral.Leaching tests of the precious metal telluride showed that both gold and silver dissolve in alkaline oxygenated cyanide solutions but at a much lower dissolution rate than metallic gold or silver. Both leaching tests and electrochemical measurements indicate that the dissolution rate of gold-silver telluride is controlled by the pH and cyanide concentration of the leachant.Roasting the gold-silver telluride materials in air at temperatures between 550 and 750°C resulted in its decomposition into a metallic gold-silver alloy and tellurium dioxide.

Jan 1, 1994

MOUNT STEWART is situated half a mile south of Leadville railway station, which is distant 240 miles by rail from Sydney via Mudgee. It forms a low ridge from which rock waste and alluvium slope gradually to the black-soil flats of the Coolaburragundy River. The Mt. Stewart mine comprises:(a) The Mt. Stewart workings in M.L. 44, parish Talbragar, Co. Bligh.(b) The Grosvenor workings in M.Ls. 44 and 45, parish Talbragar, Co. Bligh.(c) The Extended workings in M.L. 44, parish Talbragar, Co. Bligh.The workings contain 1375 ft.. of vertical shafts, 1105 ft. of underlay shafts, 800 ft. of rises and winzes, 8520 ft. of drives and crosscuts, and 18,000 ft. of stapes.The mine was first opened in 1888 as a silver-lead mine, and a waterjacketed furnace was erected during 18B2. The furnace was installed with two internally-fired tubular boilers of 35 h.p. and 25 h.p. respectively, and two Baker's rotary pressure blowers. The results of the smelting campaign indicate that, during 14 months, a total of 15,000 tons of ore were treated, yielding silver and lead. In addition to this, a quantity of matte was sold containing about 8000 oz. of silver. As a result of the treatment...

Jan 1, 1925

By Segnit ER, Jensen G

The decoppering of soft and hard leads was investigated by stirring in an open pot, using sulfur or sulfur plus pyrites, or sulfur plus pyrrhotite, as reagents. Lead samples taken during the process were analysed for copper. Dross samples were examined by optical micro- scope, SEM and XRD. Soft lead containing silver can be decoppered satisfactorily by stirring with 0.1% S at low temperatures - close to 330¦C. Soft lead, whether containing silver or not, can be decoppered satisfactorily at higher temperatures by stirring with 0.1% S plus 0.4% pyrites. Then CuFeS2, Cu5FeS4 and PbS are formed, instead of Cu2S, CuS and PbS when using S alone. Hard lead containing tin can be decoppered satisfactorily by stirring with 0.1% S at temperatures from 320-400¦C. When stirring with 0.1% S plus 0.4% pyrites, reversion of copper from dross to lead on prolonged stirring does not occur. Hard lead without tin can be decoppered with S plus pyrites better than with S alone, but the presence of antimony hinders the decoppering, which is less effective on lead with 5.5% Sb than with 2.3% Sb.

Jan 1, 1980

By D A. Deglon

Solids suspension is important in the design and operation of mechanical flotation cells, and is a necessary precondition to particle collection. Most of the fundamental hydrodynamic research that incorporates some aspect of solids suspension was done by Arbiter, Harris, and co-workers, or Schubert and co-workers. However, a need for research into solids suspension in mechanical flotation cells exists, since very little has been done since the late 1980s; a time that also coincides with the advent of round mechanical flotation cells and the subsequent dramatic increases in maximum flotation cell sizes. In this work, concentration profiles and critical impeller speeds, Njs, were measured in a 0.124 m3, round cell fitted with a 0.150 m, Bateman impeller mechanism. Two solids size fractions (75 - 106 and 150 - 250 ¦m) were tested, in ungassed and gassed conditions (JG = 0, 1 cm/s) and at various impeller speeds (300 - 900 rpm). The effectiveness of solids suspension was quantified in three ways in terms of extent of off-bottom solids suspension, suspension height (extent of solids distribution), and variation within the solids distribution, which together present a complete quantitative picture of solids suspension and distribution within the cell. Consistent trends were found when these effectiveness criteria were considered against relative impeller speed, in terms of percentage of critical impeller speed, N/Njs. Off-bottom solids suspension is complete at or above 100 per cent of Njs, with significant sedimentation occurring as the impeller speed drops below 60 per cent of Njs. Suspension heights consistently reached a level equivalent to 90 per cent of the tank diameter at the critical impeller speed, and dropped off significantly as N/Njs dropped below 60 per cent. The variation in the solids concentrations within the sampled profiles showed consistent trends in two-phase but not under three-phase conditions. The paper concludes that the critical impeller speed, Njs, commonly used in the design and operation of standard stirred tanks, is a very useful solids suspension benchmark for describing all aspects of solids suspension in mechanical flotation cells and should be correlated to system conditions.

Jan 1, 2005

By Langham B. M

A chemical study of the petrographic components of Greta (Maitland) coal, carried out by the Metropolitan Gas Co. (Melbourne), has revealed an anomaly in the composition of the durain which was thought to warrant petrological investigation.The original study, by the Metropolitan Gas Co., extended over eight shipments of coal received during the winter of 1943.The percentages of the several petrographic components were eslimated by careful handpicking of large samples of each shipment, and analyses were made of the handpicked components, which were also tested as to their gas-making and coking properties.The results are summarised in Tables 1 and 2. At first sight the components of the Greta coal bear a general resemblance in composition to those of other bituminous coals of similar rank, apart from a notable richness in volatiles, which is a distinctive feature of Greta coal. The durain has a typically higher ash content, and lower volatile content than the clarain (Table 1); and the coking behaviour of the four components is typical (Fig. 4).When, however, the analyses of Table 1 are re-calculated on a dry, ash-free basis, an anomaly appears: the clarain and the durain, on this 'pure coal' basis, have practically identical compositions, with the durain containing a slightly higher proportion of volatiles than the clarain (cf. Table 3); but the tar yield of these two components is very different (Table 1). Re-calculated on a dry, ash-free basis, the yield from the clarain is 18.9 gallons of tar per ton, while, that of the durain is 29.0 gallons per ton. The gas derived from the durain is correspondingly richer in illuminants (CH etc) and poorer in hydrogen than that from the clarain (Table 2), and is also notably richer in nitrogen.That the composition of the Greta durain is consistent is proved by the analyses of Table 3, in which the compositions of the respective durains and clarains of eight separate shipments of coal are compared. In most bituminous coals, the durain contains several per cent less volatile matter than the associated clarain, and high volatile content in a durain usually indicates a durain rich in spores.

Jan 1, 1947

By A Kuras

Segmental tunnel linings are becoming more common in Australia. One current project employing a segmental lining is the City West Cable Tunnel (CWCT) in Sydney. The project has been commissioned by Energy Australia and is currently being constructed by Thiess Pty Ltd. The project includes 1.6 km of tunnel boring machine (TBM) driven, segmentally lined tunnel. The majority of the CWCT will be excavated through Hawkesbury Sandstone. The tunnel is required to carry a 132 kV electrical circuit under SydneyÆs central business district (CBD), between Haymarket and Energy AustraliaÆs City North Substation on Sussex Street. The segmental lining has been designed as a 3.2 m internal diameter, 200 mm thick universal ring with six trapezoidal segments. The design and detailing of this segmental lining presents some noteworthy challenges, including exposure to saline groundwater, and the exclusive use of steel fibres for flexural and tensile concrete reinforcement. This paper describes some of the key elements of the segmental lining design. These include:the case for choosing segmental linings over other forms of tunnel construction;the major design checks required of a segmental lining including ground loading, hydrostatic loading, joint bearing, joint rotation, ram loading and the early strength lifting case;the benefits of using steel fibres over conventional steel reinforcement;the design approach used for steel fibre reinforced concrete;the application of 3D computer modelling in the design;the provision for components including connector dowels and gaskets;the design for passive fire resistance; andthe design for durability of steel fibre reinforced concrete in a saline environment. Segmental lining design requires the application of specialist design approaches. Input is required by the construction team, as the methods of demoulding, handling, transportation and installation impact on the lining design. As the segmental lining is functioning as immediate ground support and also a permanent lining, high standards of manufacture and construction quality control are required to ensure that the 100-year design life is met. The requirement for a watertight tunnel means that detailing and installation of the EPDM gaskets is of importance.

Jan 1, 2008

The aim of the study was to determine the ranges of stability and instability of the metal hydroxides and metal cyanide species that may be formed during the gold extraction process, Merrill-Crowe gold precipitation, and Inco S02/Air or ferrous ion cyanide removal processes.Following cyanide detoxification by the Inco S02/Air process, the main components of concern in the tailings will be:

Jan 1, 1997

According to the analysis of 126 mine gushing records and the relevant water supply and hydrogeologic condition, the gush can be classified into eight types;cave type,collapse -column. type, subterranean stream type, fault zone type, contact zone type, upper plate type, bottom heaving type and surface water invasion type. The formulae for counting the peak discharge of gushing point are further put forward in this paper.

Jan 1, 1988

My topic for today is the Crown Minerals of the future. New work initiatives are underway and the organisational structure is being overhauled. These are not insignificant changes and in this paper briefly summarises these proposals. These new work initiatives and changes to the organisational structure will have implications for the industry as a whole and also for the way individual clients interact with Crown Minerals.

Jan 1, 2003