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By J. M. Ortiz, J. P. Bertini

"In mineral resource and ore reserve estimation, several sources of information are generally available, such as diamond drillholes, reversed-circulation drillholes, and blastholes, and originate from one or more sampling campaigns and are analyzed by one or more laboratories. In such a situation, the grade measurements may not have the same precision and one should distinguish between hard and imprecise data.This work aims at studying the impact of data imprecision in resource/reserve evaluation through two case studies on simulated deposits: a porphyry copper deposit conditioned to real exploration and production data, and a gold deposit simulated without any conditioning data. Several geostatistical techniques are used to estimate the grades of selective mining units from exploration samples, including kriging, cokriging, lognormal and indicator kriging. Two types of imprecision are examined— measurements with multiplicative errors and measurements defined as intervals. The results are compared to the simulated grades of the selective mining units from a statistical and economic viewpoint.The study concludes that imprecise measurements should never be discarded because they help to improve the estimates, and that simple methods such as kriging are as efficient as more sophisticated ones for resource/reserve assessment. Finally, a few indications on how to diagnose and model the data imprecision are given."

Jan 1, 2005

By K. Lillkung, J. Kourunen, M. Latva-Kokko

"Carbon-in-leach (CIL) and carbon-in-pulp (CIP) processes utilize activated carbon to adsorb solubilized gold for recovery. Due to carbon attrition and non-ideal carbon management, however, some of the gold is lost in carbon fines and to the solution. The carbon attrition mechanism inside CIL/CIP reactors is mainly abrasion-related. This is critical to gold loss since gold loading takes place predominantly in the outer shell of the carbon particles. Thus fine carbon dust has a relatively high gold content and such a small particle size that it cannot be captured with safety screens. The attrition rate depends on ore and carbon characteristics, but it is always proportional to the mixing power intensity. This rate can be minimized by continuous suspension level measurement and control of agitation speed. In addition, a novel tank bottom structure can significantly reduce the required mixing power input compared to a flat bottom tank. A major challenge in carbon management is infrequent and inaccurate measurement of carbon concentration in the reactors. In order to reduce soluble gold losses by means of improved carbon management, Outotec has been developing a continuous in-situ measurement for carbon concentration that is tolerant to changes in slurry density.INTRODUCTION Cyanide leaching has been utilized since the late 19th century as a standard technology for hydrometallurgical gold production. Since then, gold and silver recovery rates have increased due to technological development, but very similar recovery methods are still being used. The original recovery method was to use zinc precipitation – similar to the Merrill-Crowe process, which is still common for feed materials with low throughput and high silver content. However, in most cases, activated carbon recovery is preferred due to its improved efficiency. The carbon-in-pulp process (CIP) and its modification, carbon-in-leach (CIL), have a lower residual soluble gold level and are not similarly affected by soluble base metals. The main alternative for the use of carbon is ion exchange resins. The principle of resin processes is similar to the CIL/CIP processes, with a different type of adsorbent material. Carbon processes are usually preferred over resin processes due to the significantly higher cost of resin material and the possibility to use simpler, well-established technology with carbon processes."

Jan 1, 2017

By F. P. Hassani, M. Hefni, M. F. Kermani

"This study is part of large and an ongoing investigation into the development of a light-weight and highly fluid mine fill for various applications in mining and civil operations. Foam mine fill is the new material proposed for backfilling mines, and is fabricated by mixing stable foam into a mixture of tailings, binders, and water. This paper investigates the effects of both binder dosage and the amount of foam used upon the mechanical and physical properties of foam fill, mainly in regards to compressive strength, porosity and density.Samples were prepared using tailings from a copper mine as the inert material, Normal Portland Cement as the main binding agent, and a foaming agent with a foam generator. Samples were cured for 7, 14 and 28 days and were then subjected to unconfined compressive strength (UCS) testing. Select samples were subjected to mercury intrusion porosimetry, so as to study the microstructural properties. An empirical model was then developed, using a response surface methodology to establish a relationship between the investigated parameters. INTRODUCTION AND BACKGROUNDThe disposal of mine tailings is a significant issue in the mining industry, particularly as mine production increases. Many mines re-use mine tailings for backfilling, which is a method for reducing environmental exposure to tailings, maintaining underground stability, and increasing ore recovery (Benzaazoua, Belem & Bussière, 2002).This paper introduces a new type of backfill called ‘foam mine fill’. This proposed backfill material is similar to cellular concrete, as air bubbles are entrained in cement or lime mortar, resulting in a cellular structure (Narayanan & Ramamurthy, 2000). Air voids can occupy up to 70% of the volume of concrete, which makes it light- weight, and thus can be used for a wide range of civil applications, including backfilling (Tarasov et al. 2010; Panesar, 2013). Unlike cellular concrete, the incorporation of air bubbles into a mixture of tailings, binder and water makes foam fill a potential new backfilling material. Furthermore, a preliminary investigation on foam fill samples found that pulp densities should be optimized before adding the foam, in order to produce consistent samples without foam segregation or losses (Hefni et al., 2014)."

Jan 1, 2015

By G. J. Hamilton

"THE Royalite-Canada Southern Coleville No. 1 gas strike of August 15th, 1951, and the closely following low gravity black-oil strike of August 23rd, were the first of a series of recent oil and gas discoveries in western Saskatchewan. They are in what is now known as the Coleville field, 25 miles north and west of Kindersley and 30 miles east of the Alberta-Saskatchewan border (Figure 1).Gas flows have been recorded in the Viking sand at daily rates of between 5 and 10 million cubic feet, and black oil of 15° A.P.I. gravity is produced from Mississippian sediments of Banff age at a daily rate .of 50 to 100 barrels on pump.Development drilling was carried on during the winter months, with very little attempt at step-out exploratory ventures. This year, however, a step-out programme to the northeast (Figure 2) is •being carried on in order to determine the position of a possible truncation of Mississippian sediments in that direction. Section 30 of the Coleville area has been fully developed on a 20-acre wellsite basis, and structural information is restricted to local rather than regional interpretation. No attempt will be made in this paper to interpret the Coleville area with respect to the regional geology in any but a general manner."

Jan 1, 1952

By Yongfeng Jia, Shaofeng Wang, Danni Zhang

Ferrihydrite is ubiquitous in soils, groundwater and aquatic sediments and is usually classified as "2-line" or "6-line" according to the number of diffuse XRD peaks. It has high surface area and reactivity; therefore, it may serve as a sink for sequestering trace metals, metalloids and organic matters via adsorption and co-precipitation. Although considerable attention was paid to the transformation process of this thermodynamically metastable solid, there are still some controversies on the mechanisms of the formation of goethite or hematite from the ferrihydrite precursor. This work systematically investigated the transformation of 2-line ferrihydrite produced by using different neutralization regent (CaO vs. NaOH) into crystalline products at different pHs (4, 7 and 8), three temperatures (25, 40, 75 °C) and in different media (sulfate vs. nitrate). X-ray diffraction (XRD), Raman, Fourier transform infrared spectroscopy (FTIR) and chemical extraction were employed to characterize the transformed solids as well as the redistribution of Fe between the amorphous and more crystalline phases. The results showed that the transformation product in nitrate media was hematite (major) and goethite (minor), which was independent of pH, temperature or neutralization reagent. In sulfate media, goethite was the dominant solid under slightly acidic conditions (pH 4) with 6-line ferrihydrite as the intermediate product, whereas neutral to slightly alkaline conditions still favor the formation of hematite. Chemical extraction results indicated that there was only ~3 % of amorphous phase detectable after aging at 25 °C for 280 days at slight acidic pH. In contrast,~70 % of the iron remained as an amorphous phase under neutral to slightly alkaline conditions. The results suggested that the pH as well as the reaction media (sulfate ion) plays an important role in the 2-line ferrihydrite transformation process.

Jan 1, 2016

By L. Paulino, R. A. Camilli, J. Yamamoto, J. C. Araujo

The first paper presented on this work [1], showed how bath ratio was increased from 78% to over 95% using a structured approach to reduce bath chemistry variability. This update will illustrate the steps taken and update the results presented earlier, showing the effects of long power interruptions and several load reductions as well as load increase during the period from 1999 to 2005. Current efficiency was affected by such processes upset; however, bath ratio in range (±0.05) is still higher than 90%, even after an increment of more than 6 kA. This review will explain each of the steps taken to reach stability in this critical smelting parameter.

Jan 1, 2006

By B. R. Conard

Occupational epidemiology of the nickel-producing industry has found that inhalation exposures to certain nickel-containing substances are linked to respiratory cancers and to nonmalignant respiratory endpoints. Establishing such a linkage, however, is complicated by the fact that some diseases occur long after exposure to a causal agent (i.e., some diseases have long latencies). Furthermore, most chemical agents (especially nickel substances) vary significantly in their toxicological properties and their concentrations in workplace air have varied over processing history. Because of these complications, it is critical to understand historical exposures to specific nickel substances. To assist in this effort, the author focuses on the history of smelting and its related processes at Vale Canada’s (Inco’s) Ontario operations in the first half of the 20th century.

Jan 1, 2012

By E. G. Leonardon

The question of geophysical prospecting is one that is beginning to occupy a pre-eminent place in the minds of those actively concerned in the discovery and exploitation of ore deposits. This is in marked contrast to the reception accorded such ideas when the Junior author, six and a half years ago, began introducing electrical prospectii1g to the mining fraternity on this continent. Happily, the mention of geophysics no longer evokes the sceptical and pitying smiles that it did in those days. A little reflection will show that modern geophysical methods are merely a logical development from pre-existing technique. In the study of geological problems, is it not logical to use all possible physical properties of matter? The study of crystal form and cleavage, the examination of thin sections of minerals by means of polarized light or ordinary light, in fact, utilize physical properties of minerals for the benefit of the geologist. These are, of course, laboratory methods, and the extension of the study of similar properties into field work was inevitable. This began with the magnetometric surveys, used as early as 1760 in New Jersey to locate iron ores. Eighty-four years later, John Locke's work in the United States resulted in pointing out relationships between the terrestrial magnetic field and main tectonic features of the earth's crust.

Jan 1, 1928

By John R. Sullivan, Real Daigneault, Mathieu Piché, Jayanta Guha, Gilles Bouchard

"RESUMELa stratigraphie du camp minier de Matagami se résume a la présence de deux groupes volcaniques: le Groupe du Lac Watson et le Groupe de Wabassee qui le surmonte. Les gisements de sulfures massifs volcanogènes sont situés au sommet du Groupe du Lac Watson. Ces roches sont déformées par l'anticlinal de Galinée dont l'axe, orienté E-W, plonge vers l'ouest. Le cœur de cette structure est occupé par le Complexe de la Rivière Bell.Les roches volcaniques du flanc sud de l'anticlinal sont peu déformées et pendent à 45° vers le sud. Les gites qui s'y trouvent présentent la morphologie typique des gisements de sulfures massifs volcanogènes. Ceux-ci se situent le long d'un horizon repère cherteux et sulfure, appelé ""Tuffite Clef', et leurs cheminées d'altération rejoignent, en profondeur, une zone d'altération stratiforme d'étendue régionale.Les roches du flanc nord ont été transposées tectoniquement en écailles chevauchantes, de dimension kilométrique, a l'intérieur d'un couloir de failles anastomosées d'orientation est-ouest. A l'intérieur: le ce couloir, les gites de sulfures sont déformes et sépares de leur héminée d'altération sous-jacente par des failles.Les gites de sulfures situes sur les deux flancs de l'anticlinal de 'Galinée se seraient mis en place dans un mime environnement volcanique. Leur position stratigraphique est identique puisqu' ils se 'rouvent au sommet de la rhyolite porphyrique du Groupe du Lac Watson. lis se seraient constitués au cours d'une pose volcanique recédant 1'éruption du basalte du Groupe de Wabassee. Le Complexe de la Rivière Bell est perçu comme la source de chaleur responsable de la circulation des fluides hydrothermaux qui sont à ""origine des gisements de sulfures massifs volcanogènes."

Jan 1, 1990

By Mitchell Gordon

"In almost all thickener applications the highest possible solid/liquid separation efficiency is what is desired by the user. There is a trend in the industry due to monetary restraints and environmental pressures to look at ways to extract this maximum performance by either retrofitting existing thickeners or installing the most cost effective new thickener. This paper looks at some of the common problem areas and presents a range of solutions developed by Outokumpu Mintec in North America and outokumpu's subsidiary Supaflo Technologies Pty. Ltd.The Emerging PictureAfter many hours of discussions with a large number of plant personnel over the last two years a picture began to emerge regarding current thickening operations in the industry. Initially, it seemed that everybody had their own unique process problems and therefore needed a correspondingly unique solution. Looking more closely at all the cases and the ideas that we had either implemented or suggested, it gradually became apparent that the majority of operators all had one and the same process need ....""Better Separation Efficiency""The range of operational problems that were uncovered in the survey were much more varied than expected and often were not even considered initially to be thickener problems. Often, it was only after the rejection of many solutions to the problem, generally due to capital cost, that the actual cause of the problem was looked at and found to be a thick-ener.A summary of the problems that have so far been identified is presented in Table 1. They are subdivided under three major categories of environmental, process and paste fill to highlight the wide range of mining activities that can be affected by poor thickener performance. These seem to be the major areas where the need for better separation efficiency is rooted."

Jan 1, 1995

By Desmond Y. M. Lee

This paper presents a procedure to prepare input for the computerized pit design system at Iron Ore Company of Canada. The procedure is simple and requires very little training. Also, it is general enough to accept both bench (horizontal cross section) maps and section (vertical cross section) maps. The output of this procedure is data which represent blocks of ore and waste with dollar values based on mineral content. The ultimate pit design is presented in printer-generated graphs, with numbers indicating the depths of pit bottom walls. Roads are added manually by the engineer with the aid of other computer programs. Section maps and bench maps are also printed as part of the output of the ultimate pit design.

Jan 1, 1978

By E. S. Allen, P. R. Kruesi, J. L. Lake

An electrochemical process is described for converting concentrates of base-metal sulphides to the corresponding pure metals and elemental sulphur. The application of the process to chalcopyrite is discussed. The process is also of potential interest in processing copper-nickel sulphides, and laboratory data concerning this potential are presented. The process creates neither air nor water pollution.

Jan 1, 1973

By L Tafaghodi Khajavi, M. Barati

The distribution of phosphorus between solid silicon and iron-silicon melt was determined to investigate the degree of phosphorus removal from silicon by solvent refining with iron-silicon alloys. The distribution coefficient which is the ratio of the mole fraction of phosphorus in solid to that of liquid is as follows: 0.22±0.02 (1310°C), 0.29±0.02 (1260°C) and 0.33±0.02 (1210°C). The removal percentage of phosphorus is: 84.2% (1310°C), 72.5% (1260°C), and 63.7% (1210°C). The average phosphorus content of produced silicon in the proposed solvent refining process would be over two times less than that of the conventional directional solidification. The values of interaction coefficient of phosphorus on iron at different temperatures were obtained as -3460±155 (1310°C), -3595±159 (1260°C) and -3694±119 (1210°C). Self interaction parameter of phosphorus at different temperatures are as follows: 68±4 (1310 ?C), 78±10 (1260 ?C) and 103±19 (1210 ?C). The calculated values for distribution coefficient of phosphorus at infinite dilution are: 0.22±0.00 (1310°C), 0.30±0.00 (1260°C) and 0.34±0.00 (1210 °C).

Jan 1, 2015

By W. G. Brissenden

"ALTHOUGH I SHOULD FIRST REVIEW the state of the mining art as it is today, because of the shortness of time I will confine myself to a re-view of the more important advances in that art which have been made in the past two to three decades. Then, a look at the opportunities and the challenges which now present themselves will be more meaningfulFirst, some of the more impor-tant developments in underground mining:(1) The recognition that good ventilation, visibility and working conditions are essential preliminaries to efficient production has resulted in their incorporation as a matter of practice in modern mine planning. (2) The introduction of the car-bide bit and the re-introduction of the airleg drill, and the resulting sharp rise in productivity, were early postwar developments. (3) The recovery of the coarser fraction of mill tailings for use as mine backfill also is an important cost-reducing development of recent years -and this has led to cemented backfill, which, al-though more expensive, meets certain specific needs and has tremendous potential. (4) Great strides have been made in improving explosives' materials and explosives' accessories. Millisecond-delay electric blasting caps, which improve fragmentation and reduce the seismic effect of blasting, and the development and •application for underground use of explosives are but two among many such improvements. (5) Trackless mining methods, using quarry-type equipment in some instances and specially de-signed low-headroom trucks, loaders and carrier-mounted drills in others have been successfully applied. (6) Dual-purpose load-haul units are now in use loading and hauling from open stope drawpoints, and smaller versions of this type of unit are in use in cut-and-fill and other types of stopes."

Jan 1, 1968

By Ahmad Ghahreman, Denver Cowan, Yeonuk Choi

"Previous testwork by the authors has indicated that both granular coconut shell based activated carbon and a new microporous carbonaceous bead, Lewatit® AF 5, are highly effective in improving the oxidation kinetics and decreasing the elemental sulphur yield when assisting the atmospheric oxidation of pyrite. While the two carbon catalysts show similar results and improvements to the pyrite oxidation, there are differences between them. For example, the activated carbon assisted oxidation showed faster kinetics than the AF 5 assisted oxidation, while elemental sulphur seemed to remain adhered to the surface of the AF 5 after oxidation when much of the elemental sulphur formed during the activated carbon assisted tests was found in the oxidation residue. The objective of this paper is to investigate the differences between the two catalysts through the use of scanning electron microscopy, photography, Raman spectroscopy, surface chemistry analysis, and Brunauer-Emmett-Teller (BET) surface area analysis. With this investigation the authors should be able to achieve a better understanding of the surface chemistry of the two carbon catalysts (i.e. functional groups, charges, acidity etc.) and help explain the strengths and/or the weaknesses of the catalysts when applied to the atmospheric oxidation of pyrite.INTRODUCTION Previous research conducted by the authors, indicated that both a granular coconut shell based activated carbon (activated carbon) and a microporous carbonaceous bead, Lewatit® AF 5 (AF 5), acting as a catalyst enhanced atmospheric pyrite oxidation in ferric sulphate media by approximately 40% when compared to unassisted oxidation and that elemental sulphur yields were increased from 23% to approximately 69 and 63% when assisted by AF 5 and activated carbon respectively (Cowan, Jahromi, & Ghahreman, 2017). The study indicated that although total pyrite oxidation assisted by the two catalysts was similar, differences were noticed in the impact that the two catalysts had on the outcome of the oxidation. Kinetic curves in the Cowan et al. study indicated that atmospheric oxidation of pyrite seemed to reach completion after 48 hours of oxidation when assisted by activated carbon. A similar trend was noticed in the kinetic curves for oxidation when assisted by AF 5, however the oxidation curve did not reach completion until approximately 96 hours (Cowan et al., 2017). This observation indicated that the kinetics of pyrite oxidation are enhanced by both catalysts, oxidation kinetics are much faster when assisted by activated carbon rather than AF 5."

Jan 1, 2017

By B. J. Keating

"AT PRESENT, it is not certain that any of the sulphide de in the Province of Nova Scotia attain the lower grade limit of 60 per cent sulphides over the minimum area of 1,000 square feet suggested as cut-off specifications for inclusion in this Symposium. However, several of them do include massive sections of substantial size and others represent concentrations of sulphide material that are well above average. It is felt, therefore, that a tentative classification of the deposits and presentation of their geological settings are justified and may help round out the genetic aspects of this study. Accordingly, data considered to be the most pertinent are assembled here in the event that some may fit into larger-scale patterns of mineralization that may take shape as a result of this investigation.The three principal massive sulphide deposits in Nova Scotia are the Stirling, the Smithfield, and the Walton. The locations of these are shown on the accompanying key-map (Figure 1).Three other deposits, the locations of which are also indicated on the map, are the Meat Cove, Rocky Brook, and Gays River de¬posits. Although these fall far short of the minimum dimensions and grade specifications referred to above they are singled out because they have received more than passing attention and are illustrative of the mineralization types to which they belong."

Jan 1, 1960

By L. T. Pasiechnyk

After a brief review of the various hydrocarbon storage methods currently being utilized and statistics on underground hydrocarbon storage, this paper will briefly describe the technology involved in solution mining salt to create caverns of engineered shape and size and briefly discuss the economical and environmental advantages of hydrocarbon storage in solution-mined salt caverns. Other possible uses of salt caverns will be mentioned.

Jan 1, 1978

By T. Shellhammer, A. Park

Among all pure metals, copper has the second highest thermal and electrical conductivity, next to silver. These properties coupled with a reasonable cost, make copper ideal for use in metallurgical vessels as a conductor of electrical current, as well as a lining material and protector of refractories and steel superstructures. Treatments of copper to address it’s softness and low melting point, specifically hard surfacing and calorizing, will be discussed. This paper will cover the evolution of copper to its current form, offer comparisons to other materials, and theoretical and empirical evidence on its superior performance in metallurgical vessels such as blast furnaces, basic oxygen converters and electric arc furnaces. Some case studies will be provided and finally a brief summary.

Jan 1, 2015

By G. E. Murray

Introduction The development of the method for recovering zinc from lead blast-furnace slags at Trail is interesting and important in the history of both lead and zinc metallurgy. Many efforts have been made in the past, particularly in Germany, to make economic recovery of zinc from slag. The Pape process on Oker slags was successful and is being worked at the present time. More recently the Waelz process has come to the fore. One effort at Cockle Creek, Australia is of special interest in view of subsequent developments. This was re-ported in detail by Guy Courtney in 1920(1). It deserves mention as it shows how, as in many other instances in the metallurgy of lead and zinc, important pioneering work has been done in Australia. These experiments, started over 25 years ago, comprised reduction with coke, powdered coal, and eletrothermically in carbon-lined furnaces. The so-called slag eye furnace, which volatilised the metals from a blast furnace running with a hot top, was also investigated.

Jan 1, 1933

By Alan Bauer, Melvin A. Cook

Measured detonation pressures of "prills and oil" (94/6 ammonium nitrate/fuel oil) and three of the new "slurry" blasting agents are presented and compared with computed, ideal detonation pressures and with detonation pressures expected from the measured detonation velocities. Results seem to show that the peak pressure in the detonation wave in these cases is the Chapman-Jouguet pressure and that no "spike" exists in these detonation waves. The absence of the Zeldovich-von Neumann "spike" is noteworthy in view of the very long reaction zone lengths of these mixtures. The measured detonation pressure of one of the slurry blasting agents (DBA-3") under steel confinement ( 172 kilobars) is shown to be considerably greater than the ideal detonation pressure of 75 per cent gelatin dynamite (p. = 135 kilobars) despite the fact that the detonation was still somewhat non-ideal in "DBA-3," its computed ideal detonation pressure being 180 kb. The popular 94/b AN /FO blasting agent exhibited a detonation pressure of only 13.5 kb in 5" paper tubes, but 37.5 kb in 5"• steel pipe compared with a computed ideal pressure of 40 kb.

Jan 1, 1961