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By W. L. Dalmijn

The processing of scrap and scrap cars starts with size reduction by a hammermill, or shredder. After the liberation the magnetic fraction is removed. The remaining non¬magnetic fraction mixed with other materials is screened and each fraction is processed separately. The increased use of plastic has a negative effect on the recovery of metals and waste production. At Huron Valley, Belleville Michigen, USA, the non-ferrous fraction from 5 million obsolete cars per year, containing 200,000 tons of non-ferrous metal, is processed. Aluminium Is recovered with a heavy medium separation process and concentrated with eddy current separators. The remaining heavy non-ferrous fraction is concentrated by a new combination of eddy current separation and image processing. After this separation process the zinc fraction is melted and refined and the copper, brass, stainless steel and other high-quality concentrates are sold to the secondary industries. The recycling of car scrap has become an important source of metals and materials for the secondary. materials processing industry.

Jan 1, 1995

By Binxu Zhaug, Mark Jolly, Xiaojun Dai

"In conventional investment casting process of aluminium alloys for the application of the aerospace industry, to assure the quality of the final casting, usually the foundry uses large runner system which results in low yield, high energy consumption and high GHGs emission. In one case of this investigation, the yield is between 5 ~ 10% which means that the current casting process wastes large amount of energy and generates lots of scraps. By applying a new casting method, the bulky runner system and the melting/holding time are significantly reduced, the quality of the casting is improved, and in the meantime the related energy consumption and GHGs emission are significantly decreased. In the investigation, the energy efficiencies and GHGs emission between the current and traditional processes are calculated and compared.1. IntroductionAs one of the conventional casting process, Investment Casting Process (ICP) and its applications can be traced to thousand years ago [l]. In current casting industry, ICP still plays an important role in the production of small and precious castings with high quality requirements in automobile and aerospace industries. Both casting quality and manufacturing costs which mainly consist of energy costs have crucial effects on the competitiveness of castings in the market. In the production of aluminium alloy castings using ICP, the energy cost and energy efficiency of a casting facility depend mainly on the efficiency of its melting and heat treating performance. In association with the two performances, more than 60 % of the total process energy costs are symbolised in a typical casting facility [2]. Additionally, in conventional ICP of aluminium alloys for the application of the aerospace, to assure the quality of the final casting, typically the foundry uses huge runner system including big risers/feeders which cause low yield, creates lots of scraps and generates high energy consumption. Consequently, there are huge opportunities for casting industry to choose the best practices for potential energy saving. Furthermore, the reasons such as the stringent limitation of environmental legislation in Europe and the pressure of the rising energy price force the casting industry to reduce the energy consumption and greenhouse gases (GHGs) em1ss10n."

Jan 1, 2012

By P. T. Velu

Solubility of metal oxides in the molten salt electrblytes is an important parameter in the electrochemical processing of metals and alloys. The efficiency of an electrochemical process primarily depends on the quantity of metal oxide present in the electrolyte in the dissolved form and its thermodynamic properties. The activity of CeO2 was calculated using the free energy of fusion of CeO2,{ AG°m, CeO2. The AGOm,CeO2 }was deduced from the values of enthalpy, heat of fusion and melting point of Ce02. The activity coefficients of CeO2 as a function of temperature and melt composition were calculated. The thermodynamic data such as integral molar enthalpy, entropy and Gibbs energy of formation were calculated as a function of composition and temperature.

Jan 1, 1994

By F. E. Wagner, L. J. Cabri, Y. G. Safonov, N. S. Bortnikov, A. D. Genkin, J. Friedl, G. N. Gamyanin

"A multidisciplinary investigation (including INAA, SIMS, EPMA, and Mossbauer Spectroscopy) was used to characterize gold in four of the largest Siberian mesothermal sulfide gold deposits. These are the Olympiada (""'750 metric tons gold) and Veduga (estimated at 75-100 metric tons gold) deposits in the Enisei Mountain Range and the Nezhdaninskoye (z500 metric tons gold) and Sentachan deposits in the Verchoyansk-Kolyma area. It was found that some of the mineralization is refractory in all four deposits, largely due to the occurrence of ""invisible"" gold in arsenopyrite as well as within pyrite, but with a lesser concentration. The gold concentration and its distribution varies considerably both within and between arsenopyrite grains, with implications for processing options such as heap leaching. The ore most likely to be amenable to heap leaching is the oxidized ore of the #4 orebody of the Olympiada deposit, but further quantitative mineralogical investigations are recommended for this orebody's sulfide ore and for the ores of the Nezhdaninskoye deposit. Following a full mineralogical characterization, it is possible that economic viability will depend on a combination of pre-concentration with or without pre-treatment, followed by heap leaching of some tailings products.Acknowledgements· The Russian authors performed this study under an ""Eco res"" Project which was financially supported by the Ministry of Science and New Technology of the Russian Federation. C.J. Stanley wishes to thank John Spratt and Terry Williams for help with EPMA. F.E. Wagner acknowledges the Deutsche Forschungsgemeinschaft for a grant supporting the Mossbauer studies. L.J. Cabri is grateful to the following: M. Beaulne, D. Carson and J.H.G. Laflamme for technical support, K.E. Haque for technical comments, and D.M. Hausen and W. Petruk for editorial suggestions."

Jan 1, 1997

By P. Blazy

A hydrometallurgical procedure for the recovery of metal from ore, particularly of copper from sulphide materials is described. In the course of this procedure, the raw material is first of all submitted to the action of an appropriate reducing system and then treated with a ferric salt solution which brings about the selective solubilisation of the elements to be recovered with respect to those constituting the pyritic phase. This procedure is investigated using two ore samples proceeding from massive sulphide deposits, presenting different chemical and mine- ralogical characteristics. The results of this investigation are compared with those obtained by a classical process employing a ferric salt solution. It appears that one solubilisation of copper takes place under particularly advantageous conditions when our procedure is used. The principal parameters affecting leaching of zinc, lead and copper are examined. The selectivity of this treatment is evaluated by following the change during the treatment in the pyritic phase.

Jan 1, 1976

By Wilky Desrosin, Alicia E. Ares, Carlos E. Schvezov

"In the present research the horizontal directional solidification Zn-Sn alloys (Zn-4wt. %Sn, Zn- 6wt. %Sn, Zn-10wt.%Sn and Zn-30wt.%Sn) was carried out by extracting heat in two opposite directions. For this purpose, ceramic molds, a muffie, a horizontal furnace with two heat extraction systems at the ends, a measurement, acquisition and recording temperature system, eight K-type thermocouples and an electronic recorder were used. The main parameters involved in the columnar-to-equiaxed transition, CET, were: the moment of start and end of solidification at each position under consideration, cooling rates, the average temperature gradients and critical temperature gradients at the CET, the average speed of liquid and solid interphases left and right, advancing in opposite directions. Also, solidification kinetics was found to be different between horizontal solidification two-way heat extractions, with preliminary results of the vertical unidirectional solidification. In the solidification experiments, the velocity and accelerations of the liquidus and solidus interphases usually occurs at the end solidification zone of the samples.IntroductionSolidification of metal alloys, which starts in the external equiaxed region (chill), results in two basic types of structures in a single solidified alloy sample: columnar and equiaxed. The presence of both structures indicates the occurrence of the colunmar-to-equiaxed transition phenomenon[!].Studying the colunmar-to-equiaxed transition, CET, is of great technological interest for the evaluation and design of the mechanical properties of the solidification products. To this end it is necessary to understand the mechanisms by which it occurs. As found in previous studies [2-5], the CET occurs by competition between columnar and equiaxed growth. Mainly is controlled by the parameters of casting, such as the alloy composition, the density of the present nuclei in the liquid, the cooling capacity of the metal I mold, and the degree of convection in the liquid [7-10]."

Jan 1, 2014

By Anna Wasilkowska

The study concentrates on the effects exerted by microstructure, deformation history and uniaxial stress conditions (temperature, stress state, strain rate) on the mechanical properties offerritic TRIP-aided steels for automotive applications. In low-alloyed TRIP-steels it is quite difficult to separate the effect of the austenite to martensite phase transformation from the influence of the ferritic matrix contributing to the yield stress and uniform elongation. Investigation of transformation kinetics of retained austenite as a function of the deformation temperature show that using the parameter k to characterize the retained austenite stability allows to identify regious of different temperature sensitivity separated by a transition temperature of 10±5°C. The observed low strain-rate sensitivity of the flow stress is an intrinsic property of the ferritix matrix and points to defomtation governed by slip. The ultimate tensile strength is much stronger affected by temperature than the yield stress. The influence of the temperature on the elongation is complex, because of the heating of the specimens by 60-l20°C at moderate and high strain rates. The increase of the total strain can be understood in terms of thermal softening of the ferrite. On the other hand, the steep increase of the stress during dynamic testing is an effect of accommodated elastic and plastic strains in the matrix. The strain- hardening exponent is dependent on the conditions imposed during testing. The martensite transfomtation rate is lower and the critical stress for martensite nucleation is much higher under compression compared to tensile loading. In secondary tensile tests, the yield stress increases steeply, and the ultimate tensile strength and the total elongation depend linearly on the amount of pre-straining. The results confirm that in the range of 8=10-4 s-l the TRIP-effect governs room temperature plasticity. Keywords: TRIP-steels, mechanical properties, strain rate sensitivity, temperature sensitivity, austenite stability

Jan 1, 2003

By G. Glinski, K. A. Pericleous

"Recent advances in new computational modelling techniques such as Lattice-Boltzmann and Dissipative Particle methods offer the prospect of simulating complex fluids such as colloidal and dense suspensions in industrial processes. They are referred to as mesoscopic methods since they lie between molecular dynamics at a microscopic atomistic scale «lO-9m) and traditional macroscopic CFD methods (> 1O-2m). The models behave like a 'coarse-grained' gas consisting of fictitious interacting particles, which are much larger than the real molecules of the actual fluid they represent. Inter-particle forces are set so that the collisions collectively mimic the phenomenological transport properties and flow of the underlying fluid at a macroscopic scale.Much of the developmental work to date has focused on laying theoretical foundations based on thermodynamic and kinetic theory. Successful applications include predictions of macroscopic transport properties of complex fluids and flows in porous media and filters. With the constant increase in computational power, these mesoscopic methods are now sufficiently developed to determine their suitability to simulate complex fluid flows in real industrial processes. This work describes the application of meso scopic methods to the stencil printing of solder pastes in the assembly of electronic components. The aim of this work is to assess the ability of these methods to study the transport mechanisms of individual solder particles suspended in the flux solvent as they enter and fill the micro-apertures of a stencil. This paper demonstrates the coupling of such mesoscopic methods to continuum CFD methods to predict the flow of dense suspensions (i.e. solder paste) in industrial processes."

Jan 1, 2001

By B. Yawney

A copper-nickel sulfide concentrate was leached in water at about 2000C under oxygen pressures of about 0.35 MPa. Oxidation of sulfide to sulfate was virtually complete in about 30 minutes, resulting in greater than 95% copper and 98% nickel extractions. Leaching temperature was shown to be the most important factor affecting metal extractions. Measured rates of oxygen consumption were used to develop batch kinetic data. Mini-plant continuous pressure leaching tests agreed with batch leach results. A proposed overall flowsheet is briefly examined.

Jan 1, 1976

By E. C. T. Chao

Micro-optical and synchrotron radiation-induced X-ray fluorescence (SXRF) techniques have been used to study unoxidized and oxidized samples of Carlintype sedimentar,y rock-hosted disseminated gold ore. In these samples, Where much of the gold is submicroscopic, the SXRF technique, which has a spatial resolution of about 20 ~m and a minimum detection limit (MDL) in the ppm range, is an ideal and necessary tool for precisely locating gold-rich areas in a sample. Gold-rich areas pinpointed by SXRF were later studied in detail by micro-optical methods, principally optical microscopy and scanning electron microscopy with energy-dispersive X-ray analysis (SEM-EDX). In two unoxidized and one oxidized ore samples, SXRF analyses have shown gold to be present predominantly in discrete clay-rich and silicified areas. Gold was not detected by SXRF in association with pyrite or carbonaceous materials. SEM-EDX examination of the gold-bearing areas in the unoxidized samples succeeded in identifying only two free gold particles, 0.2 and 0.5 ~m in size. In the oxidized sample, gold particles appear to be larger (but still submicroscopic) in average size and more evident in micro-optical examination after SXRF location of goldbearing areas. The findings of these studies may help to improve the efficiency of processing and recovery of gold from unoxidized ores.

Jan 1, 1987

By Philip L. Sibrell

A new process utilizing pulsed fluidized limestone beds was tested for the remediation of acid mine drainage at the Friendship Hill National Historic Site, in southwestern Pennsylvania. A 230 liter-per-minute treatment system was constructed and operated over a fourteen-month period from June 2000 through September 2001. Over this period of time, 50,000 metric tons of limestone were used to treat 50 million liters of water. The influent water pH was 2.5 and acidity was 1000 mg/L as CaCO3. Despite the high potential for armoring at the site, effluent pH during normal plant operation ranged from 5.7 to 7.8 and averaged 6.8. As a result of the high influent acidity, sufficient CO2 was generated and recycled to provide a net alkaline discharge with about 50 mg/L as CaCO3 alkalinity. Additions of commercial CO2 increased effluent alkalinity to as high as 300 mg/L, and could be a useful process management tool for transient high flows or acidities. Metal removal rates were 95% for aluminum (60 mg/L in influent), 50 to 90% for iron (Fe), depending on the ratio of ferrous to ferric iron, which varied seasonally (200 mg/L in influent), and <10% of manganese (Mn) (10 mg/L in influent). Ferrous iron and Mn removal was incomplete because of the high pH required for precipitation of these species. Iron removal could be improved by increased aeration following neutralization, and Mn removal could be effected by a post treatment passive settling/oxidation pond. Metal hydroxide sludges were settled in settling tanks, and then hauled from the site for aesthetic purposes. Over 450 metric tons of sludge were removed from the water over the life of the project. The dried sludge was tested by the Toxicity Characteristics Leaching Protocol (TCLP) and was found to be non-hazardous. Treatment costs were $43,000 per year and $1.08 per m3, but could be decreased to $22,000 and $0.51 per m3 by decreasing labor use and by on-site sludge handling. These results confirm the utility of the new process in treatment of acid impaired waters that were previously not amenable to low cost limestone treatment.

Jan 1, 2003

By Y. K. Rao

Relatively pure crystalline lead sulfate (PbSO4) can be produced by chemical vapor transport from an impure source such as the lead-acid battery paste or the roast-ore-leach-residue from a hy¬drometallurgical process-route. In a closed-reactor, transport of matter is induced by a tempera¬ture-gradient and the steady-state transfer rate can be calculated using the data on the standard free energies of formation for the species present and the pertinent binary diffusion coefficients. The present work focusses on chemical vapor transport in a tubular reactor (1.4-cm inner diameter x 10-cm long) with the source- and deposition-ends held at 850°C (T,) and 750°C (Td), respectively; PbC12(g) is the &apos;solvent&apos; or &apos;transport agent&apos; and NiSO4(s) placed in the source-zone -serves to maintain a sufficiently high S0,-potential such that the stability of the lead sulfate species is ensured. For the purposes of analysis, the gas-phase in the reactor is assumed to consist of eight species: H2O, PbC12, SO3, SO2. O2 HO, C12, and PbC14. The reaction between C12(g) and PbSO4(s) in the high-temperature source-zone produces PbCl2, SO2, and 02; four more reaction-equilibria in the same zone yield other species. In the low-temperature deposition-zone, reaction equilibrium involving PbC12, H2O, and SO, leads to the nucleation and growth of PbSO4 crystals; three other reaction-equilibria occur in this zone. By employing the virtual equilibrium state for the end-zones and coupling it to the Stefan-Maxwell diffusion equations for each of the gas species, the respective partial pressures for these, in the source- and deposition-zones, are computed at steady-state. From these data, the molar fluxes of PbCl2. PbCl4, and so forth, are determined. Allowing for the transport-enhancing effects of thermal convection, the net transport rate of lead (or PbSO4) is duly calculated for specified initial conditions. The predicted rates show very good agreement with measured rate data reported in the literature [ V. Plies, T. Kohlmann and R. Gruehn: Z. anorg. allg. Chem, 568, 62 (1989)

Jan 1, 1995

By R. H. Hanewald

INMETCO, a subsidiary of Inco Limited, is the only facility in North America that provides High Temperature Metals Recovery for nickel-, chromium-, and iron-bearing wastes. Since 1978, this process has prevented more than 775,000 tons of materials from becoming part of the nation&apos;s waste stream. The paper describes Inco&apos;s experience in metals recovery, traces the development and explains the operation of the High Temperature Metals Recovery Process, and examines the procedures and criteria used to determine whether spent catalysts meet process feed specifications. An overview of the current requirements for transporting spent catalysts is provided. The paper concludes with brief case histories of catalysts users employing High Temperature Recovery to manage spent catalyst.

Jan 1, 1995

By H. K. Lin

Pyrite oxidation in chloride solutions was investigated with cyclic voltammetry, ac impedance and potential step techniques. The pyrite oxidation in quiescent electrolytes is irreversible and controlled by diffusion. Depression of the semi-circle in the complex plane plot has been explained mathematically based on the concept of the equivalent circuit. When the semi-circle is depressed, the mathematical formula indicates that the reaction resistance should be obtained from the intersection of the semi-circle with Z-axis instead of the semi- circle diameter. The peak charging current densities at 1.10 and 0.90 V vs. SHE obtained from the equivalent circuit coupled with the ac impedance measurements match the peak current densities obtained with the potential step measurements.

Jan 1, 1997

By Antoine Allanore, Luis A. Ortiz, Donald R. Sadoway

"The steelmaking industry has drastically reduced its energy consumption in the last fifty years, and today’s technologies are considered to operate at their optimal efficiency with respect to energy needs. To cope with new constraints related to greenhouse gas (GHG) emissions, a change of paradigm is necessary. One of the promising technologies that could be deployed to help reach CO2 mitigation targets relies on the intensive use of electricity: molten oxide electrolysis (MOE). This paper presents the key process parameters that need to be tuned to address the practical needs for both high productivity in a steelmaking reactor and for an energy efficient process. Herein we show that contrary to common perception, the electrolysis process for ironmaking requires less energy than today’s chemical reduction route. Furthermore, we prove that most of the energy that must be provided to operate the electrolytic iron production cell is thermal energy which is readily generated by joule heating during electrolysis due to large currents being passed through the electrolyte. The energy consumption of the electrolysis cell is therefore shown to be highly dependent on the cell configuration and the chemistry of the electrolyte. As a consequence, the CO2-impact of the technology strongly depends on both the power production mode and the technological choices for design of the process, including cell configuration. Surprisingly enough, even when the electricity generation is not carbon-free, MOE still appears to be viable from the perspective of reducing GHG emissions providing sound reactor design considerations are made.IntroductionIn the context of greenhouse gas (GHG) emissions mitigation, the steelmaking industry is considering several techniques that could sustain the efforts and progress achieved by this sector in the last decades [1]. A recent report [2] on potential routes for low-CO2 steelmaking highlighted for all techniques both the strong dependency of CO2 emissions on electric power production mode and the need for a decrease in energy consumption per tonne of steel. Incited to innovate with respect to this last criterion, the steel industry considers electrolysis to be a promising technological solution, and in particular the molten oxide electrolysis (MOE) process. This process conducts electrolysis in a mixture of oxides that dissolve the iron oxide feed, which by the action of electric current is decomposed into liquid iron and oxygen gas. The opportunity for reduction in energy consumption during steelmaking by MOE is commonly attributed to the “direct” pathway from iron oxide to liquid metal offered by the use of a molten oxide melt and operation at a temperature above the melting point of iron, ideally 1600°C, to provide enough superheat for tapping the molten iron product:"

Jan 1, 2011

By Kiyoshi Shibata

A new assessment model has been proposed for metal production and its recycling system. The model consists of three processes, smelting of ore, cascading and upgrading of metal scrap. The present approach is to assess the total energy consumption of the system, by introducing two equations for describing the relationships between critical impurity content and the mass of production or scrap recycling. The total energy consumption in the system can be described as a function of recycling rate and performance of the upgrading process. The present model suggests that the impurity removal efficiency and yield in the upgrading process are essential to reduce the energy consumption in the systems. Especially, such points should be explicitly controlled in recycling of aluminum. The potential capability of this model was also discussed by obtaining several quantitative information required for the process design and the operational control of beneficial recycling of metals.

Jan 1, 1998

By Heinz Böni, Christian Ludwig, Bernhard Steubing, Uca Silva

"Chile will soon have to find solutions for dealing with rapidly growing quantities of Waste Electrical and Electronic Equipment (WEEE) due to its strong economy and fast increase of internet and communications technology usage. To support this process, the state of the Chilean recycling infrastructure as well as government, industry and consumer efforts to deal with ewaste were analyzed. Current e-waste quantities were assessed and future flows were predicted using a material flow analysis model. In this model computer hardware was used as tracer equipment for WEEE. Best available numbers indicate that today’s formal recycling infrastructure receives less than 3% of the annual quantities of computer waste. This study represents the most comprehensive analysis regarding e-waste in Chile, identifying relevant streams of e-waste and providing a basis for authorities and producers of electronic goods in order to take the necessary actions to establish an adequate recycling system.IntroductionSince 1991, Chile has experienced a period of strong economic growth. It is amongst the countries with the fastest development in the sector of Information and Communication Technologies (ICT) in Latin America and the number of people with access to ICT has been growing rapidly. The high growth rates of the computer market over the last years are representative for the ICT sector with the consequence that the generated quantities of electronic waste are increasing rapidly [1, 2].Waste Electrical and Electronic Equipment (WEEE) or e-waste is “any appliance using an electric power supply that has reached its end-of-life” as defined by the OECD [3]. Even though the overall waste management in Chile has improved much over the last decade, the issue of ewaste was hardly addressed. Due to the value of the materials contained in computer waste - such as precious metals, basic metals as copper or plastics - it may be assumed that an important quantity is already being recovered. This usually takes place on the informal market under questionable conditions for human health and the environment [1, 2, 4]."

Jan 1, 2008

By Huanmei Yuan, Yuanyuan Wang, Hao Bai

Composite phase change materials are widely used in energy-saving and energy efficient process. Nano-encapsulated phase change materials are especially significant for making advanced working fluid applicable to waste heat recovery or storage. In this study, silica-coated stearic acid (SA) Nano composite phase change materials were prepared from tetraethyl orthosilicate (TEOS) and stearic acid (SA) via sol-gel process. The materials were investigated by Field emission scanning electron microscopy (FE-SEM), Transmission electron microscope (TEM), Fourier transform infrared spectroscopy(FT-IR) and Differential scanning calorimeter (DSC).The FE-SEM and TEM results show that monodisperse microspheres with stable core– shell structure were formed and SA was encapsulated in the silicon dioxide shell. The FT-IR results show that there were no chemical reaction between silicon dioxide and SA, which is the chemical property of the composite material, is stable. The DSC results show that the composite phase change material has favorable heat capacity.

Jan 1, 2016

By Kenneth P. Michalek, James E. Kelly, Jonathan A. Dantzig

"Many investigations have been reported regarding the simulation of continuous casting with emphasis on in-mold heat transfer. These analyses have been limited, however, because they require either estimation or measurement of the characteristic heat transfer between the ingot and the mold. In this paper, a self-consistent model 'is presented for calculating the heat transfer between a solidifying continuous casting and the mold, in the context of the continuous casting of steel. Using both thermal and stress analyses, the air gap formed during continuous casting is calculated and used to compute the heat transfer coefficients. Iteration between the thermal and stress analyses is used to determine a self-consistent solution. IntroductionThe continuous casting process for steel is illustrated schematically in Fig. 1. Molten steel is tapped into a tundish from which it flows at a controlled rate into the continuous casting mold. The initial shell of the casting forms in the mold by transfer of heat from the metal through the mold wall to the cooling water. The remainder of the casting is solidified by application of water sprays, and/or radiation cooling below the mold.Heat transfer in the mold portion of the process is important because it controls the formation of various defects which are deleterious to subsequent processing. Examples of defects formed in this region are surface irregularities, such as cold folding and oscillation marks, and more serious defects, such as longitudinal or transverse cracks. A more catastrophic problem which may occur is a breakout, in which the shell ruptures and molten steel is discharged in an uncontrolled way."

Jan 1, 1986

By Ryosuke O. Suzuki

A combined process of electrolysis of CaO in the molten CaCl2 and of calciothermic reduction, so-called OS process, was applied to prepare metallic vanadium directly from V2O3. The fine metallic powder containing 1860 mass ppm oxygen was obtained using 0.5mol%CaO-CaCl2 melt for 10.8 ks at 1173 K. The oxygen level did not decrease further even when twice electricity was applied. Because the metallic vanadium could be electrochemically deoxidized to the level of 10 ppm oxygen from 1.48 %, the large amount of by-product, CaO, due to reduction and the large surface area of the fine particles are the reasons of high oxygen content in the reduced powder.

Jan 1, 2006