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By M. Royle, A. Bloem, R. Uken

Rock mass damage induced by mining increases the fracture frequency and joint aperture width in the pit walls and rock mass behind open pit mine slopes. The depth and intensity of this mechanical damage relative to the pre-mining state is not well understood and yet is a major factor in the development of slope stability models and operational guidelines. The induced damage can be partitioned into domains or zones. The blast damage zone is essentially a ‘free flow’ rock mass volume, which transitions quite rapidly into the excavation damage zone, which extends beyond that. In both zones, transient high in situ water pressures are often linked to unstable slope conditions. Whereas rock damage can enhance passive depressurisation in the rock mass, high infiltration rates on the other hand, as one could expect during rainstorm events, will decrease slope stability within the dilated pit rock mass, especially in the blast damage zone-excavation damage zone, by increasing pore pressures for short periods of time. Ice jacking and freshet are additional factors to consider in (sub) arctic environments and can be exacerbated by unfavorable rock fabric orientation. On a local scale, brittle deformation damage zones, in the form of faults, can contribute to slope instability, or enhanced stability because of slope depressurisation, depending on their location and orientation relative to the pit shape and the water sources. In this study, the shapes of the damage zones and their anticipated impact on infiltration and/or passive depressurisation are considered for different pit morphologies, rock mass conditions, in situ stress, and hydrogeological settings. Some unusual hydrological situations, like mining towards rivers and lakes and the potential effects on pore pressures, are also considered. This investigation has resulted in the development of a method to adjust initial hydraulic conductivity values used to estimate transient pore pressure conditions found in rock masses exposed in different pit morphologies and stress regimes as well as discontinuities’ orientation relative to open faces within the open pit mine. The changes in K values and pore pressures can then be used to determine hydrogeological influence more accurately on future pit slope stability.

Sep 1, 2025

By R. A. Snodgrass

Heap leaching is a topic that is gradually generating more interest in South Africa as more non-Witwatersrand gold deposits are being investigated. This was evident from the number of delegates (85) who supported the SAIMM School on Heap Leaching, which was held at Mintek from 29th February to 3rd March, 1988.

Jan 1, 1988

By D. Borman

The location of underground positions in mines has usually fallen to their survey department's. Their usual tasks include: ? installation of a high-precision peg network like the National Survey grid as beacons ? offset measurements to the sidewalls, and sometimes hangingwall and footwalls, of development tunnels and excavations ? offsetting of stoping panels for the calculation of face ? advance and the square meterage of area removed. Other departments build their observations into the plans produced by the surveyors. If more precision is required, they ask the surveyors to `elevate' their points with a theodolite. Apart from the survey peg network and `elevations' these measurements are usually planer measurements suitable for producing plans, sections and projection sheets. When the only representation medium was a sheet of paper or transparency, this was perfectly suitable. However the development of CAD models of the workings has changed all this. Full 3D representation is not properly catered for in the tool sets in current use, and needless hours are spent converting analogue-type observations into digital form. The basic survey models need to be augmented by the observations of other disciplines that are also required to locate positions underground. These include: ? the need for geologists to plott their mapping and ? borehole logs into 3D space ? the need for samplers to position their sample points accurately because the geostatistical models are biased and inaccurate ? the need for stoping width recorders to position their thickness observations to prevent errant evaluation and bonuses ? the need for rock engineers to place their mappings into 3D to build true geotechnical models to manage geotechnical stresses ? the need for production officials to receive updated face ? positions during the month so that they can manage the ? production and utilize their resources properly. This paper covers a new method of positioning profiling points to a suitable degree of accuracy. I believe the method is sufficiently simple and cheap for all to use. Historical methods Platinum and gold orebodies, especially in South Africa, are generally narrow tabular deposits. This made them suitable for depicting on a 2D medium like paper. The determination of stoping or face widths was not a problem, as the ore is removed in a single stoping process. Such 2D representations could be easily positioned using tape offsetting between survey pegs or points tied in from survey pegs. Problems of dip were handled by using 'Stope Sheets' which chose a best fit projection for the whole area depicted or by using true dip section sheets for inclined tunnels. Rolling reef and potholes were the common areas of difficulty. Most mines now model their orebody and plan the extraction in computer graphics. This means that the representation of the current workings has to change to support this trend. It now becomes a truly 3D problem. Mining officials find it inconvenient to have their actual workings in single-line depictions while their orebody is depicted with top and bottom contacts and the planned tunnels in 3D shapes. Geological models which form the basis for the resource model and planning process are often out of date, as the updating process is slow. The geological mapping has to be plotted onto sections and plans. These are then digitized into graphics by a draughtsman and checked by the geologist. Only then does the interpretation and model update take place. Potential methods to create 3D 'Actuals' Global positioning systems (GPS) Surface mines have been blessed by the advent of GPS technology. These simple-to-operate pieces of equipment and compatible software make it possible for all types of mine employees to locate themselves, and therefore to locate their observations. GPS are often inexpensive and give an acceptable degree of accuracy. Only in deep pits or close to the highwalls are observations hindered. Such technology cannot however, work underground. Ground penetrating radar (GPR) GPR is reported to be very useful for estimating the positions of potholes and faults. However it is still considered as providing an estimate, not a definite measurement. GPR is good for seeing into solid rock, not into open spaces. Inertia reading devices Experiments with inertia reading devices have been conducted on the mines. They were the forerunners of GPS for military guidance systems, and were even used for city navigation in the early 70s. They do however work best with heavy or fast-spinning gyros. Anglogold Ashanti's attempt to use them were discontinued in the mid-90s when the developers asked for an additional few million rand for a device that would weigh more than 12 kg and have a limited operational life.

Jan 1, 2006

The International Colloquium on Developments in Froth Flotation, which replaced the Annual University of Cape Town (UCT)/University of Stelenbosch (US) Minerals Processing Symposium, was held at the Van Riebeeck Hotel in Gordon's Bay on 3rd and 4th August, 1989. The Colloquium attracted 150 delegates from the mining, metallurgical, and chemical industries, including 9 from overseas.

Jan 1, 1989

By Y. Jiao, V. S. Thompson, D. W. Reed, Y. Fujita, J. E. Aston

Rare earth elements (REE) are vital components in modern electronics and green technology products. Supply is tight and global demand is expected to increase, leading to high risk for the economic and national security of countries largely dependent upon foreign supplies. Recycling of REE from consumer and industrial waste materials is a possible way to help meet demand. We have shown previously that biohydrometallurgy can play an economically and environmentally sustainable role in REE recycling, particularly if agriculture or food wastes are used to produce organic acid bioleaching agents. A challenge for organic acid-based bioleaching is the incomplete conversion of the carbon substrate to an optimal organic acid biolixiviant with high REE extraction capability from a variety of REE-containing feedstocks (e.g., mining wastes, magnets from end of life products, spent batteries, etc.). To help meet this challenge a metabolic model was developed for Gluconobacter oxydans to identify options for improving sugar conversion to organic acids. Model predictions were consistent with laboratory data for the microbial consumption of glucose and production of gluconic acid, and suggested that providing growth conditions with relatively high C:N molar ratios could result in lower pH biolixiviant production and thus improve bioleaching. Keywords: Gluconobacter oxydans, bioleaching, metabolic modelling, rare earth elements summaries 2019: U.S. Geological Survey, 200 p., https://doi.org/10.3133/70202434.

Jan 1, 2020

1. Mining directory The mining directory, 1990. Mines and mining equipment companies worldwide. Don Nelson Publications Limited (P.O. Box 193, Barnet, Herts EN4 BLP, England).2. Mintek reports The following reports are available from Mintek, Private Bag X3015, Randburg, 2125 South Africa. They are available at R25 (plus R3,25 GST) per copy to South African addressees, and US$25 per copy (including airmail postage) to addressees elsewhere. There is also an annual-subscription scheme for reports - R400 locally (plus R52 GST) and US$400 (including airmail postage) abroad. The subscription covers al the unrestricted reports published between 1st April and 31st March of successive years, which usualy amount to between 20 and 30. Report M392 Computer programs for optimization by the modified simplex method, by G.L. Moore. Sep. 1989. 25 pp. R25 + R3,25 GST in South Africa; US $25 elsewhere. Report M393 The preparation and certification of fourteen South African silicate rocks for use as reference materials, by E.J. Ring. Sep. 1989.21 pp. R25 + R3,25 GST in South Africa; US $25 elsewhere. Report M395 The separation of trace elements in high-purity rhodium and iridium materials, by R.V.D. Robet and S.M. Graham. Nov. 1989. 10 pp. R25 + R3,25 GST in South Africa; US $25 elsewhere. 3. Publications from Trans Tech The publications listed in this section are available at the prices given from Trans Tech Publications, P .0. Box 1254, D-3392 Clausthal-Zelerfeld, West Germany. Handling of bulk solids. Theory and practice, by P.A. Shamlou. 1988. 200 pp., US$ 59.50. Acoustic emission lmicroseismic activity in geologic structures and materials, by H.R. Hardy and F.W'. Leighton. Vol. I: 1977, 490 pp., US$45.00. Vol. 11: 1980, 500 pp., US$45.00. Vol. Il: 1983, 680pp., US$6O.00. Vol. IV: 1989, 720pp., US$ 75.00. Open pit mine design models. An introduction with FORTRANI77 programs, by E. Alaphia Wright. Early 1990, approx. 200pp., US$75.00. Bucket wheel excavator, by W. Durst and W. Vogt. 988, 450pp., US$118.00. Continuois-surjace mining, by T.S. Golosinski and F.G. Boehm (eds.). 1987, 720pp., US$128.00. Mining-science and technology. 1987, 1430pages, US$ 118.00. Practical handbook for underground rock mechanics, by T.R. Stacey and C.H. Page. 1986, 150pp., US$ 38.00. Professional users handbook for rock bolting, by B. Stilborg. 1986, 150pp., US$38.00. The lighting of underground mines, by D.A. Troter. 1982, 220pp., US$48.00. Elements of hydraulic coal mine design, by M.L. Jeremic. 1982, 16Opp., US$38.00. Continuum theory of rock mechanics, by Cs. Assonyi and R. Richter. 1979, 365 pp., US$ 58.00. Shear and bond in reinforced concrete, by G. Florin.1980, 86 pp., US$ 24.00. Theory and design of surface structures: slabs and plates, by G. Florin. 1980, 222 pp., US$ 24.00. Mineral processing laboratory manual, by A.-Z. Abouzeid. January 1990, approx. 200pp., US$48.00. Weighing and proportioning of bulk solids, by Hendrik Colijn. 2nd ed. 1983, 4OOpp., US$60.00. Solid-liquid flow. Slurry pipeline transportation, E.J. Wasp et al. 1977, 240pp. US$ 58.00. Optimum pipe size selection, by C.B. Nolte. 1978, 304 pp., US$ 60.00.Field instrumentation in geotechnical engineering, T.H. Hanna. 1985, 854pp., US$98.00. The 1990 yearbook and directory. Powder and bulk solids handling and processing. 1989/90, approx. 300 pp., US$ 124.00.

Jan 1, 1990

By J. H. van Laar, L. J. van der Walt, P. L. Crouse, H. Bissett, G. J. Puts

"SynopsisSilicon carbide nanopowders were produced using a microwave-induced plasma process operating at 15 kPa absolute and at atmospheric pressure. Methyltrichlorosilane (MTS) served as precursor, due to its advantageous stoichiometric silicon-to-carbon ratio of unity, allowing it to act as both carbon and silicon source. Argon served as carrier gas, and an additional hydrogen feed helped ensure a fully reducing reaction environment. The parameters under investigation were the H2:MTS molar ratio and the total enthalpy. The particle size distribution ranged from 20 nm upwards, as determined by SEM and TEM micrographs. It was found that an increase in enthalpy and a higher H2:MTS ratio resulted in smaller SiC particle sizes. The adhesion of particles was a common occurrence during the process, resulting in larger agglomerate sizes. SiC layers were deposited at 15 kPa with thicknesses ranging from 5.8 to 15 µm.IntroductionIt is well known that methyltrichlorosilane (CH3SiCl3 or MTS) decomposes to form silicon carbide (SiC) and hydrogen chloride (HCl) as shown in Equation [1]. The reaction kinetics and mechanisms for this reaction are thoroughly reported in the literature (Sone et al., 2000; Papasouliotis and Sotirchos, 1999; Kaneko et al., 2002; Wang et al., 2011)."

Jan 1, 2015

By P. S. Piper

In the 1960s it was suggested that the volume of stope convergence, and hence the rockburst hazard, could be reduced by the emplacement of backfill. Recent advances have facilitated the placement of large quantities of backfill underground, and a reassessment of its potential benefits as part of a regional support strategy is now timely. In this paper the principal criteria of effectiveness of backfill are taken to be its impact on face energy release rate (ERR) and average pillar stress (APS) levels, and maximization of acceptable ore extraction ratios. The possible effects of backfill on excess shear stresses (thought to modulate large seismic events) are also briefly reviewed. Analytic solutions describing backfill properties and their impact on ERR and APS in certain idealized geometries are also presented, and compared with the results of an extensive suite of computer simulations, in which parameter sensitivities are explored. Results indicate that a regional support strategy is required at depths exceeding 2 km in order to maintain acceptable levels of ERR, and backfill ribs can on their own fulfil this role at depths less than 3,3 km. At greater depths use of stabilizing pillars becomes imperative, but here too supplementary backfill ribs can reduce ERR and APS levels and permit significant increases in ore extraction ratios.

Jan 1, 1988

By A.M. Edwards

1. Book reviews Platinum in South Africa, compiled by A.M. Edwards and M.H. Silk. Randburg, Council for Mineral Technology (Private Bag X3015, Randburg, 2125 South Africa), 1987. 55 pp. U$30. Reviewer: R.D. Wintle Scientific and technological developments in extractive metalurgy-G.K. Wiliams Memorial Volume. Parkvile (Australia), The Australasian Institute of Mining and Metalurgy, 1986. $A12 (incl. surface postage). Reviewer: T.Y. OweD Ion exchange and sorption processes in hydrometa/urgy, edited by M. Streat and D. Naden. Chichester, John Wiley & Sons, 1987. 229 pp. Reviewer: B.R. Green Role of Government in mineral resources development, edited by Michael J. J ones. London, The Institution of Mining and Metalurgy, 1985. 180 pp. £40. Reviewer: K.E. Ducat 2. Recent publications Annual report 1987. International Tin Research Institute, Kingston Lane, Oxbridge, Middlesex UB8 3PJ, England, 1988.Tin and its uses no. 156. Address as above. 3. Mintek reports Application Report no. 5 The production of and alusite and other refractory minerals. 1988. 16 pp. . Application Report no. 6 The development up to commercial application of a process for the recovery of lead, copper, zinc, and silver from the Black Mountain deposit. 1988. 14 pp.

Jan 1, 1988

1. Book review Assay and analytical practice in the South African mining industry, byW.C. Lenahan and R. de L. Muray- Smith. Johannesburg, The South African Institute of Mining and Metalurgy, 1986. RlOO (R80 to Members). Reviewer: N.G. Randolph 2. Canadian publications A market profile for industrial minerals in Canadian manufacturing sectors, by M. Prud'homme and D. Francis. 1987. Micromedia Limited (144 Front Street, Toronto, M5J 1G2, Canada).The following three publications are available from the Centre for Resource Studies, Queen's University, Kingston, Ontario, Canada K7L 3N6. An analysis of Japanese coking coal procurement policies: The Canadian and Australian experience, by D.L. Anderson. Feb. 1987. $25. Technology policies in the Canadian mineral industry, edited by M.J. Wojciechowski. Sep. 1986. $20.Value-added taxation: Issues and impact for Canadian mines, by B.l. Dyack. Nov. 1986. $7.3. Mintek reports Report M295 A mineralogical investigation of refractory gold ores and their beneficiation, by P.M. Swash. Report M296 The determination, by distilation-spectrophotometry, of chlorine in apatite-type materials containing fluorine, by M. Solomons. Report M297 The interference of zirconium in atomic-emission spectroscopy using inductively coupled plasma, by P.l. Wright.

Jan 1, 1987

Edward J. Stephenson. Extractive metallurgy. Recent advances. Park Ridge (New Jersey), Noyes Data Corporation. James L. McCall and P. M. French (eds.). Interpretive techniques for microstructural analysis. 1977. Institution of Mining and Metallurgy. Prospecting in areas of glaciated terrain. London, the Institution, 1977. £16 ($D.S. 30). NIM reports Report no. 1928 A liquid-nitrogen monitor for lithium-drifted germanium detectors. (21st Nov., 1977). Report no. 1931 The equilibrium between the slag and the metal in the production of low-carbon ferromanganese. (14th Nov., 1977). Report no. 1934 The spectrometric analysis of chromium-bearing materials with particular reference to ferrochromium slags and chromite ores. (30th Nov., 1977). Report no. 1935 The construction and testing of a small mixer-settler for use in the laboratory. (30th Nov., 1977). Report no. 1933 The determination of trace elements by thin-film X-rayfluorescence spectrometry, and its application to zirconium. (30th Nov. 1977). Report no. 1942 The accuracy of assays for platinum -group metals and gold. (30th Nov., 1977). Courses on geostatistics In view of the continuing demand, the University of Leeds will offer two further courses on geostatistics in 1978, each covering ten working days (3rd to 14th April, and 3rd to 14th July).

Jan 1, 1978

By Z-B. Cheng, X-J. Liu

"Intensive mining of shallow coal seams tends to result in severe subsidence of the ground surface. Surface subsidence is a complex dynamic spatiotemporal process that constantly changes as mining advances. With Liangshuijing coal mine as a case study, 3DEC numerical software was used to simulate the development of the moving subsidence field from open-off cut to full subsidence on the working face. The results demonstrate that the formation of a subsidence field is directly related to the coal seam depth H and the extent of the mine workings. Taking the advance distance of the working face as the unit of scale, the process of surface subsidence can be divided into four stages: micro-change (H/ p), the development of surface subsidence (2H/ p), the formation of a movement subsidence field (3H/ p), and dynamic balance (4H/ p). The changing movement of a subsidence field can be fully described by the characteristics of surface subsidence value, curve slope, and the inflection position. The results provide important technical support for predicting surface subsidence and the temporal–spatial evolution features of mining subsidence. IntroductionChina’s coal output was about 3.52 Gt in 2017 (China National Coal Association, 2018), making it the largest coal producer in the world, accounting for almost half of total world coal production. Coal production and distribution play a vital role in the energy industry of China. However, entire overlying strata, from coal seam to surface, are disturbed as a result of long-term, high-intensity and large-scale mining, causing surface subsidence. This results in groundwater loss, surface desertification, vegetation loss, and mud-rock flows. These issues have become topics of common concern throughout society. According to related research results (Liu 2008), the area of surface subsidence caused by coal mining in China has reached about 600 000 ha, some 0.2 ha (and up to 0.42 ha) of surface subsidence for every 10 000 t of coal produced. Surface subsidence disasters not only damage buildings, water conservancy, transportation infrastructure, and farmland, but also cause adverse effects on individual and community lifestyles, environmental hygiene, and economic development. Deterioration of the ecological environment in mining areas has a long history and is very harmful (Lu, 2015)."

Feb 1, 2019

By C. Klutke

This paper outlines a simple methodology for mineral characterization, developed as part of the Australian Mineral Industry Research Association (AMIRA) managed research project P777 ?The Development of Heavy Suspension Techniques for High Density Separations (Replacement of Clerici?s Solution)?. The project was sponsored by De Beers, Rio Tinto and Iluka Resources. Heavy mineral characterization of samples arising from exploration, mining or metallurgical processes is frequently conducted using laboratory heavy liquid analysis. Unfortunately, there are only a limited number of high density (?heavy?) liquids and these tend to be more toxic as their density increases. Low-toxicity inorganic solutions, based on tungsten compounds, have been developed that can be utilized at relative densities (RD) up to 3.0. Beyond this value organic liquids can be used; however, this presents significant health and safety hazards. Diiodomethane (methylene iodide) having a relative density of 3.31 is commonly used. Mixtures of thallium formate and thallium malonate were found in the early 1900s by Clerici to provide liquids having specific gravities between 4.0 and 5.0. For the characterization of the heavy components of mineral sand deposits (e.g. anatase RD 3.9, rutile RD 4.2, ilmenite RD 4.4?4.7 and zircon RD4.6?4.8) there is currently no heavy liquid alternative to Clerici?s solution. Clerici?s solution is highly toxic and testing is now conducted by few laboratories worldwide, with costs reflecting the chemical costs, infrastructure costs and health and safety regimes (e.g. blood testing of exposed staff). A simple laboratory technique of density fractionation has been developed, employing suspensions of fine tungsten carbide particles in lithium heteropolytungstates solutions, that can replace Clerici?s solution in the evaluation of fine mineral sands samples (e.g. -250 +150microns). The developing methodology that can achieve low-cost, low-toxic separations at relative densities above 4.0 is outlined and the comparison of results with Clerici?s solution presented. In addition, preliminary work on density fractionation of zircon samples is presented. Zircon fractionation relates to their inclusion, radionuclide content and metamictization.

Jan 1, 2007

This paper details the preliminary design work carried out before and during the implementation of an extensive backfilling programme on Cooke 3 Shaft, Randfontein Estates Gold Mining Company (Witwatersrand) Limited. The design work is of relevance to any system utilizing a cementitious binder, and the quality control aspects are of particular significance. Problems associated with correlating laboratory results to actual field results are also briefly discussed.

Jan 1, 1988

By A. C. Wingrove

The paper outlines the selection of a dewatered tailings backfill system for the Johannesburg Consolidated Investment Gold Division, and covers the following aspects: (i) 16 Shaft pilot testwork; (ii) engineering design problems relating to the Cooke 3 Shaft backfill operation; (iii) in-line mixing - applications with respect to the Randfontein Estates Gold Mine and Western Areas Gold Mine backfill operations; and (iv) pipeline friction losses.

Jan 1, 1988

By A. P. Cook

Gas samples were taken from a wide range of target areas on dumps arising from coal mining activities. Some of the dumps had largely burned out, some were still burning, some were in the process of rehabilitation, and on others rehabilitation was essentially complete. It was found that rehabilitation was very effective in reducing emissions to tolerable levels. Even incomplete rehabilitation reduced the CO2 emissions to less than about 1 kg/m2/a, whereas some unrehabilitated areas showed emissions of over 100 kg/m2/a. Some areas where there was active combustion taking place were also sampled, and they showed as much as 7 000 kg/m2/a, but the areas concerned were very small and their total contribution accordingly low. Analyses were also made for SOx, NOx, NH3, and CH4, but these were generally (and unexpectedly) at very low levels. The mines sampled represented 53 per cent of all surface coal mining activity. Accordingly the estimated total emissions were scaled up, to arrive at estimates of 1950 000 ± 350 000 t/a C02, 2040 ± 580 t/a SOx, 306 ± 85t/a NOx, and 31 ± 9 t/a NH3 for all surface mines. Methane was detected only from burning coal, and due to the difficulty in sampling, no reliable estimate could be made of these methane emissions.

Jan 1, 2012

By K. G. Tshilombo

It should be possible to use an oxygen probe to follow iron removal during converting, if local equilibrium is established between iron in the matte and the iron oxides in the fayalitic slag. The oxygen activity is expected to increase strongly as the iron content of the matte decreases (and the iron activity in the matte drops) while the iron oxide activity in the slag remains constant. To test this idea, oxygen activities were measured in synthetic mattes (made up of mixture of Cu2S, FeS and Ni3S2) when in contact with silica saturated SiO2-FeO slags, and silica and (initially) magnetite saturated SiO2-FeO-Fe3O4slags. The measurements were performed on laboratory scale at 1250°C, using an oxygen probe consisting of a stabilized zirconia electrolyte and Fe/FeO reference, and containing the sample in a silica crucible. Electrical contact to the matte was by means of a platinum wire. The measured oxygen activity was sensitive to the iron content of the matte, and insensitive to the composition of the gas atmosphere over the melt. The measured oxygen activity was generally close to that predicted by Fact Sage calculations. This indicates that such oxygen activity measurements could be useful to monitor iron removal during converting of nickel-copper-iron mattes.

Jan 1, 2006

By J. E. Furze

World-wide hikes in the oil price and the prospect of future scar cities of liquid and gaseous fuels have given enhanced status to the South African coal industry. It is thus understandable that the colloquium held at Wit bank on 3rd and 4th October, 1979, and organized jointly by the South African Institute of Mining and Metallurgy and the South African Coal Processing Society should have attracted more than 400 delegates.

Jan 1, 1979

By F. Pinto, J. V. Lemos, A. Sousa, L. Ribeiro e Sousa

The Rossio railway tunnel was built in 1890 crossing several formations involving limestones, basalts and also sandy and clayey formations. Due to the fact that it is an old underground structure rehabilitation and repair works were performed, namely at Km 0,900 and in a zone crossed by a new tunnel from the Lisbon Metro. Reinforcement support systems were designed in the Rossio tunnel in order to prevent its stability. In this paper, repair works and anchor tests performed at km 0,900 are presented, as well as the monitoring system implemented in order to observe the structural effects induced by the construction of the works. For the interpretation of the obtained information complex 3D models was built, permitting the simulation of the sequential excavation scheme used, non-linear behaviour of the different formations, and the support systems used. Der 1890 erbaute Rossio Eisenbahntunnel durchoertert mehrere Formationen, einschliesslich einer Kalkstein-, Basalt- sowie einer sandigen und tonigen Formation. Auf Grund des Alters des unterirdischen Bauwerks wurden Instandsetzungs- und Reparaturarbeiten im Bereich km 0,900 sowie im Kreuzungsbereich mit einem neuen Tunnel der Lissabonner U-Bahn durchgeführt. Aussteifungssysteme wurden entworfen, um die Stabilität des Rossio Tunnels zu gewährleisten. Im Folgenden werden die Instandsetzungsarbeiten und Anker Tests im Bereich km 0,900 sowie das Messystem zur Ueberwachung der strukturellen Auswirkungen der Bauarbeiten dargestellt. Zur Interpretation der gewonnenen Informationen wurden komplexe 3D Modelle entwickelt, die eine Simulation des Bauablaufs und die Anwendung nichtlinearer Stoffgesetze fuer die verschiedenen Formationen und Aussteifungssysteme ermöglichten. Le Tunnel ferroviaire du Rossio a été construit en 1890, traversant des différents terrains comme des calcaires, des basaltes et aussi des formations limoneuses et sableuses. Dû à l’ancienneté de l’ouvrage, des travaux de réhabilitation et réparation ont été faits, nomment au km 0,900 et dans la zone traversée par le nouveau tunnel du Metro de Lisbonne. Des systèmes de support renforcé ont été conçus pour le Tunnel du Rossio de façon à rassurer sa stabilité. Dans ce papier, on présente les travaux de réparation et les essais d’ancrage réalisés au km 0,900, et aussi, le système d’auscultation mise au point pour l’observation des effets structuraux induits par les travaux. De façon à interpréter l’information résultant de l’observation, des modèles 3D complexes ont été utilisés, permettant la simulation de la méthode séquentielle de l’excavation, du comportement non - linéaire du terrain et, aussi les systèmes de support utilisés.

Jan 1, 2003

By W. Bleloch

Published in the Journal, September 1970, and presented at a colloquium on 'Future of the Steel Industry', 17th March, 1971. Errata (a) The final sentence in the penultimate paragraph, left hand column p. 34 of the text should read: 'In the hot regions of the bosh and stack the C+CO2=2CO reaction proceeds to CO from coke carbon and carbon dioxide generated by reduction of iron oxides by CO (the so-called solution loss of carbon)'. The italicised words have been omitted in the text. (b) Temperature in Fig. 3 is K not C. (c) In Fig. 9, connection from top plate of column 10 to heat exchanger 9 has been omitted. DISCUSSION J. B. BEEDON AND C. J. JONKER* Dr Bleloch's paper has outlined the advantages of recycling stack-gas of low nitrogen content in the blast furnace. In the first instance it would appear to be extremely beneficial in controlling the hearth temperature and allowing a 100 per cent oxygen-blast to be used. On a second point however we have to disagree. It is claimed that heat is liberated in the combustion zones by the oxidation of CO to CO2 near the tuyeres and in the subsequent reduction of the CO2 by CO. The author has hypothesized as follows, and we quote: 'The C+CO2=2 CO reaction in the outer combustion zone at about 1 700°C is no longer endothermic due to loss of stability of CO2 and its consequent dissociation into CO and free oxygen.' This statement requires closer examination. If we consider the individual events occurring with the CO in the recycled topgas, with the oxygen in the blast and with the coke in the burden, as done by Dr Bleloch, the following heat considerations emerge. All heats of reaction are calculated from the enthalpy values of each reactant and product, as well as the temperature dependence of their molar heat capacities. (a) At the tuyeres: CO+1/2 O2-+CO2 . . . . . (1) CO, CO2 at 500°C; O2 at 25°C. ?H reaction = -65 000 cals/mole CO The reaction (1) is exothermic. (b) In the outer combustion zone: CO2+C?2 CO . . . . . . . . (2) C, CO at 1 700°C; CO2 at 500 0C. ?H reaction = -56 000 cals/mole CO Reaction (2) is endothermic. The overall heat gain of reactions (1) and (2) is ?H=+56 000 - 65 000= -9000 cals/mole CO i.e. the overall reaction is slightly exothermic, the amount of heat liberated is however smaller than suggested by Dr Bleloch. (c) The dissociation CO2+CO+1/2 O2 . . . . . (3) is a highly endothermic reaction at 1 700 0C, requiring 82 000 cals/mole CO2 to proceed to completion. Furthermore, this reaction (3) is energetically not favoured to proceed, as can be observed from the free energy-temperature relationship of figure (3), which favours the formation of CO2 at 1 700 0C. Hence direct dissociation of CO2 at 1 700 0C appears to be unlikely.* The concept of recycling topgas is however still intriguing from many other points of view. Apart from providing a very efficient method of hearth temperature control, it will create a much higher CO partial pressure in the stack. Whether the rate of indirect reduction in the stack will be proportional to this partial pressure or not is un-

Jan 9, 1970