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By K. P. V. Lei

The Bureau of Mines as part of its research effort to minimize the generation of hydrometallurgical waste, investigated a sodium sulfide leaching-electrolysis procedure for treating hydrometallurgical residues for elemental sulfur and base-metals recovery. Research was conducted on a leaching residue from a lead concentrate. The following procedure was developed. 1. The elemental sulfur was dissolved as polysulfide with an Na2S solution. 2. The resultant metal sulfide bearing residue was oxidatively acid leached in a cationic membrane electrolysis cell; the metals were solu¬bilized at the anode, and a base was generated at the cathode. 3. The elemental sulfur was recovered from the polysulfide solution by neutralizing with the acid in the anolyte. Byproducts of the neutralization were H2S and a sodium salt solution. 4. Sodium sulfide was regenerated by reacting the H2S byproduct with the base in the catholyte. 5. Lead as PbCL2 was recovered from the anode residue by brine leaching, and the other metals were recovered from the sodium salt solution as metal sulfides. 6. The barren filtrate from the metal sulfide precipitation constituted the recycled electrolyte. Ninety-eight percent of the elemental sulfur, 98 pct of the lead, and up to 80 pct of other accessory metals were recovered from a residue obtained from the FeCl3-NaCl leaching of a lead concentrate.

Jan 1, 1982

By John C. Machisak

Injury data and experience, with related employment statistics, at coal mines in the United States for 1959 are presented in this publication under the following general sections: (A) General injury experience: Tables 1 to 6: Current data on number of injuries degree of injury, frequency and severity rates, average severity, and related employment and production data by work location. (B) Selected injury experience: Tables 7 to 38: Current data on principal agencies of injuries, distribution of injuries by part of body injured, days of disability, extent of hand and machine loading, experience by employment and production groups, and various other operating factors and physical conditions related to the occurrence of injuries at the Nation's coal mines.

Jan 1, 1961

By N. S. Dalal, Xianglin Shi

"INTRODUCTIONEpidemiologic studies of workers in chromate-ore related industries, 1-3 and stainless steel welding and related occupations4 have shown that they have about 20-40 times higher risk of throat or respiratory track cancer than controls. Although the actual carcinogenic substances were not identified in these statistical studies, Cr(VI) compounds (for example, calcium chromate, zinc chromate, and lead chromate) were implicated as the causative agents, whereas Cr(III) compounds were not suspected as carcinogens. s These suggestions were supporte4 by laboratory studies wherein many Cr(VI) compounds produced sarcomas at the implant or injection sites.1,5 Squamous cell carcinomas and adenocarcinomas closely resembling human lung cancer were induced by intrabronchial implants of calcium chromate in rats, 6·7 whereas Cr(DI) oxide and Cr(lll) sulfate did not induce any tumor formation.6,7While the mechanism of the chromate-induced carcinogenicity is not fully understood, it is generally thought8 that it involves some damage to DNA. Specifically, it has been reported that: a) the chromate ion, henceforth referred to as chromate, can pass through the cell membrane and enter the cell while CR(DI) does not, 9 b) chromate does not interact with either native or denatured DNA 10 while Cr(III) does, 11 and c) the final Cr-DNA complex isolated from cellular reactions of chromate is Cr(III)-DNA, with Cr(III) binding to the phosphate groups.12,13 Thus the important question is: since Cr(DI) cannot pass through the membranes, how does Cr(III)-DNA complex form? For this to happen, Cr(VI) must be reduced to its lower oxidation states, 14 ultimately to Cr(III), by some reductants in the cellular environment. Unless this reduction occurs, the DNA would not be damaged and therefore no chromate carcinogenicity would ensue. Thus the reduction of chromate to its lower oxidation states seems to be a key step in the chromate carcinogenicity .1s One of the major reductants in cellular environments is thought to be glutathione (GSH), both outside and inside the cells.16-lB Some evidence for the role of GSH in the chromate toxicity was provided by recent studies showing that exposure of hamster cells to non-toxic levels of added selemite increases the levels of GSH as well as the Cr(VI)-induced DNA strand breaks,19 and that such DNA strand breaks in hepatocytes also change in direct proportion to the GSH content. 20,21 These observations were interpreted as implying that the reduction of chromate by GSH to some reactive intennediate is an important step in the chromate carcinogenicity. 20.21 In · the present undenaking22 we have used electron spin resonance (ESR) and spin-trap methodology to investigate the reduction of chromate by GSH and find evidence for the involvement of the glutathionyl radical (GS ·) as well as Cr(V)-intermediates."

Jan 1, 1990

By D. Harrington

While apparently the hysteria with regard to silicosis and other occupational diseases has largely subsided and this subject is being more carefully considered and soberly judged, it would be poor policy for any employer to maintain that the storm has ended and that he can relax and revert to conditions as they were 5, 10, or more years ago. The fact is that the plan of paying occupational-disease compensation is now in its infancy and can be expected to grow rapidly. At present, while all of the States of the Union, including the District of Columbia and excepting only Arkansas and Mississippi, have compensation acts, only the following make provision for occupational diseases to some extent or in one way or another: California, Delaware, Connecticut, District of Columbia? Illinois, Indiana, Kentucky, Massachusetts, Michigan, Minnesota, Missouri, Nebraska, New Jersey, New York, North Carolina, North Dakota, Ohio, Pennsylvania, Rhode Island, Washington, West Virginia, and Wisconsin. Silicosis is compensable in one way or another in California, Connecticut, District of Columbia, Illinois, Kentucky, Massachusetts, Missouri, New York, North Carolina, North Dakota, Ohio, Pennsylvania, West Virginia, and Wisconsin, and possibly in other States. During the past few months, occupational-disease legislation (largely silicosis) has been considered in some form in Arkansas, California, Delaware, Idaho, Maryland, Kansas, Massachusetts, Michigan, Minnesota, Montana, Nebraska, New Jersey, Ohio, Pennsylvania, Tennessee, Utah and Washington. It will be surprising if comparatively comprehensive occupational-disease legislation is not on the statute books of nearly every State in the Union within the next 5 years. With this situation confronting him, the farsighted industrialist who has the interest of his organization at heart, if he has not already done so will immediately start to "put his house in order" by studying possible occupational disease hazards to his employees and promptly applying known remedial measures or attempting to devise such measures if none exist. Unquestionably, one of the most important of the surveys to be made relates to dust occurrence, as State laws on occupational disease are almost certain to contain provisions, on silicosis and, with almost equal certainty, the provisions of any State law are not likely to be particularly similar to those of other States.

Jan 1, 1938

By Reinhardt Thiessen

This paper presents only the highlights of previous research on the paleobotany of coal. The accumulated material has become so vast that a comprehensive review of all findings relating to paleobotany would be far too long. The fact that coal is derived from plants is now so well-known that no further comment is required, but knowledge of the mode of transformation of plant substances into coal is not so general. The plant matter goes first through processes of semirottins-, maceration, and elimination of certain material to form peat, which is then further transformed into coal. The first stage has been termed the "biochemical process," because the more important changes take place under the influence of micro-organisms. Near the end of the biochemical action an unconsolidated peat is formed. The second or "dynamochemical process," caused by the addition of superincumbent rock strata such as sandstones and shales and application of additional pressure and possibly heat through mountain-building forces, results in the formation of higher-rank coals ranging from brown coal to anthracite. These stages in trans-formation of plant material to coal have been described in previous reports.4 The main object of this paper is to bring to the notice of paleobotanists the fact that coal contains an enormous amount of material in a remarkably good state of preservation. Although some of the coal-forming matter has lost its identity, much of the original structure is retained. A large proportion of the coal, therefore, particularly of common bright coals, comprises constituents or components that invariably have retained some of the original plant structure, and many of these structures may be assigned to certain plants. The identity of these plants and of the remains forms the subject of this paper.

Jan 1, 1941

By Robert H. Ridgway

This paper presents the results of the second in the series of annual canvasses on the consumption of ferrous scrap and pig iron in the United States, inaugurated in 1935 by the Bureau of Mines and published in Report of Investigations 3329. The study was undertaken in response to requests from trade organizations and others for detailed statistics on this phase of the iron and steel industry. Thus, for the first time, producers, buyers, sellers, and consumers of iron and steel scrap have had an accurate statistical picture of this important raw material As originally contemplated, the study was to be continued on an annual basis, but, owing to budgetary limitations for the fiscal year 1937-38, the Bureau may be unable to conduct the canvass for 1937.

Jan 1, 1937

By Donald O. Capstick

A mineral survey of the 520-acre Quigg West Wilderness Study Area (MT-074-155) was conducted by the U.S. Bureau of Mines in 1986 at the request of the U.S. Bureau of Land Management in order to evaluate its identified mineral resources. The Wilderness Study Area is in Granite County in western Montana about 16 miles northwest of Phillipsburg and 27 mi les northeast of Hamilton, MT. Stony Mountain, a study area on lands administered by the U.S. Forest Service, is about 1 mile to the south-southwest and was studied concurrently. No mineral resources were identified in the Quigg West Wilderness Study Area, but high grade gold assays, as much as 1.24 ounce gold per ton, were obtained at the one prospect found. Samples from four workings contained significant gold; minor silver, molybdenum, and copper were also present. The prospect containing the narrow and discontinuous gold-bearing quartz vein straddles the south boundary of the Wilderness Study Area. The shear zone containing the vein projects toward the old Crescent mine, about 4.5 miles to the south, which shows a similar geologic structure.

Jan 1, 1987

By W. W. Graff

This paper describing the mining practice at Mine No. 5 of the Marquette range, Michigan, is one of a series being prepared by the Bureau of Mines on mining practices, methods, tend costs in the various mining districts of the United States. The top-slicing system of mining, has been used ever since the present operating company took control of the property in 1903, the main level and sublevel layout being chanced only as local conditions required and the use of mechanical equipment increased.

Jan 1, 1930

By B. J. Dalton

The Bureau of Mines Helium Research Center has as a long-range objective the development of an equation of state for helium that will allow all of the thermodynamic properties to be calculated within the accuracy with which they are known. If this objective is to be realized, a method of calculation must be known. This report gives the principles of the method we use in such problems. A computer program was developed for predicting these properties, including those at the critical point, that is perfectly general and applicable to any equation of state. To demonstrate the efficacy of our method, this computer program was used to evaluate thermodynamic properties of a Redlich-Kwong fluid in the two-phase region. Expressions for calculating various thermodynamic functions specific for this particular equation of state are derived. Numerical values are tabulated and graphs are presented for all functions calculated. It is shown that for a Redlich-Kwong fluid there are finite discontinuities in (1) the second temperature derivative of the Gibbs free energy or chemical potential at the critical point, (2) the second derivative of the vapor pressure curve with regard to the temperature on passing through the critical point, and (3) the measured heat capacity at constant volume on passing through the critical temperature when the calorimeter is filled to the critical density. It is also shown that the heat of vaporization is infinite for a Redlich-Kwong fluid at absolute zero.

Jan 1, 1969

By Milton H. Fies

The dedication of thin building, establishing a station of the U.S. Bureau of vines at the University of Alabama, bristles with significance and challenges the wisdom and courage of the people of this State. Here is united, in common aim, the Engineering School of our State University, recognized for its competency and usefulness, and the Federal Bureau of Mines. The Bureau is one of the most effective arms of our National Government. It outranks in accomplishment, measured by practical scientific contribution, any like governmental organization in all the other nations. It possesses none of the characteristics of many other bureaus of government which have created popular bias. Here is one Bureau devoid of political suggestion or aim with a personnel zealously devoted to labor in scientific re¬search - an organization marked by practical accomplishment, alleviating many of life's burdens, raking easier life's pathway, and unerringly pointing to life's possibilities.

Jan 1, 1936

By W. G. Pariseau

A U.S. Bureau of Mines case study of pillar recovery in high-grade ore near the Ross shaft at, the Homestake Mine, Lead, SD, has demonstrated the usefulness of the finite-clement method for the evaluation of shaft pillar mining plans and shaft stability. This report, one of three in a series describing the Ross shaft pillar case study, focuses on the premining stability analysis. The two-dimensional computer program UTAH2 was used in advance of pillar mining; results suggested that the shaft would remain stable. Subsequent reports describe parts 2 and 3 of the study. In part 2, borehole extensometers and other instruments were installed to provide data for model verification and shaft monitoring. Results of the recalibrated two-dimensional model confirmed the premining stability evaluation. However, after mining began, great concern developed because of the appearance of cracks and other signs of ground movement over considerable distances from the area of active pillar miping. In part 3, an intense three-dimensional modeling effort using UTAH3 was initiated. The results again showed that the shaft would remain safe. Three-dimensional analyses of alternative pillar mining scenarios indicated that more of the shaft pillar ore reserve could be recovered than previously thought.

Jan 1, 2010

By D. G. Kuehn

Positive ion sampling studies have been conducted on do discharges containing 0.33 percent sulfur dioxide in helium. Measurements were made for normalized gas pressures from 0.45 to 6.8 torr and discharge currents from 5 to 40 ma. Ion species observed included SO+, S+, SO2+, SO3+; O+, and 0+, 02+. Studies were conducted on the functional dependence of the various ion species with respect to axial distance, pressure, current, and gas flow rate. Interpretation of these results is consistent with the assumption of SO2 dissociation. Deposition of sulfur compounds was observed in the plasma container during these studies. The present results are compared with previous studies which have been conducted in SO2.

Jan 1, 1971

By Raja V. Ramani, Robert L. Frantz

"The House/Senate Joint Conference Committee has instructed the Bureau of Mines to have the Advisory Committee on Mining and Mineral Resources Research review on an annual and simultaneous basis each generic mineral technology research center (GMTC). In order to accomplish that review promptly and uniformly, committee members have revised and approved an in-depth questionnaire. That document formed the basis of their review. The information provided by that questionnaire was an important factor in their recommendations concerning the future direction of the program; a presentation was made at the last National Plan Update.The comprehensive nature of the questionnaire and the scope of the information contained therein make it an excellent retrospective of the Center. Having a clear vision of where the Center has been and knowing where it is now will help guide it into the future. It is felt that such a detailed view of the Center's facilities and research program will be of value to Center personnel and Advisory Committee members.Each aspect of the questionnaire has been examined, answered in detail, and documented throughly. With the completed questionnaire as a guide, this volume examines the research program, Center personnel presently active on GMTC projects, number of graduate degrees granted with GMTC support, GMTC publications, degree of individual interaction, technology transfer, the reference center, GMTC equipment and facilities, and any envisioned plans for future research. It is hoped that this volume will serve as a review of the years 1984-1988, the first four years of the Center's operation."

Aug 31, 1989

By W. J. Boone, Will E. DeVaney, Lowell Stroud

This report is the fifth in a series presenting equilibrium vapor - liquid data for helium- bearing natural gases . It covers a 0.41 - mole - percent - helium natural gas that may be processed in the Department of the Interior's longrange helium conservation program . A Bureau of Mines phase equilibrium apparatus was used to obtain 139 samples of equilibrium vapor and liquid phases at 85 experimental conditions at temperatures from 0 ° to -299 ° F and at pressures from 100 to 500 psia . An appendix covers phase data at 100 , 200 , and 300 psia and at temperatures from -125 ° to -275 ° F for the dehydrated gas containing its original concentration ( 0.2 mole - percent ) of carbon dioxide , and the effect of a preliminary hydrocarbon trap upon subsequent vapor - liquid compositions .

Jan 1, 1964

By A. D. Hahn

This report describes and gives the results of an examination by the Federal Bureau of Mines of ilmenite-bearing placer sand deposits in the 24-mile long valley of Otter Creek, Kiowa and Tillman Counties, Okla. Drilling and sampling was completed in three periods between October 1956 and September 1957. Mineralogic studies and mineral-dressing tests on recovery of ilmenite and other heavy minerals from composited samples of the sands were made in Bureau of Mines laboratories at Rolla, Mo., in 1957 and early 1958. Otter Creek rises in and drains the southwestern extremity of the Wichita Mountains, which are represented locally by knolls and ridges of gabbro and granite surrounded by plains floored with flat-lying Permian red beds. The valley fill consists of a basal sand-clay component, derived from weathering of the igneous rocks, and an overlying silt-clay alluvium. Ilmenite is present in significant quantity and recoverable grain size only in the basal sand-clay.

Jan 1, 1960

"For a good many years the Bureau of Mines and various state mining experi¬ment stations have endeavored to develop some method of utilizing the immense deposits of lignite in the United States. Work in relent year has indicated that the best method of this is to drive off the moisture and most of the volatile water from the lignite in some form of carbonizing apparatus leaving a residue high in fixed carbon and low in moisture and volatile matter, which by briquetting can be made into a high-grade fuel. The earlier forms of carbonizing equipment tried were complicated, costly to build and keep in repair, and could not be operated intermittently without being seriously damaged. During the year 1922, however the Bureau of Mines devised a very simple carbonizing oven which produces a uniformly well carbonized product. This oven is essentially a vertical shaft with means for supplying raw lignite at the top and discharging the carbonized limited at the lower end. Air in regulated amount is admitted to the shaft at two horizons, and a zone of combustion maintained through which the column of lignite passes. The lignite is thus carbonized by construction of its contained matter and a small proportion of its fixed carbon, leaving most of the fixed carbon in the carbonized product or ""char"". The degree of carbonization can be closely controlled by varying the volume of air supplied to the oven and the rate of travel of the charre down the shaft.The ""lignite char"" produced is a soft material resembling charcoal more than coal or coke, but somewhat harder than charcoal. A typical analysis is shown in the table headed ""Fuels,"" further on in this papers."

Feb 1, 1924

By Townsend. James W.

"INTRODUCTION As a byproduct of its mineral investigation program, the Bureau of Mines has developed a number of operating devices and techniques worthy of note. This paper, prepared under the direct supervision of Paul T. Allsman, chief, Salt Lake City Division, Branch, and under the general supervision of Lowell B. Moon, chief, Mining Branch, reports upon one such device. A simple device has been developed for measuring angles of deviation from the horizontal as recorded on a glass tube by acid etching. The device has facilities, also, for measuring the angle between the long axis of the ellipse and the north-south reference points established by a Maas compass or from an established axial lamina, on the tube, which was ori¬ented to a specific direction in the hole by rod alinement.The device was found accurate within half a degree on repeated orientations of the same tube. However, the degree of accuracy is dependent on the accuracy of personal manipulation in orienting the tube to the correct plane."

May 1, 1947

By Edward D. Thimons

The Bureau of Mines has developed a damage-resistant brattice, intended for use as a stopping in locations where blast damage to stoppings is a problem, the roof is relatively flat, and the differential pressure across the stopping is not high. Damage-resistant brattices consist of a series of vertically hung brattice panels joined to each other by Velcro connections that improve the airtightness of the brattice. When the brattice is subjected to strong blast forces, the Velcro connections peel apart, allowing the panels to open without incurring damage. The Velcro connections can then be resealed in a matter of minutes. A preliminary test in the Bureau's Safety Research Mine and subsequent long-term testing at the White Pine copper mine in Michigan and the Retsof salt mine in New York show that damage-resistant brattices withstand blasting better than conventional stoppings, while still performing as efficient air barriers when the Velcro connections are sealed.

Jan 1, 1978

This publication summarizes the research (in-house and contract projects) programmed by the Bureau of Mines for fiscal year 1984 (October 1, 1983-September 30, 1984) under its Health and Safety Technology Program. The objective of these projects is to provide an ordered and sequenced advance toward the Bureau's overall goal of providing the systems technology required to create a more healthful and safer working environment for the Nation's mining and minerals processing workers.

Jan 1, 1983

By Robert W. Ageton

Optimal planning for mining the deep, lead-zinc-silver deposits of the Coeur d'Alene mining district, Shoshone County, Idaho, could be facilitated by a knowledge of the magnitude and direction of the pressure acting in the virgin rock. The distribution of primary stresses should be considered in order to prevent possibly destructive mining-induced stress concentrations. This particular investigation was concerned with determining stress in a zone 4,000 feet below the surface and known to be ender stress concentrations due to mining operations. Disking of the stress-relief cores obtained in a vertical down hole permitted qualitative evaluation from visual observations; the results indicate that a high lateral stress existed at the time the measurements were made. Stress-ellipsoid determinations gave a compressive principal stress of -13,000 psi oriented about N 45° W and nearly horizontal, a compressive principal stress of -11,000 psi oriented about S 45° W and abut 60° off the vertical pointing away from the vein, and a compressive principal stress -5 -7,000 psi oriented N 45° E and about 60° off the vertical, pointing toward the vein. Subsequent to the overcoring stress-relief drilling, a rock burst occurred about 100 feet northwest of the test site.

Jan 1, 1967