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By P. T. Brooks

This Bureau of Mines study describes a process for recovering nickel, cobalt, molybdenum, and chromium contained in complex waste superalloy grindings that, for lack of an economical domestic recovery process, are being largely marketed abroad. The process, devised by laboratory scale operations, includes scrap preparation, dissolution of metallics in hot chlorinated acidic liquor, carbon adsorption, three successive solvent extraction separations, and selective chemical precipitations. Nearly 90 percent of the nickel, cobalt, molybdenum, and chromium were separated and recovered as oxides, carbonates, and basic sulfate products.

Jan 1, 1969

By Bruce K. Cantrell, Jon C. Volkwein

Exposure to mineral aerosol is an occupational health hazard in mining and mineral processing industries because of the risk of developing pneumoconiosis. Agricola (1556) described this hazard for metal mining in Carpathia. He described shortness of breath and consumption, conditions that are now associated with asthma and emphysema. By the end of the nineteenth century, several respiratory diseases were known to affect miners, including silicosis and coal workers' pneumoconiosis (Fletcher, 1948; Seaton et al., 1981). For example, silicosis, not tuberculosis, was clearly recognized as the hazard in the Vermont granite quarries and stone-cutting sheds (McFarland, 1927). The Gauly Bridge Tunnel disaster in the mid-1930s caused the deaths of an estimated 700 workers by acute silicosis and focused the nation's attention on this disease (Cherniack, 1986). By the mid-twentieth century, it was clear that risk of simple pneumoconiosis is associated with a miner's cumulative exposure to mine aerosol in the respirable size range and that prevention lies in reducing that exposure through regulation (Seaton, 1986). In the United States, regulation of mine worker exposure to airborne mine dust is the responsibility of the Mine Safety and Health Administration (MSHA) in the U.S. Department of Labor. The key legislation relating to improved mine worker health was the Federal Coal Mine Health and Safety Act, enacted in 1969 (U.S. Congress, 1969) and subsequently amended as the Federal Mine Safety and Health Act of 1977 (U.S. Congress, 1977). MSHA receives technical assistance from the National Institute for Occupational Safety and Health (NIOSH). NIOSH also provides recommended exposure limits (RELs) for contaminants to MSHA. MSHA's regulation of mines includes the establishment of a dust standard administratively based on the these RELs. Some mine operators must submit a dust control plan designed to meet the dust standard. Periodic mine inspections determine if mines are com- plying with both the dust standard and the dust control plans (MSHA, 1991). The most common dust measurements are those for respirable dust (according to the definition given in Fig. 26-7), that is, the fraction of aerosol particles able to reach the gas exchange region of the lungs. The other health-related size fractions (inhalable and thoracic-see Fig. 25-1, and "total" dust) are also occasionally measured. A "total" dust measurement is defined by the common practice of the last 30 years or so, using 25 mm or 37mm plastic cassettes (e.g., from PAL, MIL, SKC ). The types of mines have been categorized

By Carlton E. Brown

Impinger dust-counting methods are used by industrial hygienists for determining the number concentration of unhygienic siliceous dusts in industrial atmospheres. Various statements have been made regarding the size of the smallest particles revealed by the microscopic employed in such determinations. Published data on the subject are quite limited. This report presents information on the size of the smallest particles revealed by light-field and dark-field techniques applied to impinger and electric precipitator samples collected from experimentally established aerosols of silica dust and bituminous-coal dust. Size distribution and number concentration of particles of the various sizes in the aerosols were determined from samples collected by thermal precipitation simultaneously with the impinger and electric precipitator samples. The size of the smallest silica and bituminous-coal dust particles determined in the light-field counting method used was about 1./1, . There was relatively little variation in the values from 8 impinger and 33 A.-C. precipitator samples of silica dust and 13 impinger and 13 A.-C. precipitator samples of coal dust. The coefficients of variation of the values from the four sets of determinations were low, ranging from ± 7.7 to t 10 percent. This size of 1,14 is close to the limit of resolution of the microscopic method used and to various previously suggested values. The size of the particles determined in the dark-field counting method used was smaller than the size (about 0.28A ) of the smallest particles determined in the light-field, oil-immersion method used for the thermal precipitator samples.

Jan 1, 1951

By Walter G. Dupree

When the original version of this study was published in 1972 it was evident that a problem was developing on the energy scene. The ability of the United States to find the energy supplies it needed within its own boundaries--at least in the forms desired--was declining. Production of crude oil in the United States had peaked in 1970 and was declining slowly; environmental restrictions had begun to hamper the production and consumption of high sulfur coal; natural gas reserves were beginning to dwindle; and the development of nuclear power was proceeding more slowly than originally planned. Shortfalls in energy supply were being met through the importation of increasingly larger quantities of petroleum, but supplies were adequate and the price of the imports was below that of domestic production. The energy problem was more prospective than current. In October of 1973 the prospective problem became the "Energy Crisis' when the Arab petroleum exporting countries reduced crude oil production, imposed an embargo on the shipment of crude oil to the United States, and then raised the price of crude oil in a series of large steps. This crisis was a clear demonstration of the dangers of the dependence of the United States on imported petroleum, and of the Nation's vulnerability to the actions of the oil exporting countries. After the embargo was lifted, attention shifted to the immediate hardships resulting from the higher prices for gasoline, fuel, and electricity,

Jan 1, 1975

By G. B. Gait

This report is the fourth in a series concerning the Bureau of Mines program for microfilming maps of abandoned mines in the Pennsylvania anthracite region; a catalog of the microfilmed maps of 70 mines in the Western Middle field is presented. Previous reports were catalogs of microfilmed maps of mines in the Eastern Middle field and in the Wyoming and Lackawanna Basins of the Northern anthracite field. Additional catalogs will be published as the microfilming of significant mining areas is completed.

Jan 1, 1971

By Jack E. Fraley

In this Bureau of Mines study, sealants containing mineral wool, cement, etc, were sprayed through dry-process equipment that propels dry material pneumatically to the water-adding nozzle. Advantages over slurry applications include no mixing, no extensive cleanup, and freedom from hardened cement in equipment should power be lost. Sealants with large mineral wool nodules (>l-inch) were sprayable at rates to 900 square feet per hour for 1/2-inch thickness with little dust and smooth material flow through equipment, but they were weak for mine use, Materials containing small wool nodules (1/4-inch) were stronger but tended to plug lines because the nodules were inadequately separated in the shredder. Increasing the dedusting oil also increased line plugging by holding the nodules together in larger lumps. Best results were obtained using a 3/4-inch-nodule wool with cement binder, which provided both smooth flow through the machine and adequate strength.

Jan 1, 1977

By Melvin P. Silverman

The literature on methane-oxidizing bacteria is reviewed in regard to (1) the growth and isolation of cultures by special techniques; (2) the distribution of these organisms in nature and descriptions of individual species; (3) the physiology of methane-oxidizing bacteria as influenced by temperature, light, pH, aerobiosis versus anaerobiosis, and carbon and nitrogen sources; and (4) the biochemistry of methane oxidation revealed by studies with intact cells and subcellular systems. Present practical applications of methane-oxidizing bacteria are limited to prospecting for natural gas and petroleum deposits. Desirable areas for future research are discussed as well as some possible applications such as (1) the removal and/or early detection of methane gas in coal mines by intact culls or enzyme preparations; (2) the generation of electrical energy by microbial fuel cells using methane as fuel; (3) the growth of methane-oxidizing bacteria on methane fur their food value; (4) the purification of hydrocarbon gas mixtures using methane-oxidizing or other alkane-oxidizing bacteria; and (5) the synthesis of methane from mixtures of H2 and CO or H2 and CO2 by methane-forming bacteria.

Jan 1, 1964

By I. Iwasaki

In recent years the rapid depletion of high-grade iron ores and the demand by blast furnace operators for increasingly low-silica ores have stimulated interest in flotation studies of low-grade iron ores, such as wash-ore tailings and oxidized taconites. Four processes have been reported for the flotation separation of these iron ores--anionic and cationic collection of the iron oxides, cationic collection of siliceous gangue, and anionic collection of activated siliceous gangue (5).5/ The effectiveness of any one method, however, depends largely on the mineralogical composition and on the physical structure of the sample; hence, a comprehensive study of the floatability of the individual minerals occurring in these materials is essential. A review of the literature shows that the floatability of hematite and magnetite has been frequently investigated, whereas very little corresponding information is available for goethite, or for its more earthy form, limonite, both of which are abundant in the Mesabi and Cuyuna ores (19). The purpose of this investigation was to formulate general information on the floatability of goethite. Vacuum flotation, contact angle measurement, and simplified flotation tests using a modified Hallimond tube were used. The experimental results were correlated with the electrokinetic properties of goethite as determined by streaming potential measurement. The results were used to interpret the batch flotation tests made on an artificial mixture of quartz and goethite.

Jan 1, 1960

By W. E. Wallace, B. L. Razzaboni, P. Bolsaitis, M. J. Keane

"Therma1 and chemical treatment of respirable size silica dusts samples is shown to induce marked changes in their hemolytic activity. The cytotoxicity of crystalline a-quartz (Min-U-Sil), and fumed silica (Cab-0- Sil) particles, as measured by a hemolytic activity protocol, is decreased by calcination and can be related to the dehydroxylation of the surface. The hemolytic activity of P-cristobalite particles of respirable dust si7.e was also determined and found to be lower than that of a-quartz. The change in the surface structure resulting from thermal treatment is detectable by photo-acoustic infrared spectroscopy and zeta-potential measurements. The absorption band in the 3200-4000 cm-1 frequency region of both Cab-0-Sil and MinU- Sil disappears upon heat treatment while a sharp band, identified with single silanol groups, at 3750 cm-1 increases in intensity. The zeta potential-pH profile, in the pH range of 4.0-7 .0, of the calcined, siloxane surfaced particles is more negative than that of material with a silanol surface.The cytotoxicity of the crystalline and fumed silica dusts was also found to be strongly dependent on particle size. Fumed silica of large surface area (small particle size) exhibits an initial increase in hemolytic activity upon calcination. This result confirms other experimental observations pointing to a particle size of maximum toxicity. INTRODOCTIONThe toxicity of silica and other mineral particles, as manifested by their role in inducing pneumoconiosis, fibrosis, silicosis and other pulmonary disorders is largely traceable to the characteristics of particle surfaces and to particle morphology. The great wealth of data on the physical and chemical properties of silica is still insufficient for a comprehensive understanding of the specific parameters to be associated with fibrogenic activity and, correspondingly, with the optimum means for characterizing and quantifying the toxicity of dusts, and the design of possible preventive or therapeutic methods.The great diversity of parameters that have been proposed and tested for correlation with cytotoxicity suggest that more than one mechanism may be involved in the fibrotic activity of silica particles. The crystalline structure of the material (more active tridymite versus less active crisobalite and passive stishovite), freshly formed surfaces and free radicals associated therewith, silicic acid adsorbed onto silica surfaces, the concentration of hydroxyl groups at silica surfaces, particle size and morphology, among other properties, have been investigated and found to conelate in tests of cytotoxicity."

Jan 1, 1990

By J. L. Eakin, J. P. Powell

"The increased costs of exploration and drilling of new oil fields and the continued success of water flooding in nearly depleted oil fields have created a demand for information on the results obtained from individual projects. The Bureau of Mines has published several reports concerning water-flood activity in the Midcontinent area and at the request of the industry has continued to collect and disseminate this information. This report was written in response to these requests. It describes in detail the water-flooding projects in Anderson, Franklin, Linn, and Miami Counties, Kans., and includes methods of water treating and the results obtained. The production histories of each county and many water-flood projects are shown graphically from the date of the first development. Maps of most of the major projects, showing their status as of January 1, 1953 are presented also.The practice of injecting water to stimulate oil production was legalized in Kansas in 1935, and the first water-flooding project authorized in this four-county area was initiated by the Texas Co. in December 1935 in Linn County. Forty-nine projects2/ initiated in the area to January 1953 are estimated to have recovered approximately 10 million barrels of oil that would not have been produced by methods used previously. About 7,900 productive acres had been, or are, flooded by these projects, and approximately 136 million barrels of water had been injected.These four counties in the eastern Kansas shallow production area3/ were an important factor in the early history of the Kansas oil and gas industry. This position has been maintained from the very beginning through the early period of vacuum and air injection and into the era of water flooding. The location of the area and the relative position of the four counties and water-flooding areas in each are shown in figure 1.The first drilling for oil in this area in 1860 resulted from investigations of the existence, and use by the Indians, of so-called tar or oil springs. The first wells drilled were nonproductive, and the impending Civil War caused the search for oil to be discontinued. In 1884 a few shallow oil wells were drilled near Paola, and completion of several gas wells near that city led to subsequent drilling of an oil well, which was completed in June 1885, having an initial flow of 10 barrels of oil daily.In 1904 the original Paola gas field became a good oil-producing field. In 1905 the Rantoul field in Franklin and Miami Counties was opened; and drilling activity spread throughout the adjoining area, resulting in development of several shallow oil pools in Linn and Anderson Counties. The first ""shoestring"" pool in eastern Kansas to produce oil was probably the Paola or Pressonville shoestring, which was discovered in 1917. The rate of oil production from the area declined until 1919, when the Centerville shoestring pool was discovered. Discovery of the Colony gas field in 1921 was followed within a few months by drilling of the Garnett and Garnett and bush City shoestring pools. The Schermerhorn pool (now part of the Centerville field) s discovered in 1927, and the Kincaid shoestring pool was first drilled in 1931. The oil-production histories of the individual counties are discussed separately."

Jun 1, 1953

By Oliver Bowles

"Score of the Bureau's Investigations.There has been outlined in a previous report* the results obtained regarding the adaptability of pulverized waste slate as a filler in road asphalt mixtures. As pointed out in that report the percentage of waste at slate quarries is very high, and the Bureau of Mines has undertaken the problem of discovering new and enlarged outlets for the waste material.Many products such as paper, rubber, road asphalt, floor coverings, paints, etc., require as one of their important constituents a considerable percentage of finely pulverized inert mineral matter to give ""body"", to obtain the desired consistency, or to supply the necessary wearing or other qualities demanded. Such materials are known as ""fillers"". The possibility that slate flour might be used as a filler with advantage in several products other than road asphalt led the Bureau to undertake further investigation.The Importance of Discovering Advantageous UsesIt has been found that in some products slate may be substituted for materials now in use without any marked effect on the quality of the products. A wider use of slate in such products could result only from a definite price advantage as compared with other fillers. Mile it is probable that waste slate may be placed on the market at prices which will encourage its wider use, it is evident that a waste slate utilization industry can never attain sufficient magnitude to definitely assist the slate producers unless it is demonstrated that some definite advantage in quality may be gained when slate is substituted for fillers now in use. The main purpose kept in view throughout the inquiry has been, therefore, to find advantageous uses for waste slate in order that both producer and consumer may be benefited."

Sep 1, 1921

By C. Özgen Karacan

The methane emission rate into an underground mine environment from overburden strata during longwall mining is impacted by reservoir and geomechanical characteristics of the coal measure rocks in the overlying strata, as well as the presence of any coal seam. The reservoir characteristics and how they change during mining potentially affect the performance of gob gas ventholes, which consequently impacts the efficiency of methane control in the mining environment. This study presents reservoir and elastic properties of coal measure rocks in the Lower Monongahela Group in Greene County, southwestern Pennsylvania, of the Northern Appalachian Basin. Since the source of methane in this region from underground mining is located between the Sewickley coal and the Pittsburgh coal, a specific emphasis was given to this interval. Core analyses were performed in the laboratory to determine rock porosity and permeability. Geophysical logging data (gamma, density, sonic) obtained from two exploration boreholes were used for evaluating formation boundaries, shale contents, log porosities, and geomechanical properties of formations. Permeability was also calculated using density-log data and empirical equations and compared with laboratory measurements and slug tests performed in isolated intervals of boreholes. The results presented in this study can be used as data sources for reservoir studies related to the production and control of methane.

Jan 1, 2009

By S. H. Ash

The United States Bureau of Mines has published relatively little on the flooding and unwatering of coal and metal mines. Bulletin 229, Fifty-Nine Coal-Mine Fires, published in 1927, contains several instances of the flooding of mines or sections thereof to extinguish fires but does not describe their unwatering. Report of Investigations 2649, Explosion Hazards Incidental to Unwatering Coal Mines, published in 1924, warned against the possibility of gas accumulations in flooded mines and indicated the precautions to be taken. Report of Investigations 2255, An Unusual Hazard in Reopening Long-Flooded Timbered Metal Mines, published in 1921, told of methane being pocketed and the danger thereof. The flooding of mines originates in many ways. At some mines flooding followed reopening after what was thought to be permanent abandonment; also, explosions have caused some mines to be flooded. Extinguishing fires, accidental encountering of underground streams or flooded old workings, and caves of strata admitting water from underground workings, water-bearing strata, or surface accumulations have also flooded all or parts of mines. Unfortunately, un watering often necessitates much study and causes apprehension largely because experiences in similar situations are not generally known, as few descriptions of successful or unsuccessful methods are available. The job has sometimes been contracted for outside the local management involved and has become a matter of record for the contractor only. As the cost-plus contract system often employed in the past is now known to be expensive, careful managements elect to handle the problem themselves, in line with the general policy of cutting expense where possible. This report describes specific in-stances of successful unwatering by operators.

Jan 1, 1933

By W. L. Crentz

In Fayette County, the Pittsburgh bed has been the major source of production for almost two centuries. Although historical documentation is not available, there is evidence, that the Pittsburgh bed may have been discovered in Fayette County near Mt. Braddock, Pa., as early as 1753. The earliest known reference to coal in western Pennsylvania was recorded in 1758 by a Quaker trader, James .Kenny, who reported having seen coal in Fayette County. The production of coke from Pittsburgh coal was begun in 1841, when two 10-foot beehive ovens were erected in the Connellsville region to make coke .for shipment by river to the market. The Connellsville, region extends from Latrobe, Pa., in Westmoreland County to South of Uniontown, in Fayette County. Connellsville coke was used with great success in the Clinton furnace in 1859.

Jan 1, 1951

By A. F. Baker

Tests were conducted in commercial foundries to determine the suitability of calcined anthracite as a cupola fuel. The calcined anthracite performed satisfactorily at two of the three foundries where iron-melting tests were conducted. Performance at the third installation was unsatisfactory because metal temperatures deviated widely and, in general, were lower than is desirable for the type of castings being made.

Jan 1, 1963

By Horace C. Porter, F. K. OVITZ

The various fuel investigations that were being carried on by the technologic branch of the United States Geological Survey were transferred by law on July 1, 1910, to a new federal bureau, the Bureau of Mines, that was authorized to continue the investigations and make public reports of the results. In consequence of this transfer, the following report is published as a bulletin of the new bureau. The United States Geological Survey had been engaged in analyzing and testing coals, lignites, and other mineral fuel substances under authority given by act of Congress. This work, now centered at the experiment station at Pittsburg, Pa., had its beginning in the operations of the coal-testing plant erected at the Louisiana Purchase Exposition in St. Louis, Mo., in 1904. The results obtained at that plant showed that the work of determining the fuel value of the coals and lignites in the United States with a view to increasing efficiency in their utilization would be incomplete if it did not include systematic physical and chemical researches into the processes of combustion. Hence in its later investigations the Survey carried on such re- searches, concentrating attention on those lines of inquiry which promised results of greatest economic importance. This bulletin is a report on an investigation of the volatile matter in several typical coals-its composition and amount at different tem- peratures of volatilization. As the investigation is still in progress and will doubtless include other coals than those already examined, the bulletin may be considered a preliminary report, stating the prob- lems studied, the methods used, and the results thus far obtained.

Jan 1, 1910

By D. Harrington, W. J. Fene

For nearly 30 years the Bureau of Mines has contended that mine explosions can be prevented and has pointed out to the industry ways and means by which they could be avoided. The record of co2l-mine explosions • during the past fiscal ?Bar bears out the :Bureau1s contention, inasmuch as fewer men were killed by coal-mi~e e:xplosions in the United States during that year than in :gi_y corresponding 12 months in the history of coal mining in the United States, insofar as records are available; and more than a year has elapsed since·a major explosion (in which five or more men were killed) has occurred, this being t.1-J.e first continuous 12- month period without a major coal-mine explosion disaster in the United States in more than 60 years. The methods of preventing mine e:iiplosions are well known to experienced, well-informed persons cngnged in coal mining. Despite this knowledge, many coal-mine operutors continue to use practices and methods that they should know have resulted in countless explosions, and mine workers persist in following past procedure or in breaking safety rules and practices almost certain eventually to result in disaster. ' Virtually all explosions are the result of human failure, such as carelessness or neglect by officials or workers or others. These human failures can be corrected chiefly by ed.ucation and proper and adequate supervision and strict discipline. In some instances mine officials are ·lax, careless, poorl~• informed, and often incompetent; end in many instances miners have repulsed the introduction of known preventive methods because of sheer obstinacy, ignorance, heedlessness, or possibly fear that the operator was trying to o'bta.in some unfair adva.,.'1. tago or would neglect some other phase of accident or e,:plosion prevention. The freedom of the fiscal year 1938-39 from major coal-mine explosions ar..d frora any considera~le number of fat,JJ.i ties from minor explosions is a. matter for congratulation, but on the other hand. the occurrence of one rather bad e~losion in each of tho 3 calendar years 1937

Nov 1, 1939

By L. C. IlsLey

[In 1922 a conference of representative coal-mine operators, cable manufacturers, mining-machine manufacturers, and representatives of the United States Bur eau of Mines vas held at the Pittsburgh Experiment Station, regarding suitable cables for use with permissible raining machines. This conference recommended that the Bureau investigate rubber-sheathed trailing cables in order to obtain specifications for tests leading to approval for rise with mining machines. Effective until such time as an investigation could be made, the bureau asked the several manufacturers of approved mining machines to recommend cables for wise with their machines. In general the Cables recommended tentatively approved. Arrangements for the tests were completed in 1927. Concentric-type cables were investigated first, and Reports of Investigations, Serial No. 2909, covering the tests, was issued in January, 1929.]

Jan 1, 1929

By Herbert H. Einstein

Rock mass deformability is commonly predicted using correlations with RQD or other indices of rock mass quality, or by extrapolation from large in-situ tests. Based on the probabilistic description of rock masses empirically developed in Part I a new approach was attempted in modeling for predictions of deformability. This approach decomposes the rock mass into spatially variable joints described by probability distributions, and intact rock blocks. Stiffnesses and elastic parameters are associated with the joints and intact blocks respectively, and deformations built up by adding the contributions of each. This model allows relaxation of many of the simplistic geometric assumptions which constrain parallel attempts to model deformation in rock masses. The model has been applied to four standard cases in order to test its results against previously existing models, and to check whether it replicates empirical correlations. When joints are taken as parallel, common empirical correlations are closely approximated by the model output. However, the closeness to empirical correlation breaks down when variability of the jointing geometry is increased.

Jan 1, 1979

By Terry R. Neumann

In 1987 and 1988, the U.S. Bureau of Mines conducted a mineral resource investigation of the 31,400-acre Muddy Creek Wilderness Study Area (UT-060-007). The investigation was requested by the Bureau of Land Management and authorized by the Federal Land Policy and Management Act of 1976 (Public Law 94-579). The study area is located in Emery County, Utah, about 50 air-miles southwest of Green River, Utah. The wilderness study area is in the San Rafael Swell region of the Colorado Plateau Physiographic Province. Rocks in the area consist of gently dipping sedimentary strata of Permian, Triassic, and Jurassic age.

Jan 1, 1988