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By Yongbao Zhu

The Ag2O-mediated reactions of cycloaurated compounds with a general formula Au(L)Cl2 (L = bi-dentate C?N ligand) with thiosalicylic acid, N-acetyl cysteine or 1,2-benzenedithiol in DMF proceeds via ligand substitution of the Au?Cl bonds to afford the S-O and S?S adducts all in good yields. The reactivity of the dichloro, S-O and S-S adducts towards thiols were examined by reacting with cysteine in an aqueous medium, revealing that all of Au-Cl, Au-O and Au-N are labile for thiol displacement. The measurement of the inhibitive activities of these compounds against human cathepsins B and K showed that the dichloro and S-O adducts are effective inhibitors with IC50 values ranging from 0.1 to 2.6 -M, and that the S-S adducts are inactive.

Oct 1, 2003

By T. Hofbauer, M. J. Dry, G. B. Harris, C. W. White

"Urban Mining is a term that is increasingly being used, and represents an appreciable source of secondary materials for the metals extraction industry, a source that does not incur mining costs, but does, at present, incur considerable disposal costs. Electric Arc Furnace Dust (EAFD) is probably the most common of these materials, with an estimated global production of 8 million tonnes annually, of which 1 million tonnes is generated in North America. The contained annual metal value in EAFD at current prices is of the order of $6 billion, yet, apart from the zinc, virtually none of this is recovered.Despite many attempts over the years, with pyrometallurgical, hydrometallurgical or hybrid processes, currently the only commercially viable method of treating these materials is smelting in a Waelz Kiln (or a Rotary Hearth Furnace), which essentially recovers only the zinc, in an impure oxide form, and generates a secondary slag waste, which is still toxic and requires disposal. This paper describes the development of a chloride-based treatment process to recover all components of the EAFD in a marketable form, which centres around the novel hydrochloric acid recovery and recycle operation. Laboratory, miniplant and pilot plant data are presented, leading to the definition of a viable process flowsheet enabling the recovery of pure iron and zinc products (the principal components of EAFD), together with secondary products such as copper, silver, lead, cadmium, magnesium and manganese. A rigorous mass-energy balance is used to examine the preliminary economics involved."

Jan 1, 2014

By T. Alan O'Hara

"Annual mining revenue can be computed by formulae relating metal prices, smelting schedules, concentrate grade and recovery to known ore grade and an assessment of core samples. Operating costs at different daily tonnages are related to orebody shape, mining method, milling process and general plant services. Capital costs are related to sizing of mining equipment, mine development, plant-site topography, climate and accessibility, plant services and personnel housing. IntroductionA crude guide to the average 1978 cost of mine projects is shown in Figure 1, but the costs of many mine projects have differed widely from the graphed average costs of $800,000 T0.6 for underground mine/mill projects and $400,000 T 0.6 for low-grade open-pit mine/mill projects.High mine project costs and high operating costs are characteristic of open-pit mines with high stripping ratios, underground mines with thin orebodies, mills with complex metallurgy, and projects located in isolated regions with severe climate, mountainous topography, and lacking access to existing roads, towns and electric power. When none of these adverse conditions prevailed, the mine project cost was typically much less than the graphed average cost. Virtually all the conditions likely to cause high capital and operating costs are known from knowledge of the local topography, climate or accessibility, or can be assessed by tests on core samples, as soon as the orebody has been outlined by drilling .A more accurate estimate of over-all project capital cost and operating cost can be made from a summation of items of cost after judging the effect of specific local conditions on each item of capital and operating cost. This paper offers guides in judging the effect of local conditions on the sizing and 1978 cost of specific items of capital cost and operating cost and operating cost of mine projects. When the specific items of capital cost and operating cost are totaled and measured against expected net revenue and taxes over the life of the mine using the net-present-value or discount-cash-flow methods, the result should show whether the mine project development is clearly feasible, doubtfully feasible or clearly uneconomic. If the development of the mine project is clearly feasible, or probably feasible, a detailed feasibility study by experienced consulting engineers should be commissioned before any financial commitments are made; but if project development appears to be uneconomic, the time and cost of a detailed feasibility study is not warranted."

Jan 1, 1980

By Da-Qiang Cang, Qingde Wang, Wei Wang, Wen-Bin Dai, Min Guo, Yu Li

Utilization of both slag and its heat for hot slag is a great challenge for iron and steel industry. Many methods of hot slag modification for directly converting hot slag into value-added materials were researched in recent years, and waste heat of hot slag could thereby be transformed into inner energy or chemical energy of the materials. In this paper, an experiment of converting hot slag directly into glass ceramics by hot slag modification method was conducted. A cooled modifiers mainly composed of fly ash were firstly heated though a cyclone furnace and then fell into a molten bath to mix with hot steel slag. Half of hot slag was used as raw materials and accordingly about half energy consumption, about 5MJ/kg for melting raw materials was saved in the process compared with that of traditional producing method. Frit quenched from the modified hot slag had a higher basicity of 0.6-0.7 than traditional frits in order to reduce the needed amount of cold modifiers and accordingly utilize more hot slag and its waste heat. Glass ceramics were further prepared from the frit and a heat treatment of one-stage method is more suiter to such frit than that of two-stage method. The glass-ceramics with basicity of 0.6 and heat-treated by one stage method had the best performance with bending strength of 146.46 MPa, Vickers hardness of 6.79 GPa, water absorption rate of below 2% and shrinkage rate of around 10%.

Jan 1, 2015

By J. Desroches, J. Burghardt, N. Whitney, B. Lecampion, A. Surdi, M. Houston, S. Stanchits

There is accepted evidence that multistage fracturing of horizontal wells in shale reservoirs results in significant production variation from perforation cluster to perforation cluster. In fact, only a fraction of the perforation clusters seem to contribute to production in many shale gas and shale oil plays. In many cases, the orientation of the lateral section of these wells is determined by lease boundaries rather than principal stress directions, and these often do not coincide. When horizontal wells are misaligned from the far-field principal stress directions, the fracture must reorient from the near-wellbore principal stress directions, which are aligned with the wellbore, to the far-field principal stress directions. The primary objective of this study is to learn how various completion designs influence the near-wellbore fracture geometry when such a misalignment exists. A secondary objective is to understand the influence of rock fabric features, such as mineralized natural fractures, on this reorientation process. To understand these effects, eight laboratory hydraulic fracturing tests were conducted using a true triaxial vessel with 914 mm × 762 mm × 762 mm samples of Niobrara shale. Several different completion designs were studied, including the use of fracture initiation slots with several different orientations and the use of perforations selectively located to encourage a smooth transition from the near- to far-wellbore region. The tests were carefully scaled as accurately as possible to provide insight into the field near-wellbore phenomena. Pressure and fluid flux at the wellbore, deformation of the block, acoustic velocity, and induced acoustic emissions were acquired during the tests. Additionally, sized particles were also injected to gauge the fracture width away from the wellbore. After the test, the blocks were dismantled, and the fracture geometry was mapped in 3D. These measurements allow one to clearly differentiate the fracture initiation and the breakdown—meaning the peak pressure—to be clearly differentiated; the fracture was already well developed when the maximum pressure was reached. The study reveals non-negligible tortuosity and aperture restriction in the near-wellbore region. In the field, this would translate to high treating pressures, uneven proppant distribution, and possibly near-wellbore screenouts. The test results show that, of the configurations tested, the best approach is to use deep slots that are aligned with the far-field principal stress directions. The oriented perforation design did not achieve the simple, smooth transition that was hoped for, and instead produced multiple competing near-wellbore fractures and considerable tortuosity. The study also demonstrated that the presence of planes of weakness, such as mineralized natural fractures, near the slot tip can result in poor near-wellbore fracture geometries, even for the best completion configuration. We conclude from these tests that the misalignment of the well with a principal stress direction creates near-wellbore complexity that, in turn, creates uncertainty in proppant distribution and, therefore, production; proppant might avoid up to a half of the created fracture. Regardless of the wellbore orientation, this uncertainty is further increased by the presence of mineralized features in the rock fabric that can strongly alter or stop the growth of the hydraulic fracture. Preventing those effects by changing the completion alone proves difficult, and new strategies are required to ensure a reliable stimulation of shales.

Jan 1, 2015

By Neil Camarta

$6 Billion Dollar Education ?? Construction is like war ? you need a command and control organization ?? A strong Owner?s team is a must ?? Smaller is better ? break the project into bite size chunks ?? New technology is risky ? lots of construction and start-up risk ?? Safety can be successfully managed ?? Don?t expect contractors to ?work well together? ?? Never, ever let Mining Engineers run stuff than can catch fire

May 1, 2008

By C. R. Fast, G. C. Howard

The loss of fluid to the formation adjacent a fracture governs the areal extent of the fracture and the success of hydraulic fracturing as a production stimulation technique. The three flow mechanisms which control this loss are the result of the viscosity of the fracturing fluid and the permeability of the formation to the fracturing fluid, its wall building properties, and the combined effects of viscosity and compressibility of the reservoir fluid. The effects of these flow mechanisms can be evaluated in terms of a fracturing fluid coefficient, the fundamental concepts of which are developed in the paper. The fracturing fluid coefficient, which may be used in calculating the areal extent of fracturing, affords a direct measure of the effectiveness of fracturing fluids. The area of hydraulically created fractures is in-creased as the coefficient is de-creased. The fifteen-fold variation noted in this coefficient for the commercially available fracturing fluids tested resulted in a six-fold difference m the calculated areal extent of the fracture system.

Jan 1, 1961

By J. R. Giegerich

"IntroductionMINING operators in common with other operators are confronted today with two serious problems, shortage of experienced workmen and rising costs. The following review of practices at the Sullivan mine of The Consolidated Mining and Smelting Company of Canada, Limited, outlines certain measures that have been responsible, during recent years, for minimizing the effect of these two problems. The paper is divided into three main sections:( 1) Training programmes and job studies( 2) Improved mechanization and equipment( 3) Large-scale methods of operationTraining Programmes and Job StudiesJob TrainingJob training courses were introduced at Cominco immediately after the last war and proved to be a great benefit to the operations. There were three courses given, Job Instruction Training, Job Safety Training, and .Job Relations Training. These were spread over a period of two years and were taken by all operating supervisors and some key operators.The courses were introduced by a trained instructor from the British Columbia Department of Labour. This man trained twelve of our employees as instructors by giving them an intensive one-week course. Similarity between the three courses was such that the instructors trained in the first one were very readily trained for instruction in the two succeeding courses."

Jan 1, 1952

By W. Banda

"Trial application of air decks on a production shot improved fragmentation (32% reduction in x50). Empirical fragmentation models and digital image processing software were used to estimate fragment size distribution of the blasted muck pile. The x20, x50, and x80 passing fractions, and top size were 42, 265, 683, and 1,455 mm, respectively. Air-deck application reduced explosives load in blastholes, lowering total charging cost by US$20/hole (15% decrease) and the powder factor to an average of 0.86 kg/m3 (12% decrease). Blast results were 443,624 t of blasted material from the block (90% of total muck pile) was smaller than 900 mm.RÉSUMÉ L’application pilote de trous d’air dans le cadre du coup de mine effectué pour commencer la production a amélioré la fragmentation (une réduction de 32 % des x50). Des modèles empiriques de fragmentation et un logiciel de traitement numérique des images ont permis d’estimer la composition granulométrique des fragments du tas de déblais abattus. Les fractions de passé de crible de x20, x50, x80 et la dimension supérieure étaient représentées par des dimensions respectives de 42, 265, 683 et 1 455 mm. L’application de trous d’air a permis de diminuer la charge d’explosifs nécessaires dans les trous de mine, réduisant ainsi les coûts totaux de chargement de 20 $ US/trou (soit une réduction de 15 %) ainsi que le facteur de chargement (facteur poudre) à une moyenne de 0,86 kg/m3 (soit une réduction de 12 %). Les coups de mine ont résulté en 443 624 tonnes de matériaux abattus du bloc (soit 90 % du tas de remblais total) mesurant moins de 900 mm. INTRODUCTIONThe main objectives of production blasting are to achieve optimum rock fragmentation and to minimize overall production costs. Because blast fragmentation significantly affects the profitability of a mine, blasting is the first step of the size reduction in mining: An optimum size distribution is required to maximize the performance of mining and subsequent milling processes. If the fragmentation size distribution can be modelled and controlled, operations performance will improve. Blast fragmentation modelling is important in mineto- mill optimization: It allows the estimation of blast fragmentation distributions that can be modelled in downstream mining processes to determine the optimum blast design."

Jan 1, 2018

By S. Setayeshgar

The identification of potential accidents on construction sites has been a major concern in the construction industry and it needs a proactive safety plan to reduce the risk of accidents. There are no efficient methods for checking if safety measures are taken properly on construction sites. Consequently, workers on site are not given enough awareness about dangerous areas. In addition, construction sites are dynamic and on-site situations are changing in terms of permanent and temporary structures and facilities. This information can be represented using Building Information Modeling (BIM). This paper proposes the integration of BIM and safety risk analysis by considering the risk levels associated with the work spaces of different construction tasks. Work spaces are generated in a BIM model according to the Work Breakdown Structure (WBS) of the project, reference objects in the BIM, and the schedule and resources of the task. Each work space is assigned to one or more tasks or functions, e.g., work spaces for specific tasks, shared spaces (paths), storage spaces, or spaces prohibited to workers. The assignment of work spaces is based on the workers, equipment and materials involved in the task. All the work spaces are associated with a specific duration according to the schedule of the project. Then risk evaluation of the construction site is applied in order to evaluate safety risks based on their severity and the degree of exposure of workers. For example, work spaces for storing hazard materials and for heavy construction equipment have higher risks than other work spaces. The results of the risk evaluation can be visualized in a 4D BIM model.

Aug 1, 2013

By T. I. Urbancic, C-I. Trifu

"ABSTRACTSeveral case studies are presented on the use of seismic techniques to map active structures, evaluate changes in stress levels, and identify the conditions leading to large magnitude seismic events and the generation of rock-bursts in Canadian mines. The results suggest that microseismicity can be used to identify the orientation of active fractures; define regions of relatively high and low stress, and those most likely to host a rockburst; determine the role of local stress on observed shear failures; and identify the path of stress transfer associated with the remote triggering of rockbursts. Additionally, the conditions leading to rock-bursts can be characterized by a significant increase in the clustering of microseismic events along the fault plane orientation of an impending event, and an increase in the effective stress levels. It is concluded that the analysis of microseismicity provides the means for remotely monitoring rock mass behaviour as a result of mining."

Jan 1, 1997

By I. Nakatsugawa

Chemical conversion coating is a process to create thin oxide/hydroxide film containing several inorganic/organic compounds by way of chemical deposition reaction. In case of the application to Mg mobile electronic housings, the film should possess a good electric conductivity while keeping adequate corrosion resistance and working as a paint base. The use of toxic/hazardous chemicals is strictly prohibited from the environmental aspects. This paper describes the recent trend of conversion coating used for Mg electronic housings and analyzes critically from the point of surface technology. The importance of cleaning process and understanding of surface microstructure are particularly emphasized with several experimental results.

Jan 1, 2006

By A. L. Mular

This paper provides a worthwhile contribution to the knowledge needed for calculating and using mathematical models of grinding circuits. The computer search algorithm proposed should remove much of the guesswork as well as reduce computer processing costs and improve the accuracy of estimated parameter values for grinding mill models.

Jan 1, 1970

By Francis Wm. Gray

The preparation of a paper read before this Society in 1927 on Undersea Mining led to representations to the Deputy Minister of Mines at Ottawa, Dr. Chas. Camsell, and to the Director of the Geological Survey and the Director of the Mines Branch, which resulted in the undertaking by these bodies of a geological, physical, and chemical survey of the Sydney coalfield, combined with revision of the geological maps, on all of which much progress has been made. Preliminary studies revealed the necessity for a new base-map on a scale that would permit the representation of the whole coalfield from cape Dauphin to Mira bay on one sheet, and in the making of this map the Geodetic and Topographical Surveys have collaborated, with the assistance of airplane surveys for filling-in of detail. The new map will show all the data accumulated by 50 years of active mining and will show also the extent of mine workings, with level-contours under the sea. Dr. W. A. Bell, of the Geological Survey, has, over a number of seasons, studied in the field the historical geology with the purpose of elucidating the sequence of earth movements that have determined the structure of the coalfields, especially those that have governed the course and extent of the complementary folds that traverse the Sydney coalfield. Dr. B. R. MacKay, of the Survey, and the officers of the Fuel Testing Laboratories at Ottawa have made exhaustive studies of the Phalen seam, chemical and microscopic, intended to elucidate the conditions under which this seam was deposited, and some very interesting conclusions have been reached.

Jan 1, 1934

By William M. Luff

This paper outlines the regional geology and history of the area, and summarizes the stratigraphy, structure and geology of the Brunswick No. 12 mine area. The Brunswick No. 12 deposit is a stratiform massive sulphide body. It occurs in rocks of the Tetagouche Group, which is believed to range in age from Lower to Middle Ordovician. The stratigraphic sequence, including the stratiform orebody, in ascending order consists of older metasedimentary rocks, augen schist, metasediments, augen. schist, footwall metasediments, the -massive sulphide body, iron formation, hanging-wall metasediments, siliceous tuff, basic volcanic rocks , basic iron formation and a porphyry dyke. This sequence is similar to that at some other deposits in the area. Four phases of structural deformation are known to be present in the Brunswick No. 12 mine area. The first deformation folds (F1 ) and associated faulting are the most important factors in determining the distribution of the massive sulphides. This deformation has resulted in the massive sulphides being separated into four zones: the Main Zone, the West Zone, the East Zone and the V-2 Zone. Brunswick Mining and Smelting Corporation Limited is actively mining, developing and exploring the deposit.

Jan 1, 1977

By S. Banisi, A. Haji-Zadeh, A. R. Hasankhoei, M. Maleki-Moghaddam

At the concentration plant of the Gol-E-Gohar Iron Ore Company (Iran) three 9m × 2.05m AG (Autogenous) mills (fixed speed) are used in parallel in a dry operation. The test works conducted in a scale down mill with a diameter of 1m indicated that conventionally used "deflector" type liners did not provide efficient environment for grinding. In this research, to improve the grinding efficiency, a new design using low profile end liners incorporating radial ribs of proper height was investigated. In order to determine an appropriate liner design at different operating conditions, a 100cm×10.8cm model mill was used for experimentation. The special design of model mill made it possible to increase the radial ribs height in steps of 6mm up to 18.5mm. The transparent end of the mill enabled accurate trajectory determination by image analysis. The results indicated that the new lower height profile deflectors and 15.5mm-height (14.5cm in industrial scale) radial ribs improved the mill performance while avoiding excessive pressure drop across the mill and wear on the liner. The image analysis showed that the use of new liners increased the distribution of coarse particles across the mill cross section from 28% to 35%. A new liner design was proposed by decreasing the number of liners in each slice from 5 to 4 pieces. The thickness of the inner head liners reduced from 45cm to 30cm and the outer deflector liners replaced by radial ribs. The distance between the feed and discharge inner head liners increased from the original 115cm to 145cm which increased the effective length of the mill by 26%. The new design reduced the weight and volume of end liners by 9% and 23%, respectively. It was predicted that the new liners design increases the mill throughput by 10% and reduces the metal consumption by 20%.

Jan 1, 2016

Several inorganic reagents and organic polymers were tested as depressants in the single mineral flotation of ultrafine iron oxide and hydroxylapatite with Dowfroth 250 as a frother. It was observed that the inorganic reagents and the low molecular weight polymers generally caused dispersion of the ultrafine particles, and consequently their recovery into froth products more or less equaled the recovery of water. On the other hand, the high molecular weight polymers caused different degrees of flocculation of the ultrafine particles, and their recoveries were much lower than the recovery of water. These observations pointed to a need to re-define flotation depressants in fine particle flotation. The traditional definition of a flotation depressant, i.e., to make particle surfaces hydrophilic by forming a hydrophilic film and/or by removing collector and activator coatings, is sufficient for relatively coarse particles. However, to prevent fine and ultrafine particles from floating, a successful depressant should not only make the particles hydrophilic, but also enlarge the particle sizes so that they do not enter the froth product by mechanical entrainment. Polymeric depressants are ideal for these purposes. The different schemes to use polymeric depressants in the selective flotation of fine and ultrafine particles were discussed These schemes involve the integration of the polymeric depressants into other size enlargement processes such as shear flocculation, oil agglomeration, etc., for hydrophobic particles.

Jan 1, 2004

By D. H. Ryan, B. Abdul, M. Pernechele, E. Asselin

Hydrometallurgical processing of sulphide concentrates at medium temperature (150°C) produces residues, which contain valuable metals (Cu, Ni) as well as sulphur and iron bearing minerals and phases. The low solubility of iron during the medium temperature processing of sulphide ores can favour the formation of poorly crystalline, nano-scale iron oxide/oxyhydroxide phases. A better understanding of the formation and structure of these iron precipitates may elucidate key factors that would ultimately result in lower valuable metal losses and more stable leach residues. Residues from two medium temperature leach processes were characterized by Mössbauer Spectroscopy. Some portions of the Mössbauer Spectrum were suspected to be linked to jarosite but could not be positively identified as such. There was a broad range of disorder and substitution present in the material and solely attributing it to jarosite proved difficult. Various synthetic jarosites with Cu substitution were precipitated for Mössbauer analysis. These were then characterized by Quantitative X-Ray Diffraction (QXRD), Scanning Electron Microscopy (SEM), Inductively Coupled Plasma Mass Spectroscopy (ICP-MS) and Mössbauer Spectroscopy. The Mössbauer Spectra of the synthetic jarosites is compared with that of the residues from medium temperature (150°C) sulphide concentrate leaching.

Jan 1, 2014

By Angus D. Campbell

"IntroductionThe subject assigned to me tonight gives unlimited scope. The material available is so voluminous and leads into so many ramifications, and the memories of the Camp are so vivid and treasured, that it is difficult to decide just what to use. Then, too, the geologists are the story-tellers of our tribe - I am only a hard rock miner.Members of the Cobalt Branch and Cobalters everywhere will agree without question that this Cobalt camp has been the greatest of all influences on Canadian mining. To those who do not know Cobalt, our opinion may seem prejudiced and our statement exaggerated.Be that as it may, discussion on this subject can be profitable, since it is worthwhile now and then to think on 'whence we came' and 'where we are going'.In the revival of interest in the Cobalt camp, we hope our guests may feel some of the old Cobalt Spirit, which has become the Spirit of the North.Visitors may even, while here, catch a glimpse of that whimsical little guardian spirit of the camp - the original goblin, the Kobold - for which Cobalt was named.While Kobold brings that good luck which plays so important a part in mining, he can have his evil moments, as in his original German home. There, when he made the silver disappear from their good ore, they cursed the grey ore, calling it Kobold.Although this little goblin bas frequently upset our best mining plans and geological calculations, be has played the game as well. He placed •some silver on the surface, and when he hid ~t at depth he left dues .for its finding. He has rewarded many who sought his treasure and is still rewarding those who have persevered and had faith in him. t:lis influence and that of Cobalt camp has probably had a greater influence on your work and your mining areas than you realize"

Jan 1, 1950

By R. H. Schonewille

One of the many challenges in developing new metallurgical processes is choosing the best option for validating process design parameters and establishing the process operating window. Historically this has been achieved by constructing pilot or demonstration plants of considerable size and complexity, to enable integrated operation of all key process units for a significant duration. While this would appear to be the best option for minimizing technical risk, it is often impractical from a perspective of cost, schedule, resources or bulk sample acquisition. Such an undertaking can even provide a false sense of security, as the optics of running a complete scaled-down version of a commercial plant suggest a high level of process understanding, regardless of the challenges encountered during operation. Xstrata Nickel has undertaken numerous process development and improvement projects over the past 15 years to support green field project development and continuous improvement in existing operations. The approaches used have included; computer simulation, cold flow modeling, construction of pilot test units in third party facilities, commercial plant referencing and the more conventional construction of integrated test plants. Regardless of the strategy employed, the keys to success have included; managing stakeholder expectations, involving the commercial plant design engineers in the planning stage, anticipating subsequent data and sample requirements and most importantly, constructing and operating complex demonstration plants only as a last resort. This paper provides examples of various process development approaches used by Xstrata Nickel and discusses the rationale specific to each project.

Jan 1, 2011