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By G. Barr

"The Polymetallic Twin Metals Project deposits in Northern Minnesota are being developed by Twin Metals Minnesota. Amongst the flowsheet alternatives being examined at a prefeasibility study level is one involving flotation of a bulk concentrate followed by high temperature autoclaving of the concentrate using the PlatsolTM Process to solubilize all the valuable metals in the concentrate (Cu, Ni, Pt, Pd and Au). Autoclave operating conditions have been established in which recoveries of all the pay metals are in the 92 to 99% range, and the autoclave residence time has been reduced to an hour. The stability of the precious metals in solution after autoclaving has been assessed, as well as the impact of internally recycling process liquors to the feed to the autoclave.INTRODUCTIONPlatinum group metals (PGMs; platinum, palladium, rhodium, ruthenium, iridium and osmium) are traditionally recovered from their ores by production of a high-grade concentrate by flotation and/or gravity concentration followed by smelting of the concentrate. Concentrates are smelted to remove nonsulphide minerals and converted to remove iron and sulphur. The resulting high PGM grade matte is processed hydrometallurgically to leach the base metals, leaving a residue with a very high grade (20-40%) PGM concentrate for final refining to individual PGMs. Due to the complexity of this process and its high capital cost, this process can only be applied economically to high grade PGM ores. Lower grade PGM concentrates might be accepted as copper and nickel concentrates but may not yield attractive payment terms for the PGMs. The mineralized Duluth Gabbro region of Minnesota hosts several low grade base and PGM deposits and Twin Metals Minnesota is working to develop the Twin Metals Project deposits. Earlier studies at both pre-feasibility and feasibility level, by other mining companies, have failed to yield an economically viable project based on the traditional process. It is possible to produce a saleable copper concentrate from these ores, but economic recovery of nickel and PGMs into saleable concentrates proved elusive.In the late 1990’s and early 2000’s the Platsol™ process was developed at SGS in Lakefield, Ontario (at the time Lakefield Research Limited) for the NorthMet deposit (also within the Duluth Gabbro) owned by PolyMet Mining. The process developed was a high temperature chloride-assisted pressure oxidation process capable of dissolving simultaneously the base metals (Cu, Ni, Co, Zn), gold and the PGMs."

Jan 1, 2012

By J. W. Reynolds

Introduction The Sullivan mine, at Kimberley, B.C., is the principal source of ore for the Consolidated Mining and Smelting Company of Canada, Limited. Current production amounts to about 2,500,000 tons of lead-zinc ore a year. With approximately 1,600,000 feet of percussion drilling and 700,000 feet of diamond drilling being carried on each year, any improvements in drilling practice are important. Testing of new equipment and drill bits is a major function of the Testing Department at the mine. Tungsten carbide bits have been the subject of many tests since 1947 and have been used in operations since 1948. This paper details with the methods of testing and gives comparative data on performance and costs for tungsten carbide bits as compared to steel bits. Operational use of tungsten carbide bits started in April, 1948, and the extent of application has increased considerably since that time. The scale of employment is illustrated in Table I, which also shows other statistics on the use of carbide bits. Up to the present time eighteen types of carbide bits or tipped steel, as made by six different manufacturers, have been tested. In general, one supplier's bits have been used in operations, but some large-scale operational tests have been carried out with other types. The types tried are shown in Table II. To date they have been, the subject of 33 tests, covering the destruction of 804 bits over an observed footage of 42,586 feet.

Jan 1, 1951

By Charles T. Harper

The uranium deposits discovered by Amok (Canada) Ltd. in the Cluff Lake area of north western Saskatchewan occur at or near the southern edge of the uplifted basement core of the Carswell circular structure. Two types of mineralization, distinguishable, by their geological and structural setting and mineral paragenesis, have been recognized. The N-Claude type is characterized by a relatively simple mineral assemblage, consisting of uraninite or pitchblende with coffinite, and is accompanied by variable amounts of graphite and organic matter, and Fe, Cu, Pb and Mo sulphides. Both N and Claude orebodies occur within quartzofeldspathic gneisses of the basement core. On the other hand, the D-type ore has a complex mineral assemblage consisting of: uraninite, pitchblende, thucholite and coffinite, along with native gold and selenium; gold tellurides, and selenides of Pb, Bi, Ni and Co; sulphides of Fe, Cu and Pb; and organic matter. The D orebody occurs within carbonaceous shales at the base of the Athabasca Formation as well as in fault zones in regolithic quartzo feldspathic gneisses above the inverted unconformity. An age of 1050 m.y., which is consistent with a period (circa 1200-1000 m.y.) of widespread hydrothermal activity and uranium mineralization or reworking within and adjacent to the Athabasca Basin, has been obtained from uranium mineralization from the D orebody. Later reworking (circa470 m.y.) of the mineralization occurred at the intersection of older mineralized shear zones with radial faults produced during meteorite impact.

Jan 1, 1978

By A. A. Ruitenberg, L. R. Fyffe

"This paper compares several distinct types of mineral deposits associated with different families of granitoid rocks in the New Brunswick Appalachians. Porphyry copper deposit s are associated with late-stage differentiates of Lower to Middle Devonian I-type igneous complexes. Contact metasomatic deposits were formed where these plutons intrude carbonate rocks and they gave rise to vein deposits in fracture zones near wrench faults. The I-type granitoids were emplaced mainly in areas of thin continental crust and locally along prominent faults in areas of thick continental crust.In contrast, tin-tungsten-molybdenum-bearing greisen deposits and skarns, and antimony-bearing quartz veins are associated with predominantly S-stype granitoid complexes ranging in age from Middle Devonian to early Carboniferous. The mineral deposits occur within or along the contacts of very fractionated (specialized) late phases of these intrusive complexes, which are characterized by high K2O/Na2O, Rb/Sr and Rb/Ba, and low Fe, Mg, Zr and Ti contents. These specialized granitoids are in a large wrench fault zone that cuts across thick continental crust in southwestern and central New Brunswick.IntroductionA great variety of igneous intrusions and subvolcanic stocks were emplaced in the New Brunswick Appalachians during the latter stages of and immediately after the Acadian Orogeny (late Lower to Middle Devonian) and during the subsequent Hercynian Orogeny (Carboniferous). The presence or absence and characteristics of mineral deposits associated with these intrusions reflect the level of intrusion, the composition of the associated igneous rocks and the composition of the invaded sequences.Nickel-copper sulphide deposits occur in mafic intrusions in the St. Stephen area of the southwestern Magaguadavic - St. Croix Zone and in the Goodwin Lake area of the northeastern Mirarnichi Zone. Contact metasomatic and vein-type copper-rich base metal sulphide deposits and porphyry copper deposits with or without molybdenum are related mainly to high-level granitoid stocks of intermediate composition in the Matapedia-Tobique and northwest Miramichi zones. Tintungsten - molybdenum deposits with or without base metal sulphide minerals and antimony-uranium deposits are mainly associated with Upper Devonian and Lower Carboniferous biotite-muscovite granites and related 'subvolcanic intrusions that occur in an arc-shaped belt extending from the southwestern Magagaudavic - St. Croix Zone into the central Mirarnichi Zone."

Jan 1, 1982

By Brian Hart, Zhe Chen, Liuyin Xia, Mana Pourdasht, Stamen Dimov

"Gold losses related to carbonaceous matter (CM) during processing are a significant problem in the gold processing industry. Inherent CM in gold ores can behave similarly to activated carbon in its ability to adsorb gold cyanide. This phenomenon is termed preg-robbing as the surface adsorbed gold cannot, for the most part, be recovered. Research has identified that gold adsorption by inherent CM is linked to the specific surface area, pore structure, degree of C disorder and surface functional groups. One of the strategies to inhibit CM preg-robbing prior to leaching is a chemical oxidation; a process linked to modification of the surface functionality. In this study, the variability in gold cyanide adsorption due to oxidation with different reagents has been investigated. Variability in gold cyanide adsorption by CM is examined in relation to structural and surface modifications using TOF-SIMS, XPS and Raman spectroscopy.INTRODUCTION A major obstacle for effective gold recovery during carbon in leach (CIL) or carbon in pulp (CIP) processes carbonaceous gold ores is the presence of carbonaceous matter (c-matter) which has the ability to adsorb, or preg-rob gold from the cyanide leach solution. It can be responsible for poor recoveries as the carbonaceous materials (CMs) within the ore competes with activated carbon used during the leaching and adsorption phase of processing (Cay, 2014). Preg-robbing capacity can vary significantly with mild preg-robbing ores showing absorption capacities of less than 1 g Au/t ore, while severe preg-robbing ores may have CM with the capacity to preg-rob more than 500 g Au/t ore (Dunne, 2007). Research by a number of groups have shown that the degree of C disorder has some influence on the ability of the carbonaceous material to adsorb Au(CN)2- (Miller et al, 2005, Helm et al, 2009, Hart et al, 2010). It is also apparent the adsorption characteristics of carbonaceous material is affected by changes in surface chemistry (Dimov, 2016). Various treatment including; flotation to remove the carbonaceous material (Wills, 2010), addition of surface blinding agents (for example kerosene) to passivate or blanket the carbon surfaces (Dimov, 2016), addition of strong adsorbents (eg. activated carbon or resin) to compete with the carbonaceous material and passivation or surface coating by oxidation (pressure, roasting, chlorination and biological oxidation), have been employed prior to leaching in an attempt to minimize the gold losses (Dunne, 2013)."

Jan 1, 2017

By L. K. Smith, C. R. May, K. R. Schrag, H. Buchwald

"New contracts for 65 million long tons of coking coal valued at over $900 million, over the next 15 years, herald the rebirth of Alberta's coal industry. The industry is optimistic that export orders may reach 20 million tons per annum by the mid-1970's. Coal will be extracted from underground and surface mines and it is expected that the total labour force will double from the present 1,200 men within the next two years. Ali the health hazards associated with coal mining are likely to be encountered and it will be incombent on the Provincial Department of Health to specify the standards which relate to health and environment where no such standards have previously existed. This paper examines some of the problems which are being encountered in setting up an environmental health program and reviews the practicability of environmental monitoring methods, with special reference to respirable dust."

Jan 1, 1969

By Neil Campbell

"The gently-dipping Devonian dolomite beds south of Great Slave lake in northern Canada are nearly every-where concealed by a cover of glacial drift and muskeg. Nevertheless, in 1898 or earlier, four small outcropping areas of dolomite, richly mineralized with lead and zinc sulphides, were discovered. Exploration work performed here up to the end of 1930, included intensive trenching and drilling of the showings, together with mapping and wide-spaced drilling in the surrounding region. This work proved that the discoveries are isolated pockets of mineralization much too small to be commercially valuable by themselves. No evidence of orebodies elsewhere was reported.Meanwhile, mapping by the G.S.C. in the Shield far to the east disclosed major Precambrian faults, some of which can be projected southwesterly (under a cover of Paleozoic sediments) to the vicinity of Pine Point. During the period from 1940 to 1947, consideration was given, by The Consolidated Mining and Smelting Company Ltd., to evidence of a theoretical possibility that, although apparently dormant in Paleozoic times, these faults may have provided a structural control and a source of ore-bearing solutions in some post-Devonian period. From this, it was postulated that the breaks might have created, in the overlying dolomite, a linear array of orebodies concealed by overburden but lying in a belt of considerable length and in a position predictable within practical limits. A program of drilling designed to test and exploit this specific concept was conducted from 1948 to 1955.he drilling within the new, theoretically-defined search area resulted in the discovery of many lead-zinc ore-bodies, none of which was exposed at the surface. Some of these are large and (as indicated by 1965 production records) very rich. They are situated 1 to several miles distant from, and apparently not connected to, the earlier-known surface discoveries. The drilling also disclosed that the ore, which consists of disseminated sphalerite and galena replacements together with colloform sphalerite and coarse galena cavity fillings, occurs mainly at certain stratigraphic horizons within a large, coarsely-recrystallized dolomite barrier reef. Considerable fracturing and folding was found. It has been suggested that reef development was influenced by post-Precambrian tectonic movements associated with the old faults in the basement complex. The ore may have been deposited by solutions moving from distant sources to favourable structural and chemical environments in or related to the reef.In more recent exploration performed in the course of preparing for mining production, the rate of ore discovery within the same general geological context has been greatly accelerated by the use of new geophysical techniques and drilling equipment. Reserves of 21.5 million tons, averaging 4 per cent lead and 7.2 per cent zinc, were reported in 1965, and production from open pits at the rate of approximately 248,000 tons of concentrates per year is in progress"

Jan 1, 1966

By W. F. McDermott

This paper covers the development, construction and operation of a 53-mile slurry pipeline operating in Tasmania, Australia. Special development techniques are discussed, as well as the operation of this line and its impact on transportation from remote areas.

Jan 1, 1970

By Loris S. Russell

THE plains of southern Alberta constitute one of the classic areas of geological investigation in Canada, for it was here in 1874, and in 1881 to 1883, that George Mercer Dawson (1, 2, 3) made the pioneer observations that are basic to all subsequent work on the interior plains of Canada. Dawson's work was extended eastward by R. G. McConnell ( 4) and northward by J. B. Tyrrell( 5) , but it remained. for D. B. Dowling to re-examine Dawson's Bow and Belly River Area and to make certain necessary revisions in the stratigraphical system of his predecessor. In 1917, Dowling published his memoir, The Southern Plains of Alberta( 6) , which remained for over ten years the last word on the stratigraphy and structure of the area described. It is generally conceded that Dowling's work made known the existence of a great artesian basin beneath the semi-arid plains of southeastern Alberta. In addition, his structural studies greatly stimulated the search for natural gas and petroleum. The most recent general publications on this area by the Geological Survey are based on the field work of M. Y. Williams, E. J. Whittaker, W. S. Dyer, and P. S. Warren, between the years 1923 and 1926. Their results were embodied in the Calgary Sheet (7) and the memoir, Geology of Southern Alberta and Southwestern Saskatchewan (8). By this time, the number of geologists working in Alberta in the development of the petroleum and natural gas industries had become large, and in 1931 the Alberta Association of Petroleum Geologist~ offered the Donaldson Bogart Dowling Memorial Symposium on Stratigraphy of Southern Alberta( 9) , a most valuable series of papers descriptive both of the ,surface stratigraphy and that observed in the well records.

Jan 1, 1937

By H. Wilton Clark

"IntroductionTHE CANADIAN use of short-period delay-action detonators in coal shooting has been carried on for about two years, mostly in British Columbia, and this is a preliminary report on progress to date. Entire coal faces are being shot successfully with one application of electric current.The electric blasting cap came into use about the beginning of the century. The low-tension electric cap, the type most commonly used, consists essentially of a metal tube containing an initiating explosive. Two wires lead into the end of the cap and are connected inside the cap with a short 'bridge wire .of very high resistance. This •bridge wire is buried in a match-head of a readily ignitable powder composition. When current goes through the lead wires, the bridge wire becomes extremely hot and sets• off the match-head which, in turn, ignites the powder just below it in the tube. This explosion sets off the main charge of explosive. Thus, by connecting a group of caps to a source of electric .current, a number of charges could be exploded simultaneously. This immediately became of great value to mine and quarry operators. Explosives could now be used to break up large masses of material at one time, as against the older, slow method .of blasting small amounts with single charges.The next step was to develop a delay detonator which would allow charges of explosive to fire one after the other, one or two seconds apart. Such detonators allowed first blasts to relieve some rock burden before the next charge fired, giving the second charge an easier task in forcing out more rock, and so on for the rest of the series of charges."

Jan 1, 1953

By D. Komljenovic, E. Lafontaine, J. Paraszczak

Availability of the production equipment used in underground mines has a substantial impact on production costs and, thus, on mine profitability. Appropriate collection of pertinent data and information, as well as use of adequate performance measures and their analyses, can help mine operators identify cost-effective opportunities to improve equipment availability. This paper presents study results aimed at reviewing and analyzing means and measures used to quantify equipment availability and its contributing factors (reliability, maintainability and maintenance support) in several Canadian underground mines. It overviews sources, as well as quality and quantity of relevant data and information, and examines performance measures and their definitions, as applied to surveyed mines. Problems concerning data acquisition and meaningfulness of the performance measures are discussed. The paper concludes with some suggestions and recommendations concerning several aspects of equipment availability assessment. Evidence suggests that the latter may become a more useful tool for mine operators in their efforts to reduce production cost.

Jan 1, 2008

By P. P. Rosario

A research project was conducted at the University of British Columbia (UBC) resulting in the development and evaluation of a novel comminution circuit incorporating autogenous grinding and parallel trains of cone crushers and high-pressure grinding rolls (HPGR). A primary driver for the circuit was to treat ore from deposits with clay and variable hardness. This paper summarizes the unique pilot-plant test program that was developed as a basis for experimental simulation and lists the main findings of the research, including the circuit?s potential operational cost savings compared to a conventional SAG circuit.

Jan 1, 2012

By G. K. Lee, E. R. Mitchell

Designers of combustion processes may select aerodynamic conditions which produce only superfine fly ash. Although it is not usually anticipated that this will create a problem, such as has been found to agglomerate in high-velocity gas streams, to plug mechanical dust separators in a short time, and to contribute to atmospheric pollution. The problem is a fundamental one, and may be approached in several ways. The authors, in the course of their combustion research program, had occasion to examine the agglomeration of ash, ranging from sub-micron to 17 microns in size, produced in a (coal and oil) dual-fuel-fired steam generator. Several theories, supported by extensive laboratory studies, have provided some understanding of a probable mechanism of agglomeration. As a result, certain precautions are suggested in the design and selection of combustion processes and equipment.

Jan 1, 1962

By J. B. De Hart

This paper has been confined to the consideration of the working of thick seams, from six feet to sixteen feet, which are pitching at about thirty degrees to the horizontal. The discussion has been limited to these set conditions because they are the ones of commonest occurrence in the Southern Alberta bituminous coal district, because, from the point of view of safety, thin seams are more easily worked, and because a discussion of all the possible combinations of thick and thin seams pitching at angles varying from zero to ninety degrees with the horizontal would involve a task impossible in the time available. It has been assumed that the mine makes gas freely and that the coal is friable and tends to make inflammable dust which is highly explosive. Since the problem requires the taking into account means of maintaining a high proportion of lump coal, it is further assumed that lump coal commands a price considerably higher than the price which can be obtained for run-of-mine or for slack coal. Figure 1, tabulating the various factors which must be considered and their relation to each other, indicates diagrammatically the complexity of the problem. Any method of working becomes divided into two distinct components, the active workings of the mine and the old abandoned workings. While these are in a measure distinct, they are nevertheless inter-related, as shown in the diagram.

Jan 1, 1930

By Ian R. Muirhead

Over the past year or so, a number of mining companies have been meeting to examine the role of research in surface mining and, in particular, how to establish a collaborative research effort for the surface mining industry. A review has been completed which has identified the topics that are of interest to the surface mining companies for undertaking collaborative research. This has identified key subject areas such as Operations & Equipment; Maintenance; Environment & Reclamation; and Stability. Specific research projects for the initial research effort have been selected which include Wireless Data Communications, Analysis and Management; Application of GPS in Mining; and Tires for Heavy Haulers. In addition, attention has also been focussed on finding a suitable low cost, but effective, organization to coordinate and manage the collaborative research. The recently formed CONRAD Organization (Canadian Oilsands Network for Research and Development) appears to be a suitable candidate and discussions are ongoing with that group. This paper provides a summary of the review of surface mining research needs and of the status of the establishment of a collaborative research body for surface mining.

Jan 1, 1996

By C. L. Emery, A. V. Corlett

"The stress equilibrium is disturbed in a body of rock by a mine opening and is restored by a redistribution of the stresses around the opening. The pattern of the redistribution of unilateral stress around an opening has been established by mathematical analysis and photoelastic measurements. The pattern for multilateral stress is found by superimposition of unilateral fields. The mathematical analysts do not use the elastic moduli as parameters and they are not significant in photoelastic work. The medium is isotropic. The concept of unilateral stress from vertical loading and the classical pattern of its stress distribution around openings does not explain commonly observed failures around the perimeters of mine openings. They show evidence of compression where tension is postulated.When it is recognized that few minerals and perhaps no rocks are Hooke Solids, most rocks must be St. Venant Solids. The components have varying degrees of elasticity and viscosity. The assembly will be-have elastically to rupture under shock loading, but when loaded short of rupture will adjust viscously to equilibrium. Similarly, the highly elastic components may initiate rupture before equilibrium can be established when stress is instantaneously relieved. Polycrystalline adjustments may produce permanent deformation. The mechanics of consolidation, especially in sedimentary deposits, ac-quire a stress component normal to the direction of compaction which can exceed that of the loading. It is one source of prestress. There are others. The principles of prestress design are based on the normal beam reactions, modified by a built-in compression in the lower chord. When the beam is loaded to design limits, the lower chord retains some compression and the whole beam depth is effective in compression. Some of the . common evidences of failure in compression over a mine opening can be duplicated in a prestressed experimental model.When the triaxial stress pattern is recognized and suitable measuring techniques are devised, mine design can be done on a rational basis."

Jan 1, 1959

By Arthur Barnes, Mika Muinonen, M. J. Lavigne

"The carbothermic reduction of chromite ore to produce high carbon ferrochromium is among the most energy intensive metal extraction processes performed, due not only to the highly endothermic nature of the reduction reactions but also the very high operating temperatures required for the smelting operation to separate the chrome-containing alloy from the discard slag.KWG Resources and XPS have collaborated over the last 3 years in developing a patented (Winter) processing alternative to the traditional smelting operation in which all processing takes place in the solid state at temperatures many hundreds of degrees lower than those required for liquid processing. Amongst the attractions of the process are much lower capital costs, as well as reduced operating costs, particularly of energy.A techno-economic study on the new process identifies a reduction in overall energy consumption of 70% against conventional processing and approximately 40% lower than the current best practice. By utilising more natural gas than coal based energy sources, the KWG process is able to show an overall 50% reduction in greenhouse gas emissions compared with the most energy efficient current practice. The impact of the new process on future processing is therefore regarded as highly significant, with global energy reductions equivalent to the effect of completely eliminating energy demand from a country the size of Italy.The study concluded that the potential for this process to completely revolutionise the global ferrochrome industry should not be underestimated. Its impact reaches far beyond exploitation of a regional natural resource."

Jan 1, 2015

By Rajiv Kalra

This paper reviews the following aspects of the world?s largest manufactured Grinding Mill?s in terms of diameter and power, along with the world?s biggest shop assembly and trial run of the mills delivered to Sino Iron Magnetite Project in Australia. 1. An overview of the basic flow sheet of the Sino Iron (Magnetite) Project located in Australia 2. An overview of in-house designed CITIC Heavy Industries 12.2 m (40ft) F x 11 m(36ft) LG ? 28MW AG mills including FEA and major components 3. In-house manufacturing at CITIC-HIC work in Luoyang China of all major components for 6 off Ø12.2 m(40ft) AG mills and 6 off Ø7.9 m(26ft) x 13.6 m(44.6ft) LG-2 x 7.8 MW Ball Mills 4. Major aspects of design and preparation of the biggest shop trial run of Ø7.9 m(26ft) x 13.6 m(44.6ft) LG Ball Mill witnessed by international EPCM?s and clients in July 2009. 5. Major aspects of one piece assembly of 1300 tonne rotating element of the Ø12.2 m(40ft) x 11 m(36ft) LG AG Mill and Ø7.9 m F (26) x 13.6 m(44.6ft) LG Ball Mill at the port of the export China and transport to Australian Port and then to site. 6. An insight to unique installation methods used for Ø12.2 m(40ft) and Ø7.9 m(26ft) rotating element lifting on the mill foundation in one piece assemblies. 7. CITIC Heavy Industries present capability for in house design and manufacture of Grinding Mills up to Ø13.7 m (45 ft) with 35 MW Gearless drives and Ø12.2 m(40ft) with 2 x 10 MW Geared Mill drives

Jan 1, 2012

By Raju S. Sagi

This paper deals primarily with the different types of drilling methods used by the Iron. Ore Company of Canada for sampling the soft and friable hematite-limonite (secondary) iron ore deposits found in the Scheferville area. The problems associated with drilling, sampling, sample handling and sample preparation. for chemical analysis of these ores are discussed. Systematic evaluation of the various drilling methods led to the selection of an integrated drilling system. This system consists of a rotary dual- tube - reverse-circulation drill, with tricone bit, polymer mud and mechanical sample splitter, The historic al development of this drilling system is described in detail, as are the equipment , sample flow and quality control checks carried out to obtain representative samples. This integrated drilling and sampling system has been used satisfactorily on a routine basis for determining the grade and tonnage of ore for the various deposits for the last five years (1972-76) in the Schefferville area.

Jan 1, 1977

Orebodies of the Renison Bell - Mt. Bischoff tinfield in Tasmania are stratabound, conformable lenses of massive cassiterite-bearing pyrrhotite, with underlying discordant, fault-fracture-controlled and more siliceous ore. The deposits occur in eugeosynclinal, trough-deposited sedimentary and mafic volcanic rocks which are stratigraphically equivalent to diff erentiated volcanic rocks that contain volcanogenic massive base metal sulphide deposits in a parallel arc to the east. Textures of the massive pyrrhotite ore suggest that it has undergone metamorphic recrystallization. Although the massive ore contains both monoclinic and hexagonal pyrrhotite, a study of a few samples from one orebody suggests that their distribution is stratigraphically controlled, with the monoclinic variety abundant only at the base. The distribution pattern of rare-earth elements in massive ore is similar to that of volcanogenic massive base metal sulphides in New Brunswick, and suggests that mixing of sea water with exhalative hydrothermal brines occurred during ore deposition. Tin is a common accessory element in many volcanogenic massive base metal sulphide deposits providing strong evidence that it, too, is transported and deposited by volcanic affiliated hydrothermal brines. Sedimentary rocks containing the massive orebodies are fine grained, thinly laminated, compositionally banded and of mixed chemical sedimentary-tuffaceous origin. They include finely recrystallized chert, carbonate-rich and pyritic varieties; and soft sediment deformation structures in these rocks suggest that dense sulphides deformed underlying, less dense chert prior to lithification. Close to ore the chert becomes massive and coarsely recrystallized, as does the carbonate, which is here strongly enriched in Fe and Mn. Apatite is present in pyritic, cherty and carbonate-rich beds and in the ore itself, in all of which it shows a similar pattern of rare-earth element distribution, suggesting that it is of marine sedimentary origin. These deposits have traditionally been considered as epigenetic replacements of favourable carbonate horizons by hydro thermal flu ids derived from later Devonian porphyritic intrusions. Some of these intrusions have associated tinbearing greisens. The above relationships suggest, alternatively, that, like massive base metal sulphides, the tin deposits were of original syn-sedimentary origin. Circulating hydrothermal brines generated during early Cambrian eugeosynclinal subsidence and tectonism rose through steep fault-fractures, there giving rise to the discordant orebodies, and were discharged on the sea floor, where the massive pyrrhotite lenses were precipitated with the associated cherts and carbonates. In some places, Devonian intrusions remobilized the earlier deposits, forming greisens and newepigenetic veins. Finally , the geologic selling of these deposits, in trough deposited sedimentary and mafic volcanic rocks, suggests another favourable environment for massive sulphide exploration which is quite different from the domal felsic volcanic environment so heavily favoured currently in North America

Jan 1, 1979