Development of the Twin Metals Minnesota Flowsheet Incorporating the Platsol™ Process

"The Polymetallic Twin Metals Project deposits in Northern Minnesota are being developed by Twin Metals Minnesota. Amongst the flowsheet alternatives being examined at a prefeasibility study level is one involving flotation of a bulk concentrate followed by high temperature autoclaving of the concentrate using the PlatsolTM Process to solubilize all the valuable metals in the concentrate (Cu, Ni, Pt, Pd and Au). Autoclave operating conditions have been established in which recoveries of all the pay metals are in the 92 to 99% range, and the autoclave residence time has been reduced to an hour. The stability of the precious metals in solution after autoclaving has been assessed, as well as the impact of internally recycling process liquors to the feed to the autoclave.INTRODUCTIONPlatinum group metals (PGMs; platinum, palladium, rhodium, ruthenium, iridium and osmium) are traditionally recovered from their ores by production of a high-grade concentrate by flotation and/or gravity concentration followed by smelting of the concentrate. Concentrates are smelted to remove nonsulphide minerals and converted to remove iron and sulphur. The resulting high PGM grade matte is processed hydrometallurgically to leach the base metals, leaving a residue with a very high grade (20-40%) PGM concentrate for final refining to individual PGMs. Due to the complexity of this process and its high capital cost, this process can only be applied economically to high grade PGM ores. Lower grade PGM concentrates might be accepted as copper and nickel concentrates but may not yield attractive payment terms for the PGMs. The mineralized Duluth Gabbro region of Minnesota hosts several low grade base and PGM deposits and Twin Metals Minnesota is working to develop the Twin Metals Project deposits. Earlier studies at both pre-feasibility and feasibility level, by other mining companies, have failed to yield an economically viable project based on the traditional process. It is possible to produce a saleable copper concentrate from these ores, but economic recovery of nickel and PGMs into saleable concentrates proved elusive.In the late 1990’s and early 2000’s the Platsol™ process was developed at SGS in Lakefield, Ontario (at the time Lakefield Research Limited) for the NorthMet deposit (also within the Duluth Gabbro) owned by PolyMet Mining. The process developed was a high temperature chloride-assisted pressure oxidation process capable of dissolving simultaneously the base metals (Cu, Ni, Co, Zn), gold and the PGMs."