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By M. Celikin, M. Isac, R. I. L. Guthrie, S. Ge

Horizontal Single Belt Casting (HSBC) is a near-net-shape casting process in which molten metal is directly cast into thin strips, at high cooling rates (order of several 100°C/s), with the potential for high volume, friction-free, continuous production of metal strips. This casting process was used in the present work to produce strips of Al-Mg alloys in the AA5000 series, with additions of Sc and Zr. Such aluminum alloys show exceptional potential as a structural material for transportation/aerospace applications. To demonstrate the suitability of the HSBC process to manufacture competitive strip products of Al-Mg-Sc-Zr, the mechanical properties and microstructures of the strips produced using the HSBC process were compared with conventionally cast products. The effects of annealing on the mechanical properties of the strip-cast Al-Mg-Sc-Zr alloys were also investigated.

Jan 1, 2014

By R. Glenn Madill

Western Canada is defined, for the purposes of this paper, as that part of the Dominion bounded approximately by the 95th and 141st meridians of longitude and the 49th and 80th parallels of latitude. It is comprised of Manitoba, Saskatchewan, Alberta, British Columbia, Yukon, and that portion of the Northwest Territories lying to the west of the 95th. meridian. The first magnetic observations made in Western Canada were in the interests of navigation by sea. Observations were made by Captain Middleton in Hudson bay at Churchill and York Factory in 1725, and along the Pacific coast by Captain Cook in 1778 and Captain Vancouver in 1792. The first systematic magnetic survey in Western Canada was made between 1819 and 1826 by Sir John Franklin in his widely distributed explorations. It is of interest to find that while the first magnetic declination observations made in Hudson bay and along the Pacific coast were purely in the interests of navigation, the next investigations, which were made in the Western Arctic, included measurements of inclination and force with those of declination. There was a valid reason for this more complete research into the magnetic field as the construction of declination charts depended on the position of the north magnetic pole. Halley promulgated a theory 1683 that " the globe of the Earth may be regarded as one great magnet, having four magnetic poles, two of them near each pole of the equator, and that in those parts of the world which lie near any of those magnetic poles the needle is chiefly governed thereby, the nearest pole being always predominate over the more remote" . The position of a magnetic pole may be defined as a point where the inclination is 90 degrees and the horizontal force zero. It is obvious that the position cannot be' defined by declination observations alone since, for some distance from the magnetic pole, .the horizontal force is too weak to give directive force sufficient to effect the pointing of a compass.

Jan 1, 1948

By T. Gerritsen, T. Plikas, K. Ochoa, M. Loveless, R. MacRosty, J. Reichart, R. Pula

Sidewall accretion in a smelting furnace plays an important role in furnace integrity as it provides protection to the sidewall cooling elements and thereby extends the furnace campaign life. The extreme thermal and mechanical stresses in the furnace and changes in the slag chemistry can cause the sidewall accretion to melt or break away decreasing the lining protecting the cooling elements. Thin accretion is highly undesirable as it increases the risk of exposing the cooling elements to the molten bath and in the worst case may lead to a failure. Therefore, monitoring the sidewall accretion on an operating furnace is extremely important to manage furnace integrity and to support safe furnace operation. Operators often generate estimates for sidewall accretion and refractory thickness using either copper cooler temperatures or heat load into the cooling water circuits. Multivariate statistical models, on the other hand, have the capability to consider all the process measurements simultaneously to provide a more reliable estimate. This paper describes the application of multivariate statistical models for sidewall integrity monitoring on a Flash Converting Furnace (FCF) and also discusses the online implementation of these models as the Sidewall Accretion Monitoring System. INTRODUCTION Rio Tinto’s Kennecott Utah Copper (KUC) smelter located near Salt Lake city, Utah operates a Flash Smelting Furnace (FSF) and a Flash Converting Furnace (FCF) to produce high-grade matte and blister copper respectively. Since the commissioning of smelter in 1995, several improvements were made to these furnaces to increase their efficiency and operational safety. At present, Kennecott smelter is known to be among the lowest-emission and highest energy recovery copper smelters in the world. Since the smelter start-up, Kennecott has invested in several advanced furnace monitoring practices to evaluate the integrity of the furnaces and improve their campaign life. An example is their temperature monitoring system installed for the smelting and converting furnaces, which continuously monitors the furnace sidewall temperatures and notifies the operators during temperature excursions. During an investigation on the converting furnace, it was revealed that there were frequent temperature excursions in the settler sidewall area towards the reaction shaft end of the furnace that caused significant furnace downtime. The reason for the sidewall temperature excursions was not clearly known.

Jan 1, 2019

By Robert D. Irvine

"Enhanced concern for protection of the environment and attendant actions by environ-mental regulatory authorities in support of this concern are influencing, to varying degrees, the demand and supply of a range of industrial minerals in a number of jurisdictions. These influences take a variety of forms.In this paper, the author seeks to delineate certain broad trends which are occurring relative to industrial minerals and the environment and then, through a series of examples, to outline opportunities, developments, and impacts respecting a number of industrial minerals produced and consumed in Canada and the United States."

Jan 1, 1996

"THE OTTAWA BRANCH, CIM, each year holds a symposium on a subject of topical interest. The symposium this year was on Canada's Offshore Mineral Resources, at which papers were presented by: Dr. Donald G. Crosby, chief, Resource Administration Di-vision, Department of Energy, Mines and Resources, Ottawa; John A. Beesley, head, Legal Division, Department of External Affairs, Ottawa; and David W. Smith, man-ager, offshore exploration and production, Shell Canada Limited, Calgary. Because of the interest which this topic holds for our members, and because of the wealth and significance of information presented, the three papers -representing the first comprehensive review of our offshore resources -are reproduced herewith. The opening remarks of the Chairman, Dr. F. K. North, Professor of Geology, Carleton University, are also recorded, together with a few of the questions asked by the large attending audience. The symposium was held February 13th, and was organized by Dr. W. M. Tupper, chairman of the Branch Program Commit-tee. Differences in the extent of the continental shelf will be noted in the papers. These differences are related to slightly different definitions of the continental shelf by the authors."

Jan 1, 1969

By Michel Chouteau

"A very conductive zone was revealed in 1977 and 1978 by magnetotelluric (MT) measurements carried out near Ste-Mathilde, 6 km northeast of La Malbaie . In order to identify the structure causing the anomaly, thirty-five MT soundings were recorded in 1980 and 1981 on and around the conductor within a radius of4 km. Results confirmed that the conductor is of limited extent (less than 2 km by 0.4 km). The proposed model is a highly conductive vertical slab, the top of which is within 200 m from the surface. At a depth of approximately 825 m this structure joins a conductive layer which extends to the northwest but not to the southeast. The large conductivities and the depths involved can only be explain ed by a fractured zone flooded with electrolytic solutions, by graphite veins or by metallic mineralization (sulphides). The former seems to be the most likely hypothesis because an EW fault running across this zone could have allowed percolation of water and the leaching of disseminated pyrite out of a mylolisthenite filling the fault.IntroductionLa Malbaie is located 130 km northeast of Quebec City on th e North Shore o f the St. Lawrence River (Fig. I). Four major groups o f rocks have been mapped in this area: charnockitic rocks to the west , granitic rocks in the north east and southeast, gneiss and pegmatites northwest and south of La Malbaie , and Paleozoic sediments in the Clermont-La Malbaie Valley and along the shore of the St. Lawrence River (Rondot, 1966). Two major features dominate the structure of the region: Logan ' s line , a major thrust fault beneath the St. Lawrence which separates the Grenville Province to the north from the Appalachian regime to the south, and the Charlevoix Crater , a large Paleozoic impact crater that created an almost perfect annula r structure centred on Mont des Eboulements (Rondot, 1970). Ste-Mathilde is a village lying 6 km northeast of La Malbaie, just outside the ring-like graben zone caused by readjustments after meteorite impact. The survey area spreads over a granite body which is more than 2 km long and 0.6 km wide, surrounded by a wide migmatite zone which is injected by many bodies of pegmatite, the latter likely related to the granite body (Fig. 2). A zone of leptynites lies west of the area. An east-west trending fault (FA1) related to the Charlevoix Crater runs mid -way across the survey area; a second parallel fault (FA2) south of FAI separates the gneissic rocks from the Paleozoic sediments. The overburden is usually thin with outcrops frequently encountered except for the centre of the survey are a where 10 m of glacial sediments are expected (E. Gaucher, 1982, personal communication)."

Jan 1, 1985

By R. S. Boorman, L. J. Surges

"Ore reserves at Brunswick Mining and Smelting totalled 101(106) tonnes grading 97 grams tonne-1 silver at the end of 1981. Silver is recovered as a byproduct in the copper, lead and bulk concentrates and is lost to the zinc concentrate and plant tailings. Recovery of silver for the year 1981 was 58,5%. The loss of potential revenue is in excess of Cdn $50(106) year-1 at current silver prices and milling rates.Silver is known to occur in solid solution in galena and as tetrshedrite. Evidence indicating the identity and significance of a third silverbearing mineral assemblage is reviewed and the distribution of silver losses is detailed. Characteristics of each the carrier which may be responsible for observed distribution, including size, surface quality, liberation and composition are considered, and the third carrier is shown to have possible implications for improved silver recovery by other Canadian producers as well as by Brunswick Mining.Silver tetrahedrite tailings distributed tailings and losses occur as coarse, free and as very fine unliberated galena in losses of the third carrier are between the zinc concentrate and are concentrated in the finest size fractions. Process alternatives for enhanced silver recovery by physical and chemical means are reviewed."

Jan 1, 1983

By V. Labiouse, F. Orellana

"Hollow cylinder samples can be tested for both the characterization of rock properties and the physical modelling at reduced scale of engineering applications. Particularly, this type of experimental setup can be used to simulate different stress conditions around underground openings, as already developed in the petroleum engineering field e.g. to study the instabilities around deep wellbores during either drilling or the oil production phase. Some authors have also used this technique to successfully characterize the damaged zone around underground openings in the tunneling engineering field looking for an efficient design of their support.This article presents a new hollow cylinder testing device developed at the Rock Mechanics Laboratory of the Ecole Polytechnique Fédérale de Lausanne (EPFL), Switzerland. It allows a full and independent control of the confining pressure and pore water pressure conditions at both the inner and outer boundaries of Thick-Walled Hollow Cylindrical samples. In order to mimicking a tunnel excavation in a porous rock mass, after initial recovery of the in-situ stress and pore water pressure, the hollow cylinders are subjected to a decrease in the internal confining pressure. Moreover, X-Ray Computed Tomography scans of the specimens are performed through the testing cell before and after the mechanical unloading to monitor the displacements undergone and the sample damage. The equipment, testing procedure and data analysis techniques are briefly presented in the paper.The good performance of the apparatus has already been checked on weak rock specimens, among others on Boom and Opalinus Clay samples. In many configurations, the mechanical unloading is found to induce a Damaged Zone (DZ) around the central hole. Its geometry and extent show a great similarity with in-situ observations around tunnels driven in the Boom and Opalinus Clay formations. Such similarities contribute to increase confidence in the understanding and modelling of the ongoing processes."

Jan 1, 2015

By E. M. De Souza, R. Penner

"Water is encountered at the majority of underground mines, both over their lifetime and during each stage of development and production. The dewatering system is one of the most important and costly components of an underground mining operation and it is often not well designed and analyzed. An effective design of a mine dewatering system will greatly reduce its energy cost as well as improve working conditions and reduce production costs. A computer-based system, called Qpump, has been developed to assist the underground operator to effectively design and/or assess over-all and local mine dewatering systems. The design features and principles used in the development of Qpump are introduced and an example which illustrates typical applications is presented.IntroductionTraditionally, dewatering operations have been given lower priority than many other operations in underground mining. Invariably water will be encountered during the sinking of the mine shaft, during development and subsequent production. The dewatering system thus becomes a very important component of an underground mine operation and, in fact, any mine manager will attest to the importance and necessity of an efficient mine dewatering system.The water problem is of varying importance at different mines. There are several factors that contribute to the water encountered. It is a function of the mining method and techniques utilized (backfill system, drilling and raising technology, dust control sprays, shaft water rings, etc.) and of prevailing conditions (ground water, rock structure and permeability). In some cases a mine may be so dry that little pumping is required while in others, the weight of water pumped may exceed by many times that of ore mined.The successful design and application of a mine dewatering system is dependent upon the operating conditions of each specific operation. There are no standard procedures and systems which can be used for all mining situations. However, an effective water system will greatly reduce the energy and production costs of a mine, improve working conditions and eliminate headaches because of flooded working places."

Jan 1, 1993

The cost benefits of controlling dilution of extracted ore have been very well understood by miners and mining professionals for many years. However, as we strive towards more mechanization, the dilution factor has been compromised in order to fit ?equipment? that is better suited to provide improved safety and productivity. Alternately, the drilling and ground support is accomplished by handheld drilling. In 2007, a short study, commissioned by CAMIRO (Canadian Mining Industry Research Organization) on the safety of hand held drilling vs. mechanized drilling, concluded that the risk of injury with handheld drills was seven times greater than with mechanized drills. Armed with this data, MEDATech Engineering proposed to the CAMIRO group to fund development of a ?MICRO Bolter?.

May 1, 2009

By G. K. Lee, Whaley. H., F. D. Friedrich, I. C. G. Ogle

"IntroductionCurrent coal combustion activities at the Canadian Combustion Research Laboratory (CCRL) reflect the increasingly important contribution that coal is expected to make in meeting our future energy requirements and in reducing our dependence on foreign oil. Widespread use of coal will, however, be heavily dependent on the ability of conventional and emerging combustion systems to cope with the disruptive conflicts caused by variations in fuel quality, on requirements for better equipment availability .and on the implementation of progressively more stringent environmental constraints.To minimize these conflicts, Energy, Mines and Resources Canada has embarked on a systematic sequence of research, development and demonstration- scale (R, D and D) initiatives to stimulate the utilization and competitiveness of thermal coal in both domestic and export markets through a number of complementary in-house projects and external contracts, considered to have short- to intermediate-term benefits to industry and society.Many of the in-house projects are funded in part by industry, whereas the external contracts are either fully funded (100070 government funding) or jointly funded (50% government - 50% project proposer).External contracts and shared-cost projects are an important adjunct to the CCRL in-house effort on coal combustion, because research data can be more effectively transferred to industry and because the commercialization of novel combustion systems can be accelerated significantly."

Jan 1, 1980

By Alan E. Renshaw

"This paper is a practical overview of ways to reduce cost in the design and operation of an Arctic mine. The economically important issues of the Arctic mine that will be addressed include: permafrost and the active zone in general terms; road building in and over permafrost; Arctic geotechnical mine design considerations; pit dewatering techniques in sub-zero temperatures; and blasting frozen materials with techniques to obtain optimal results. A final section on a few special topics conclude this paper.Although this paper primarily refers to near surface conditions more closely associated to an Arctic surface mine, many of the ideas and techniques contained in the paper also apply to the surface construction of an Arctic underground mine."

Jan 1, 1996

By Jose R. Hernandez-Aguilar

"This paper revisits data from previous studies (Hernandez-Aguilar, 2010, 2011) to better understand the link between metallurgical performance and bubble size (Db) in the collection (pulp) zone of full-scale flotation systems. To obtain conclusive evidence exclusively related to the collection zone, the experiments were designed in those studies to control both the bubble generation method and the influence of the froth zone on the overall metallurgical performance in industrial and pilot-scale flotation columns. The results showed that generating small (1 mm) bubbles had a significantly higher beneficial effect on the recovery of coarse (> 75 µm) particles compared to the effect on fine (< 16 µm) particles. It was observed that, under certain practical conditions, the recovery of liberated coarse particles was close to zero, but could be recovered almost completely by reducing bubble size. The evidence revealed an apparent inconsistency of the so-called “k–PSb” model: at constant froth recovery, increasing Sb did not always result in higher recovery, as the model predicts. Overall, the evidence showed that it was not the Sb but the bubble size that proved to be a more reliable link to metallurgical performance. Only under highly suboptimal bubble size conditions (Db = 3 mm) did the froth zone seem to play a role, possibly reflecting an effect of pulp-zone bubble size on froth stability. However, for the most part, both the bubble generation method and the froth zone played inconsequential roles. An empirical model that better describes the kinetics of particle collection is proposed.INTRODUCTIONStudies showing the link between metallurgical performance and the interactions of bubbles and particles in the collection (pulp) zone of industrial flotation systems are scarce. A common belief among a number of mineral processing practitioners considers that “small” bubbles are favourable to recover “small” particles and that, conversely, “larger” bubbles are more efficient at floating “coarse” particles. However, perceptions like this are often substantiated by anecdotal evidence rather than by rigorous data analysis. What is the optimum bubble size for a particular case, how operating conditions can be adjusted to control a target bubble size, and whether the bubble size needs to be changed in the first place to optimize the operation of a flotation plant are questions that usually remain without solid answers.The studies reported by Hernandez-Aguilar (2010, 2011) were, in part, performed to test the effect of bubble size on flotation response and, thus, help address some of the above questions. The focus of the studies was to optimize the metallurgical grade-recovery performance of the Cu-Mo separation plant at Teck’s Highland Valley Copper mine (HVC). The outcome was compelling and significantly valuable: consolidated production data showed that in 2008 – the year when the recommendations from the studies started to be implemented – the Mo plant recovery was 89%, and gradually increased to 92% and 94% in 2009 and 2010, respectively, along with an increase in Mo concentrate grade. (Note: these production figures were not included in the publications quoted above; however, they were shown during an oral presentation at the 43rd Annual Meeting of the Canadian Mineral Processors in 2011.)"

Jan 1, 2016

By Isabel F. Barton, J. Brent Hiskey

Chalcopyrite (CuFeS2) is the earth’s most abundant copper ore mineral, but is refractory to leaching with sulfates, chlorides, and other common lixiviants and oxidants. This has led to increasing research into alternative lixiviants for recovering Cu from chalcopyrite. Here, we review the leach kinetics of chalcopyrite in glycine, ionic liquids, and methanesulfonic acid, compared to baseline ferric sulfate and ferric chloride. Glycine (CH2NH2COOH) has long been used in applications such as biocatalysis and electroplating, and has recently been examined as a lixiviant for whole ores and concentrates of both copper and gold. It is nontoxic, biodegradable, and capable of strongly complexing Cu2+. Compatible oxidants are peroxide, dissolved oxygen, and ferric sulfate. Chalcopyrite leaching rate in glycine is chemical reaction-controlled, but the effects of grain size and the reaction orders with respect to lixiviant and oxidant concentrations and mass transfer vary. The use of ionic liquids as a leaching agent for chalcopyrite has been extensively investigated in recent years. This system is based primarily on the use of the imidazolium molecule (C3H5N2), which is a planar 5-member ring structure. This lixiviant has been applied to the leaching of chalcopyrite in the form of pure mineral, concentrates, and ores. Kinetics of ionic liquid leaching of chalcopyrite vary substantially depending on the type and concentration of ionic liquid. Methanesulfonic acid (HCH3SO3) is one of the newest lixiviants available in leaching, having only been examined in the last decade. It has been examined as a substitute for sulfuric acid, since it is less corrosive, is biodegradable, and breaks down to carbon dioxide and sulfate over time. The rate of copper leaching from chalcopyrite by methanesulfonic acid is controlled by diffusion and exhibits a strong dependence on oxidant type and concentration. Despite promising reaction rates and total extraction by some of these novel lixiviants, comparison with baseline ferric sulfate and ferric chloride systems makes it doubtful that any will be commercially viable in the near term. Only at very high reagent concentrations and temperatures, and/or very fine grain size, did any of the systems perform comparably to the much cheaper ferric chloride at extracting Cu from chalcopyrite. Most had similar overall reaction rates and total extraction to ferric sulfate, which is relatively common and cheap. However, the leaching kinetics of these novel lixiviants offer valuable insight into the dissolution behavior of chalcopyrite in various systems.

Jan 1, 2019

One Data Set for the Lifecycle Complete data captured at the logging stage benefits the entire life cycle Exploration Technical Studies Production and Milling Visible Light Spectrum Hyperspectral, put simply, is the interaction of light with matter based on the nature and chemical structure of the specimen. SpectrumWe develop the library to match the liberation size fraction Analyses every 1mm2 1 meter of NQ core = 35 000 analysis data Crystal size detection : 0.1 micron

May 1, 2013

By M. Sutherland

"Increased efforts to improve mine safety have led to various successful forms of ground control in Canadian underground mines. At Inca Limited&apos;s T-3 Mine in Thompson, Manitoba, a perimeter blasting method has been implemented in jumbo drilled development headings.The technique utilizes an increased number of perimeter blast holes in the drill pattern while decreasing the linear charge density of explosives in any individual perimeter hole. The decrease in perimeter charge density means less blast damage to the surrounding structure.The benefits realized include increased safety through less loose ground and substantially less scaling time, less overbreak and improved long-term drift stability. This paper highlights the development and implementation of the perimeter blasting program.IntroductionThompson Mine Thompson Mine is a 6000 ton per day underground nickel mine located just outside the city of Thompson, 400 miles north of Winnipeg. The mine is serviced by the T-I shaft and by the T-3 shaft. The shafts are 10 000 ft apart and are connected on several levels with the deepest operating levels at T-1 and T-3 being 4000 ft and 2400 ft respectively.The T-3 Mine presently produces 52% of the total Thompson Mine production and 65070 of the 3000 ft of mine development each month. Current development of the 5 million ton 1, C orebody below 2400 level at T-3 will maintain these production and development ratios.Depending on equipment requirements, development headings at T-3 Mine vary in size. The 1, C ramp, at 17 1/2 ft wide by 10 1/2 ft high, is presently the largest development heading at T-3. Fifty- two per cent of the development footage is done with four Gardner Denver two boom electric /hydraulic jumbos and one Gardner Denver one boom electric /hydraulic jumbo. The remaining 48% is driven with hand-held jack-leg drills."

Jan 1, 1990

By G. M. Hughes

"400 cubic foot Agitair Flotation Cells are in use at Sherritt Gordon's Fox and Ruttan Mine Cu-Zn concentrators. The 4 impeller model No. 120, used at the Fox Mine Operation, appears to offer superior agitation and aeration qualities compared to the single impeller model 120A, in use at Ruttan. The advantages of the model 120 are most significant with ores of high specific gravity and coarse grind.IntroductionSherritt is using 400 cubic foot Agitair flotation machines at both the Fox and Ruttan Mine Concentrators.At the 3000 tpd, Cu-Zn Fox concentrator, 18 model 120 machines have been in operation since May, 1969.The 10000 tpd, Cu-Zn operation at Ruttan utilizes 49 model 120A machines. The plant started operation in May, 1973.The 4-impeller model 120 flotation cell has been marketed by Galigher since the early 1960's but the single impeller model 120A is relatively new.Model 120 Agitair -Cell DataThe Model 120 (Dwg. 1) has floor dimensions of 101 x 10' and a lip height of 2~ to 4 feet to provide up to 400 cubic feet of volume. This machine is shown with a froth crowder and stabilizer plates which are optional.Each motor drives two agitators. 20 HP is recommended by Galigher but 25 HP is more realistic with massive sulphides. The SG of ?ox ore is about 3. 6.The Model 120 can handle up to 600 cubic feet of air per cell at 2 psig which requires 5-6 HP at the blowers. Air volume to each impeller is controlled by a valve from a main header.During the first 3 years of operation at Fox there were few mechanical problems with the 120's."

Jan 1, 1974

By J. B. Mawdsley

A LITILE north of the geographic centre of the Province of Saskatchewan, 150 miles north of the city of Prince Albert, is a narrow green-stone and sedimentary belt of pronounced structural characteristics. This belt, generally known as the Sulphide Lake belt, is about two and a half miles wide. During the past three years prospecting has uncovered numerous gold-bearing showings occurring chiefly along the centre of the belt for a distance of at least nine miles. The number of these showings, the nature of some of them, and their relationship to strong structural features, make it altogether likely that intensive work will eventually locate ore-bodies that will be of economic importance. The discovery of gold in the fall of 1938 on the south shore of Mackay lake, about five miles northwest of the Sulphide Lake gold-bearing belt, indicates that there are neighbouring zones of interest. This paper, an attempt to outline the present status of the interesting mineralized belt, is based largely on the information gained on a five-day tour of this district, made in August, 1939, on behalf of the Department of Natural Resources of the Province of Saskatchewan. The Sulphide Lake belt is named after a small lake centrally located in it. This lake and others are just north and within short portage distances of some of the long bays along the north shore of Lac La-Ronge, an irregular, island-studded lake, about twenty miles in diameter, in relatively rocky Precambrian country, just north of the Palaeozoic contact. The fur-trading post and settlement of Lac La-Ronge is on the west shore of this lake and a road, now under construction, will shortly link this community with the city of Prince Albert. In the past, the most direct route was an indifferent canoe route, in part following Montreal lake and river; more recently, the aeroplane has made this section easily accessible.

Jan 1, 1940

By Jochen Petersen, Alison Lewis, Cledwyn Mangunda

Run-off and waste water streams high in dissolved metal content are generated in all mining operations. The metals pose a threat to life due to their persistent bio-accumulative toxic (PBT) characteristics. Hence, there is a need to treat mine waste water effectively. Lime precipitation is the technology of choice through which Fe, as the major metal species, is removed as Fe (III) oxyhydroxides with other metals co-precipitated and/or adsorbed. Sulphates are removed as gypsum or incorporated into the Fe phases. The resulting sludge has poor dewatering characteristics and is deposited in landfills, with an inherent risk of returning the Fe back into the water cycle through leaching. This study seeks to understand the mechanisms behind the formation of this sludge in terms of product quality. The relationship between process conditions and product characteristics has been investigated through exploring the effect of Fe (III) concentration on the precipitate product characteristics (particle size distribution (PSD), size, morphology and structure) and quality (in terms of filterability, settling ability, etc.) in a simplified system. Neutralisation of acidic synthetic aqueous Fe (III) sulphate streams containing 50, 400 and 800 mg/L Fe(III), respectively, was effected by mixing it in a continuous stirred tank reactor (CSTR) with dissolved calcium hydroxide for pH control at a residence time of 15 minutes. Precipitate samples analysed for morphology and PSD, using nanoSEM and Zetasizer respectively, showed a general decrease in PSD and zeta potential with increases in feed Fe (III) concentration. These results were used to infer the particle size enlargement mechanisms of Fe (III) oxyhydroxide precipitates under a given set of operating conditions. Preliminary product quality results indicate that a high concentration (800 mg/L) leads to the rapid formation of metastable precursors with poor product quality, whilst a low concentration (50 mg/L) leads to formation of thermodynamically more stable precipitates with good product quality. The approach demonstrates a potential route forward in terms of linking operating conditions to the attainment of desirable characteristics rather than specific precipitate phases which are difficult to identify.

Jan 1, 2016

By Claudio Rocha Rosales

"Peñoles is a mining group with integrated operations in the smelting and refining of non-ferrous metals, and is also a chemicals producer. Peñoles is the world’s foremost producer of refined silver, metallic bismuth and sodium sulphate and is the leading Latin American producer of refined gold, lead and zinc. The Met-Mex Peñoles Zinc Plant commenced operations in 1973 with an annual production capacity of 105,000 t/y. Year after year the production has been increased, and at present, the production capacity is 240,000 t/y. In this paper, the leaching process,particularly the operation of the jarosite circuit is reviewed ,specifying process improvements to treat high iron calcines.INTRODUCTIONThe purpose of the leaching process is to recover the metals, mainly zinc,through a series of extraction stages with sulphuric acid solutions, which progressively increase the zinc recovery. After the series of acidification stages,the solution, which is rich in iron, is sent to the jarosite circuit to separate the zinc from the iron (Garcia & Valdez, 1996).The first step of the leaching process is the neutral leach circuit which produces a zinc sulphate solution that is sent to the purification section for the removal of impurities such as cadmium, cobalt and copper, after this solution is sent to the tankhouse to feed the electrolytic cells."

Jan 1, 2016