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By Daniel J. Corkery

Mines in Canada and the United States are subject to regulations limiting ammonia, nitrate and nitrite levels in mine effluents released into the environment. The primary source of these nitrogen compounds is typically explosive used in blasting operations, as ammonium nitrate (AN) remains a significant component of most explosives used in the mining industry. The amount of AN entering a local water drainage system is related to site conditions, explosives used, explosive handling and blast efficiency. Mining operators acknowledge AN loss to mine water from blasting operations. However, the mechanisms by which ammonia, nitrite and nitrate are entering the water drainage system, or the relative contribution of specific mechanisms, may not necessarily be assessed or monitored adequately. Characterization of these mechanisms, through systematic investigations, allows a mining operation to focus its efforts on reducing AN loss. This paper outlines a strategy for investigating the mechanisms through which AN enters the mine water drainage system and methods to mitigate this loss. This strategy includes collection and analysis of data to identify and quantify the AN loss mechanisms, design and implementation of tests to mitigate this loss, and assessment of the results. Such investigations are not intended to be a separate one-time project, but part of a long-term process of continual feedback and optimization that is related to the collection and reporting of AN levels for regulatory purposes. The implementation of the strategy must be tailored to each mine?s requirements and existing conditions.

Oct 1, 2010

By Steve McMullan, Blaine Webster, Ian Johnson, Ron Matthews

"Time domain spectral Induced Polarization (IP) data from the Tower, Jojay and Laurel Lake gold deposits in northern Saskatchewan are presented. The resistivity data shows both resistivity lows (due to fault, shear or alteration zones) and resistivity highs (due to silicification) in the area of the deposits. The high resistivity zones suppress and distort coincident IP responses, calling f or high quality surveys and special care in interpreting the IP data.Electromagnetic methods are not effective in locating the deposits. This is due, in part, to masking by conductive cover. The Jojay Lake deposit has a strong magnetic response. A more indirect magnetic association is seen for the Tower Lake deposit. The Laurel Lake deposit has no magnetic signature. Magnetic data are useful in defining structure in all cases.All three deposits are outlined in the IP survey results. IP anomaly amplitudes from the pole-dipole array are from two times (Tower and Laurel Lak e) to six times (Jojay Lake) background values. Gradient array IP anomalies are of less amplitude. The spectral time constant is short for the Tower and Laurel Lak e deposits and long for the Jojay deposit. This implies that the metallic sulphides in the Jojay deposit are more interconnected than those of the other two deposits. INTRODUCTIONInduced polarization / resistivity surveys are commonly used in gold exploration program s in the Canadian shield because the IP method is effective in detecting disseminated metallic sulphides which are often found associated with gold. Other common geophysical sur vey methods such as magnetics, VLF and EM are not generally capable of direct detection of disseminated sulphides. Since the introduction of the IP method in the 1950s, it has undergone continuous improvement. The most recent improvement is the development of time domain receiver s which sample the full de cay and record it in digit al form. This results in a more complete measurement of the response which permits analysis and enhancement of data quality and the derivation of a nomaly parameters which characterize the measured decay. This extension of conventional time domain IP methods is called spectra l IP, a term first introduced by Pelton et al. working in the frequency domain Spectral IP surveys are attractive because they allow the possibility of discriminating between IP responses which have similar amplitudes but are due to dissimilar geo logic targets. The discrimination can be important in the selection of IP anomalies for follow-up.Time domain spectral IP survey results are presented over three known gold deposits in northern Saskatchewan-Tower Lake, Jojay Lake and Laurel Lake. The surveys were initiated and supported by Cameco-A Canadian Mining and Energy Corporation (formerly the Saskatchewan Mining and Development Corporation-SMDC) and were carried out by JVX Limited using the Scintrex IPR-II receiver and attendant spectral analysis software."

Jan 1, 1989

By D. K. Sarkar, J. Perron, J. D. Brassard

"Nearly perfect spherical shaped water drops rolling-off from the surface of lotus leaf is one of the beauties of nature. This kind of surface is called superhydrophobic, since the water does not like it. Physically, a superhydrophobic surface provides a contact angle (CA) of water over 150°. The combinations of both mico-nanostructure topography as well as low surface energy are essential to have such high CA on a surface. Nano-micro structured superhydrophobic surfaces have been developed in different methods. (i) Monodispersed fluorinated silica nanoparticles have been synthetized via Stöber Sol-Gel process and deposited on various surfaces, such as aluminium or glass, to obtain transparent superhydrophobic thin films. (ii) Similarly, zinc stearate nanocomposite coating has been fabricated by spray process on the same substrates. These thin films are found mechanically robust with drag reduction of coefficient 16% lower than as-received surfaces. (iii) By electrodepositing pure zinc on steel surfaces and further coating it with diluted room-temperature vulcanized silicone rubber, the surface become superhydrophobic. This superhydrophobic surface protects the steel against corrosion by increasing the polarization resistance from 1.5 k? on steel to 44.4 k?. This coating also reduced the ice adhesion on the steel surface 6.3 times as compared to bare steel substrates. Globally, these superhydrophobic surfaces have tremendous applications against corrosion reductions, drag reductions and ice adhesion reductions.INTRODUCTIONSuperhydrophobic coatings are increasingly attractive to the industry and academia due to their unique self-cleaning properties as a result of their water repelling characteristics. Fabrication of superhydrophobic coating is an inspiration from nature as water is seen to repel on many natural surfaces such as those of the lotus leaves, butterfly wings, water striders’ legs, and so on (Gao & Jiang, 2004; J. Huang, Wang & Wang, 2006; Neinhuis & Barthlott, 1997; Zheng, Gao & Jiang, 2007). This non-wetting phenomenon is well understood on lotus leaves, shown on the Figure 1 (a), and it is considered as the basis of the studies of superhydrophobicity. The existence of this binary structure on the surface of the lotus leaves allows a large amount of air entrapment and consequently reduces the contact area of water on it and the presence of low surface energy waxy components with reduced affinity to water together leads to the superhydrophobic properties. The phenomenon is shown on Figure 1 (b). Cassie and Baxter (Cassie & Baxter, 1944) as well as Wenzel (Wenzel, 1936) proposed two mathematical models to explain the wetting phenomena on rough surfaces that leads to superhydrophobic properties. By definition, superhydrophobic surfaces are characterized by a water contact angle value = 150° with the rolling off of water drops from the surfaces (Sarkar & Saleema, 2010). Superhydrophobic surfaces find tremendous importance in the technological world where it can applied in domains such as anti-corrosion, anti-biofouling, electrowetting, icephobic and even in drag reductions (Bushnell & Moore, 1991; Cao, Jones, Sikka, Wu & Gao, 2009; Carlborg & van der Wijngaart, 2010; Carré & Mittal, 2009; Y. Huang, Sarkar & Chen, 2010a; R. Karmouch, Coude, Abel & Ross, 2009). However, the most important challenge faced by industries is their feasibility large scale in an effective an economical manner."

Jan 1, 2016

By Helen Morrison, Chris Staun, James Vaughan

"Mercury is introduced into the Bayer refining process as a trace element in bauxite. During the digestion stage, a portion of the mercury is extracted which partitions between the flash tank off-gas, vapour condensate and bauxite residue streams. A technology or treatment that stabilises mercury in the solid phase during digestion would prevent environmental management issues that may arise from the presence of mercury in condensate and non-condensable gases. This study examines the effect of process additives on the deportment of mercury under Bayer digestion conditions. Bauxite digestion experiments were conducted in batch autoclaves in the presence of additives. Process liquor was analysed for mercury content using a thermal desorption technique. Pyrite and copper hydroxide were evaluated for their suitability as additives.INTRODUCTIONMercury is an ancient metal characterised by electrochemical nobility, volatility, low solubility in water and a liquid state at room temperature (Holleman and Wiberg, 2001). The biogeochemical cycle of mercury is complex. Elemental mercury may enter the atmosphere due its volatility, where it can be transported long distances. After settling and adsorption to sediments, methylation is catalysed through microbial metabolism (Qureshi et al., 2009). Methylated mercury species are potent neurotoxins, and bioaccumulation of mercury is well documented, particularly in seafood (Kozin et al., 2013, Pan et al., 2014, Pollman, 2014). Environmental regulations for mercury emissions are becoming increasingly stringent (UNEP, 2015). Considerable research has already been performed and technologies developed for the remediation of mercury in wastewater and the trapping of mercury from industrial stack emissions. Wastewater technologies usually target ionised mercury using adsorbent, ion exchange and complexation mechanisms (Krishnan and Anirudhan, 2002, Li et al., 2015a, Chiarle et al., 2000), while stack emission technology is dominated by impregnated activated carbon adsorbents (Gao et al., 2013, Zheng et al., 2012). Related developments include piezoelectric amalgamating sensors for in line detection of gaseous elemental mercury in industrial stack emissions (Kabir et al., 2015, Sabri et al., 2011). There is a paucity of research regarding removal of mercury from the Bayer process."

Jan 1, 2016

By S Sokhanvaran

Electrodeposition of silicon from a cryolite based electrolyte at a relatively low temperature (1000°C) is a promising approach to generate high purity silicon. In order to obtain fundamental data pertaining to electrowinning of silicon from Cryolite?SiO2 melts, density and electrical conductivity measurements were made. A range of temperatures and SiO2 contents was studied for each property. It was found that while density has an inverse relationship with temperature, the dependence for electrical conductivity is direct. Increasing silica content up to the saturation limit (~ 5 wt%) increases the density whereas further increase in SiO2, lowers the melt density. On the other hand, the conductivity is lower for the melts with greater SiO2 content, at any temperature.

Jan 1, 2011

By Hamid-Reza Manouchehri

Coarse particles flotation is controlled by detachment (particle hydrophobicity and flotation cell turbulence) For composite particles (the bubble may attach to good hydrophobic region, but the expansion of the three phase line of contact is limited. Hence, the equilibrium contact angle, characteristic of the hydrophobic region, may never be attained, and the force of attachment is decreased relative to that possible for homogenous hydrophobic surfaces.

May 1, 2013

By Arsalan Talebzadeh

Construction -Surface ?First two intake fans constructed in 2007; third fan added in 2008 to reduce resistance in the system. 450 HP fans. ?Excavation for exhaust fans started in 2008. ?In parallel with underground construction in preparation for the changeover. ?Bulkhead in place prior to completion/ commissioning of

Oct 1, 2010

By Jacque Turgeon, Gontran Foy

"The Mineral Research Centre of the Quebec Department of Energy and Resources has worked extensively on the development of a dry process to extract pure mica flakes from a phlogopite ore. The liberation of mica from the gangue is effected basically by impact crushing, and the ground ore is screened into several fractions, each having a fairly narrow range of grain size. Each sized fraction is then fed to an air separator where heavy grains are separated from light flaky grains. Heavy fractions are returned to hammer mills where gangue minerals are ground finer and blocky mica particles are exfoliated. A second stage of screening is performed and each fraction is sent to an air separator. This sequence is repeated until mica products are virtually free of gangue. These different fractions are then treated in a cage mill in which mica flakes undergo a more orderly exfoliation along cleavage planes. The ground mica is again submitted to a final screening stage, after which each fraction constitutes a final commercial product.This process permits the recovery of about 70% of the mica contained in the ore. The over-all process will be described along with technical details of each unit operation. Recent work on a wet grinding method to produce very fine mica will also be discussed.IntroductionRecords of production of mica in Quebec date back to 1886. Production has been more or less continuous since that time, with peak activity during the war years. Production was interrupted in 1966, but started again in 1972 when Marietta Resources and Laviolette Mining and Metallurgical Corporation started their joint operation in Canton Suzor, northwestern Quebec. Mica deposits of more or less importance exist in different parts of Quebec, of which three have attracted attention in recent years: the Canton Suzor deposit, the Canton Lamy deposit and the Canton Chasseur deposit. The Suzor orebody was first identified by Carl Faesler in 1936, who described the rock as ""brown biotite in flakes half an inch in diameter, with interstitial augite, apatite and feldspar""."

Jan 1, 1982

By R. A. L. Drew, G. Mendoza-Suarez, J. Filipi, R. Vintila, J. A. Kozinski

Economics and environmental considerations along with the increasing demand of hydrogen encourage development of novel technologies such as plasma processing of hydrocarbons and thermal cracking of natural gas. Plasma discharges, either in thermal or non-thermal regimes are expected to allow low temperature and fuel flexible on-site hydrogen generation. The main drawback of thermal plasma reformers is the high-energy consumption resulting from high-temperature operation. On the other hand, non-thermal plasma, generated by dielectric barrier discharge (DBD), is able to simulate the chemical reactions employing much lower energies than those required by thermal treatment processes. The non-thermal plasma process allows for instance, a direct conversion of methane into hydrogen and carbon black with no CO2 release. The focus of this research was on the GHG-free method of H2 generation in compact non-thermal plasma reactors using low, medium and high permittivity dielectric ceramics. A stable, non-thermal plasma was generated by placing a dielectric ceramic between two electrodes with a 25 thou gap and applying an alternating current of 1-5kHz and voltages of 4-8kV. In order to ensure energetic efficient plasmas, experiments were conducted to analyze the behaviour of different permittivity ceramics. It was found that the dielectric properties of a ceramic, when used in a DBD reactor, have a strong influence on the discharge characteristics, which in turn influence the power consumption. Higher dielectric constant resulted in higher conversion rates of methane (higher yield of hydrogen and carbon). At the same time, the mechanical properties of the dielectric material, which are closely associated with its processability, influenced its resistance to electron bombardment, as well as thermal and mechanical damage. Therefore a reliable ceramic should have good dielectric properties, in addition to good thermo-mechanical stability.

Jan 1, 2004

By X. -G. Chen, A. M. Nabawy

A novel manufacturing technique for Al-TiB2 nanocomposites has been developed, in which TiB2 nanoparticles were incorporated into liquid aluminum under mechanical stirring and in the presence of a K2ZrF6 flux-wetting agent. The microstructure of the Al-TiB2 nanocomposites was studied using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The microhardness test was conducted to investigate the strengthening effect of TiB2 on the aluminum matrix. The TiB2 nanoparticles were successfully incorporated and dispersed into the aluminum melt in the presence of the K2ZrF6 flux during mechanical stirring. In the as-cast microstructure, most nanoparticles segregated in the interdendritic regions as a result of particle redistribution during solidification. The addition of 2, 5 and 10 wt% TiB2 nanoparticles increased the composite hardness by 60, 90 and 150% respectively when compared to commercial purity aluminum, indicating that the TiB2 nanoparticles imposed a significant strengthening effect on the aluminum matrix. The role of K2ZrF6 flux agent on the incorporation of nanoparticles into aluminum melt was discussed.

Jan 1, 2014

By L. Mohammadi

Outline ?Background on the accident at the Sullivan Mine No.1 Waste Dump ?Holistic approach to understand the reason for accidents (Atmospheric) ?Specific hazards at reclamation sites ?Regular atmospheric risk assessment at reclamation sites ?Fuzzy risk assessment ?Managing risk at legacy sites

May 1, 2010

By M. S. Greenfield, E. Cocchiarella, S. Chubbs

"At Dofasco sNo.4furnace a variation of the basic oxygen steelmaking process, Klockner Oxygen Bottom Maxhutte (K-OBM), is used to produce steel. Large amounts of hot gases and particulate are evolved during the oxygen blowing phase. A quencher and a venturi scrubber are used to collect over 99.5% of the particulate. In 1990, the authors investigated the effect of foamy slag on the particulate emissions from the furnace. The amount of lime added early in the oxygen blowing cycle was reduced, making the slag more viscous and foamy for a six minute period. Instantaneous particulate emissions were monitored throughout the blow by analyzing quencher and venturi scrubber water samples. Particulate emissions were reduced up to 59% during the foamy slag period.IntroductionThe reduction of the amount of waste generated or control of emissions at source is at the top of the ""3R"" hierarchy of waste management (Reduce, Reuse, Recycle). Process and operating practice changes are often the most economical ways to control emissions. At Dofasco, they investigated the effect of operating practice changes, specifically the formation of a foamy slag, on particulate emissions from steelmaking furnaces. They wanted to determine if a foamy slag changed the quantity and nature of the fume evolved from the K-OBM furnace over the oxygen blowing phase.The Basic Oxygen Steelmaking ProcessesThe basic oxygen steelmaking process (BOP) generates large quantities of very fine metal oxide fume during the production of steel. In this process, scrap steel and molten iron (hot metal) from blast furnaces are charged into a steelmaking furnace. Then pure oxygen is injected and a lime flux added . The oxygen reacts with carbon dissolved in the molten iron to form carbon monoxide. Oxygen lances can have secondary nozzles which introduce oxygen above the bath. This secondary oxygen, known as post-combustion, bums some of the carbon monoxide radiating the heat back to the bath. Particulate and gases rich in carbon monoxide are ejected from the furnace during the oxygen blowing phase and are collected by a gas cleaning system. Typically, more than 99.5010 of the particulate is scrubbed from the gases by high energy venturi scrubbers or electrostatic precipitators. The oxide sludge or dust collected may have elevated zinc and lead which is unsuitable for recycle to blast furnaces. Due to the presence of these undesirable elements, treatment and disposal of steelmaking oxide dust is difficult and costly."

Jan 1, 1993

By G. Robert Guillet

"Ontario enjoys the advantage of its proximity to the large industrial market of northeastern North America. Together with Quebec and fifteen nearby U.S. states, an industrial base of more than half the total for both countries is provided by a population of 100 million.Mineral fillers such as barite, calcium carbonate, kaolin, mica, silica and talc are of major importance in the manufacture of paper, paint, plastics, rubber, vinyl tile, carpet backing, putty, caulks, sealants and adhesives. Ontario has all of these minerals, but domestic production falls short of demand in some cases, and mica and kaolin are not produced at all.This paper reviews the market and outlines the distribution of the major filler-consuming plants of northeastern North America. It also identifies the principal producers of filler minerals in the United States and Canada.IntroductionOf all the uses for industrial minerals, mineral fillers are probably the least understood. Originally used primarily to add low-cost bulk to a variety of commodities without seriously affecting their properties, filler minerals have become essential components that enhance and extend the properties of their hosts. Hence the term ""extender"" which, for all practical purposes, is synonymous with ""filler"". Today, fillers and extenders are not solely low-cost additives, but ingredients that provide essential characteristics to the products they fill.The major markets for mineral fillers are paint, paper, plastics, rubber, adhesives and floor coverings. But there are many others: putty, pesticides, wire and cable coatings, caulking and asphaltic compounds, oilcloth, wall-paper, joint cements, inks, sealants and many others. Barite, calcium carbonate, kaolin, mica, silica and talc are among the more important filler minerals discussed in this paper, but there are at least a dozen others. And the increasing practice of coating the mineral surfaces with certain coupling agents or metal stearates is constantly expanding the range of characteristics and hence the marketing opportunities.Whiteness, particle shape, fineness of grind and cost are the principal considerations in selecting a filler, but other characteristics such as weight, opacity, hardness and chemical inertness may be dominant considerations in specific applications."

Jan 1, 1987

By Claude Bazin, François Robichaud

The control of the operation of a semi autogenous grinding mill is mainly based on power and bearing pressure measurements. Image based sensors can provide on-line measurements of the size distribution of the ore feeding a SAG mill allowing the control of this variable that impacts the operation of this equipment. This paper investigates the potential of using the information from such type of sensor to maintain a SAG mill feed target size distribution by manipulating the speed of the ore extractors below an ore stockpile. A PID and adaptive predictive controller for the size distribution are studied using a simulator for a stockpile and the equipments used for ore withdrawing from the pile. The proposed controller is found to give a good performance while remaining easy to tune.

Jan 1, 2014

By A. Zarei-Hanzaki, S. M. Fatemi-Varzaneh, M. Haghshenas

The microstructure in modified semi-solid ALTHIX (A356) alloy consists of aAl phase with Al/Si eutectic structure. Silicon phase in eutectic structure is coral like with fine fibers. The lack of good ductility in this alloy is related to the presence of silicon fibers. Accordingly many investigations have been recently conducted to modify the Si morphology through Thermomechanical processing on this alloy. In the present work an ALTHIX (A356) alloy was deformed at 450°C, 500°C and 540°C through different strain rates. Consequently the silicon fibers were broken into small particles. The results indicated that the Si particles may coarsen according to Ostwald ripening mechanism at 540°C deformed by rate of0.0005 sec-1 & 0.0001 sec-1-

Jan 1, 2006

By Alf Hartling

"Most of the Paleozoic section of the Williston Basin is a thick accumulation of numerous carbonate to evaporite, shallowing upward, cyclic sequences. These sediments were deposited in broad epeiric seas, and the deposition of the evaporite facies marked the final stage of each cycle. Many of the sequences display a pervasive replacement dolomite in the uppermost portion of the carbonate units. This secondary dolomitization is, at least in part, an early diagenetic event, synchronous with evaporite deposition.The inception of evaporite precipitation resulted in the seepage of a dense, Mg-rich brine into the underlying sediment. The heavy brine moved down the gentle regional dip displacing the more normal marine interstitial pore fluid and dotomitized the primary calcitic sediments en route. The supply of Mg-ions decreased away from the source, and correspondingly, the degree of dolomitization decreased and larger crystals formed because of slower nucleation at fewer sites.The seepage refluxion of dolomitizing brines gave rise to the frequently observed textural variation of cryptocrys talline, impervious dolomite grading into a finely sucrosic, permeable dolomite down-dip. This diagenetic facies change provides the critical up-dip barrier for potential hydrocarbon reservoirs. The lateral pool boundaries are controlled by either structural relief or a similar diagenetic facies change. The reservoirs are capped by the tight evaporites.Hydrocarbon production is attained from diagenetic traps in the Mississippian Oungre Zone and the Ordovician Red River 'C' Zone . Reservoir creation and the pooling mechanism are the result of dolomitization by the seepage refluxion of dense, Mg-rich brines beneath restricted, hypersaline lagoons. When formulating an exploration/ exploitation program for these oil prone horizons, it is essential to understand the complete geological history in order to establish where the reservoirs will be found and to define the areal extent of each accumulation."

Jan 1, 1984

By F. Boudreault, C. Hendricks, M. Scobie

Drilling accuracy represents an important quality control factor in minimizing dilution. Apart from geology, the factors governing drilling accuracy are largely within the control of the mine. Setup location and alignment, as well as actual drilling accuracy, can all be monitored toward their improved control. Trajectory deviation during drilling, although usually beyond the control of even the most experienced and conscientious driller, can be accounted for (if not full controlled) by down-hole surveying of blastholes prior to explosives loading. This paper reviews the available instrumentation for improved drill setup and recent field experience with several commercial systems designed for monitoring borehole deviation. It reports on a recent survey of 50 Canadian mines which use blasthole stoping and addresses the reasons for the apparent lack of interest in instrumentation: i.e. does this reflect a lack of awareness of the technology, perceived inadequacies in its performance or a predominant reliance on productivity (drilling and mucking) as a measure of operational efficiency? The survey findings supported the latter viewpoint and showed that very few Canadian mines operate drilling incentive programs that are related to drilling accuracy.

Jan 1, 1994

By John C. Taylor

"The non-ferrous pyrometallurgical industry has been under extreme pressure since 1980 and significant changes are taking place, principally in the copper, nickel and lead industries. This paper reviews some of these changes, particularly with respect to smelter capacity, major technical trends, and the industry's response to increased energy costs and environmental constraints.The Canadian metal mineral production for 1985 has been estimated at a value of over $8 billion, of which half is derived from copper, nickel, lead and zinc production. It is in our national interest that the Canadian industry remain competitive in the world market and continue its traditional contribution to the Canadian economy. IntroductionPyrometallurgy by definition requires energy, usually in the form of fuel, and produces process gas streams which can no longer be discharged directly to atmosphere in most countries. While the industry has been under varying degrees of pressure over the past fifteen years, it is just since the early 1980s that major changes have taken place, due, to a large extent, to an oversupply on the primary metal markets and depressed prices. These factors, combined with a surge in the price of oil, have resulted in some trends developing which must be recognized by those in the industry who plan to be in operation and competitive in the next decade.Although the value of Canada's mineral production, in terms of constant dollars, has decreased by more than 35% over the period from 1980 to 1985, the bulk of this production is exported and the industry still makes a significant contribution to the Canadian economy."

Jan 1, 1988

By M. Pierce

Empirical relations exist for the estimation of rock block strength at scales larger than standard core sizes. Two recently published relations account for the significant impact that microflaws (pores, open cracks, veins) and weathering/alteration can have on scale effect. These relations were used to estimate the rock block strength of heavily microfractured quartzite from the Bingham Canyon Mine. Predictions were compared to the results of Uniaxial Compressive Strength (UCS) tests conducted on cylindrical core samples of varying microfracture intensity and diameter. The comparison confirms the sensitivity to microfracturing suggested by existing relations and suggests that they would benefit from more detailed consideration of microfracture strength, density and persistence over a range of scales. The results of a numerical study illustrate how Synthetic Rock Mass (SRM) modeling techniques could be used to complement empirical data in the development of such relations.

May 1, 2009

By Larry G. Twidwell, Corby G. Anderson, Camille M. Fleuriault

"The selective precipitation of iron as ammonium jarosite is a well-established industrial technology in base metals hydrometallurgy. It is a key technology in minimizing iron tenors which would be disruptive to downstream processing. It also provides a more readily filterable iron solid to better facilitate materials handling. This paper elucidates the fundamentals behind industrial iron precipitation. Then, the details of the successful optimization of an industrial ammonium jarosite circuit are presented.HYDROMETALLURGICAL IRON REMOVAL FUNDAMENTALS Iron is the fourth most abundant element in the Earth’s crust (5% by weight) and is often found in complex ores such as sulphide-bearing formations. Iron represents an issue though during leaching, a technology which is widely used for the treatment of this type of ore: •,Iron has the particularity of forming hydroxides when leached under certain conditions. Iron hydroxides form a viscous gel, which is difficult to filter and traps valuable elements such as silver. •,Iron is solubilized along with other metals and interferes with the subsequent extraction steps. As a result, purification of the pregnant leach solutions is required to achieve economical extraction of base metals. In the 1960s, metallurgists developed iron precipitation processes for solution purification (Habashi, 1999). Nowadays, precipitation of iron bearing species, such as goethite, hematite or jarosite, has become one of the most common methods used in the industry to purify leach liquors. To be suitable, the precipitate has to be readily filterable and thus must not be too fine of particle size. Precipitation can take place in autoclaves at medium to high temperatures, under an oxygen or air overpressure (Tourre, 1984, Fleuriault 2016, Fleuriault Anderson Shuey, 2016))."

Jan 1, 2016