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By K. J. Maggs

The U.S. Bureau of Mines has investigated the chemical vapor deposition of diamond films on tungsten substrates. The effects of deposition parameters on the adhesion of the films was determined. The films were produced using a hot filament chemical vapor deposition system. Parameters investigated were substrate temperature and methane concentration in the feed gas. Film quality, morphology, and composition were characterized by scanning electron microscopy and Raman spectroscopy. Adhesion testing was performed using an indentation technique, and the results were quantified by relating adhesion to interface fracture toughness. Diamond films with well-faceted crystalline morphology with grain size greater than 1 µm had poor adhesion properties regardless of substrate temperature or methane concentration. Diamond films with smooth morphologies consisting of rounded clusters of small (<0.2 µm) diamond crystallites and amorphous carbon phases displayed much higher adhesion, although the conditions that led to the growth of these films are not understood.

Jan 1, 2010

By A. E. Nagel, J. E. Carpetta, M. G. Zabetakis, T. D. Moore

The method of moving averages was found useful in assessing the nature of methane emission in coal mines. Emission rates were influenced markedly by the presence of abandoned oil and gas wells in the vicinity of the mine. Such wells appeared to increase the flow rate of methane into the mine by a factor of 2 to 30 in an active mine in the Pittsburgh coal seam.

Jan 1, 1972

By W. H. Eddy

The Bureau of Mines conducted laboratory batch flotation tests and continuous pilot plant flotation tests on a complex calcareous fluorspar ore from Cave-in-Rock, Ill., to determine the technical feasibility of producing commercial-grade concentrates by the sodium fluoride-calcium lignin sulfonate-fatty acid method of concentrating fluorspar previously developed by the Bureau. The continuous flotation tests, treating about 150 pounds of ore per hour, produced fluorspar concentrates assaying 96.4 percent CaF2; 90 percent of the fluorspar was recovered.

Jan 1, 1967

By Michael P. Moore, Christopher J. Rise

"Over the past twenty years, there have been numerous studies which have attempted to correlate the prevalence of Coal Workers' Pneumoconiosis (CWP) with different characteristics of the coal seam. Some investigators have tried to find a relationship, or the lack of a relationship, between the rank of coal seams and the incidence of CWP. Others have attempted to show that there is a positive correlation between the mean mass of respirable dust in the mine atmosphere and the prevalence of CWP. Still others have tried to determine the influence of the quartz content of respirable dust on the incidence of CWP. Unfortunately, many of these different investigations have conflicting conclusions.One area of research with conflicting conclusions deals with the relationship between the rank of the coal and the incidence of CWP. For example, an inves¬tigation conducted in Pennsylvania and West Virginia coal mines concluded that the prevalence of CWP increases with an increase in coal rank (1). A study in Great Britain also observed a close relationship between the rank of coal and the prevalence of CWP (2). However, another study involving 312 Appalachian coal miners concluded that the association between coal rank and CWP might be fortuitous and that other factors may be more important (3). In addition, an investigation involving 2,600 miners during a period of twenty years in Great Britain established that there is only a weak correlation between the prevalence of CWP and the rank of the coal (4). Consequently, it appears that there is still uncertainty as to whether or not the rank of the coal seam has an influence on the development of CWP.Another area of investigation concerns the relationship between the mean mass of respirable dust present in the mine atmosphere and the prevalence of CWP. A study involving 4,122 miners over a period of ten years in Great Britain noted a high correlation between the mean mass of respirable dust and the incidence of CWP (5). Another investigation involving 3,154 British face workers con¬cluded that the overall mass of respirable dust is the factor most closely related to the ten-year attack rate of CWP (6). However, a study conducted in thirty-one mines in the United States concluded that it is doubtful that the quantity of respirable dust alone is responsible for the difference in the prevalence of CWP (7). Even though there are conflicting conclusions, there are many more investigators who confirm, rather than deny, the relationship between the mean mass of respirable dust and the development of CWP.The third subject of investigation is the role of quartz in the incidence of CWP. For example, two studies in Great Britain concluded that the quartz content in coal mine dust has no relationship to the prevalence of CWP (8,9). But a study involving 312 Appalachian coal miners revealed that the level of exposure to free silica plays an important role in the development of CWP (10). Once again, the conclusions reached by different researchers are conflicting.Probably the most important factor in the discrepancy among the studies is the variability among different coal mines. A mine operating in an inherently ""dusty"" seam may have a low concentration of respirable dust while a mine operating in a less dusty seam may have a high concentration of respirable dust. This discrepancy is a result of variables such as the effectiveness of ventilation or the efficiency of the water sprays. Consequently, it is very difficult to compare the dustiness of different coal seams by in-mine measurements of the respirable dust concentration. A laboratory test would more accurately characterize a coal seam according to its respirable dust production."

Jan 1, 1988

By V. M. Benson

A simplified, routine method for determining lithium in lithium-bearing rock is presented. The sample is decomposed by repeated treatments with nitric, hydrofluoric, and perchloric acids. Since this procedure does not appreciably dissolve beryl, interference by beryllium (the principal interfering cation) is minimized for most samples. The salts are brought into solution with water and enough citric acid-ammonium citrate buffer is added to make the final volumetric dilution 0.20 M with respect to citrate. The addition of citrate greatly reduces anion interference in the hydrogen-oxygen flame, slightly increases the intensity of the lithium 671 millimicron emission line, and reduces the effect of most of the interfering cations to the extent that analytical separations are not necessary. The accuracy of results of single determinations of lithium in a pegmatite containing spodumene, lithium-bearing mica, and beryl are approximately equal to that obtained by other flame methods, INTRODUCTION This investigation was undertaken in Bureau of Mines laboratories to develop a reliable, rapid, routine analytical method for determining lithium in lithium-bearing minerals. The requirements of the procedure were that the method should be applicable to the analysis of a variety of lithium-bearing ores and test products, and the results would be reasonably accurate for materials containing 0.05 to 8 percent Li20.

Jan 1, 1961

By Marcia L. Harris

The National Institute for Occupational Safety and Health (NIOSH), as part of its continuing research program for evaluating coal dust explosion hazards, has investigated several areas in which current practices may need to be updated in order to adequately protect mines against coal dust propagated explosions. In the United States, current rock dusting requirements remained largely unchanged since 1969. US Title 30 Code of Federal Regulations Section 75.403 is based on a coal dust particle size survey performed in the 1920s and later was supplemented by full-scale testing of the rock dust ability to inert a coal dust explosion. NIOSH recently conducted a comprehensive survey of US underground coal mines to determine the range of coal particle sizes found in dust samples collected from the mine entries. Due to advancements in technology and modern coal mining techniques, the current coal dust particles in intake airways are significantly finer than those found in the mines in the 1920s. According to past full-scale dust explosion test results, the current rock dusting practices used in today?s mines to inert a coal dust explosion may not be adequate. Other closely related issues such as rock dust testing methods and sampling procedures are discussed.

Jan 1, 2009

By George L. Gates

The Bureau of Mines developed a rapid instrumental method of analyzing oil well scales containing primarily barium sulfate. After removal of oil and water by carbon disulfide) the scale was dissolved in strong hydrochloric acid. The cations, barium, calcium, strontium, magnesium, and iron, were determined with the flame photometer using the method of additions. Sulfate was deter-mined colorimetrically after separation by selective adsorption on an alumina column. Phosphate was determined colorimetrically and carbonate titrimetrically. The method was reasonably accurate, although iron and magnesium were found to have mutual interference.

Jan 1, 1965

By J. P. Hansen

The Bureau of Mines has investigated the S02 leaching of MgO from high-MgO-bearing Florida phosphate concentrates. The S02 was effective in leaching some of the MgO from three phosphate concentrates; flow rate of the S02 and leach time were major factors in determining the amount of MgO leached. Calcining the samples, then grinding to minus 200 mesh, and elevating the leach temperature gave only small increases in the amount of MgO leached. The research also showed that some of the MgO was so intimately associated with the phosphate mineral that it could not be removed by S02 leaching. This amounted to about 0.6, 0.7, and 1.0 pct MgO in three leached residues. The calculated heads for the three concentrate samples averaged 1.4, 1.1, and 1.5 pct MgO, respectively, before leaching.

Jan 1, 1985

By A. D. Garman

The mining ordinance of Costa Rica dates from 1830. In spite of the numerous attempts to enact a new ordinance , it has been so much amended and reamended during the hundred years of its existence either expressly or , more often , by implication , and sometimes by Executive Decrees of which the validity has been called in question - that in most cases no one but a lawyer thoroughly conversant with Costa Rican mining practice could properly advise with reference to it . The present attempt at a digest of these laws is based on the 1929 edition of Bolandi and Johanning - the only source available in Washington . Apparently this edition has no official character , and the editors themselves often made surmises although one would think that definite facts would be available in Costa Rica where it was published .

Jul 1, 1930

By William A. Beck

"The Piedmont Manganese Belt extends from Taliferro County, Georgia, 70 miles in a northeasterly direction through Greenwood County, South Carolina, and conforms with the trend of the Piedmont Province. The total area of the belt is reported to be about 1,000 square miles, and the maximum-width is about 24 miles.Manganese has been known to exist in the belt since 1845. M. Tuomey mentioned a deposit in the Edgefield district on Hard Labor Creek in South Carolina in a report on the geology of South Carolina published in 1848.Ore was first mined about the time of the first World War, when the Colley mine, near Lincolnton, Ga., was. Opened. The only operation in the area at present is that of the Abernathy & Kehaya Mining Co., at McCormick, S. C.The geographical position of the belt is from west longitude 82° 57’, north latitude 33° 39' to west longitude 82° 06', north latitude 34° 08'. The towns of Washington and Lincolnton, Ga., and McCormick and Greenwood, S. C., are in or near the belt.An exploratory project of the Bureau of Mines was started on the McCormick, S. C., deposit in April 1944, and trenching, test pitting, and hand-auger drilling-were done on a small scale until early in October 1944. (Fig. 1.) In November 1944 work was begun on a property 12 miles north of McCormick, known as Parsons Mountain, which is leased to M. H. McKnight by the United States Forest Service. From March 15 to March 24, 1945, work was done on the property of Mrs. H. B. Ross, which is known as the Morgan farm.The Abernathy & Kehaya manganese mine contains what is locally known as the Dorn gold mine; mineral rights on the property were owned by M. G. & J. J. Dorn, Inc."

Apr 1, 1946

By R. G. Sandberg

Many gold-bearing ores throughout the Western United States contain small quantities of mercury. The presence of mercury not only decreases the gold-loading capacity of the activated carbon, but complicates the fire refining of cathodes and creates a potential health hazard. The Bureau of Mines investigated methods to limit mercury extraction during gold ore leaching and to remove mercury from cyanide leach solu-tions. Mercury dissolution was reduced from 40 to 10 pct by decreasing NaCN concentration from 20 lb to 0.34 lb per ton of solution at a pH of <11. When 0.1 lb CaS per ton of ore was added to a leach slurry, mer-cury extraction was reduced from 27 to 0.4 pct. Less than 0.5 pct of the mercury was solubilized when <0.1 lb CaS per ton of are, along with lime and NaCN, was added to a simulated grinding circuit.

Jan 1, 1984

By R. D. Leitch

The work of the United States Bureau of Mines on stream pollution by coal-mine drainage has included a study of seasonal variations in acidity and volume of several streams in Pennsylvania. The acidity of these streams has been determined during the two or three years prior to 1930 and the results may be considered to represent "normal" low water conditions. The summer of 1330, however, was unusually dry and represents what may be termed "extreme low water conditions on these streams. This report is a comparison of the results obtained for extreme low water of 1930 and for other years. The streams investigated were Buffalo Creek in Somerset County, Indian Creek (lower 5 miles) in Westmoreland County, Little Toby Creek in Elk and Jefferson Counties, Daguscohonda Run in Elk County and West Creek in Elk and Cameron Counties. These will be treated separately in the order given. Most of the descriptive matter and physical data pertinent to the streams and drainage basins are taken from published reports of the Pennsylvania State Water Supply Commission, 1917.

Jan 1, 1931

By A. W. Khair, M. Ahmad

"Bit wear has been proven to have a significant effect on respirable dust generation in coal cutting system. The mechanism of bit wear can be adhesion, abrasion. oxidation, or diffusion. depending on cutting conditions. This paper presents a portion of an extensive ongoing series of studies to better understand the principles of bit wear and dust generation. Used bits collected from underground coal mines were analyzed to identify the basic principle of bit wear in coal and rock cutting. Distribution of weight loss and conical height loss of worn bits were studied and bit wear was divided into four stages according to weight loss. Utilizing these worn bits, Laboratory experiments have been carried out to study the effects of bit wear on coal cutting system and respirable dust generation. An Automated Rotary Coal Cutting Simulator was use to perform the experiments. Acoustic emission monitoring is applied to study the effect of bit wear on fracture formation and dust generation. INTRODUCTIONContinuous miners were introduced in the 1950’s and became the major equipment in underground coal production. Now the larger production in the coal industry has increased the demand for continuous miners and their use. It is well known that serious dust problem is also introduced with the use of continuous miners, especially with recent increase in productivity. On the other hand, legal restrictions are made ·more strict by the Mine Health & Safety Administration for the respirable dust generated by the continuous miners to prevent coal workers from incidence of pneumoconiosis. The incidence of pneumoconiosis depends on dust concentration, exposure time, and physical properties of dust. Of them, dust concentration is the best parameter for the assessment of the risk of pneumoconiosis. Although a lot of research work has been done to reduce dust concentration substantially, some areas are still required further investigation to meet the strict regulations. One of the areas is about bit wear and dust generation. In this area, the principles of bit wear and effect of bit wear on dust generation are major concerns."

Mar 1, 1992

By Spencer P. Howell

One of the important problems in metal mining , tunneling or quarrying is the most economical method of bringing down the ore or rock . The two factors having great influence in determining this are arilling and blasting costs . In considering the efficiency of the explosive used , the diameter of cartridge has always been supposed to play an important part . However , the Bureau's attention has been called to the lack of definite data on the effect of cartridge diameter on the strength and sensitiveness of high explosives . This information is especially valuable to the user of explosives as it assists him to determine what diameter of borehole is most economical . A paper* on "The effect of cartridge diameter on the strength and quickness of high explosives " was submitted to the sub- committee on Drills and Drill Steel of the 24th Annual Convention of the American Mining Congress by Charles S. Hurter , Technical Representative of the E. I. duPont deNemours and Co. In this paper Mr. Hurter points out that the physical characteristics of an explosive most affected by the diameter of cartridge are rate of detonation and sensitiveness to explosion by influence , and that both increase with increase in diameter . As there is a continuing tendency to the use of smaller diameter drill holes in order to lower drilling costs , and as the smaller drill hole requires a smaller diameter of explosive cartridge than larger drill holes do , this paper has been prepared to show the effect the diameter of cartridge will have on the strength and sensitiveness of the high explosives which may be used . Accordingly , the Bureau of Mines , in cooperation with the Institute of Makers of Explosives , has carried out a series of tests to show the effect of cartridge diameter on the strength and sensitiveness of certain high explosives .

Jan 1, 1923

By A. L. Engel

A representative sample of gold-silver ore from the Keystone Mine, Manhattan, Nye County, Nev., was submitted for these tests. The ore was an altered diorite rock with very small amounts of sulfide minerals of copper, lead, zinc, antimony, and arsenic disseminated in fine grains throughout. As indicated by test results, much of the silver content of the ore apparently was associated with these sulfide minerals. The gold probably occurred with iron oxides in the ore. Assays showed 0.16 ounce of gold and 2.8 ounces of silver per ton of ore. This investigation was made to study application of activated carbon in the cyanidation treatment of the ore. The treatment proposed for u.se at the mill is as follows: The ore is crushed to minus-10-mesh size and separated into plus -and minus-65-mesh portions. The minus-10, plus 65-mesh sands are cyanided by leaching and the minus -65-mesh slimes by agitating. After 48 hours of agitation the slime pulp is thickened to about 1:1 water:solid ratio, and part of the pregnant solution is recovered. The pulp is then diluted to a 2:1 ratio, and the remaining dissolved values are extracted with the activated carbon. The barren pulp then can be discarded. This procedure eliminates the necessity for further washing the slime pulp and also recovers most of the excess sodium cyanide required for extracting the optimum amount of silver from this portion of the ore.

Jan 1, 1951

By Eugene Frey

The Romur is one of several properties in the Copper Mountain mining district, Fremont County, Wyo., that contain scheelite deposits. The district lies on the southern slope of the Bridger Mountains, 18 miles northeast of Shoshoni and 15 miles from the rail point at Bonneville on the Chicago, Burlington & Quincy Railroad (figs. 1 and 2). The tungsten deposits occur in a zone of pre-Cambrian schists and gneisses that have been cut by numerous basic dikes and granite pegmatite dikes. Scheelite occurs in lenses and pods that lie parallel to the foliation and bedding in the metamorphic rocks. The more important deposits are found in a lime-silicate rock consisting primarily of zoisite but with small quantities of quartz and carbonate. Scheelite was found in December 1941, and the area was mapped by the U. S. Geological Survey early in 1942. In November 1942 the Bureau of Mines commenced work on the Stardust-Comet group for the purpose of developing reserves for war requirements. The initial work consisted of driving an alit in the ore zone a distance of 109 feet. This zone was sampled during the progress of the work, and subsequently surface and underground exposures on adjoining properties also were sampled (figs: 5, 6, 7, and 8). One hundred twenty-four samples were obtained. Sample and assay data are shown in tables 2, 3, and 4.

Jan 1, 1950

By H. Reginald Hardy

This report is Volume III of a three volume final report dealing in general with the microseismic monitoring of a longwall coal mine. The research presented in Volume III was undertaken as part of the overall microseismic project in an effort to relate, if possible, observed micro seismic activity with surface subsidence. A discussion in regard to the correlation of these factors is presented in Volume I of the final report. Field measurements of subsidence carried out at a Central Pennsylvania Coal Mine are described. Comparative analysis of actual field results with data obtained using empirical and finite element techniques Has undertaken. Comparison of field results with published National Coal Board data revealed marked differences. The influence of stronger rock beds overlying the coal seam in the current study was assumed to I be the main cause. Use of the general Gaussian profile resulted in a satisfactory fit to the field data provided the value of the maximum field subsidence was used in the analysis. In general, when low tensile strengths were assumed for the associated rocks, finite element techniques gave results which compared well with the observed field data. The study also indicated that at shallow depths there is a marked difference in subsidence over dip and rise sides of the coal-face, maximum subsidence being shifted more towards the dip side. Finally, time-dependent deformations were shown to be insignificant shortly after mining operations ceased.

Jan 1, 1977

By T. Kessler

The purpose of this investigation was to evaluate the application of a spark-source mass spectrograph equipped with a spinning-electrode system for the study of various high-molecular-weight materials derived from coal. Conclusions from the investigation of anthracene, phenanthrene, chrysene, coronene, truxene, a coal-tar pitch (800 to 850 C softening point), and anthracene-chrysene synthetic mixtures follow: 1. Simplified mass spectra of anthracene, phenanthrene, chrysene, coronene, and truxene, from which the molecular weights were easily determined, were obtained by the spinning-electrode system. 2. Eight structural types having molecular weights from 178 to 252 corresponding to compounds previously observed in an electron impact mass spectrum of a coal-tar pitch sample were affirmed by this technique. 3. Mass spectra obtained from synthetic mixtures of anthracene and chrysene demonstrated that the technique is applicable for semiquantitative analysis.

Jan 1, 1967

By M. Howard Berliner

The Harding pegmatite dike is well known for the production of spodumene and lepidolite in the period 1920 to 1930. It attained greater prominence during the last war by being the largest producer of domestic tantalum ore from the rare mineral microlite. The deposit is believed to be the only proved reserve of tantalum ore in the United States today. In 1943 the main portion of a large tantalum-bearing zone in the Harding dike was developed by the Bureau of Mines with the assistance of the Federal Geological Survey. Analysis of this zone from 39 diamond drill holes and quarry exposures showed a large deposit containing 2 pounds of microlite per ton and 21 percent spodumene, In September 1948, the Bureau of Mines resumed development of the deposit with a view to extending the tantalum-bearing zone farther to the southwest or delimiting the ore body. Seven diamond-drill holes failed to penetrate the ore zone in its southwestward projection, Much of the following general information is summarized from the report on the first exploratory work of the Bureau of Mines by John H. Soule.2/

Jan 1, 1949

By J. D. Davis

"Introduction.Sixty years ago, M. Berthelot found that ethylene could be selectively absorbed from gaseous mixtures by concentrated sulphuric acid, and that the compound formed by the chemical union of the gas and acid was readily decomposed by heating with water, yielding ethyl alcohol. Only within the last few years has there been any attempt to make use of this discovery technically.Bury*, working in England at the Skinningrove Iron Works and on a commercial scale, developed a technical method for converting, the ethylene of coke-oven as into alcohol. With a gas containing less than 3 per cent of ethylene, he obtained a yield of 1.6 gallons of alcohol per ton of coal carbonized.De Loisy** perfected a technical method for treatment of coke-oven as for alcohol. Evidently this work was carried out on a semi-commercial scale. His method is based on the use of catalytic agents for hastening the absorption of ethylene by sulphuric acid. He uses part of the spent acid for drying the gases and pact for the manufacture of ammonium sulphate. Excess acid is reconcentrated by waste heat. Others have worked on the problem, but so far there has been no large recovery of ethylene from coke-oven gases. The chief difficulty seems to lie in the low efficiency (about 50% of methods and tae relatively low concentrations of ethylene in the gases treated. Gas from Trent amalgam*** contains much larger percantages of ethylene than does coke-oven gas, as Will presently be shown, and if it should ever prove practIcal to treat industrial ;as for alcohol, this gas would offer attractive possibilities,* Bury, Ernest, Ethylene as Alcohol from Coke-Oven Gas: Gas Journal' Vol. 148, D. 30, 1919, pp. 718.** DC Loisy, M.E., Sur un procede' industrial de fabrication syntlotique de l'alcool et de l'ether a partir des gaz de distillation de la houil Comp Rend, vol. 170, Jan. 1920, p. 50-3.*** A paste consisting of approximately part oil such as that obtained as for cleaning coal. See Perrott. in cleaning coal, Chem 3 parts finely pulvarized coal and 1 final product in the Trent, process StJ, and Kinney, S.P. The use of oil Vol. 35 August 3, 1921, p, 183.. & Met."

Nov 1, 1922