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By A. Tohn, L. May, Adham. K.

The path from process conception to commercial implementation poses significant technical, economic, and sometimes political challenges for every project team. Solving the technical challenges typically distinguishes successful projects from those that fail. Here, the authors provide an outline for technical success based on lessons learned from years of experience in process design and R&D. Challenges faced by new technology developers, with regard to design and definition, are described. Experience-based methods to avoid missteps are shared. Special emphasis is placed on the selection of viable unit operations, definition of known and unknown parameters, experimental screening of options, and piloting for scalable design information. Use of computational models to define, assist, and interpret the pilot operations and results are described. Furthermore, the value of active collaboration amongst the design, research, and owner team is demonstrated.

Jan 1, 2011

By S. Gößling-Reisemann

Most copper ores contain valuable co-products such as molybdenum, gold, silver, nickel, etc. Sulphuric acid and steam are valuable by-products, which are generated dur¬ing copper production. The environmental impacts from mining and refining therefore need to be shared between these by-products and co-products, an issue in Life Cycle As¬sessment (LCA) referred to as allocation. There are different, recognised methodologies for doing so: burdens can be allocated based on the market values of these commodities, they can be allocated by mass, volume, molar amount, functionality, or other physical, technical or economic factors. All of these methodologies have their respective merits and restrictions, and the choice is usually case specific. Nevertheless, the choice between alternative methodologies can have dramatic effects on the LCA results. Recycling in LCA has to be handled in a similar way, as it essentially constitutes a special case of co¬production. The existing standards (ISO 14040 ff.) allow different methods for imple¬menting recycling and allocation into metal LCAs (open loop, closed loop, value cor-rected substitution, etc.), which are still a subject of discussion in the scientific community. However, the methodology used can significantly influence the ecological profile of copper and copper products. We will present an overview of the different methodologies available for including recycling and allocation and give an analysis of how the meth¬odological choice affects the final LCA results. This work will be followed up by quantitative case studies.

Jan 1, 2007

By Garston H. Blackwell

For ageing open pit mining operations where the economic viability of another pushback is questionable, mine life can be extended by increasing the wall slope. If the steepening is started where ore intersects the pit wall, the capital outlay for waste stripping is minimal. Such a venture must be conducted safely, and a basic requirement would include loading equipment capable of working remotely. In the application described, alternatives in the choice of loader included equipment available on site, or the purchase and assembly of used equipment. Only electric cable shovels were in use at the operation, and it was thought that these would be more capable of digging high muck piles at the productivity demanded by an increasingly efficient mill, and in a challenging environment less suited to a rubber tired loader or hydraulic front shovel. A decision was made to convert an older electric cable shovel to remote controlled operation and to include the application of semi-robotic control. The conversion was completed successfully and is described, along with methods developed for remote operation of a shovel, and the application of various sensors for semi-robotic operation. A plan of operations to mine out several completed double benches and make two quadruple benches with wide catchment berms is depicted. On completion of this task, the working benches developed would be wide enough to operate at near full production. Prior to moving the remote controlled shovel back into the pit, a large wall instability became active, eventually closing the operation. The instability could have been safely mined using the remote controlled shovel.

Aug 1, 2013

By J. R. MacDonald

MINING literature contains very few descriptions of operations producing as little as 25 to 30 tons of ore per day. The purpose of this paper is to discuss the gradual development of a mining method for such a small-scale operation at the No. 2 mine of Central Patricia Gold Mines, Limited, and in doing so to review several systems of stoping applicable to narrow ve1ns. MAIN ECONOMIC FACTORS TO BE CONSIDERED (1) Overhead.-The outstanding feature of most mines operating on a single narrow vein is chat of small daily tonnage. The reason for this low output can be readily understood. The strictly limited ore-reserves present a condition unfavourable for a policy of large initial expenditures, with the result that the capacity of the plant provided must be governed by the? amount of ore in sight at the time when mill construction is planned. This is immediately reflected in the cost per ton, there being relatively few tons over which to distributed the more or less static charges, such as hoisting, heating, supervision, administration, pre-production expenses, and other write-offs. (2) Development.-In mining this type of orebody, the main factor contributing to high costs is unquestionably the small tonnage of ore made available by a given amount of development. Thus, for example, from the data tabulated below it can be seen chat, assuming a 12-in. vein and a drifting cost of $9.00 per foot, the development charge for this item alone would be 71 cents per ton. Add to this the charges for raising, cross-cutting, shaft-sinking, and pumping, besides charges arising from development in waste, and the figure will be very considerably higher than 71 cents.

Jan 1, 1941

By T. Nomura, N. Saitoh, K. Tamaoki, Y. Konishi

We have developed new recycling technologies, based upon an eco-friendly biotechnology, in order to extract precious and rare metals sourced from end-of-life products and electronics. We have been focusing on the metal ion-reducing bacteria, Shewanella algae and Shewanella oneidensis, that are able to reduce and deposit gold ions (Au(III)) or PGMs ions (Pd(II), Pt(IV) and Rh(III)) into metal nanoparticles at room temperature within 120 min. When processing the aqua regia leachate of printed circuit boards, Shewanella bacteria were able to rapidly and selectively collect gold ions under acidic conditions in the presence of heavy metal ions, proposing a new bio-recovery system for gold. This biotechnological procedure also has the potential to allow the recovery of PGMs from the leachate of automotive catalysts. Shewanella bacteria were also able to successfully perform the complete reduction and deposition of the PGM ions. The ability to collect the PGM ions suggests that this represents a new process for the biorecovery of PGMs from used automotive catalysts. Our proposed biological method enables the rapid and highly efficient recovery of precious and rare metals via separation and concentration utilizing microbial reactions at room temperature.

Jan 1, 2014

By C. J. Li, J. L. Feng

In the present study we focuses on developing the poroelasticity model that deals with adsorptioninduced permeability change mostly occurred in porous media constituted several phases such as coal. The underlying pressure induced by adsorption is obtained by Virial expansion form, which is substantially founded on statistical physics. The corresponding thermodynamic pressure applying on the pore surface is then used to detail the pore pressure and further to evaluate the macroscopic volumetric strain and the porosity. In the process of physical adsorption, the adsorbed phase is in thermodynamic equilibrium with the gas phase regardless of pore size, and the corresponding chemical potentials are all equal. The relationship between surface strain and volumetric strain is derived under infinitesimal deformation conditions to gain an explicit formulation of pore surface area with respect to volumetric strain and porosity. After the formulation of surface stress modified by the Langmuir isothermal adsorption is derived, the differential micromechanical constitutive equations of porous media are obtained. By supposing that the ratio of current permeability to initial is equal to the cubic ratio of current porosity to initial porosity, the differential equations for permeability change is consequently derived. The numerical simulations by the present model for permeability change of coal induced by adsorption of CO2 and CH4, respectively, are presented under confined stress conditions. The predictions from the model are good in agreement with the experimental data of sorption-induced permeability change of coals in the literature.

Jan 1, 2015

By R. Siwik, N. K. Davé

"The national reactive tailings (RATS) program is a co-operative industry-government effort to develop practical techniques for closure of reactive tailings areas. This paper summarizes the RATS program objectives and areas of research, and details the Noranda/CANMET project on the Waite Amulet tailings.Geophysical and biohydrogeochemical investigations were carried out at an inactive copper-zinc mine tailings site, Waite Amulet, in Noranda, Quebec. Geophysical investigations consisted of seismic, electromagnetic conductivity and electrical resistivity surveys to determine the thickness of the layers above bedrock and to map conductivity variations within the tailings and the immediate outlying area. Biohydrogeochemical investigations consisted of installing multilevel piezometer nests to determine groundwater flow patterns and porewater chemistry, obtaining solid core samples and characterizing for physical, chemical and mineralogical parameters, and iron oxidizing and sulphate reducing bacterial counts.The geophysical survey indicated a bedrock ridge extending under the tailings from the northeastern outcrop which may act as a porewater boundary layer. The survey also indicated a 2 to 20 m clay layer underlying the main tailings dam. Preliminary results of the saturated zone porewater chemistry have indicated three major zones of high electrical conductivity varying between 1,000 to 12,000 µs and pH between 3.4 to 8. Lower pH and high metal and sulphate concentrations were obtained in a shallow zone near the water table. With depth, the concentration of metal and sulphate ions decreased and pH increased below the water table. The underlying clay layer is relatively impervious -and most of the seepage from the tailings is probably exiting from the sides of the impoundment dam."

Jan 1, 1987

By Bian Xue, Wu Wenyuan

High quality, mono-dispersed, hollow CeO2 microspheres with high surface area were produced by a spray pyrolysis method at 700oC. CeCl3 was used as the raw material of the process rather than Ce(NO3)3 because the latter is relatively difficult to obtain in industrial quantities. X-ray diffraction and electron microscopy results confirm the high quality synthesis of hollow CeO2 microspheres with narrow size distribution, good mono-disperse, and good reproducibility. The process of the formation of mono-dispersive CeO2 microspheres was investigated by chemical dynamics and a possible mechanism is proposed. This simple method for synthesis of CeO2 microspheres is easily scaled up to fabricate other metal oxide nanostructured materials at industrial scale.

Jan 1, 2014

By D. Laguitton, D. Cimon

"BILMAT is one of the most powerful algorithms in existence for material balance computation in mineral processing flowsheets. It is based on a hierarchical decomposition coupled with the Lagrange multipliers method widely reported in the literature. Flowrates can be calculated optionally for pulp, solid or water. Assays are adjusted for a variety of subnetworks, such as assays of the solid as well as assays of fractions of the solid called level 4 data (l: pulp, 2:solid and water, 3:assays of solid, 4:assays of classes of solid).BILMAT4 is a new implementation of BIU1AT that operates in a new microcomputer environment and makes the method more accessible than ever. Its main features are a full-screen colour editor allowing graphic flowsheet drawing and data entry with automatic error checking. Mass balance equations are automatically generated by analysis of the graphics and corresponding data, thus relieving users from the error-prone definition of networks. Sensitivity analysis is performed to assess confidence intervals of computed flowrates and adjusted assays.BILMAT4 incorporates an option for gold leaching circuits where the element to be balanced appears in both the solid and liquid phases with negligible effect on the mass flows of solids. Recoveries are computed in all streams. This program is currently released by CANMET as part of the CAMP collection for Computer Aided Mineral Processing. A complete sample run of the program is discussed."

Jan 1, 1989

By M. Leijd, K. S. Forrester, M. Saxon, M. Oczlon

This paper provides an introduction to wet high intensity magnetic separation (WHIMS) and its successful application to the beneficiation of rare earth element (REE) enriched eudialyte. The analysis includes an in-depth reporting of the deportment of key elements as well as a statistical interpretation of the relative importance of operational parameters including magnetic field intensity, flow velocity, and matrix loading density. Conclusions are drawn on the relative success of the technology, potential areas for process improvement, and the research direction that continues to be investigated. Three original equipment manufacturer (OEM) technologies were subjected to a series of screening and characterization tests to identify the optimal operating parameter set to magnetically beneficiate eudialyte from Norra Kärr, Sweden. Upon the completion of the characterization test it was apparent that the Metso HGMS technology was superior with respect to REE recovery and gangue rejection for the Norra Kärr composite. The Metso HGMS was then subjected to a series of verification tests to confirm the repeatability and reproducibility of the system.

Jan 1, 2014

By J. W. Scott, G. G. R. Falkenberg

"The Syncrude project is an integrated complex designed to mine, extract and upgrade bitumen from the Athabasca tar sands to produce 129,000 barrels per day of synthetic crude oil. This paper provides a brief general description of the location, history and geology of the tar sands and the overall organization and structure of the project. The major emphasis and the bulk of the detail presented deals with the extraction plant; a material handling and mineral processing installation designed to treat 312,000 tons per day of tar sand feed.History of the Tar SandsThe Athabasca tar sand deposit was recorded in 1788 by Peter Pond, however the first serious geological mapping and exploration did not begin until 1915. Little interest was taken in the deposits until the Second World War, when the governments of Canada and Alberta conducted an extensive exploration program. In addition a number of pilot plants were sponsored during the 1940 -1950 decade. The hot water separation process was successfully demonstrated on the pilot plant scale during 1948 -49, and was established commercially in 1967 in the G.C.O.S. plant. The Syncrude plant, due to come on stream in April 1978, also employs the hot water separation process."

Jan 1, 1978

By Darrell McClarty, Roger Payne, Matt Haggis, Michael Courtin, Deborah Berthelot

"Over forty years of uranium mining in the Elliot Lake region of Ontario (I 956-1996) has resulted in the production of over 300 million pounds of uranium. With the completion of mining activity, Rio Algom Limited and Denison Mines Limited are utilizing progressive environmental technologies and management systems to reduce and manage the environmental risks associated with the 150 million tonnes of potentially acid-generating tailings in nine regional waste management areas. Water covers designed to reduce oxygen entry and thereby significantly inhibit acid generation have been applied at six of the sites with the Quirke site serving as a demonstration site for the Mine Environmental Neutral Drainage program. All five of Rio Algom Limited' s effluent treatment plants are monitored and controlled from a central control station utilizing a Supervisory Control and Data Acquisition (SCADA) system based on ""Fix Dmacs"" technology. Scheduling, auditing and reporting of plant operating and environmental monitoring programs for the entire watershed are controlled utilizing the Regional Environmental Information Management System (REIMS). Proper application of these technologies and management systems facilitates delivery of cost-effective environmental monitoring, care and maintenance programs at these sites and provides tools to demonstrate compliance with all environmental performance criteria.IntroductionCost-effective management of multiple tailings management areas distributed throughout a 35 km watershed requires the application of leading-edge environmental technologies. Long-term monitoring, care and maintenance costs must first be minimized through the application of decommissioning technologies that inhibit acid generation and minimize the release of contaminants from the sites. On-going operating costs must then be controlled through the application of environmental management strategies that optimize the allocation of resources while ensuring compliance with regulatory and Company environmental requirements.Using sites in the Serpent River Watershed as an example, this paper demonstrates the effectiveness of water covers as a decommissioning strategy to inhibit acid generation. In addition, the Telemetered Environmental Operating Control System and Regional Environmental Information Management System are reviewed as examples of the application of environmental technologies to the management of environmental programs."

Jan 1, 1998

By K. Sinding, R. Poulin

"Recent land-use decisions in British Colwnbia, and the publication of a report on compensation for expropriations of resource interests, have highlighted the nature of land use policies. Landuse decisions, such as the creation of large new parks, raise three principal issues which have implications for how land-use policy is conducted and how it impacts on the mining industry. The first is the identity of the parties advocating different land-use policies and their motives for doing so, the second is the changing nature of benefits derived from land, and the third is the change of property-rights regime which is devised to accommodate the (changing) benefits from using land and natural resources, as well as the interests of the different parties involved.Involved Parties and BenefitsThe process of establishing or modifying property rights depends on the interest groups involved. Three distinct categories, each with distinct incentives which can influence the process, must be distinguished: private claimants, politicians and bureaucrats (Libecap, 1989).The first groups claim rents and management powers through asset ownership. They may be incumbent owners seeking enforcement of the status quo, new claimants seeking redistribution of assets, or third parties who depend on the distribution of assets (e.g. lenders, labour suppliers and contractors). Some infonnal property arrangements can be negotiated within the group whereas others requires action in the political arena through lobbying politicians for (re)allocation of property rights and influencing bureaucrats for favourable administrative decisions. The second category is politicians, who direct the powers of the state to change or enforce property rights. Both incwnbents and office-seekers fall in this category and their actions and opinions are shaped by their constituencies and financial backers. However, not all causes can be championed and trade-offs have to be made, resulting in decisions that maximize political benefits. The third category of parties in the process is the bureaucrats. The power to manage has been delegated by politicians but bureaucrats also have opportunities and incentives to further their own interests. These can include maintaining or expanding jurisdictional turf or increasing operating budgets (Libecap, 1989)"

Jan 1, 1994

By Terry Aben

Outline ?Review of standards that can be used to identify current coating conditions and optimal points to perform coating maintenance. ?Identify how standards can be used to extrapolate the future condition of coatings to achieve predictive maintenance planning. ?Demonstrate how the above can be combined with project estimating to generate a data driven, quantitative, predictive, risk-based asset integrity maintenance program for Protective Coatings. The Value of Asset Integrity Programs ?Maximize the benefit produced from the investment in maintenance spending. ?Get the best bang for your buck! ?Don?t perform maintenance work before it is necessary ?Money is invested early with no increase in the service life extension. ?Don?t delay until it is too late. ?Planned Maintenance is far less costly than Reactive Maintenance. ?Identify the Optimal Point for Maintenance.

Nov 1, 2011

By Alex Luyima, Michael Moats

"In the present work, the oxidation of manganous and chloride ions on a mixed metal oxide (MMO) anode from a 40 ºC electrolyte containing 160 g/L sulfuric acid (H2SO4) with various concentrations of Mn2+ and Cl- was studied using cyclic voltammetry. These results indicated that Mn2+ concentration does not affect Cl2 evolution on a non-MnO2 coated MMO anode. However once MnO2 deposits on the MMO anode, Cl2 evolution is inhibited. The effects of manganous concentration and chloride concentration on the amount of MnO2 deposited in one hour were also evaluated. Cl- concentration did not affect the amount of MnO2 generated. Increasing Mn2+ concentration resulted in an increase in the amount of MnO2 deposited.INTRODUCTIONThe electrolytic recovery of zinc (Zn) is a well-known process and is estimated to produce approximately nine million tons of Zn per year worldwide (Recendiz, Nava, Lartundo-Rojas, Almaguer, & Gonzaleza, 2009). The Zn produced by this process is of high purity and has a wide range of applications, such as galvanizing (car body parts, pipes, metal wires, etc.), sacrificial anodes in offshore industries, casting alloys, alloying of brass, primary and secondary battery industries, etc.The electrochemical production of Zn employs aluminum cathodes and lead-silver anodes (Pb- Ag) (Recendiz et al., 2009). The Zn containing mineral (ZnS) is usually associated with other elements such as Mn, Mg, Ca, Cd, Cu, Cl, Fe, F, Co, Ni, Al, As, Sb, Si, Sn, Ge, Hg etc. (Nijjer, 2000). After processing of ZnS concentrates, the electrolyte obtained still contains residual metallic and non-metal impurities. Some of these impurities can impact the corrosion rate of Pb-Ag anodes."

Jan 1, 2016

By P. Keller, T. E. Lister, G. G. Clark, L. A. Diaz

As electronic technology continues to evolve there is a growing need to develop processes which recover valuable material from antiquated technology. This need follows from the environmental challenges associated with the recovery of raw materials and fast growing generation of electronic waste. Although present in small quantities in electronic devices, the availability of raw materials such as rare earths and precious metals becomes critical for the production of high tech electronic devices and the development of green technologies (i.e. wind turbines, electric motors, and solar panels). Therefore, the proper recycling and processing of electronic waste presents an opportunity to stabilize the market of critical materials, providing a proper disposal and treatment of a hazardous waste stream. This paper describes the development and techno-economic assessment of a comprehensive process for the recovery of value and critical materials from electronic waste. This hydrometallurgical scheme aims to selectively recover several value streams (base metals, precious metals, and rare earths) present in electronic waste. The economic feasibility for the recovery of rare earths from electronic waste is mostly driven by the efficient recovery of precious metals, such as Au and Pd (ca. 80 % of the total recoverable value). Rare earth elements contained in magnets (speakers, vibrators, and hard disk storage) can be recovered as a mixture of rare earth oxides which can later be reduced to the production of new magnets.

Jan 1, 2016

By M. M. Papic, J. C. Whitehead

"A sample of Hat Creek coal has been extracted using supercritical aromatic solvents in a laboratory-scale extraction unit. Extract yields in the range 21 to 27 per cent of dry-ash-free coal were obtained.These yields are significantly lower than yields available from high-volatile bituminous coal and some lignites. Thus in a combined extraction/hydrocracking scheme for the production of liquid fuels from Hat Creek coal the char product would exceed that required to supply the energy and hydrogen requirements of the process. Excess char could be used for the production of power or gas for sale.IntroductionThe Supercritical Gas Extraction (SGE) process developed by the U.K. National Coal Board operates in two stages: an extraction stage in which a coal extract is separated from mineral matter and undissolved coal and a subsequent hydrogenation stage.The SGE process is based on the ability of a compressed supercritical fluid to dissolve relatively high molecular weight substrates. It is operated under conditions where a hydrogenrich portion of the coal is selectively extracted in a short residence time extraction stage leaving a hydrogen-deficient char. The process schematic shown in Figure I illustrates that the extract produced is separated from the solvent and passed to a conventional hydroprocessing stage while the char product is utilized in the production of heat, power and hydrogen for the process. An extract yield in the order of 50 per cent dry-ash- free coal represents a ""balanced"" case for such a process in which there is just sufficient char for the provision of these commodities."

Jan 1, 1985

By V. I. Peresypkin, A. Y. Lein, N. S. Bortnikov, Yu. A. Bogdanov

"Abstract - The lipid component in hydrothermal deposits of the Logachev vent field, at 14°45_N of the Mid-Atlantic Ridge (MAR) and Broken Spur vent field, at 29°N of the MAR, was studied. Biochemical, gas chromatographic (GS), and molecular mass methods (GC-MS) research established the mixed nature of the organic matter (OM) including phytoplanktonogenous, chemosynthesized lipids, and lipids of questionable origin. Specific local conditions around the sulfide ores of the black smokers (absence of free oxygen and presence of reduced copper, which prevents OM degradation) facilitate the preservation of biogenic material, including bacteria. The main differences between the lipid compositions of the hydrothermal deposits of these two vent fields relate to the variable nature of hydrothermal circulation systems.At the 14°45_N vent field, high-temperature hydrothermal fields are forming due to the reaction of sea water with upper mantle ultrabasic rocks during serpentinization (a deep hydrothermal circulation system). High pressure and temperature (>400°C), a reducing environment and the presence of various metal oxides are favorable for the abiogenic synthesis of CH4 and oil hydrocarbons (HC). At the Broken Spur vent field, hydrothermal deposits are forming above axial crust magma chambers due to the interaction of sea water and basalts (an axial hydrothermal circulation system). Abiogenic synthesis of HC also occurs in this situation, but to a considerably lesser extent."

Jan 1, 1999

By Ken Musgrave

"A program is described that helps managers and supervisors control maintenance more effectively. Work- order generation, preventive maintenance, repair parts inventory, planning and scheduling, reporting, analyzing costs, printing purchase orders and other functions are covered. Flexibility often permits integration with other programs such as payroll, cost accounting and materials management.The Role of MaintenanceMaintenance provides a service to allow the rest of the operation to do its job effectively. Its success should not be measured by maintenance cost alone, but also by its effectiveness in reducing downtime and maximizing production. It can make sense to spend more maintenance dollars if this results in an even greater contribution from increased production.The Cost of MaintenanceIn mining companies, maintenance costs can be as much as half of operating costs. Maintenance has generally not been given the management attention that an expenditure of this magnitude deserves."

Jan 1, 1986

By B. Krysa, A. Mitsui, T. L. Koehler

The presence of arsenic, even at trace levels, in copper processing leads to the risk of arsine gas where reducing conditions exist that can reduce any soluble arsenic present to its minus 3 valance state and generate hydrogen gas from the solutions. This risk is understood to be significant within the industry, particularly in the case of liberator cells where copper concentrations in solution are drawn down to remove the copper and impurities from the bleed stream. However, there are numerous other potential areas where the arsine gas risk exists including contact between active metal such as iron, zinc or aluminum and arsenic bearing solutions in pyrometallurgical dust treatment, refining and acid plant operations. In turn this breaks down to different mitigating strategies dependent on the risk scenarios considered; for example, how this risk interacts with Change Management, Confined Space Entry or Contractor Training. The ISO 45001 is an emerging standard meant to improve employee safety, reduce workplace risks and create safer working conditions all over the world. The paper shows a case study of how a framework consistent with the tenets of ISO 45001 has been used to provide a consistent assessment of this risk for a wide variety of copper operations and the expectations of how this may be used to effectively improve the effectiveness of barriers against future incidents. INTRODUCTION Arsine gas (AsH3), first identified in 1775, is a highly poisonous, colorless, non-irritating gas with a mild garlic odor that is heavier than air. Arsine gas is generated when reducing conditions are generated in the presence of hydrogen ions and arsenic compounds. Present permissible occupational exposure limit as defined by Occupational Safety and Health Administration (OSHA) as an 8-hour time-weighted average is ppm (0.2 mg/m3). Further increasing the risk, conventional respiratory protection utilizing half or full masks with gas filtering cartridges provide minimal protection against arsine. In copper processing plants, the risk of arsine generation is well understood in liberator cells, which are part of the electrolysis process. In this process, solutions containing copper are reduced in copper concentration removing not only the copper, but also arsenic, antimony and bismuth. The residual solution can be bled to control impurity build-up in the refinery. In this process, if the copper concentration is reduced to the point where As3- can form, arsine gas is generated via reaction with hydrogen ions generated during the plating process. The copper concentration at which arsine gas is generated depends on copper concentration at the cathode surface, the temperature and the acidity. As a result, there is always a risk of arsine gas generation in the liberator cell. Process measures to minimize or mitigate arsine evolution are tight control on final copper concentration, warm temperatures, fresh feed distribution and internal acid recirculation rates. Operator exposure protection measures are hooding, ventilation, arsine detection systems, restricted personnel access, automated shutdown controls and pre-defined evacuation plans.

Jan 1, 2019