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By Bruno Deves Flores

O presente trabalho tem como objetivo investigar a influência da adição de carvão vegetal e do seu tamanho de partícula na reatividade do coque. Para isso, um carvão vegetal de eucalipto foi adicionado a um carvão médio volátil americano em três teores (3%, 5% e 8%) e em duas faixas granulométricas distintas (abaixo de 1 mm e entre 3 mm e 4 mm). O carvão individual e as misturas de carvão/carvão vegetal foram carbonizados em um forno de escala laboratorial (1 kg). A reatividade dos coques produzidos e do coque de referência foi avaliada e comparada usando análise termogravimétrica. Também foram realizadas análises morfológicas através de microscópio óptico e eletrônico, usando amostras antes e após os ensaios termogravimétricos. Baseado nos resultados, a influência da introdução de carvão vegetal na reatividade do coque foi analisada e discutida neste trabalho.

Aug 1, 2018

By Timothy A. Clancy

To help reduce the Nation's dependence on imported chromite, the Bureau of Mines is conducting research on the use of dolomites as an alternate material. Dolomite is a plentiful domestic resource and offers certain advantages as a refractory raw material. A review of the literature has indicated that there are many sources of high-purity dolomite in this country and that European nations use a greater proportion of dolomite refractories, primarily in steelmaking, than the United States, The Bureau of Mines characterized 14 domestic dolomites as to chemistry, density, mineralogy, microstructure, and thermal behavior, to develop baseline data on their suitability as refractory raw materials.

Jan 1, 1983

By Khaled Morsy

The studied mine extracts the Sewickley seam using room-and-pillar method. The overburden at study site ranges from 400 to 800 ft. Eight years earlier, the Pittsburgh seam was mined 80 ft underneath the Sewickley seam. Parts of the mains at the study site experienced problems of rib spalling associated with floor heave. Numerical modeling was used to explain the mechanism of ground control problems encountered at the mains of the upper seam. The modeling results show that the ground control problems encountered were caused by multiple seam interactions with the previously mined longwall panel of the lower seam. Based on the modeling results, a criterion to predict the probability of multiple seam interactions was proposed.

Jan 1, 2006

By Hendrick A. D. Kirsten, A. Clayr Alexander

Stillwater Mining Company is currently developing a second underground palladium and platinum mine approximately 21 km (13 miles) west of their existing Nye operation in the Bear tooth Mountains of southern Montana. Portals for the two access tunnels required at the new site were excavated in limestone talus to accommodate4.6 m (15 feet) diameter tunnel boring machines. A review of the technical design, field conditions and construction of the portals is presented.

Jan 1, 2001

By Mark DeSalvatore

Currently, at Caltrans, the Office of Structure Design is carrying out an extensive seismic retrofit program involving transportation structures throughout California. The goal of the retrofit program has been to upgrade existing transportation structures to meet the present seismic codes and anticipated loads that are generated during a seismic event Part of the retrofit program involves retrofitting existing structure foundations when required. To determine if the foundations of a specific structure need to be retrofitted, an engineering analysis of the existing foundations has to be done. If the engineering analysis of the structure foundations determines that the foundations will not meet the load carrying demands required by the structural engineer, the existing foundations are then retrofitted. The retrofit projects that require foundation modifications can be separated into two general cases. The first case comprises structures where the original designs will not meet the demands of the present seismic design code. In this case, the existing foundations are not capable of providing the load capacities the current seismic code requires. The second case consists of structures where the retrofitting of the superstructure will increase the required load carrying capacity of the existing foundations during a seismic event In this case, the anticipated load demands on the existing foundations are greater than the foundations are capable of providing. For either of the cases listed above, the present strategy for increasing the capacity of the existing structure foundation consists of installing tiedown anchors or large capacity piles to provide the required resistance to seisraically induced loads.

Jan 1, 1993

By J. N. Van der Merwe

"A major shortcoming of the statistical back-analysis of coal pillar strength is that it relies on the asmined pillar dimensions, not taking into account time-related pillar scaling with subsequent reduction in pillar width. The paper describes an investigation where the rate of pillar scaling was applied to the pillars in the databases of failed and unfailed pillars. The reduced pillar sizes were then used in the same method of statistical back-analysis that had been used in the past.This resulted in an equation for pillar strength which predicts significantly greater pillar strength than the previous statistical analyses, which is similar to the strength which had been found earlier by direct testing of large specimens underground. It is concluded that the lower strengths found by previous statistical analyses are due to the incorrect pillar width being used and that by adjusting the pillar sizes to compensate for scaling, more credible results that correspond to direct testing are obtained.As the newly derived strength equation is time-dependent, it follows that the safety factors and probabilities of failure are likewise time-dependant. An equation to determine the probability of failure is also developed. This results in the safety factor being close to unity at a probability of failure of 50%, which is aligned to statistical expectation. IntroductionSince the Coalbrook mine disaster, caused by massive pillar collapse, there have been several attempts at analysing and defining the strength of coal pillars. It was realized in the very beginning that performing classical strength tests on coal specimens in a laboratory and then transferring those results to real coal pillars could not be successful. The scatter of results is one problem and, more seriously, there is a size effect (at least for small specimens) that made the transformation of strength results to much larger coal pillars underground all but impossible.Two main schools of thought then emerged. Some researchers preferred to perform direct strength tests on large specimens underground, while others relied on statistical back-analysis of failed and unfailed pillar cases, attempting to determine the differences in size and shape that would allow a satisfactory prediction of failure. The latter school of thought resulted in the method that was widely accepted by the South African coal mining industry, described in the landmark publication by Salamon and Munro (1967)."

Jul 1, 2019

By David Whalen

Mobile equipment in oil sand mining operations experience more maintenance problems than similar equipment in other surface mines, due to soft underfoot conditions. Oil sand properties are known to vary with temperature, bitumen content and previous loading cycles. One of the challenges is the widely variable underfoot pressure which supports shovels and trucks. In the case of a heavy hauler driving on in-pit roads, each tire is supported by a different ground stiffness resulting in an apparent uneven surface. Driving over uneven ground causes twist in the truck frame, which is transmitted to the dump body. Through a finite element analysis of a haul truck dump body, it was shown that slight frame twists produce localized stresses in the intersections of the floor stiffeners. These stresses are at times greater than those resulting from the maximum ore weight and are primarily responsible for cracking in these intersections. Syncrude maintains high quality haul roads, which are constructed of gravel, and makes every effort to keep the shovel pit roads as smooth as possible. This problem cannot be avoided through operational practices only and must also be accounted for in the design of haul truck bodies.

May 1, 2003

A way back in 1851-2 an army of diggers had commenced the conquest, of the now famous goldfields of Australasia. At that time, and in the Colony of Victoria, more that 10,000 were camped on and around the slopes of the silurian ridges over which Ballarat East h'as been built. A wonderfully rich golden harvest was soon gathered from the alluvial found high on these slopes, and from runs (or gutters) which got their rise on them, and were traced down gullies into a broad valley. In due course it was ascertained that the valley carried a main gutter which represented the unity of the higher ones, and further explorations proved this gutter to have a westerly and then a southerly trend toward and under a basaltic plateau, on the top ofwhich Ballarat West and Sebastopol now stand. In the records of alluvial gold mining all the world over the Ballarat field can be classed amongst the richest. Gold in pieces the size of beans, in, stringy filigree bits, in dust and in solid lumps (the largest of which weighed more than 2,200 ozs.), was obtained in the comparatively shallow ground on the slopes; and speaking generally, great and uniform richness was met with along a belt of country on which, in a north and south line, the present quartz mines of Ballarat East are at work. It was noticed by the diggers that when the gutters crossed the upturned edges of the ,strata, the gold deposits in them were patchy, and that when they trended north and south on this beltthey carried rich deposits for longer distances. In time it was also noticf!d that a class of stringy, irregular shaped quartz occurrences, in a bottom of soft slates, in the, immediate vicinity of tpe g)ltter, meant greater richness, and (in the aIluvial) on the higher ground slabs of quartz would now and then be met with, in which strings and spongy masses of gold were found. As the shallow alluvial became worked out the diggers turned their attention to the quartz occurrences, and, now and again the striking of a flat make of a very golden nature would cause quite a stir in the local mining world.

By W. Pariseau, S. Puri, S. Schmelter

Introduction Joints often have profound effects on elastic properties and strength of rock masses and therefore on rock slope stability. In surface mine slopes, joints are usually too numerous to be taken into account individually, so an equivalent properties approach is necessary. Previous work that treats a jointed rock mass as an equivalent composite material of joints and intact rock between resulted in excellent agreement between estimated and true rock mass elastic moduli in case of fully persistent joints (e.g., Pariseau, 1999) Rock mass failure mechanisms on joints and through intact rock were retained obviating the need for an equivalent rock mass strength. Impersistent joints, which are not continuous on a joint plane, can be accommodated (Pariseau, 2003). However, slope stability analysis of a large, deep copper mine indicated a need for computational efficiency even in two-dimensional analysis of vertical sections through pit walls (Puri, 2006). The analyses by the popular finite element method used small elements of bench size near the pit slopes and much larger elements away from the pit walls. The reasons for the graded meshes were numerical quality (small elements) and computational economy (large elements). Small elements contained only a few joints, while the larger elements contained hundreds of joints and led to impractical computation run times (days!). A new modeling procedure that recognizes sufficiently large elements as representative volume elements (REV’s) overcomes this obstacle. A companion improvement recognizes the concept of a representative area element (RAE) in association with joint impersistence and the probability that joint material occupies a considered site. Both are steps towards greater model realism and a practical slope stability analysis procedure. Consider the open pit mine photo shown in Figure 1(a), a companion plan view in Figure 1(b), and the problem of slope stability where high slope angles favor economics but low slope angles favor safety. These competing factors in surface mining generally result in some sections of the mine that have unstable slopes that require monitoring and perhaps mitigating action to improve stability. Although stability of a given section may not be easy to quantify with a single number, useful design guidance can be obtained from a finite element analysis of a proposed mining sequence leading to future pit slopes and profiles. The presence of water from rain and snow melt indicates a need for a coupled analysis that links water pressure, effective stress and total stress (Schmelter, 2001).

Jan 1, 2007

By M. R. Pickus, I. W. Pickus

ORDINARILY age-hardening is thought of as being associated with a limited solubility of one metal in another. Much less has been written about the type of age-hardening that attends the formation of superstructures. Solid solutions generally have a disordered or random arrangement of atoms; that is to say, in a unit cell, such as that of the face-centered cubic lattice, there is no distinction between atomic sites. Atoms of a given metal may occupy cube corners or face centers. Under certain conditions, however, some alloys develop what is known as an ordered structure. In this case, cube corners would be occupied by only one type of atom and face centers by another type, Associated with this ordering process are many interesting changes in physical and electrical properties. Moreover, in many instances the alloys become susceptible to age-hardening. From the evidence now to be described, it appears that age-hardening in 14-carat gold alloys is due to the formation of both a super-structure and a precipitate. Alloys of the metals gold, silver and copper were known in antiquity. The available knowledge regarding their constitution has been ably summarized and extended by Sterner-Rainer,1 Janecke,2 Carter,3 Wise,4 and Coleman.5 Despite the long familiarity with these alloys and the numerous investigations of their properties that have been made, there is still much that remains unexplained. It has been known for a long time that the hardness of these alloys is closely related to the rate of cooling, Similar changes have been observed in the binary gold-copper system,6 one alloy of which corresponding to the formula Cu3Au, has been the subject of a careful and competent report by the English investigators, Sykes and Evans.7 They have established the fact that the shift of atoms from the ordered to the disordered condition takes place in some critical temperature range. At temperatures above the critical range the structure is random, and at temperatures below it the structure is ordered. No difference between these two structures is revealed by the microscope. Both have a face-centered cubic lattice and complete solubility, so that there is no evidence to suggest that the changes in properties are associated with a phase change, The more slowly the alloy is cooled, the higher is the degree to which the ordering process proceeds and the more marked is the increase in hardness. As experimental data were accumulated on 14-carat gold alloys, several contradictions arose. Certain observations tended to confirm the existence of a superstructure, while other observations seemed to be inconsistent with such a transformation. PRESENT INVESTIGATION As a focal point about which to develop this subject, it is expedient to consider first

Jan 1, 1943

By A. Nuric, S. Nuric, L. Kricak, M. Negovanovic, S. Mitrovic

"SynopsisRotary drilling with rolling tricone bits is the most widely used method for drilling large-diameter blast-holes in large surface mining operations. This drilling method is applicable to a wide range of soft to hard rock materials. This paper presents a fuzzy model for predicting the penetration rate of tricone rotary blast-hole drilling. The model is based on data obtained during the drilling of blastholes in rocks with various uniaxial compressive strengths in the Veliki Krivelj open pit mine, Bor, Serbia. The model was developed using the fuzzy logic toolbox of MATLAB with the Mamdani inference system. The fuzzy model was tested with 23% of the total dataset. The results obtained show the high reliability of predicting the penetration rates. Although there are possible limitations in applying the model to other open pit mines because of differences in rock properties, the prediction methodology applied in this paper can be used in many other predictions of the penetration rates.IntroductionAccording to Tamrock, rotary blast-hole drill operations depend on four important elements:•,Torque in the drill string drive sufficient to turn the bit in any strata encountered•,A high bit loading capability (pulldown force) sufficient for optimum penetration•,An air volume sufficient to remove chips generated during the drilling and to provide cool air to the drill bit bearings•,The selection of the proper type of bit for the material being drilled (Tamrock, 1984).The effects of rock mass parameters on the choice of the type of tricone bits were investigated by Kricak (1997)."

Jan 1, 2015

By W. K. Connor, O&apos

Thermal Treatment Technology Division Albany Research Center, U.S. Dept. of Energy Oregon. This evaluation included a characterization study and direct smelting tests conducted in a bench-scale electric arc furnace (EAF). In contrast to other thermal treatment technologies considered for these wastes (i.e., fluidized bed combustion), direct smelting in the EAF can process 100% of the wastes without prior beneficiation, and utilizes solid oxidant additions (in this case iron ore) rather than air to oxidize the carbon. This solid oxidant addition is advantageous because it results in the production of several value-added furnace products. These products include cast iron resulting from the reduction of the iron oxides, baghouse dust containing virtually all of the zinc from the residues, and a clean (nonhazardous) slag product suitable for recycle as concrete aggregate or construction fill. Offgas from the smelting furnace also holds potential as fuel gas for cogeneration. The direct smelting tests conducted thus far were successful at producing the desired furnace products, exhibiting the potential for complete recycle of the waste pile. A cast iron product of comparable quality to conventional cast irons was produced, at nearly 80% iron recovery to the metal. The slag product was determined to be nonhazardous, based on the EPA TCLP. Lead and zinc partitioning to the dust product was greater than 99%. The material balance over the furnace indicates that for every ton of feed processed, 540 lb. of cast iron, 600 lb. of slag, and 150 lb. of dust would be produced. Energy consumption was roughly 1.10 kWxh/lb of feed material. Prior experience suggests that these figures measured in the bench-scale furnace would translate to 0040 to 0.50 kWxh/lb at the industrial-scale.

Jan 1, 2000

By Frank Cappuccitti, James A. Finch, Stéphanie Gélinas

"A colorimetric technique, originally developed for methyl iso butyl carbinol (MIBC) based on the Komarowsky reaction, has been extended to a wide range of common mineral flotation frothers. The procedure, which is briefly described, is shown suited to on-site determinations in a campaign at Kennecott Utah Copper Copperton Concentrator (Rio Tinto). Some observations are described, including: frother (MIBC) concentration evolution down a bank, frother distribution between pulp and froth phases, and loss of frother over time due to adsorption on certain minerals. A possible interference with a fuel oil addition was overcome. MIBC in recycle water was also measured.The ability to monitor frother easily will help interpret gas dispersion behaviour and should permit further optimization of flotation cell hydrodynamics and chemistry. The capability to directly measure should help optimize the type, amount and location of frother addition, and to assess frother recycled with reclaim process water.INTRODUCTIONOwing to the lack of analytical methods, the task of determining frother concentration in plant flotation circuits is not routinely performed. Industrial sites seldom outsource analyses that are both costly and inconvenient, due to the necessity of shipping freeze-dried samples to remote testing facilities. A more direct colorimetric method has recently been demonstrated for the laboratory characterization of common industrial frothers (Gélinas and Finch, 2004). The approach, based on the Komarowsky reaction (Penniman et al., 1936; Coles et al., 1942; Duke, 1947), was previously described by Parkhomovski et al. (1976) for methyl iso butyl carbinol (MIBC). The reaction involves the interaction of the OH group of a higher alcohol, concentrated sulphuric acid, and salicylaldehyde, to yield coloured solutions with intensities that can be analyzed by UV-visible spectrophotometry."

Jan 1, 2005

By N. A. White

Whereas the ultimate world supply of energy minerals-defined as fossil fuels and fissile materials - is controlled by geological factors, the actual supply at any particular time is controlled by economic feasibility, technological innovations and /or political decisions. This paper identifies and discusses the principal uncertainties surrounding the international availability of energy minerals from now until the end of the century. A brief comparison is also made between energy and non-energy minerals. Genuine shortage s of energy minerals are now of a very long-term nature, whereas artificial ones may occur at any time and have a serious effect on the world economy due to the dependence of most OECD countries on imports of energy mineral . This paper argues that events over the last decade, such as the demand for a New International Economic Order, the OPEC increase in crude oil prices and the growing international lobby on environmental issues especially relating to nuclear safety - will progressively lead to a major, long-lasting transformation of the energy scene world wide. This transformation will encompass demand, in terms of conservation and efficiency, the supply mix of the various energy minerals , the supply system and the structure of the different energy industries . It is already affecting the role of governments and reaching into the question of national sovereignty both of developed countries, such as the U.K., Norway and Australia, and the developing countries, thereby making energy minerals a key area of international relations.

Jan 1, 1978

By Derrick D. Dasenbrock

Three piers of a new river bridge are supported on 1.067 m diameter open-end steel pipe piles. At time of drive, and after pile re-strikes, high-strain dynamic capacity values at plan tip elevations, were as low as 23% of design requirements. Pile lengths were extended 20% to 40% deeper than planned at two piers, driving to rock, impacting both the project cost and schedule. The significant discrepancy between predicted and observed capacity was investigated through a series of coordinated dynamic tests; a full-scale test pile was installed and monitored over 221 days by both dynamic and quasi-static methods. Unusually slow strength gains were observed by dynamic monitoring on all piles installed at the site. CPT soundings were advanced at the test pile and through the pile interior to investigate the soil plug. High-strain dynamic methods were found to have significant limitations in properly assessing the long-term capacity of large-diameter open-end pipe piles during driving and short-term pile re-strikes. As the benefits of large diameter high-capacity open-end pipe piles are numerous, the geotechnical community needs to address appropriate construction monitoring and control of these foundation types to take full advantage of these systems. An improved understanding of the physical effects of pile installation and the impact on soil strength assessment while driving and long term soil strength gain should be developed and incorporated into both design and monitoring procedures to avoid either unsafe or needlessly costly designs.

Jan 1, 2006

Allis Mineral Systems ARCO Coal Company Buckley Powder Co. CALCO, Inc. Coal Magazine Colowyo Coal Company Continental Conveyor & Equipment Company Crane & Hoist Sales Cummins Southwest, Inc. Energy West Mining Company Paul J. Epley FMC Corporation The Falkirk Mining Company Fleischli Oil Co., Inc. T. J. Gundlach Machine Company Halbach & Braun Harnischfeger Corporation Hemscheidt Corporation Hyatt Regency Beaver Creek Jennmar Corporation Joy Technologies, Inc. K&P Sales Engineers, Inc. Kennametal, Inc. Kerr-McGee Coal Corporation McLanahan Corporation National Coal Association The North American Coal Corporation Northwestern Resources Company Peabody Coal Company Phillips Machine Service, Inc. Pincock, Allen & Holt, Inc. Pittsburg & Midway Coal Mining Co. Roberts & Schaefer Company Rust Tractor Company Salt River Project Santa Fe Pacific Coal Corporation Schroeder Industries Shearson-Lehman Brothers Southern Pacific Transportation Stamler Corporation Trapper Mining Inc. Wagner Equipment Company Western Energy Company Wheeler Machinery Company

Jan 1, 1992

By Robert B. Bittner

The Sutong Bridge across the lower Yangtze River in China will have, when completed, the longest span (1,088 m) and the highest towers (306 m) of any cable stayed span in the world. The foundations for this record setting span will also be record setting. They are located in water depths exceeding 30 m with maximum flows exceeding 3 m/sec. The soil at the site of the main pylons consists of layers of silty sands and silty clays extending to bed rock at 270 m below river elevation. This paper describes the innovative methods used by the team of foundation designers and constructors to support this record setting bridge at this very challenging site. This paper covers three specific topics related to the foundations of the Sutong Bridge: ? Design and construction of the 131 drilled shaft (2.8/2.5 m diameter and 114/117 m long) under each of the two main pylons, ? Design and construction of the scour protection for the two main pylons, ? Construction methods used to construct the waterline pile caps (113.8 m by 48.1 m by 13.3 m deep) under each pylon.

Jan 1, 2005

By Jaeheon Lee, Junmo Ahn, Jiajia Wu

In this project, low grade copper ore samples were obtained from two mining sites in the US, and they were chalcopyrite-rich (sample A) and conichalcite-rich (sample B) ore. Copper grades were 0.6% and 0.4% for the two samples, A and B, respectively. Leaching experiments were conducted by bottle roll tests for 24 hours, and various lixiviant systems were applied. Methanesulfonic acid (MSA) and glycine were used as alternative lixiviants to sulfuric acid. Oxidants including ferric ion and hydrogen peroxide were tested. The results showed the copper extraction of sample A increased after adding 1 g/L ferric ion in sulfuric acid and MSA solution, from 20% to 36%, but further increase was not observed with higher ferric ion concentration. The copper recovery increased significantly with H2O2 concentration, and over 80% copper recovery was obtained with 10% H2O2. For sample B, the copper dissolution kinetics were relatively fast and reached the maximum value in five hours. Around 60% copper were extracted in sulfuric acid and MSA solution. Copper recovery slightly increased after adding ferric ion and H2O2. Glycine is a weaker lixiviant for both samples, the copper extractions were 36% and 4% respectively. INTRODUCTION Chalcopyrite is the most abundant copper sulfide mineral on earth, and it is one of the most refractory copper minerals regarding chemical processing. The declining copper grade and depletion of copper oxide deposits stimulate the development of hydrometallurgical process to extract copper from chalcopyrite. The dissolution of chalcopyrite by ferric ion is normally illustrated as Equation (1) and (2) (Dutrizac & MacDonald, 1974): CuFeS2 + 4Fe3+ → Cu2+ + 5Fe2+ + 2S0 (1) CuFeS2 + 4Fe3+ + 3O2 + 2H2O → Cu2+ + 5Fe2+ + 2H2SO4 (2) However, slow kinetics are usually observed from chalcopyrite leaching at ambient temperature and pressure. Researchers attribute the slow kinetics to passivation during chalcopyrite dissolution, and different passivation products are also proposed (Klauber, 2008). In recent years, many efforts have made to develop new methods to extract copper from chalcopyrite, such as utilizing bacteria or stronger oxidant (Zhao et al., 2015; Ruiz-Sánchez & Lapidus, 2017).

Jan 1, 2019

By John D. Morton, J. H. LaVerne Palmer, Douglas J. Belshaw

An extensive programme of ground instrumentation and observation was carried out for the West Duff in Outfall Sewer tunnel project prior to and during construction, to establish the performance characteristics of the rock through which the tunnel and appurtenant openings were dug and to examine the nature of the lining-to-ground interaction. The existence of high horizontal residual ground stresses was confirmed, and values established by overcoring. Rock deformations and stress changes were monitored during tunnelling. Permanent stress and strain monitoring devices were set into the final lining and these are continuing to operate. INTRODUCTION The site is located on the north shore of Lake Ontario at Pickering, some 20 miles (32 kilometres) east of Toronto, Canada where a variable thickness of glacial or interglacial sediments overlies bituminous shale bedrock of. the Collingwood Formation which is lower Ordovician age. Approximately 50 feet (15 metres) of glacial cover exists at the shaft, though this thins abruptly at the regressing cliffed shoreline such that several small areas of exposed bedrock exist in the lakebed. The general location, overall geological section and detailed site plan and profile are illustrated in Figs.1,2 and 3 respectively. General properties of the rock as established during an extensive test drilling and site investigation programme are listed in Table 1, while stress determination by USER overcoring stress meter device are given in Table ll. These data formed the basis of analyses which were done to examine the intended outfall design, and to detail the construction procedure and the observational instrumentation programme.

Jan 1, 1979

By W. Curlook, V. G. Papangelakis, M. Baghalha

A pressure acid leaching process has been developed for the extraction of metal values, nickel, copper, cobalt and zinc, from base metal smelter slags. The basic concept contemplates cooling the smelter slags through solidification sufficiently slowly to induce a good measure of crystallization; and subsequently, after fine grinding, to pressure leach such slags at around 250°C while applying oxygen overpressure, utilizing smelter byproduct sulphuric acid. High levels of extraction of the slags' metal values are thereby achieved. It has been shown that if the same slags are quenched thereby producing an amorphous structure, the resulting metal extractions are very low. The process is applicable to smelting furnace throwaway/discard/dump slags, as well as to in-process converter slags. By extracting the bulk of the residual base metal values in the throwaway/discard/dump slags, the resulting leached residues are rendered virtually benign vis-à-vis the external environment.

Jan 1, 2004