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By L. F. Christianson

The presence of salt in crude petroleum has been known for many years, but recently the percentage of chloride salts of calcium, magnesium, and sodium produced with some crude oils has increased to such an extent that the removal of the salty compounds is imperative for some refiners and their presence causes considerable apprehension for others. The exact reason for this increase of salts is not known definitely, but in all probability a combination of factors contributes to the condition. The most important are acidizing of wells, development of new fields producing crude oils of greater salt content, and the depletion of old fields with an attending increase in the production of emulsified brine. Due to handling

Jan 1, 1938

By L. F. Christianson

The presence of salt in crude petroleum has been known for many years, but recently the percentage of chloride salts of calcium, magnesium, and sodium produced with some crude oils has increased to such an extent that the removal of the salty compounds is imperative for some refiners and their presence causes considerable apprehension for others. The exact reason for this increase of salts is not known definitely, but in all probability a combination of factors contributes to the condition. The most important are acidizing of wells, development of new fields producing crude oils of greater salt content, and the depletion of old fields with an attending increase in the production of emulsified brine. Due to handling

Jan 1, 1938

By Christopher C. Jobes

Computer-aided control of a mining machine requires a guidance system to aid remote positioning of the machine by determining its position and heading. The mechanical position and heading system (MPHS) developed by the U.S. Bureau of Mines provides such navigation information during face maneuvers. This report describes the required theory, which yielded a reliable algorithm for calculating machine position and heading, and implementation of this theory in hardware and software design, which made surface testing of the MPHS possible. Analysis of the errors and test results showed that the MPHS provides reliable results and can, therefore, provide useful guidance information for face navigation.

Jan 1, 2010

By D. A. Reynolds, C. R. Holmes

The Bureau of Mines - American Gas Association ( EM - AGA) carbonization test has been used to determine the carbonizing properties of 66 American coals and a larger number of coal blends . A summary of the results obtained for the first 30 coals , including 6 blends , has been published ,4/ and results for individual coals have been reported as the investigations were completed . A bibliography of all publications pertaining to this work has been issued recently . Many of the coals were carbonized at 800 ° and 900° C. in two sizes of retorts ( 13- and 18 - inch diameters ) ; and , because the quality of coke is affected by changing the size of the retort , this report has been prepared to show the average physical properties of coke from the two sizes . This report also purposes to extend the correlation of the physical properties of coke with the rank of coal made by Fieldner and Davis in their summary of the EM-AGA tests on the first 30 coals .

Jun 1, 1942

By E. L. Rawlins

The Bureau of Mines, with the cooperation of the Natural Gas Association of America, has conducted a study of leakage losses from natural-gas transmission lines. This study has shorn that surveys to determine the leakage from transmission lines lead to line repair work that not only aids in the conservation of gas, but can be made to show financial returns of large magnitude.2 In order to conduct the study, it was necessary to develop accurate and reliable methods of determining the actual leakage from pipe lines. METHODS OF TESTING Three methods that were developed and used to determine the leakage losses from high-pressure natural-gas transmission lines are: (1) The "pressure-drop" method, (2) The "metering-in and metering-out" method. (3) The "metering-in" method.

Jan 1, 1926

By Oliver Q. Leone

The effect of oxygen content in the anode metal on titanium electrorefining characteristics was studied. Increasing quantities of oxygen in the anode resulted in increased anode scale formation, decreased anode and cathode current efficiencies, lower titanium recovery efficiencies, and higher oxygen content of the cathode products. The titanium electrorefining process performed best when the anodes did not contain more than 0.5 percent oxygen, although anode dissolution was recorded for alloys containing up to 25 percent oxygen. Back emf affords a useful index of an alloy to electrorefining.

Jan 1, 1965

By J. M. Stuve

Low-temperature heat capacities and the enthalpy of formation were deter-mined calorimetrically by the Bureau of Mines for CuO?CuS04. The derived standard entropy (S°298.15) was 40.36±0.04 cal/deg-mole, and the enthalpy of formation (?H°f) was -219.l±0.3 kcal/g-mole. A large thermal anomaly was observed in the heat capacity of CuO?CuS04 at 20±0.1 K. Gibbs energy of formation data are tabulated up to 1,200 K. Construction details of a precision low-temperature adiabatic calorimeter capable of determining heat capacities of solids in the temperature range 5 to 320 K are given. A calibrated miniature germanium resistance thermometer was incorporated into the calorimeter to extend the range of accurate measurements below 15 K. High-resistance dc heater windings were used throughout the cryostat to reduce heat conduction of inner connecting wires.

Jan 1, 1975

By R. R. Sayers, W. J. McConnell

"The health, comfort, and efficiency of men engaged in the mining industry may be impaired, in some instances very seriously, by abnormal physical conditions of the mine air or by variations in its composition. This is true in some of sheet metal mines of the West where high temperatures with varying humidities are encountered. Physiological studies have been made in some of these mines showing the effects of various temperatures end humidities. As it is difficult to carry out studies on many controlled temperatures, it was thought best to make the experiments in a laboratory and apply the results to the industry insofar as practicableThe effects of moderately high temperatures and humidities are more difficult to measure perhaps than the extreme conditions, but may be predisposing causes of fatigue, discomfort and disease, A cooperative study of the physioloical effects of heat and humidity is being conducted by the Bureau of Mines and the U. S. Public Health Service cooperative with the American Society of Heating and Ventilating Engineers, in the Research Laboratory of the Bureau of Mines at Pittsburgh, Pa."

Mar 1, 1924

By E. P. Youngman

This paper is one of a series of digests of foreign minim legislation and court decisions that is being prepared in advance of a general report relative to the right of American citizens to explore for minerals and to own and operate mines in various foreign countries. This interpretation of the minim lams of Ceylon has been prey tired from the best available information in Washington and is released subject to amplification and correction, if necessary, by United States foreign-service officers. INTRODUCTION Ceylon has no basic mining law; the general rules governing the granting of mineral concessions and affecting legal titles of concessionaires are laid down in Ceylon Government ordinances or are found in the authorized forms for licenses and leases. The material available in the preparation of this digest is as follows:

Jan 1, 1933

By Joseph J. Wallace

1. The Pittsburgh is the most important bed in Washington County from the standpoint of present production and recoverable reserves. 2. Known measured and indicated reserves in all beds, based on a minimum thickness of 14 inches and 1,800 short tons per acre-foot of coal in place, are estimated at 4,181 million short tons as of January 1, 1954. Of this total, 4,132 million short tons is in beds 28 inches and more thick. Areas in some beds were omitted from the estimate because available data relative to the bed characteristics are too meager for making an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves.

Jan 1, 1955

By O. C. Ralston

The Bureau of Mines has under development on a technical scale an electrolytic process for treating oxidized ores of zinc , using caustic soda as an electrolyte . Whereas the Bureau process can alternately make either solid zinc or zinc dust , the following paper , from the Ludwigshafen research laboratory of the well -known I. G. Farbenindustrie , A. G. , of Germany, deals only with production of zinc dust from sodium zincate solutions and may well serve as introduction to the subject for American metallurgists . The Bureau of Mines pioneered in the idea ; a study on laboratory scale by H. J. Morgan and 0. C. Ralston was made early in the First World War, and published in Transactions of the American Electrochemical Society . The Eckardt paper , translation of which follows , goes more thoroughly into the preparation of electrolytic zinc dust , and later publications of the Bureau of Mines will deal with broader details and application of the idea to treatment of lowgrade ores and metallurgical intermediates , which is the point where Eckardt left off . 4 The Eckardt report became available through operations of Field Information Agency , Technical ( FIAT ) of the Office of Military Government for Germany (US ) , which made bibliofilm copies of the files of internal technical reports of many of the German industrial establishments , Eckardt's report is dated April 1939 and was taken on FIAT Microfilm Reel MM 106 , frames 82-101 , which is on file as Publication Board Document 41411 in Office of Technical Services of the U. S. Department of Commerce , Washington , D, C , Eckardt points out that the normal source of zinc dust is the blue powder of the zinc retorts , which decreases in volume every year owing to technologic improvements in zinc smelting. I. G. saw the importance of making a

May 1, 1948

By R. E. Cumings

The Bureau of Mines made electrorefining tests in inert-atmosphere, molten salt cells to develop methods for the preparation of high-purity molybdenum. Seven of the electrolytes investigated were suitable for the preparation of refined metal. The electrolytes were composed of molybdenum chloride in alkali chlorides or mixtures of alkali and alkaline-earth chlorides. An electrolyte composed of potassium chloride and potassium hexachloro-molybdate was selected for a larger scale, more detailed study on the basis of its ease of preparation, its ability to retain the molybdenum salt, and the type of deposits obtained. High-purity molybdenum in the 99.99-percent-purity range was successfully prepared as dense plate up to 80 mils thick and as dendritic crystals. The temperature of electrolysis and the current density were major factors in determining whether plate or dendritic crystals of molybdenum were obtained.

Jan 1, 1966

By E. P. Youngman

This paper is one of a series of digests of foreign mining legislation and court decisions that is being prepared in advance of a general report relative to the right of American citizens to explore for minerals and to own and operate mines" in various foreign countries. In the preparation of this interpretation of the laws of Norway, use has been made of William R. Orrmins' translations of various acts of the Norwegian Government, which were forwarded from the American consulate at Oslo^ and transmitted to the Bureau of Mines through the courtesy of the State Department. This digest is released subject to amplification and correction, if necessary, by the proper American foreignservice officers.

Nov 1, 1932

By D. Harrington, C. W. Owings

The mining industry is gradually realizing that safety education and safety inspection are economic factors that may not be overlooked as a means of reducing operating costs . Many mine operators , however , have failed to realize the benefits of safety , and the efforts of the more progressive mining companies are offset by the carelessness of neighboring companies when the accident records of a community or a State or the nation as a whole are considered . This tendency is indicated by the data collected by the safety division of the United States Bureau of Mines . During the fiscal year ended June 30, 1930 , relatively definite information: was secureä concerning 34 mine explosions , 24 mine fires , and 29 miscellaneous accidents ; these accidents are by no means all of the explosions , fires , and miscellaneous accidents which occurred in the mines of the United States during the period; but the data on the fires and explosions constitute a record of all of those types of accidents that were called specifically to the attention of the safety division , and the miscellaneous accidents include those on which definite , detailed data were obtained by the safety division .

Jan 1, 1931

By A. W. Ambrose

"Introduction.Oil-field operations have often been carried on under great stress and haste, in which the prime purpose has been to put the wells down rapidly as possible, without regard to a few of the various factors affecting cost. In such fields as Burkurnett, Texas, where the well locations are town lots and other small tracts, the operator was concerned primarily with in drilling. In such cases a few thousand dollars more or less in the cost of a well not considered. We are reaching a time, however, when our reserves a,more definitely outlined and properties are being along more economic lines. Operators are becoming more concerned with the actual cost of this work, and are gradually learning that fuel consumption can be reduced in drilling and producing without delaying the speed of drilling, and in the case of production, it will greatly reduce the unit cost per barrel of production.Types of Field Boilers.In the oil fields there are in general two types of boilers; those which are used for drilling wells and are of a more or less portable character, and those established later in a more permanent form and serve for the purpose,of generating steam for producing the oil. As a rule, the latter type of boilers are larger than those of the drilling type. Usually, little care is given to the installation of drilling boilers; particularly in attempting to set them up in such a way as to avoid waste in of fuel. Because of the temporary nature of these installations there may be some justification for not giving them more,attention in this resend, but it is believed that a few precautions could be taken that would amply repay the cost and trouble taken. In connection with the boiler plants that are afterwards established, when a few producing wells have been,brought in with a life of two to ten years and probably longer, much care to the boiler-plant construction and to the installation of recording instruments which will assist in operating the plant at minimum cost."

Nov 1, 1920

By G. L. Hundley

The Bureau of Mines has devised a procedure to recover chromium chemicals from concentrates derived from low-grade domestic chromites. These domestic chromites contain silicon and aluminum impurities at levels that are too high to permit processing by present industrial processes. The Bureau procedure consists of reacting chromite with molten NaOH under oxidizing conditions to form sodium chromate (Na2Cr04)' The reaction product is leached with methanol to recover the majority of the unreacted NaOH, then with water to extract the Na2Cr04 and the remainder of the NaOH. The Na2Cr04 product is recovered by evaporative crystallization from the aqueous solution. This report presents laboratory results of studies to determine the optimum leaching conditions for the reaction products of several domestic chromite concentrates. Results of solution purification and crystallization studies are also presented. The concentrates are from a variety of sources including the Stillwater Complex in Montana, Red Bluff Bay and the Kenai Peninsula in Alaska, and a Ni-Co laterite from southern Oregon. Sodium chromate crystals were produced that contained less than 0.01 pct NaOH.

Jan 1, 1988

By L. H. Adami, E. G. King

The heats of formation of four sulfides --MnS ( alabandite ) , FeS ( hexagonal pyrrhotite ) , ZnS ( wurtzite ) , and CdS ( greenockite ) -- were determined by hydrochloric acid solution calorimetry . The heats of formation from the metals and rhombic sulfur at 298.15 ° K are , respectively , -51.01 ± 0.19 , -23.81 ± 0.24 , -45.86 ± 0.20 , and -35.70 ± 0.30 kcal /mole . The corresponding free energies of formation were calculated from the heats of formation and the pertinent entropy values .

Jan 1, 1964

By Irving Hartmann

Several recent ignitions of firedamp - a mixture of methane and air - in American coal mines have been attributed to frictional heating when hard rocks were struck while cutting and drilling coal seams. Although none of these ignitions caused severe explosions, they call attention to a problem that can become increasingly significant as mechanized mining is developed further. The power in and rapid release of energy from high-speed machinery has increased the rates of advance into virgin coal creating many problems. Unforeseen faults and hard mineral inclusions may be encountered; coal brought down in this way is finer in size; more gas is released from the seam; it is frequently more difficult to provide adequate ventilation at the' face; and new roof-support problems must be solved. In particular, continuous mining machines (also known as continuous miners) greatly increase the frequency of contact between cutter bits and minerals. In view of these conditions, it may be expected that more gas ignitions will occur as a result of frictional heating unless the situation is understood and remedial measures are introduced. The problem of frictional heating is not new in coal mining. In Europe, particularly in England, it has been a concern for more than a century. During the last 15 to 20 years frictional ignitions have been a major cuase of explosions in British mines. Explanations for the greater number of such ignitions in England may be the special character of the coal measure strata, the mining methods, the rate of gas emission and possibly its composition, and less effective ventilation near the face. To reduce the ignition hazard, considerable laboratory and field research has been conducted, particularly by the Safety in Mines Research Establishment, Ministry of Fuel and Power of Great Britain. Much of the information presented in this report has been drawn from these studies.

Jan 1, 1955

By Foster Fraas

The objective of this research was separation of one highly conductive mineral from a second conductive mineral , a procedure which is impractical in commercial electrostatic separators using metal rolls . Such separators permit separation of nonconductive from conductive minerals . A new technique involved use of carrier electrode rolls specially prepared by anodizing and / or oxidizing at high temperatures to form suitable oxide surfaces . Specific oxides included aluminum , copper , and nickel . The significant result provided by the new surfaces was the extension of the separation range to higher conductivities , an extension in relative mineral conductivity from 10-14 mhos . The results are in accordance with the blocking- layer theory .

Jan 1, 1964

By R. R. Schehl

The Bureau of Mines has developed a quantitative Analysis for pyrite in coal by X-ray diffraction that can be accomplished in little more than 1 hour. To minimize the sample analysis time, data processing has been completely computerized with pertinent output information displayed on a VR12 cathode-ray tube display. Use of this computerized system is not only advantageous during the experimental stages of the pyrite analysis project but would also be essential if the X-ray diffraction procedure is accepted as a standard method of analysis.

Jan 1, 1973